JP2568038B2 - Method of manufacturing material for polishing surface plate - Google Patents

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a polishing platen material used for lapping Si wafers and the like.

[0002]

2. Description of the Related Art Generally, in lapping a Si wafer or the like, slurry-like abrasive grains are supplied between a pair of upper and lower polishing platens and a workpiece, and the rotary motion of the platen is utilized while applying a processing pressure. Then, the cutting edge of the abrasive removes a necessary amount of stock from the work piece, and the flatness of the surface plate is transferred to the work piece. Such polishing is
Not only wafers but also many are used for the purpose of flattening the surface of workpieces such as glass, jewels, metals and ceramics. Especially, recently, the demand for Si wafers has been increasing year by year due to the development of electronics. There is a tendency.

Usually, in polishing a Si wafer, Al ₂ O ₃ and ZrO ₂ are used as abrasive grains, and their grain size is # 1000 mesh and average grain size is 16 microns. As the polishing platen in this case, cast iron (JIS-FCD45) containing spheroidal graphite has been often used conventionally. The base (base material) of this JIS-FCD45 is
It has a ferrite structure and hardness of Hv (Vitzkas hardness load of 5
(Measured at 00g) is about 140, and the graphite particle size is 100 to 1
It is a material having physical properties of 50 μm. When a Si wafer is polished using a polishing platen made of this material, in the polishing state, Al ₂ O ₃ and ZrO _{2 as} abrasive grains are selectively present and distributed at the site where graphite grains are present. S in the state
The i wafer is polished. In this case, the abrasive grains are S
While polishing i-wafer, polishing surface plate material (JIS-F
The CD45) is also polished (weared) at the same time.

That is, in a base plate having a relatively soft base such as a ferrite structure, wear due to hard abrasive grains is likely to proceed, and the flatness of the polishing platen is deteriorated. As described above, during polishing, the flatness of the polishing platen is directly transferred to the surface of the work material, and as a result, the flatness of the work material is deteriorated and high-precision polishing cannot be performed. There's a problem.

In addition, conventionally used JIS-FCD
The graphite particle size of the 45 platen is as large as 100 to 150 μm, and since the abrasive grains are selectively present in this graphite portion, they are relatively non-uniformly distributed. There are problems that the flow of the abrasive grains becomes non-uniform, the processing speed is reduced, and the surface plate is non-uniformly worn, and as a result, flaws are likely to occur on the surface of the Si wafer.

[0006]

SUMMARY OF THE INVENTION The present invention has been made in view of the above points, and maintains the flatness and smoothness of a polishing platen by reducing the amount of wear of abrasive grains during polishing as much as possible. In addition, it is an object of the present invention to provide a method for producing a material for a polishing platen in which the distribution of abrasive grains is dispersed as finely as possible to uniformly promote the flow of abrasive grains.

[0007]

In order to achieve the above-mentioned object, the first method for producing a material for a polishing platen according to the present invention comprises a spheroidal graphite cast iron, an austenitizing heat treatment, and
By applying a quenching process at a speed faster than air cooling ,
The spherical graphite having a graphite particle size of 100 μm or less and a graphite particle number of 70 / mm ² or more is dispersed in a base material having a hardness of 200 or more. Also, the present invention
The second method of manufacturing the material for the polishing platen is
By applying an iron temper treatment to iron, the Vickers
Graphite particle size of 100 μm or less in a base material having a hardness of 200 or more,
Spherical graphite with 70 or more graphite particles / mm ² dispersed
It is characterized by

The above-mentioned spheroidal graphite cast iron preferably contains carbon, silicon, manganese, and magnesium as essential components, and the balance substantially consists of iron, and more specifically, by weight ratio, C: 2.7-3.5%, S
i: 2.0 to 2.7%, Mn: 0.5 to 1.0%, P: 0.03% or less,
S: 0.03% or less, Mg: 0.03 to 0.07%, Ni: 0.2 to 0.
6%, Cu: 0.3 to 0.7%, and the balance preferably Fe.

One of the features of the method for producing a material according to the present invention is that the amount of wear due to the abrasive grains can be reduced as much as possible as the polishing platen. For this purpose, the hardness of the base of the platen is at least It is preferably Hv 200 or more, and in this case, the base material structure is preferably a pearlite, bainite, or martensite or tempered martensite structure by heat treatment in order to improve wear resistance.

Polishing is carried out by supplying abrasive grains to the surface of the workpiece through the polishing platen. The flatness and the abrasive grains of the polishing platen are uniformly and finely dispersed, and the flow is smooth. Is essential. The former, that is, the flatness, is greatly affected by the wear resistance of the polishing plate material, and the latter, that is, the uniformity, and the dispersibility are greatly influenced by the graphite shape, particle size, and particle distribution.
In order to uniformly disperse the abrasive grains and promote a uniform flow of the abrasive grains, the material is spheroidal graphite cast iron rather than flake graphite cast iron, and the graphite particle size is a dimension adapted to the size of the abrasive grain. It is essential. It is also preferable that the graphite particles are as small as possible and evenly distributed. In particular, since the average grain size of 16 μm is used for the Si wafer, the grain size of graphite is larger than that of the grain, and the grain size is 100 μm or less, preferably 30 to 5 in order to make the graphite particles more evenly distributed.
The range is 0 μm. Also, the distribution of graphite particles (cross-sectional density)
Is preferably 70 / mm ² or more and the spheroidization rate is 80% or more.
However, the spheroidization rate is not particularly limited to this range.

It is necessary to have the above-mentioned properties over the depth direction of at least 15 mm from the surface of the polishing platen.

The preferred embodiments of the present invention will be described below.

The material according to the present invention has a weight ratio of C: 2.7-
3.5%, Si: 2.0 to 2.7%, Mn: 0.5 to 1.0%, P, S <
0.03%, Mg: 0.03 to 0.07%, more preferably Ni:
The composition is preferably 0.2 to 0.6%, Cu: 0.3 to 0.7%, and the balance being Fe.

As already mentioned, the polishing platen material is required to have good wear resistance against abrasive grains such as Al ₂ O ₃ and ZrO ₂ . For this reason, J
It is important for IS-FCD45 to be a spheroidal graphite cast iron that has a metal structure with good wear resistance by heat treatment, has a predetermined hardness (Hv> 200), and has excellent mechanical properties.

The purpose of adding each composition component and the reason for limiting the composition range will be described below.

When C exceeds 3.5%, the mechanical properties, particularly tensile strength, do not exceed the target of 70 Kgf / mm ₂ , while when C is less than 2.7%, the distribution of graphite particles is 70 particles / mm ₂ or more. It is not preferable because it does not become.

Si is added to improve the spheroidization rate and castability, but if Si is 2.7% or more, ferrite is present due to heat treatment and the hardness tends to decrease, so that Hv200
It becomes difficult to do the above. In addition, the temperature at which austenite is formed rises, the heat treatment temperature rises, and as a result, oxides are easily generated, and it is necessary to remove this as a platen material, which is not desirable.

If the Si content is 2.0% or less, the castability becomes particularly poor,
Undesirable shrinkage cavities are likely to occur as a surface plate.

When the Mn is 0.5% or less, the surface plate (wall thickness 40 to 60 m
As in the case of m), in the thick casting, the ferrite tends to be generated at the time of air cooling in the central part, and the wear resistance is deteriorated. On the other hand, if it exceeds 1%, the hardened phase tends to segregate at the grain boundaries and becomes brittle, which is not desirable.

Since P and S reduce the formation of inclusions, it is desirable to reduce them as much as possible. Since the inclusions are hard and irregularly present, it is easy to scratch the Si wafer. Therefore, in each case, 0.03% or less is preferable. When the content is 0.03% or more, inclusions (Fe ₃ P, MnS,
(MgS, etc.) is generated, which is not desirable.

Mg is an alloying element necessary for spheroidizing graphite, and if it is 0.03% or less, the spheroidization rate is unlikely to be in a preferable range (for example, 80% or more), while if it exceeds 0.07%, atypical carbides are formed. Is easily generated, which is not preferable.

Ni and Cu are used to make the structure uniform, for example, to make the structure uniform in the depth direction from the surface to eliminate hardness variations, and particularly to maintain Hv30 to 50 in a region of 20 mm from the surface. It is an effective element. Further, Ni has an effect of preventing oxide formation during heat treatment.

When Ni is 0.2% / or less, these effects are small, and when 0.6% or more is added, it is not so effective for these effects and it is not economical. On the other hand, Cu is 0.3% like Ni.
Below, there is little effect on the uniformity, and on the contrary, 0.7% Cu
When added above, Cu phase is precipitated in the matrix, the structure becomes non-uniform, and the wear resistance tends to deteriorate.

Ni and Cu are not necessarily essential elements in the present invention, but they are desirable alloy components for the uniformity of the structure and the prevention of scale.

In the case of the above composition, in the case of heat treatment, the temperature of heat treatment needs to be a temperature at which the structure can be austenite, and is about 850 ° C. or higher, preferably about 9
It is around 30 ° C.

The polishing platen material obtained by the manufacturing method of the present invention can be effectively applied to a polishing platen material other than a Si wafer, which is polished by using abrasive grains such as jewelry, metal materials, glass and ceramics. Needless to say.

[0027]

【Example】

(Example 1) A spheroidal graphite cast iron having the components shown in Table 1 was cast to manufacture a cast surface plate for abrasives. Before machining such as slitting, it was heated to 930 ° C. and air-cooled. in this case,
Microscopic examination was conducted at a depth of 20 mm from the surface, whereupon the spherical graphitization ratio was 90%, the graphite particle size was 30 to 50 μm, and the distribution was 150 particles / mm ² . The base had a fine pearlite structure and the hardness was Hv250 by the air cooling treatment. This material was machined into a surface plate. This was put to practical use for polishing Si wafers, and the results are shown in Table 2 below. Conventional FCD45
Defects in defects are reduced to 75% (100% for FCD45) compared with polishing of No. 1, and platen life (hereinafter also referred to as life)
Was improved by 150% (FCD45 is set to 100%).
Further, the amount of wear was reduced by 40% (100% for FCD45), which showed desirable characteristics as a platen material. (Example 2) Spheroidal graphite cast iron having the components shown in Table 1 was cast,
I made a surface plate. The spheroidization rate of graphite in the depth direction of 20 mm from the surface is 85%, the grain size of graphite is 30 to 50 μm, and the grain size of graphite is 7
The distribution was 0 / mm ² .

The cast product was heated to 930.degree. C., then cooled in a furnace to form a ferrite structure in the matrix and machined into slits. After machining, an austenite structure was formed at 930 ° C, and an austempering treatment was performed at 300 ° C to form a bainite structure. The hardness was Hv350. Oh
A change in the flatness of the surface caused by the tempering treatment was subjected to polishing to correct the flatness, and used as a polishing platen. Si wafers were polished using this polishing platen, and as shown in Table 2, flaws on the surface of the Si wafer were reduced to 65% (FCD45 is 100%), and life was improved by 170% (FCD45
Is 100%), and the amount of wear is reduced by 50% (FCD
45 was set to 100%) to show desirable characteristics as a platen material. (Example 3) A slab was cast using the spheroidal graphite cast iron shown in Table 1. The cast product had a spheroidization rate of 90% in a depth direction of 20 mm, a graphite particle size of 30 to 50 μm, and a distribution of 70 graphite particles / mm ² .

This cast product was heated to 930 ° C. and cooled in a furnace to form a ferrite structure in the matrix and machined into slits. After processing, it was made into an austenite structure at 930 ° C. and processed into an austemper at 350 ° C. to form a bainite structure. The hardness was Hv300. Austemper
The change in the flatness of the surface caused by the treatment was corrected on the surface plate by polishing. As shown in Table 2, defects on the surface of the Si wafer were reduced to 70% and the life was improved by 160%. The amount of wear was reduced by 50%, which showed desirable characteristics as a platen material. (Example 4) Spherical cast iron having the composition shown in Table 1 was cast to produce a surface plate. The cast product has a spheroidization rate of 80% from the surface to at least 20 mm in the depth direction, a graphite particle size of 30 to 50 μm, and 100 graphite particles / mm ² distribution. 9 for casting
Heat to 30 ° C and cool in a furnace to make the matrix a ferrite structure,
Machined such as slits. After machining 930 again
Heated to 0 ° C and quenched in oil. The hardness was Hv550. After quenching, polishing was performed to correct the flatness of the surface, and the surface plate was finished. When the Si wafer was polished using this,
As shown in Table 2, compared to the conventional FCD45 surface plate, Si
Defects on the wafer surface are reduced to 45%, life is 220
%, And the amount of wear decreased to 20%, showing desirable characteristics as a platen material. (Example 5) A slab cast product was manufactured using the spheroidal graphite cast iron having the composition components shown in Table 1. The cast product has a spheroidization rate of 80% and a graphite particle size of 50 to at least 20 mm in the depth direction from the surface.
1000 μm, 100 graphite particles / mm ^{2 are} distributed. The cast product was heated to 930 ° C. and cooled in a furnace to form a ferrite structure in the matrix, and machined as a surface plate such as a slit. After processing, it was heated again to 930 ° C. and quenched in oil. The hardness was Hv500. After quenching, polishing was carried out to correct the flatness of the surface and finished as a polishing platen.

Using this, the Si wafer was polished.
As shown in Table 2, defects on the surface of the Si wafer were reduced to 50%, the life was improved to 200%, and the wear amount was reduced to 25%, which showed desirable characteristics as a surface plate material. Example 6 A slab cast product was manufactured using the spheroidal graphite cast iron having the compositional components shown in Table 1. The cast product has a spheroidization rate of 73% from the surface to at least 20 mm in the depth direction and a graphite particle size of 30-
50 μm, graphite particles are distributed in 100 particles / mm ² . The casting is heated to 930 ° C and then quenched and further 4
The base was tempered at 50 ° C. to have a tempered martensite composition and machined as a surface plate such as a slit. The hardness was Hv386. After that, polishing was performed to correct the flatness of the surface, and the polishing plate was finished.

Using this, a Si wafer was polished.
As shown in Table 2, defects on the surface of the Si wafer were reduced to 50%, the life was improved to 200%, and the wear amount was reduced to 25%, which showed desirable characteristics as a surface plate material. (Comparative Example) A slab cast product was produced using spheroidal graphite cast iron having the composition shown in Table 1. The cast product has a spheroidization rate of 75% and a graphite particle size of 100 at least 20 mm from the surface in the depth direction.
The number of graphite particles was 60 particles / mm ² at ˜150 μm. The cast product was heated to 930 ° C. and cooled in the furnace to make the matrix a ferrite structure. The hardness was Hv140. After heat treatment, it was machined as a surface plate such as slits. Although the Si wafer was polished using this surface plate, as shown in Table 2, it was inferior to the surface plate of the embodiment as a surface plate material such as flaw defects on the surface of the Si wafer, life of the surface plate, and wear amount. .

[0032]

[Table 1]

[0033]

[Table 2]

[0034]

As is clear from the results of the above Examples and Comparative Examples, the polishing platen material obtained by the manufacturing method of the present invention is different in flatness of the platen itself from the conventional materials. ,
Both show desirable characteristics in terms of life and wear amount,
Moreover, it has an excellent effect that the surface of the member to be polished is not scratched.

 ─────────────────────────────────────────────────── ─── Continuation of front page (72) Takanobu Nishimura Inventor Takanobu 4 Keio Works, Toshiba Corp. 2-4 Suehiro-cho, Tsurumi-ku, Yokohama-shi, Kanagawa (72) Inventor Shoji Kinoshita 378 Oguni-machi, Oguni-machi, Nishiokitama-gun, Yamagata 378 Toshiba Ceramics Co., Ltd. Oguni Factory (72) Inventor Norio Masuda 378 Oguni Town, Oguni Town, Nishiokitama District, Yamagata Prefecture Toshiba Ceramics Co., Ltd. Oguni Factory (56) Reference JP-A-56-114570 (JP, A) 19/11 (1967) p. 71-76 5th Foundry Society Symposium Text "Abrasion Phenomena and Wear Resistance of Cast Iron" Japan Foundry Association (Sho 53-10-12) 18-25

Claims (10)

(57) [Claims] 1. A method for producing a polishing platen material made of spheroidal graphite cast iron, wherein the spheroidal graphite cast iron is subjected to an austenitizing heat treatment and then to a quenching treatment at a rate of air cooling or higher to obtain a Vickers hardness. A method for producing a material for a polishing platen made of spheroidal graphite cast iron, characterized in that a spheroidal graphite having a graphite particle size of 100 μm or less and a graphite particle number of 70 / mm ² or more is dispersed in a base material of several 200 or more. . 2. The method for producing a polishing platen material according to claim 1, wherein the spheroidal graphite cast iron has a spheroidization rate of 80% or more. 3. The polishing plate material according to claim 1, wherein the spheroidal graphite cast iron contains carbon, silicon, manganese, and magnesium as essential components, and the balance is substantially iron. Manufacturing method. 4. The spheroidal graphite cast iron further comprises nickel,
The method for producing a material for a polishing platen according to claim 3, further comprising: and copper. 5. The spheroidal graphite cast iron in a weight ratio of C: 2.
7-3.5%, Si: 2-2.7%, Mn: 0.5-1
%, P: 0.03% or less, S: 0.03% or less, Mg:
0.03 to 0.07%, Ni: 0.2 to 0.6%, C
The method for producing a material for a polishing platen according to claim 1, wherein u: 0.3 to 0.7% , the balance being Fe and incidental impurities. 6. A method for producing a material for a polishing platen comprising spheroidal graphite cast iron, wherein the spheroidal graphite cast iron is subjected to an au-temper treatment to obtain graphite particles in a base material having a Vickers hardness of 200 or more. Diameter 100 μm or less, number of graphite particles 70 / mm ²
A method for producing a material for a polishing platen comprising spheroidal graphite cast iron, characterized in that the spheroidal graphite is dispersed. 7. The method for producing a material for a polishing platen according to claim 6, wherein the spheroidization ratio of the spheroidal graphite cast iron is 80% or more. 8. The polishing plate material according to claim 6, wherein the spheroidal graphite cast iron contains carbon, silicon, manganese, and magnesium as essential components, and the balance is substantially iron. Manufacturing method. 9. The spheroidal graphite cast iron further comprises nickel,
The method for producing a material for a polishing platen according to claim 8, further comprising: and copper. 10. The spheroidal graphite cast iron in a weight ratio of C:
2.7-3.5%, Si: 2-2.7%, Mn: 0.5
~ 1%, P: 0.03% or less, S: 0.03% or less, M
g: 0.03 to 0.07%, Ni: 0.2 to 0.6%,
The method for producing a material for a polishing platen according to claim 6, wherein Cu: 0.3 to 0.7% , the balance being Fe and incidental impurities.