JP2501865C - - Google Patents
Info
- Publication number
- JP2501865C JP2501865C JP2501865C JP 2501865 C JP2501865 C JP 2501865C JP 2501865 C JP2501865 C JP 2501865C
- Authority
- JP
- Japan
- Prior art keywords
- compound
- aluminoxane
- group
- zirconium
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 claims description 91
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 29
- 239000002904 solvent Substances 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 16
- 150000002430 hydrocarbons Chemical class 0.000 claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims description 12
- 238000004321 preservation Methods 0.000 claims 1
- 239000000243 solution Substances 0.000 description 52
- -1 polyethylene Polymers 0.000 description 37
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- 239000003054 catalyst Substances 0.000 description 23
- 239000005977 Ethylene Substances 0.000 description 18
- 150000001336 alkenes Chemical class 0.000 description 18
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 18
- 239000000203 mixture Substances 0.000 description 18
- 239000004711 α-olefin Substances 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 11
- 125000004429 atoms Chemical group 0.000 description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 9
- MCULRUJILOGHCJ-UHFFFAOYSA-N Triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 8
- 239000002685 polymerization catalyst Substances 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 229910052719 titanium Inorganic materials 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 230000000737 periodic Effects 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 150000003624 transition metals Chemical class 0.000 description 7
- 229910052726 zirconium Inorganic materials 0.000 description 7
- 150000003755 zirconium compounds Chemical class 0.000 description 7
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 6
- DIOQZVSQGTUSAI-UHFFFAOYSA-N Decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 229910052723 transition metal Inorganic materials 0.000 description 6
- 239000004698 Polyethylene (PE) Substances 0.000 description 5
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 150000003623 transition metal compounds Chemical class 0.000 description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 230000027455 binding Effects 0.000 description 4
- 125000004432 carbon atoms Chemical group C* 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- 230000037048 polymerization activity Effects 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 125000001485 cycloalkadienyl group Chemical group 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000000379 polymerizing Effects 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- RZJRJXONCZWCBN-UHFFFAOYSA-N Octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- LOKCKYUBKHNUCV-UHFFFAOYSA-L dichlorozirconium;methylcyclopentane Chemical compound Cl[Zr]Cl.C[C]1[CH][CH][CH][CH]1.C[C]1[CH][CH][CH][CH]1 LOKCKYUBKHNUCV-UHFFFAOYSA-L 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- KLGZELKXQMTEMM-UHFFFAOYSA-N hydride Chemical compound [H-] KLGZELKXQMTEMM-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 230000002194 synthesizing Effects 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-Dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 1
- 229940106006 1-EICOSENE Drugs 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-Hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-Octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 1
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 1
- FEHOJGJULHOCKY-UHFFFAOYSA-N 2-methylpropylaluminum(2+);propan-2-olate Chemical compound CC(C)[O-].CC(C)[O-].CC(C)C[Al+2] FEHOJGJULHOCKY-UHFFFAOYSA-N 0.000 description 1
- MIPONTMOFWTMJD-UHFFFAOYSA-N 3-methylbuta-1,3-dienylaluminum Chemical compound CC(=C)C=C[Al] MIPONTMOFWTMJD-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-Methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H Aluminium sulfate Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- KYZYACQSIRDNPY-UHFFFAOYSA-M C1=CC=CC1[Zr](Cl)(C)C1C=CC=C1 Chemical compound C1=CC=CC1[Zr](Cl)(C)C1C=CC=C1 KYZYACQSIRDNPY-UHFFFAOYSA-M 0.000 description 1
- ROIFAGUVJHMTFQ-UHFFFAOYSA-N C=C.C1=CC2=CC=CC=C2C1[Zr](C)(C)C1C2=CC=CC=C2C=C1 Chemical compound C=C.C1=CC2=CC=CC=C2C1[Zr](C)(C)C1C2=CC=CC=C2C=C1 ROIFAGUVJHMTFQ-UHFFFAOYSA-N 0.000 description 1
- NTOYAXVZHAFFQZ-UHFFFAOYSA-N C=C.C1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1)(C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C=C.C1=CC2=CC=CC=C2C1[Zr](C1C2=CC=CC=C2C=C1)(C=1C=CC=CC=1)C1=CC=CC=C1 NTOYAXVZHAFFQZ-UHFFFAOYSA-N 0.000 description 1
- CESLSWBEWKCNQE-UHFFFAOYSA-N C=C.C1=CC2=CC=CC=C2C1[Zr](CC)(CC)C1C2=CC=CC=C2C=C1 Chemical compound C=C.C1=CC2=CC=CC=C2C1[Zr](CC)(CC)C1C2=CC=CC=C2C=C1 CESLSWBEWKCNQE-UHFFFAOYSA-N 0.000 description 1
- UJUWHDJYQLMLJO-UHFFFAOYSA-M C=C.C[Zr](Cl)(C1C=Cc2ccccc12)C1C=Cc2ccccc12 Chemical compound C=C.C[Zr](Cl)(C1C=Cc2ccccc12)C1C=Cc2ccccc12 UJUWHDJYQLMLJO-UHFFFAOYSA-M 0.000 description 1
- KUJMHICFLZGXLB-UHFFFAOYSA-M CC[Zr](Cl)(C1C=CC=C1)C1C=CC=C1 Chemical compound CC[Zr](Cl)(C1C=CC=C1)C1C=CC=C1 KUJMHICFLZGXLB-UHFFFAOYSA-M 0.000 description 1
- VYLVYHXQOHJDJL-UHFFFAOYSA-K Cerium(III) chloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
- UZYSHEGONRRYCO-UHFFFAOYSA-M Cl[Zr](C1C=CC=C1)(C1C=CC=C1)C1CCCCC1 Chemical compound Cl[Zr](C1C=CC=C1)(C1C=CC=C1)C1CCCCC1 UZYSHEGONRRYCO-UHFFFAOYSA-M 0.000 description 1
- AJJLZCBNLYJTBS-UHFFFAOYSA-M Cl[Zr](C1C=CC=C1)(C1C=CC=C1)c1ccccc1 Chemical compound Cl[Zr](C1C=CC=C1)(C1C=CC=C1)c1ccccc1 AJJLZCBNLYJTBS-UHFFFAOYSA-M 0.000 description 1
- QDKBEHBKWLDTTE-UHFFFAOYSA-M Cl[Zr](Cc1ccccc1)(C1C=CC=C1)C1C=CC=C1 Chemical compound Cl[Zr](Cc1ccccc1)(C1C=CC=C1)C1C=CC=C1 QDKBEHBKWLDTTE-UHFFFAOYSA-M 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N Decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- KSCFJBIXMNOVSH-UHFFFAOYSA-N Dyphylline Chemical group O=C1N(C)C(=O)N(C)C2=C1N(CC(O)CO)C=N2 KSCFJBIXMNOVSH-UHFFFAOYSA-N 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N Hafnium Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- DCAYPVUWAIABOU-UHFFFAOYSA-N Hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 1
- NNPPMTNAJDCUHE-UHFFFAOYSA-N Isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 1
- OYPFPCPYIAPNGR-UHFFFAOYSA-N N-methyloxan-2-amine Chemical compound CNC1CCCCO1 OYPFPCPYIAPNGR-UHFFFAOYSA-N 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L Nickel(II) sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- CCCMONHAUSKTEQ-UHFFFAOYSA-N Octadecene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N Octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N Trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- DPDRERHSWAYQIZ-UHFFFAOYSA-M [Br-].C[Zr+]1(CC1)(C1C=Cc2ccccc12)C1C=Cc2ccccc12 Chemical compound [Br-].C[Zr+]1(CC1)(C1C=Cc2ccccc12)C1C=Cc2ccccc12 DPDRERHSWAYQIZ-UHFFFAOYSA-M 0.000 description 1
- PUHQUSXWPXLFCC-UHFFFAOYSA-L [Br-].[Br-].C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 Chemical compound [Br-].[Br-].C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 PUHQUSXWPXLFCC-UHFFFAOYSA-L 0.000 description 1
- IECPFDGLEFJVAD-UHFFFAOYSA-M [Cl-].CC[Zr+]1(CC1)(C1C=Cc2ccccc12)C1C=Cc2ccccc12 Chemical compound [Cl-].CC[Zr+]1(CC1)(C1C=Cc2ccccc12)C1C=Cc2ccccc12 IECPFDGLEFJVAD-UHFFFAOYSA-M 0.000 description 1
- YUJDNAVJDLLINF-UHFFFAOYSA-L [Cl-].[Cl-].CC1=C(C)c2ccccc2C1[Zr++]1(CC1)C1C(C)=C(C)c2ccccc12 Chemical compound [Cl-].[Cl-].CC1=C(C)c2ccccc2C1[Zr++]1(CC1)C1C(C)=C(C)c2ccccc12 YUJDNAVJDLLINF-UHFFFAOYSA-L 0.000 description 1
- UQMANSDECLBVBN-UHFFFAOYSA-L [Cl-].[Cl-].COc1ccc2C(C=Cc2c1)[Zr++]1(CC1)C1C=Cc2cc(OC)ccc12 Chemical compound [Cl-].[Cl-].COc1ccc2C(C=Cc2c1)[Zr++]1(CC1)C1C=Cc2cc(OC)ccc12 UQMANSDECLBVBN-UHFFFAOYSA-L 0.000 description 1
- YBDQDJQQEJJFPS-UHFFFAOYSA-L [Cl-].[Cl-].Cc1ccc(C)c2[C@H](C=Cc12)[Zr++]1(CC1)[C@@H]1C=Cc2c1c(C)ccc2C Chemical compound [Cl-].[Cl-].Cc1ccc(C)c2[C@H](C=Cc12)[Zr++]1(CC1)[C@@H]1C=Cc2c1c(C)ccc2C YBDQDJQQEJJFPS-UHFFFAOYSA-L 0.000 description 1
- MCPUUBRVQORFFZ-UHFFFAOYSA-L [Cl-].[Cl-].Cc1cccc2C=CC(c12)[Zr++]1(CC1)C1C=Cc2cccc(C)c12 Chemical compound [Cl-].[Cl-].Cc1cccc2C=CC(c12)[Zr++]1(CC1)C1C=Cc2cccc(C)c12 MCPUUBRVQORFFZ-UHFFFAOYSA-L 0.000 description 1
- PAVLWCZQYRYPMJ-UHFFFAOYSA-M [H-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 Chemical compound [H-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 PAVLWCZQYRYPMJ-UHFFFAOYSA-M 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- AZWXAPCAJCYGIA-UHFFFAOYSA-N bis(2-methylpropyl)alumane Chemical compound CC(C)C[AlH]CC(C)C AZWXAPCAJCYGIA-UHFFFAOYSA-N 0.000 description 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000005712 crystallization Effects 0.000 description 1
- SJVLZCPSDQQCDY-UHFFFAOYSA-L cyclopenta-1,3-diene;dichlorozirconium(2+) Chemical compound [Cl-].[Cl-].[Zr+4].C1C=CC=[C-]1.C1C=CC=[C-]1 SJVLZCPSDQQCDY-UHFFFAOYSA-L 0.000 description 1
- CMPQHMYIQNCWIY-UHFFFAOYSA-L cyclopenta-1,3-diene;zirconium(2+);dichloride Chemical compound [Cl-].[Cl-].[Zr+2].C1C=CC=[C-]1.C1C=CC=[C-]1 CMPQHMYIQNCWIY-UHFFFAOYSA-L 0.000 description 1
- 238000005115 demineralization Methods 0.000 description 1
- 230000002328 demineralizing Effects 0.000 description 1
- GWWKZPLMVIATIO-UHFFFAOYSA-L dibromozirconium Chemical compound Br[Zr]Br GWWKZPLMVIATIO-UHFFFAOYSA-L 0.000 description 1
- MIILMDFFARLWKZ-UHFFFAOYSA-L dichlorozirconium;1,2,3,4,5-pentamethylcyclopentane Chemical compound [Cl-].[Cl-].CC1=C(C)C(C)=C(C)C1(C)[Zr+2]C1(C)C(C)=C(C)C(C)=C1C MIILMDFFARLWKZ-UHFFFAOYSA-L 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- YEMLBLTUNOJCQH-UHFFFAOYSA-N diethoxy(2-methylpropyl)alumane Chemical compound CCO[Al](CC(C)C)OCC YEMLBLTUNOJCQH-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000008079 hexane Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- VAMFXQBUQXONLZ-UHFFFAOYSA-N icos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- NEMYBHYAISOMTI-UHFFFAOYSA-N methanolate;2-methylpropylaluminum(2+) Chemical compound [O-]C.[O-]C.CC(C)C[Al+2] NEMYBHYAISOMTI-UHFFFAOYSA-N 0.000 description 1
- 229940053662 nickel sulfate Drugs 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 229940038384 octadecane Drugs 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000004291 polyenes Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Family
ID=
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