JP2023142300A5 - - Google Patents
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- Publication number
- JP2023142300A5 JP2023142300A5 JP2022049139A JP2022049139A JP2023142300A5 JP 2023142300 A5 JP2023142300 A5 JP 2023142300A5 JP 2022049139 A JP2022049139 A JP 2022049139A JP 2022049139 A JP2022049139 A JP 2022049139A JP 2023142300 A5 JP2023142300 A5 JP 2023142300A5
- Authority
- JP
- Japan
- Prior art keywords
- cellulose
- resin
- carbamate
- fibrous cellulose
- microfiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 229920002678 cellulose Polymers 0.000 claims description 196
- 239000001913 cellulose Substances 0.000 claims description 193
- -1 polypropylene Polymers 0.000 claims description 99
- 239000000835 fiber Substances 0.000 claims description 69
- 239000000843 powder Substances 0.000 claims description 55
- 239000004743 Polypropylene Substances 0.000 claims description 48
- 229920001155 polypropylene Polymers 0.000 claims description 48
- 239000000805 composite resin Substances 0.000 claims description 47
- 239000004698 Polyethylene Substances 0.000 claims description 41
- 229920000573 polyethylene Polymers 0.000 claims description 41
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 33
- 239000002245 particle Substances 0.000 claims description 21
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 20
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 7
- 235000010980 cellulose Nutrition 0.000 description 186
- 229920001410 Microfiber Polymers 0.000 description 105
- 239000003658 microfiber Substances 0.000 description 105
- 229920005989 resin Polymers 0.000 description 66
- 239000011347 resin Substances 0.000 description 66
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 55
- 238000011282 treatment Methods 0.000 description 43
- 108090000790 Enzymes Proteins 0.000 description 38
- 102000004190 Enzymes Human genes 0.000 description 38
- 229940088598 enzyme Drugs 0.000 description 38
- 239000002994 raw material Substances 0.000 description 31
- 238000010438 heat treatment Methods 0.000 description 29
- 238000002156 mixing Methods 0.000 description 28
- 239000004202 carbamide Substances 0.000 description 27
- 229920003043 Cellulose fiber Polymers 0.000 description 26
- 238000001035 drying Methods 0.000 description 26
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 23
- 238000000034 method Methods 0.000 description 22
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 20
- 235000019441 ethanol Nutrition 0.000 description 19
- 239000006185 dispersion Substances 0.000 description 17
- 230000003014 reinforcing effect Effects 0.000 description 17
- 229920001131 Pulp (paper) Polymers 0.000 description 16
- 230000002776 aggregation Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- 238000004898 kneading Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000002253 acid Substances 0.000 description 14
- 230000018044 dehydration Effects 0.000 description 14
- 238000006297 dehydration reaction Methods 0.000 description 14
- 229910052739 hydrogen Inorganic materials 0.000 description 14
- 239000001257 hydrogen Substances 0.000 description 14
- 239000002002 slurry Substances 0.000 description 14
- 239000000945 filler Substances 0.000 description 13
- 239000002655 kraft paper Substances 0.000 description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000002612 dispersion medium Substances 0.000 description 12
- 125000001183 hydrocarbyl group Chemical group 0.000 description 12
- 238000005054 agglomeration Methods 0.000 description 11
- 239000002270 dispersing agent Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 description 10
- 108010059892 Cellulase Proteins 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- 206010061592 cardiac fibrillation Diseases 0.000 description 9
- 230000007423 decrease Effects 0.000 description 9
- 230000002600 fibrillogenic effect Effects 0.000 description 9
- 239000011121 hardwood Substances 0.000 description 9
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 9
- 239000011122 softwood Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
- 206010016807 Fluid retention Diseases 0.000 description 8
- 239000012736 aqueous medium Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- 239000004645 polyester resin Substances 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 7
- 125000003118 aryl group Chemical group 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 230000008569 process Effects 0.000 description 7
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- 229920003232 aliphatic polyester Polymers 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 108010002430 hemicellulase Proteins 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002121 nanofiber Substances 0.000 description 6
- 229920001225 polyester resin Polymers 0.000 description 6
- 229920001282 polysaccharide Polymers 0.000 description 6
- 239000005017 polysaccharide Substances 0.000 description 6
- 150000004804 polysaccharides Chemical class 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
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- 238000004220 aggregation Methods 0.000 description 5
- 238000005452 bending Methods 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- 230000005484 gravity Effects 0.000 description 5
- 235000014655 lactic acid Nutrition 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 238000010306 acid treatment Methods 0.000 description 4
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- 125000003277 amino group Chemical group 0.000 description 4
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- 125000000753 cycloalkyl group Chemical group 0.000 description 4
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- 238000004519 manufacturing process Methods 0.000 description 4
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- 238000012545 processing Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 108010008885 Cellulose 1,4-beta-Cellobiosidase Proteins 0.000 description 3
- OWIKHYCFFJSOEH-UHFFFAOYSA-N Isocyanic acid Chemical compound N=C=O OWIKHYCFFJSOEH-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- XLJMAIOERFSOGZ-UHFFFAOYSA-N anhydrous cyanic acid Natural products OC#N XLJMAIOERFSOGZ-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 229920006167 biodegradable resin Polymers 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
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- 230000001737 promoting effect Effects 0.000 description 3
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- 239000012779 reinforcing material Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 150000003672 ureas Chemical class 0.000 description 3
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 3
- LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 2
- WHBMMWSBFZVSSR-UHFFFAOYSA-N 3-hydroxybutyric acid Chemical compound CC(O)CC(O)=O WHBMMWSBFZVSSR-UHFFFAOYSA-N 0.000 description 2
- 102100032487 Beta-mannosidase Human genes 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- UCTWMZQNUQWSLP-UHFFFAOYSA-N adrenaline Chemical compound CNCC(O)C1=CC=C(O)C(O)=C1 UCTWMZQNUQWSLP-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 238000010009 beating Methods 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 108010055059 beta-Mannosidase Proteins 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 210000002421 cell wall Anatomy 0.000 description 2
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- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
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- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 2
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- SFLSHLFXELFNJZ-QMMMGPOBSA-N (-)-norepinephrine Chemical compound NC[C@H](O)C1=CC=C(O)C(O)=C1 SFLSHLFXELFNJZ-QMMMGPOBSA-N 0.000 description 1
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
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- ZNHBMOUCJIUSNM-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;ethane-1,2-diamine Chemical class NCCN.OCCN(CCO)CCO ZNHBMOUCJIUSNM-UHFFFAOYSA-N 0.000 description 1
- 150000000369 2-ethylhexanols Chemical class 0.000 description 1
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- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
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- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical class CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 1
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| JP2022049139A JP7449323B2 (ja) | 2022-03-24 | 2022-03-24 | 繊維状セルロース複合樹脂 |
| PCT/JP2022/046809 WO2023181538A1 (ja) | 2022-03-24 | 2022-12-20 | 繊維状セルロース複合樹脂 |
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| JP2012149230A (ja) | 2010-12-27 | 2012-08-09 | Sumitomo Metal Ind Ltd | 摺動部材とその製造方法 |
| JP7110691B2 (ja) | 2018-04-12 | 2022-08-02 | 東洋インキＳｃホールディングス株式会社 | 樹脂組成物および成形体 |
| JP2020063350A (ja) | 2018-10-16 | 2020-04-23 | 旭化成株式会社 | セルロース強化ポリオレフィン系樹脂組成物の製造方法 |
| JP2021080316A (ja) | 2019-11-14 | 2021-05-27 | 住友金属鉱山株式会社 | 熱伝導性組成物 |
| WO2021100672A1 (ja) | 2019-11-19 | 2021-05-27 | 凸版印刷株式会社 | 包装体の製造方法、包装材用フィルム並びにこれを備える積層フィルム及び包装材 |
| JP7483418B2 (ja) | 2020-03-11 | 2024-05-15 | 大王製紙株式会社 | 繊維状セルロースの製造方法、及び繊維状セルロース複合樹脂の製造方法 |
| JP2021172705A (ja) | 2020-04-21 | 2021-11-01 | オイレス工業株式会社 | 摺動部材用樹脂組成物及び摺動部材 |
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