JP2022078226A - Spray product - Google Patents
Spray product Download PDFInfo
- Publication number
- JP2022078226A JP2022078226A JP2022034588A JP2022034588A JP2022078226A JP 2022078226 A JP2022078226 A JP 2022078226A JP 2022034588 A JP2022034588 A JP 2022034588A JP 2022034588 A JP2022034588 A JP 2022034588A JP 2022078226 A JP2022078226 A JP 2022078226A
- Authority
- JP
- Japan
- Prior art keywords
- repellent
- component
- pest repellent
- pest
- spray product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007921 spray Substances 0.000 title claims description 14
- 230000002940 repellent Effects 0.000 claims abstract description 267
- 239000005871 repellent Substances 0.000 claims abstract description 267
- 241000607479 Yersinia pestis Species 0.000 claims abstract description 168
- 230000002708 enhancing effect Effects 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 49
- QLHULAHOXSSASE-UHFFFAOYSA-N butan-2-yl 2-(2-hydroxyethyl)piperidine-1-carboxylate Chemical compound CCC(C)OC(=O)N1CCCCC1CCO QLHULAHOXSSASE-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229950011440 icaridin Drugs 0.000 claims abstract description 11
- 239000003205 fragrance Substances 0.000 claims description 25
- 238000002156 mixing Methods 0.000 claims description 19
- 238000001816 cooling Methods 0.000 claims description 16
- 230000035597 cooling sensation Effects 0.000 claims description 15
- 230000000844 anti-bacterial effect Effects 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 9
- 239000003380 propellant Substances 0.000 claims description 9
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 claims description 8
- 229960001673 diethyltoluamide Drugs 0.000 claims description 8
- 238000013329 compounding Methods 0.000 claims description 7
- 239000004615 ingredient Substances 0.000 claims description 7
- RFFOTVCVTJUTAD-UHFFFAOYSA-N cineole Natural products C1CC2(C)CCC1(C(C)C)O2 RFFOTVCVTJUTAD-UHFFFAOYSA-N 0.000 claims description 6
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 6
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 claims description 5
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 5
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 claims description 3
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 claims description 3
- RFFOTVCVTJUTAD-AOOOYVTPSA-N 1,4-cineole Chemical compound CC(C)[C@]12CC[C@](C)(CC1)O2 RFFOTVCVTJUTAD-AOOOYVTPSA-N 0.000 claims description 3
- WEEGYLXZBRQIMU-UHFFFAOYSA-N 1,8-cineole Natural products C1CC2CCC1(C)OC2(C)C WEEGYLXZBRQIMU-UHFFFAOYSA-N 0.000 claims description 3
- XHXUANMFYXWVNG-UHFFFAOYSA-N D-menthyl acetate Natural products CC(C)C1CCC(C)CC1OC(C)=O XHXUANMFYXWVNG-UHFFFAOYSA-N 0.000 claims description 3
- WEEGYLXZBRQIMU-WAAGHKOSSA-N Eucalyptol Chemical compound C1C[C@H]2CC[C@]1(C)OC2(C)C WEEGYLXZBRQIMU-WAAGHKOSSA-N 0.000 claims description 3
- PSMFFFUWSMZAPB-UHFFFAOYSA-N Eukalyptol Natural products C1CC2CCC1(C)COCC2(C)C PSMFFFUWSMZAPB-UHFFFAOYSA-N 0.000 claims description 3
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims description 3
- 229930184148 Spiranthol Natural products 0.000 claims description 3
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 claims description 3
- 229940116229 borneol Drugs 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 claims description 3
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 claims description 3
- ROBXZHNBBCHEIQ-UHFFFAOYSA-N ethyl 2-aminopropanoate Chemical compound CCOC(=O)C(C)N ROBXZHNBBCHEIQ-UHFFFAOYSA-N 0.000 claims description 3
- 229960001047 methyl salicylate Drugs 0.000 claims description 3
- TUIMRCFXWGKBNT-UHFFFAOYSA-N n-ethyl-2-(5-methyl-2-propan-2-ylcyclohexyl)acetamide Chemical compound CCNC(=O)CC1CC(C)CCC1C(C)C TUIMRCFXWGKBNT-UHFFFAOYSA-N 0.000 claims description 3
- ZYTMANIQRDEHIO-UHFFFAOYSA-N p-menth-8-en-3-ol Chemical compound CC1CCC(C(C)=C)C(O)C1 ZYTMANIQRDEHIO-UHFFFAOYSA-N 0.000 claims description 3
- 229940041616 menthol Drugs 0.000 claims description 2
- LMXFTMYMHGYJEI-UHFFFAOYSA-N p-menthane-3,8-diol Chemical compound CC1CCC(C(C)(C)O)C(O)C1 LMXFTMYMHGYJEI-UHFFFAOYSA-N 0.000 claims description 2
- 229930006948 p-menthane-3,8-diol Natural products 0.000 claims description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 claims 2
- XHXUANMFYXWVNG-WCQGTBRESA-N [(1s,2r,5s)-5-methyl-2-propan-2-ylcyclohexyl] acetate Chemical compound CC(C)[C@H]1CC[C@H](C)C[C@@H]1OC(C)=O XHXUANMFYXWVNG-WCQGTBRESA-N 0.000 claims 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 37
- AXMPPCGZGUAUBS-UHFFFAOYSA-N ethyl 2-(hexanoylamino)propanoate Chemical compound CCCCCC(=O)NC(C)C(=O)OCC AXMPPCGZGUAUBS-UHFFFAOYSA-N 0.000 abstract 1
- 239000000796 flavoring agent Substances 0.000 abstract 1
- 235000019634 flavors Nutrition 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 26
- -1 dl-camper Chemical compound 0.000 description 18
- 241000256856 Vespidae Species 0.000 description 15
- 239000000443 aerosol Substances 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 8
- 238000012790 confirmation Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 241000255925 Diptera Species 0.000 description 7
- 241000257303 Hymenoptera Species 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- VZRKEAFHFMSHCD-UHFFFAOYSA-N Ethyl 3-(N-butylacetamido)propionate Chemical compound CCCCN(C(C)=O)CCC(=O)OCC VZRKEAFHFMSHCD-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000003242 anti bacterial agent Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229940027359 ir-3535 Drugs 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- 239000011550 stock solution Substances 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000003623 enhancer Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- XHXUANMFYXWVNG-ADEWGFFLSA-N (-)-Menthyl acetate Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(C)=O XHXUANMFYXWVNG-ADEWGFFLSA-N 0.000 description 4
- 241000256059 Culex pipiens Species 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical compound C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 239000000077 insect repellent Substances 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 3
- 210000003491 skin Anatomy 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- 239000001605 (5-methyl-2-propan-2-ylcyclohexyl) acetate Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 2
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 241000238366 Cephalopoda Species 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- 241000510032 Ellipsaria lineolata Species 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 230000006399 behavior Effects 0.000 description 2
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000002781 deodorant agent Substances 0.000 description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 239000003759 ester based solvent Substances 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 239000005453 ketone based solvent Substances 0.000 description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- 229940044120 2-n-octyl-4-isothiazolin-3-one Drugs 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 241000256837 Apidae Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 241000256835 Polistes Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229940072049 amyl acetate Drugs 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- SWUIQEBPZIHZQS-UHFFFAOYSA-N calone Chemical compound O1CC(=O)COC2=CC(C)=CC=C21 SWUIQEBPZIHZQS-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- CXPOFJRHCFPDRI-UHFFFAOYSA-N dodecylbenzene;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1 CXPOFJRHCFPDRI-UHFFFAOYSA-N 0.000 description 1
- 230000000856 effect on pests Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940093499 ethyl acetate Drugs 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 1
- 239000004306 orthophenyl phenol Substances 0.000 description 1
- 235000010292 orthophenyl phenol Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- FURYAADUZGZUGQ-UHFFFAOYSA-N phenoxybenzene;sulfuric acid Chemical compound OS(O)(=O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 FURYAADUZGZUGQ-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fats And Perfumes (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Abstract
Description
本発明は、害虫に対する忌避効果を向上した害虫忌避組成物、及び当該害虫忌避組成物を含む害虫忌避液剤に関する。 The present invention relates to a pest repellent composition having an improved repellent effect on pests, and a pest repellent solution containing the pest repellent composition.
害虫忌避組成物は、害虫に対する忌避効果を有する成分（以下、「害虫忌避成分」）を含有することにより、害虫を排除し、害虫による刺咬被害等を防止するものである。 The pest repellent composition contains a component having a repellent effect against pests (hereinafter, "pest repellent component") to eliminate pests and prevent bite damage caused by pests.
近年、害虫忌避組成物に害虫忌避成分の忌避効果を増強する成分（以下、「忌避増強成分」）を配合することが試みられており、例えば、忌避増強成分として抗菌剤を配合した害虫忌避組成物が開発されている（例えば、特許文献１を参照）。特許文献１の害虫忌避組成物は、フェノール系抗菌剤、ベンゾチアゾール系抗菌剤及びイソチアゾリン系抗菌剤といった抗菌剤を、忌避増強成分として含有している。 In recent years, attempts have been made to add a component that enhances the repellent effect of a pest repellent component (hereinafter, "repellent enhancing component") to a pest repellent composition. A product has been developed (see, for example, Patent Document 1). The pest repellent composition of Patent Document 1 contains an antibacterial agent such as a phenol-based antibacterial agent, a benzothiazole-based antibacterial agent, and an isothiazolin-based antibacterial agent as a repellent enhancing component.
特許文献１の害虫忌避組成物は、皮膚や着衣等へ直接処理する用途を想定しており、人体への接触が考えられるため、忌避増強成分として刺激の少ない抗菌剤を用いている。 The pest repellent composition of Patent Document 1 is intended for direct treatment on the skin, clothes, etc., and may come into contact with the human body. Therefore, an antibacterial agent with less irritation is used as a repellent enhancing component.
しかしながら、刺咬被害をもたらすハチ類の防除では、ハチ又はハチの巣に対して害虫忌避組成物を処理することが想定され、害虫忌避組成物が直接人体へ接触することがない。このような用途では、忌避増強成分に必ずしも人体への刺激の少ない物質を用いなくてもよい場合がある。また、人体への刺激がある物質であっても、配合量の調整により人体への過度な刺激を抑えることも可能である。これらの観点から、忌避増強成分として有用な物質は、抗菌剤に限らず他にも存在し得ると考えられる。 However, in the control of bees that cause bite damage, it is assumed that the pest repellent composition is treated on the bee or the beehive, and the pest repellent composition does not come into direct contact with the human body. In such applications, it may not always be necessary to use a substance that is less irritating to the human body as the repellent enhancing component. Further, even if the substance is irritating to the human body, it is possible to suppress excessive irritation to the human body by adjusting the blending amount. From these viewpoints, it is considered that a substance useful as a repellent enhancing component may exist not only as an antibacterial agent but also as another substance.
本発明は、上記問題点に鑑みてなされたものであり、害虫忌避成分の忌避効果を増強させる新たな忌避増強成分を含有する害虫忌避組成物、及び害虫忌避液剤を提供することを目的とする。 The present invention has been made in view of the above problems, and an object of the present invention is to provide a pest repellent composition containing a new repellent enhancing component that enhances the repellent effect of the pest repellent component, and a pest repellent solution. ..
上記課題を解決するための本発明に係る害虫忌避組成物の特徴構成は、
害虫忌避成分と、
忌避増強成分としての冷感香料と、
を含むことにある。
The characteristic composition of the pest repellent composition according to the present invention for solving the above-mentioned problems is
Pest repellent ingredients and
Cooling fragrance as a repellent ingredient,
Is to include.
本構成の害虫忌避組成物によれば、害虫忌避成分による通常の忌避効果が、忌避増強成分としての冷感香料により増強される。その結果、冷感香料の配合による相乗効果により、優れた忌避効果を得ることができる。 According to the pest repellent composition of this composition, the normal repellent effect of the pest repellent component is enhanced by the cooling fragrance as the repellent enhancing component. As a result, an excellent repellent effect can be obtained due to the synergistic effect of blending the cooling fragrance.
本発明に係る害虫忌避組成物において、
前記害虫忌避成分は、ディート、３－（Ｎ－ｎ－ブチル－Ｎ－アセチル）アミノプロピオン酸エチルエステル、及びイカリジンからなる群から選択される少なくとも一つであることが好ましい。
In the pest repellent composition according to the present invention
The pest repellent component is preferably at least one selected from the group consisting of DEET, 3- (Nn-butyl-N-acetyl) aminopropionate ethyl ester, and icaridin.
本構成の害虫忌避組成物によれば、害虫忌避成分として上記の適切なものを使用しているため、冷感香料の配合による相乗効果が顕著となり、より優れた忌避効果を得ることができる。 According to the pest repellent composition of the present constitution, since the above-mentioned appropriate pest repellent component is used, the synergistic effect due to the blending of the cooling fragrance becomes remarkable, and a more excellent repellent effect can be obtained.
本発明に係る害虫忌避組成物において、
前記冷感香料は、ｌ－メントール、メンチルアセテート、乳酸メンチル、ｌ－メンチルグリセリルエーテル、メンチルピロリドンカルボン酸カンファー、Ｎ－エチル－ｐ－メンタンカルボキシアミド、ｄｌ－カンファー、イソプレゴール、１，４－シネオール、１，８－シネオール、ボルネオール、チモール、スピラントール、酢酸リナリル、サリチル酸メチル、３－ｌ－メトキシプロパンジオール、７－メチル－３，４－ジヒドロ－（２Ｈ）－１，５－ベンゾジオキセピン－３－オン、２，４－ジメチル－３－シクロヘキセニルカルボキシアルデヒド、及びメチル－Ｎ－３，７－ジメチル－７－ヒドロキシオクチリデン－アンスラニレートからなる群から選択される少なくとも一つであることが好ましい。
In the pest repellent composition according to the present invention
The cooling sensation fragrances include l-menthol, menthyl acetate, menthol lactate, l-mentyl glyceryl ether, menthylpyrrolidone carboxylic acid camphor, N-ethyl-p-menthancarboxyamide, dl-camper, isopregol, 1,4-cineole, and the like. 1,8-cineol, borneol, timol, spiranthol, linaryl acetate, methyl salicylate, 3-l-methoxypropanediol, 7-methyl-3,4-dihydro- (2H) -1,5-benzodioxepin-3 -On, 2,4-dimethyl-3-cyclohexenylcarboxyaldehyde, and at least one selected from the group consisting of methyl-N-3,7-dimethyl-7-hydroxyoctylden-anthranilate. preferable.
本構成の害虫忌避組成物によれば、上記の適切な冷感香料を忌避増強成分として使用しているため、害虫忌避成分の忌避効果を十分に増強することができる。 According to the pest repellent composition of the present constitution, since the above-mentioned appropriate cooling fragrance is used as the repellent enhancing component, the repellent effect of the pest repellent component can be sufficiently enhanced.
本発明に係る害虫忌避組成物において、
前記害虫忌避成分と前記忌避増強成分との配合比が、５：１～３０００：１（質量比）に設定されていることが好ましい。
In the pest repellent composition according to the present invention
It is preferable that the blending ratio of the pest repellent component and the repellent enhancing component is set to 5: 1 to 3000: 1 (mass ratio).
本構成の害虫忌避組成物によれば、配合比が適切な範囲にあるため、忌避増強成分としての冷感香料による冷感刺激が強くなり過ぎることや、忌避増強成分が不足することで害虫忌避成分の忌避効果を十分に増強できなくなることを防ぐことができる。 According to the pest repellent composition of this composition, since the compounding ratio is in an appropriate range, the cooling sensation stimulus by the cold sensation fragrance as the repellent enhancing component becomes too strong, and the pest repellent component is insufficient, so that the pest repellent is repelled. It is possible to prevent the component from being unable to sufficiently enhance its repellent effect.
本発明に係る害虫忌避組成物において、
前記忌避増強成分の揮散期間の８０％以上の期間に亘って前記害虫忌避成分が揮散するように構成されていることが好ましい。
In the pest repellent composition according to the present invention
It is preferable that the pest repellent component is configured to volatilize over a period of 80% or more of the volatilization period of the repellent enhancing component.
本構成の害虫忌避組成物によれば、害虫忌避成分の揮散期間中に忌避増強成分が全て揮散して失われることがないため、害虫忌避成分の揮散期間を通して冷感香料の配合による相乗効果が十分に発揮される。また、忌避増強成分の揮散期間と害虫忌避成分の揮散期間とが８０％以上重複するように忌避増強成分の量を調節することで、過剰な添加によるコストの上昇を抑制することができる。 According to the pest repellent composition of this composition, since all the repellent enhancing components are not volatilized and lost during the volatilization period of the pest repellent component, the synergistic effect of blending the cooling sensation fragrance is obtained throughout the volatilization period of the pest repellent component. It is fully demonstrated. Further, by adjusting the amount of the repellent enhancing component so that the volatilization period of the repellent enhancing component and the volatilization period of the pest repellent component overlap by 80% or more, it is possible to suppress an increase in cost due to excessive addition.
本発明に係る害虫忌避組成物において、
抗菌成分をさらに含むことが好ましい。
In the pest repellent composition according to the present invention
It is preferable to further contain an antibacterial component.
本構成の害虫忌避組成物によれば、抗菌成分により菌の増殖を抑制することができるので、害虫忌避組成物を人体又は着衣へ直接塗布する用途等において、発汗の際の各種の菌が発生する臭いを抑えることができる。 According to the pest repellent composition having this configuration, the growth of bacteria can be suppressed by the antibacterial component, so that various bacteria are generated during sweating in applications such as when the pest repellent composition is directly applied to the human body or clothes. It is possible to suppress the smell of sweat.
上記課題を解決するための本発明に係る害虫忌避液剤の特徴構成は、
上記何れか一つに記載の害虫忌避組成物を含むことにある。
The characteristic composition of the pest repellent liquid agent according to the present invention for solving the above-mentioned problems is
It is intended to contain the pest repellent composition according to any one of the above.
本構成の害虫忌避液剤によれば、本発明の害虫忌避組成物を含むことで、害虫忌避成分による通常の忌避効果が、忌避増強成分としての冷感香料により増強される。その結果、冷感香料の配合による相乗効果により、優れた忌避効果を得ることができる。 According to the pest repellent liquid having the present constitution, by including the pest repellent composition of the present invention, the usual repellent effect of the pest repellent component is enhanced by the cooling fragrance as the repellent enhancing component. As a result, an excellent repellent effect can be obtained due to the synergistic effect of blending the cooling fragrance.
以下、本発明の害虫忌避組成物、及び害虫忌避液剤について説明する。ただし、本発明は、以下に説明する実施形態に限定されることを意図しない。 Hereinafter, the pest repellent composition of the present invention and the pest repellent liquid agent will be described. However, the present invention is not intended to be limited to the embodiments described below.
本発明は、害虫忌避組成物に冷感香料を配合することで、害虫忌避成分のハチ類等への忌避効果を増強することを本発明者らが新たに発見し、冷感香料を忌避増強成分として利用することを着想したものである。本発明の害虫忌避組成物（害虫忌避液剤）によって防除することが可能な害虫の種類としては、例えば、ミツバチ、クマバチ、フタモンアシナガバチ、セグロアシナガバチ、キアシナガバチ、コガタスズメバチ、モンスズメバチ、ヒメスズメバチ、オオスズメバチ、キイロスズメバチ、及びチャイロスズメバチ等のハチ類、アカイエカ、チカイエカ、ヒトスジシマカ等の蚊類、蚋、ユスリカ類、ハエ類、コバエ類、チョウバエ類、イガ類等が挙げられる。 In the present invention, the present inventors have newly discovered that by blending a cooling fragrance with a pest repellent composition, the effect of the pest repellent component on repelling bees and the like is enhanced, and the cooling fragrance is enhanced. The idea is to use it as an ingredient. Types of pests that can be controlled by the pest repellent composition (pest repellent) of the present invention include, for example, honeybees, bear wasps, paper wasps, paper wasps, paper wasps, paper wasps, wasps, wasps, and wasps. , Polistes rothney, and wasps such as paper wasps, mosquitoes such as paper wasps, paper wasps, and wasps, silkworms, wasps, flies, wasps, butterfly flies, and squids.
＜害虫忌避組成物＞
本発明の害虫忌避組成物は、主成分として、害虫忌避成分と、忌避増強成分とを含有する。また、本発明の害虫忌避組成物は、さらに、抗菌成分を含有してもよい。
<Pest repellent composition>
The pest repellent composition of the present invention contains a pest repellent component and a repellent enhancing component as main components. In addition, the pest repellent composition of the present invention may further contain an antibacterial component.
害虫忌避成分としては、ディート、３－（Ｎ－ｎ－ブチル－Ｎ－アセチル）アミノプロピオン酸エチルエステル（以下、「ＩＲ３５３５」と表記する）、イカリジン、及びｐ－メンタン－３，８－ジオール等が挙げられる。上掲の害虫忌避成分のうち、ディート、ＩＲ３５３５、及びイカリジンが好ましく使用される。忌避増強成分の配合による相乗効果は、害虫忌避成分、及び忌避増強成分のそれぞれの種類の組み合わせによってその度合いが異なるが、特に、ディート、ＩＲ３５３５、及びイカリジンは、後述する忌避増強成分としての冷感香料との組み合わせにより、忌避増強成分の配合による優れた相乗効果を得ることができる。ディートは、長年にわたる使用実績がある。ＩＲ３５３５は、ディートとほぼ同等の忌避効果を有しながら、ディートよりも人体に対する安全性が高い。イカリジンは、忌避効果が高く、安全性も高い。なお、上掲の各害虫忌避成分は、単独で用いてもよいし、複数種を混合して用いてもよい。 Examples of the pest repellent component include DEET, 3- (Nn-butyl-N-acetyl) aminopropionate ethyl ester (hereinafter referred to as "IR3535"), icaridin, p-menthane-3,8-diol and the like. Can be mentioned. Of the above pest repellent components, DEET, IR3535, and icaridin are preferably used. The degree of synergistic effect due to the combination of the repellent enhancer varies depending on the combination of each type of the pest repellent ingredient and the repellent enhancer, but in particular, DEET, IR3535, and icaridin have a feeling of coldness as the repellent enhancer described later. When combined with a fragrance, an excellent synergistic effect can be obtained by blending the repellent enhancing component. DEET has a long history of use. IR3535 has almost the same repellent effect as DEET, but is safer to the human body than DEET. Icaridin has a high repellent effect and is highly safe. Each of the above-mentioned pest repellent components may be used alone or in combination of two or more.
忌避増強成分としては、冷感香料を用いる。冷感香料の例として、ｌ－メントール、メンチルアセテート、乳酸メンチル、ｌ－メンチルグリセリルエーテル、メンチルピロリドンカルボン酸カンファー、Ｎ－エチル－ｐ－メンタンカルボキシアミド、ｄｌ－カンファー、イソプレゴール、１，４－シネオール、１，８－シネオール、ボルネオール、チモール、スピラントール、酢酸リナリル、サリチル酸メチル、３－ｌ－メトキシプロパンジオール、７－メチル－３，４－ジヒドロ－（２Ｈ）－１，５－ベンゾジオキセピン－３－オン、２，４－ジメチル－３－シクロヘキセニルカルボキシアルデヒド、メチル－Ｎ－３，７－ジメチル－７－ヒドロキシオクチリデン－アンスラニレート等が挙げられる。なお、上掲の各冷感香料は、単独で用いてもよいし、複数種を混合して用いてもよい。 A cooling fragrance is used as the repellent enhancing component. Examples of cooling fragrances are l-menthol, menthyl acetate, mentyl lactate, l-mentyl glyceryl ether, menthylpyrrolidone carboxylic acid camphor, N-ethyl-p-menthancarboxyamide, dl-camper, isopregol, 1,4-cineol. , 1,8-cineol, borneol, timol, spiranthol, linaryl acetate, methyl salicylate, 3-l-methoxypropanediol, 7-methyl-3,4-dihydro- (2H) -1,5-benzodioxepin- Examples thereof include 3-one, 2,4-dimethyl-3-cyclohexenylcarboxyaldehyde, methyl-N-3,7-dimethyl-7-hydroxyoctylden-anthranilate and the like. In addition, each of the above-mentioned cooling fragrances may be used alone or in combination of two or more.
冷感香料は人体への接触により冷感刺激をもたらすが、ハチ類の防除等、害虫忌避組成物が人体へ直接接触することが想定されない用途では、冷感刺激への対処を考慮することなく使用することができる。また、害虫忌避組成物が人体へ直接接触する用途でも、冷感香料の配合量を調節することで、過度な冷感刺激を抑え爽やかな肌感覚を得ることができる。 Cooling fragrances bring about a cooling sensation stimulus by contact with the human body, but in applications where it is not expected that the pest repellent composition will come into direct contact with the human body, such as controlling bees, without considering how to deal with the cooling sensation stimulus. Can be used. Further, even in the case where the pest repellent composition comes into direct contact with the human body, by adjusting the blending amount of the cooling sensation fragrance, it is possible to suppress an excessive cooling sensation stimulus and obtain a refreshing skin sensation.
抗菌成分としては、各種の一般的な抗菌性化合物を用いることができる。例えば、通常のフェノール系抗菌成分や四級アンモニウム塩の抗菌成分、イソチアゾリン系抗菌成分など各種の化合物を用いることができる。これらは単独で用いてもよいし、複数種を混合して用いてもよい。フェノール系抗菌成分としては、特に限定はされないものの、３－メチル－４－イソプロピルフェノール、オルト－フェニルフェノール等が例示される。ベンゾチアゾール系抗菌成分としては、５－クロロ－２－メチル－４－イソチアゾリン－３－オン、２－メルカプトベンゾチアゾール等が例示される。さらにイソチアゾリン系抗菌成分としては、２－ｎ－オクチル－４－イソチアゾリン－３－オン、５－クロロ－２－メチル－４－イソチアゾリン－３－オン等が挙げられるが、これらに限定されるものではない。 As the antibacterial component, various general antibacterial compounds can be used. For example, various compounds such as a normal phenol-based antibacterial component, an antibacterial component of a quaternary ammonium salt, and an isothiazolin-based antibacterial component can be used. These may be used alone or in combination of two or more. The phenolic antibacterial component is not particularly limited, and examples thereof include 3-methyl-4-isopropylphenol and ortho-phenylphenol. Examples of the benzothiazole-based antibacterial component include 5-chloro-2-methyl-4-isothiazolin-3-one, 2-mercaptobenzothiazole and the like. Further, examples of the isothiazolin-based antibacterial component include 2-n-octyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, etc., but are not limited thereto. not.
本発明の害虫忌避組成物には、害虫忌避成分、忌避増強成分、及び抗菌成分の各効果を阻害しないものであれば、他の成分が含まれていても構わない。そのような成分の例として、例えば、殺虫成分、消臭成分、除菌成分、持続成分等が挙げられる。 The pest repellent composition of the present invention may contain other components as long as they do not inhibit the effects of the pest repellent component, the repellent enhancing component, and the antibacterial component. Examples of such components include insecticidal components, deodorant components, sterilizing components, sustained components and the like.
上掲の各成分の配合にあたって、人体への過度な冷感刺激を抑制しつつ、優れた忌避効果を得るためには、害虫忌避成分と忌避増強成分との配合比（質量比）は、５：１～３０００：１に調整されることが好ましく、５０：１～３０００：１に調整されることがより好ましく、１００：１～１５００：１に調整されることがさらに好ましい。害虫忌避成分と忌避増強成分との配合比が５：１未満の場合（すなわち、忌避増強成分の配合量が害虫忌避成分の配合量に対して１／５を超える場合）、忌避増強成分の比率を増やしても忌避効果の増強が頭打ちとなり、忌避増強成分の過剰分に応じたコスト面でのデメリットが生じ、さらに、害虫忌避組成物が人体へ直接接触する用途では、忌避増強成分としての冷感香料による冷感刺激が強くなり過ぎる虞がある。なお、忌避増強成分の比率を増やしても忌避効果の増強が頭打ちとならないようにするためには、忌避増強成分の揮散期間の８０％以上の期間に亘って害虫忌避成分が揮散するよう調整することが好ましい。害虫忌避成分と忌避増強成分との配合比が３０００：１を超える場合（すなわち、忌避増強成分の配合量が害虫忌避成分の配合量に対して１／３０００未満の場合）、忌避増強成分が不足するため、害虫忌避成分の忌避効果を十分に増強できない虞がある。 In blending each of the above ingredients, in order to obtain an excellent repellent effect while suppressing excessive cooling sensation to the human body, the blending ratio (mass ratio) of the pest repellent component and the repellent enhancing component is 5. It is preferably adjusted to 1: 1 to 3000: 1, more preferably 50: 1 to 3000: 1, and even more preferably 100: 1 to 1500: 1. When the blending ratio of the pest repellent component to the repellent enhancing component is less than 5: 1 (that is, when the blending amount of the repellent enhancing component exceeds 1/5 of the blending amount of the pest repellent component), the ratio of the repellent enhancing component Even if the amount is increased, the enhancement of the repellent effect will reach a plateau, and there will be a disadvantage in terms of cost depending on the excess amount of the repellent enhancing component. Furthermore, in applications where the pest repellent composition comes into direct contact with the human body, cold as a repellent enhancing component There is a risk that the cooling sensation stimulus due to the fragrance will become too strong. In order to prevent the enhancement of the repellent effect from reaching a plateau even if the ratio of the repellent enhancing component is increased, the pest repellent component is adjusted to volatilize over a period of 80% or more of the volatilization period of the repellent enhancing component. Is preferable. When the compounding ratio of the pest repellent component and the repellent enhancing component exceeds 3000: 1 (that is, when the compounding amount of the repellent enhancing component is less than 1/3000 of the compounding amount of the pest repellent component), the repellent enhancing component is insufficient. Therefore, there is a possibility that the repellent effect of the pest repellent component cannot be sufficiently enhanced.
上述のように調製された本発明の害虫忌避組成物は、忌避増強成分として配合された冷感香料の作用により、害虫忌避成分の忌避効力が増強され、優れた忌避効果を発揮することができる。 The pest repellent composition of the present invention prepared as described above can exhibit an excellent repellent effect by enhancing the repellent effect of the pest repellent component by the action of the cooling fragrance blended as the repellent enhancing component. ..
＜害虫忌避液剤＞
本発明の害虫忌避液剤は、上述した各成分を適切な質量比で配合し、これを溶剤に溶解させることで得られる。溶剤としては、アセトン、メチルエチルケトン、ジエチルケトン、シクロヘキサノン等のケトン系溶剤、メタノール、エタノール、ブタノール、プロパノール、イソプロパノール等のアルコール系溶剤、エチレングリコール、ジエチレングリコール、トリエチレングリコール、プロピレングリコール、１，３－ブチレングリコール、ジプロピレングリコール等のグリコール系溶剤、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノブチルエーテル、トリエチレングリコールモノメチルエーテル等のグリコールエーテル系溶剤、トルエン、キシレン、ノルマルヘキサン、ｎ－パラフィン、イソパラフィン等の炭化水素系溶剤、酢酸エチル、酢酸ブチル、酢酸アミル、乳酸エチル等のエステル系溶剤などが挙げられる。溶剤が水溶性である場合は、適量の水を混合することも可能である。
<Pest repellent>
The pest repellent liquid of the present invention can be obtained by blending the above-mentioned components in an appropriate mass ratio and dissolving them in a solvent. Examples of the solvent include ketone solvents such as acetone, methyl ethyl ketone, diethyl ketone and cyclohexanone, alcohol solvents such as methanol, ethanol, butanol, propanol and isopropanol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol and 1,3-butylene. Glycol solvents such as glycol and dipropylene glycol, glycol ether solvents such as diethylene glycol monomethyl ether, diethylene glycol monobutyl ether and triethylene glycol monomethyl ether, hydrocarbon solvents such as toluene, xylene, normal hexane, n-paraffin and isoparaffin. Examples thereof include ester solvents such as ethyl acetate, butyl acetate, amyl acetate and ethyl lactate. If the solvent is water-soluble, it is also possible to mix an appropriate amount of water.
害虫忌避液剤中の害虫忌避成分の濃度は、好ましくは５ｗ／ｖ％以上、より好ましくは７ｗ／ｖ％以上に調整される。害虫忌避成分の濃度が５ｗ／ｖ％未満の場合、十分な忌避効果を発揮することが困難となる虞がある。害虫忌避成分の濃度の上限については、特に限定されないが、現実的には使用する溶剤における害虫忌避成分の飽和濃度となる。 The concentration of the pest repellent component in the pest repellent is preferably adjusted to 5 w / v% or more, more preferably 7 w / v% or more. If the concentration of the pest repellent component is less than 5 w / v%, it may be difficult to exert a sufficient repellent effect. The upper limit of the concentration of the pest repellent component is not particularly limited, but in reality, it is the saturated concentration of the pest repellent component in the solvent used.
害虫忌避液剤中の忌避増強成分の濃度は、好ましくは０．０１～０．１ｗ／ｖ％に調整される。忌避増強成分の濃度が０．０１ｗ／ｖ％未満の場合、忌避増強成分が不足するため、害虫忌避成分の忌避効果を十分に増強できない虞があり、忌避増強成分の濃度が０．１ｗ／ｖ％を超える場合、忌避増強成分としての冷感香料による冷感刺激が強くなり過ぎる虞がある。 The concentration of the repellent enhancer in the pest repellent is preferably adjusted to 0.01-0.1 w / v%. If the concentration of the repellent enhancing component is less than 0.01 w / v%, the repellent enhancing component is insufficient, so that the repellent effect of the pest repellent component may not be sufficiently enhanced, and the concentration of the repellent enhancing component is 0.1 w / v. If it exceeds%, the cooling sensation stimulus by the cooling sensation fragrance as a repellent enhancing component may become too strong.
また、本発明の害虫忌避液剤には、界面活性剤、可溶化剤、分散剤、安定化剤、ｐＨ調整剤、着色剤などの添加剤を加えることも可能である。 Further, additives such as a surfactant, a solubilizer, a dispersant, a stabilizer, a pH adjuster, and a colorant can be added to the pest repellent liquid of the present invention.
上述のように調製された本発明の害虫忌避液剤は、スプレー剤として使用することができる。本発明の害虫忌避液剤をスプレー剤として使用する場合には、例えば、蓄圧式のポンプ式スプレーのヘッドが付いた容器に害虫忌避液剤を封入することで、スプレー製品を構成することができる。あるいは、本発明の害虫忌避液剤をシートに含侵し、シートタイプの製品を構成してもよい。 The pest repellent of the present invention prepared as described above can be used as a spray agent. When the pest repellent of the present invention is used as a spray, for example, a spray product can be configured by enclosing the pest repellent in a container equipped with a pressure-accumulation pump-type spray head. Alternatively, the pest repellent of the present invention may be impregnated into the sheet to form a sheet-type product.
また、上述の害虫忌避組成物と有機溶剤とを混合した害虫忌避液剤をエアゾール原液とし、噴射剤とともに耐圧容器に加圧充填することで、エアゾール製品を構成することができる。エアゾールを作製するにあたっては、作業性を考慮して、初めに有機溶剤に害虫忌避組成物を溶解させてエアゾール原液（害虫忌避液剤）を調製する。そして、このエアゾール原液を噴射剤とともに耐圧容器に封入する。 Further, an aerosol product can be formed by using a pest repellent solution obtained by mixing the above-mentioned pest repellent composition and an organic solvent as an aerosol stock solution and pressurizing and filling a pressure-resistant container together with a propellant. In preparing the aerosol, in consideration of workability, the pest repellent composition is first dissolved in an organic solvent to prepare an aerosol stock solution (pest repellent). Then, this aerosol stock solution is sealed in a pressure-resistant container together with the propellant.
有機溶剤の特性は、エアゾールを噴射したときの噴霧粒子の形成に影響するため、適切な粘度に調整したものが使用される。有機溶剤の粘度は、２０℃において１０ｍＰａ・ｓ未満が好ましく、５ｍＰａ・ｓ未満がより好ましい。エアゾール原液の調製に使用可能な有機溶剤を例示すると、ノルマルパラフィン、及びイソパラフィン等の炭化水素系溶剤、エタノール、イソプロパノール、ｎ－プロパノール等のアルコール類、プロピレングリコール、１，３－ブチレングリコール、１，４－ブチレングリコール、ジプロピレングリコール等のグリコール類、ジエチレングリコールモノブチルエーテル等のグリコールエーテル類、ケトン系溶剤、及びエステル系溶剤等が挙げられる。なお、上掲の有機溶剤は、単独での使用に限定されず、二種以上を組み合わせて使用しても構わない。 Since the characteristics of the organic solvent affect the formation of spray particles when the aerosol is sprayed, those adjusted to an appropriate viscosity are used. The viscosity of the organic solvent is preferably less than 10 mPa · s at 20 ° C., more preferably less than 5 mPa · s. Examples of organic solvents that can be used to prepare the aerosol stock solution include normal paraffin, hydrocarbon solvents such as isoparaffin, alcohols such as ethanol, isopropanol and n-propanol, propylene glycol, 1,3-butylene glycol, 1, Examples thereof include glycols such as 4-butylene glycol and dipropylene glycol, glycol ethers such as diethylene glycol monobutyl ether, ketone solvents, ester solvents and the like. The above-mentioned organic solvent is not limited to use alone, and two or more kinds may be used in combination.
エアゾール原液は、水を配合して水性エアゾール剤に調製することも可能であり、この場合、必要に応じて界面活性剤が添加される。界面活性剤を例示すると、ポリオキシエチレンアルキルエーテル類、ポリオキシエチレンアルキルフェニルエーテル類、ポリオキシエチレンポリオキシプロピレンアルキルエーテル類、ポリオキシエチレンアルキルアミノエーテル類などのエーテル類、ポリエチレングリコール脂肪酸エステル類、ポリオキシエチレンソルビタン脂肪酸エステル類、ポリオキシエチレングリセリン脂肪酸エステル類などの脂肪酸エステル類、ポリオキシエチレンスチレン化フェノール、脂肪酸のポリアルカロールアミドなどの非イオン系界面活性剤、ポリオキシエチレン（ＰＯＥ）スチリルフェニルエーテル硫酸塩、ポリオキシエチレン（ＰＯＥ）アルキルエーテル硫酸塩、ドデシルベンゼン硫酸塩などのアニオン系界面活性剤等が挙げられる。 The aerosol stock solution can be prepared as an aqueous aerosol agent by blending water, and in this case, a surfactant is added as needed. Examples of surfactants include polyoxyethylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, ethers such as polyoxyethylene alkyl amino ethers, polyethylene glycol fatty acid esters, and the like. Polyoxyethylene sorbitan fatty acid esters, fatty acid esters such as polyoxyethylene glycerin fatty acid esters, nonionic surfactants such as polyoxyethylene styrylated phenols and polyalkalolamide fatty acids, polyoxyethylene (POE) styryl Examples thereof include anionic surfactants such as phenyl ether sulfate, polyoxyethylene (POE) alkyl ether sulfate, and dodecylbenzene sulfate.
噴射剤は、エアゾール原液を粒子状にして勢いよく噴射させるため、常温常圧でガス状のものが使用される。また、噴射剤には、圧力容器内において、上述の各種成分を変質させない安定性が求められる。そのような噴射剤を例示すると、液化石油ガス（ＬＰＧ）、ジメチルエーテル（ＤＭＥ）、窒素ガス、炭酸ガス、亜酸化窒素ガス、及び圧縮空気等が挙げられる。これらのうち、容易に入手可能であり、且つ取扱い易いＬＰＧ、及び窒素ガスが好ましく使用される。なお、上掲の噴射剤は、単独での使用に限定されず、二種以上を組み合わせて使用しても構わない。 As the propellant, a gaseous one is used at normal temperature and pressure in order to atomize the undiluted aerosol solution and inject it vigorously. Further, the propellant is required to have stability in the pressure vessel so as not to deteriorate the above-mentioned various components. Examples of such propellants include liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, nitrous oxide gas, compressed air and the like. Of these, LPG and nitrogen gas, which are easily available and easy to handle, are preferably used. The above-mentioned propellants are not limited to use alone, and may be used in combination of two or more.
噴射剤は、エアゾール原液（ａ）と噴射剤（ｂ）との容量比率（ａ／ｂ）が、４０／６０～８０／２０となるように調整される。容量比率（ａ／ｂ）が上記の適切な範囲に調整されている場合、耐圧容器内でのエアゾール剤の内圧は、０．２５～０．７０ＭＰａ（２５℃）となる。 The propellant is adjusted so that the volume ratio (a / b) of the aerosol stock solution (a) and the propellant (b) is 40/60 to 80/20. When the volume ratio (a / b) is adjusted to the above-mentioned appropriate range, the internal pressure of the aerosol agent in the pressure-resistant container is 0.25 to 0.70 MPa (25 ° C.).
〔害虫忌避効果確認試験〕
本発明の害虫忌避組成物による忌避効果を確認するため、害虫忌避成分と忌避増強成分との組み合わせ、及びその配合比を種々変更して害虫忌避液剤（実施例１～１４）を調製した。また、比較のため、忌避増強成分を配合していない害虫忌避成分のみの害虫忌避液剤（比較例１～７）を調製した。実施例１～１４、及び比較例１～７の各害虫忌避液剤に使用した各種成分、害虫忌避成分と忌避増強成分との配合比（質量比）を表１に示す。実施例８の害虫忌避液剤については、表１中には記載していないが、害虫忌避成分及び忌避増強成分以外の他の成分として緑茶消臭エキス０．０１ｇをさらに含む。なお、本実施例は、任意の倍率でのスケールアップが可能である。従って、実施例中に示す各成分の質量単位ｇ（グラム）は、質量部又は重量部と読み替えることができる。
[Pest repellent effect confirmation test]
In order to confirm the repellent effect of the pest repellent composition of the present invention, pest repellent solutions (Examples 1 to 14) were prepared by variously changing the combination of the pest repellent component and the repellent enhancing component and the blending ratio thereof. In addition, for comparison, pest repellents (Comparative Examples 1 to 7) containing only the pest repellent component containing no repellent enhancing component were prepared. Table 1 shows various components used in each of the pest repellents of Examples 1 to 14 and Comparative Examples 1 to 7, and the compounding ratio (mass ratio) of the pest repellent component and the repellent enhancing component. Although the pest repellent liquid of Example 8 is not shown in Table 1, 0.01 g of green tea deodorant extract is further contained as a component other than the pest repellent component and the repellent enhancing component. In this embodiment, it is possible to scale up at an arbitrary magnification. Therefore, the mass unit g (gram) of each component shown in the examples can be read as parts by mass or parts by weight.
害虫忌避液剤の調製にあたっては、各成分を混合してエタノール５５．０ｇに均一に溶解し、さらに精製水を加え、全量で１００ｍＬの害虫忌避組成物とした。これを蓄圧式のポンプ式スプレーのヘッドが付いた容器に充填した。 In preparing the pest repellent, each component was mixed and uniformly dissolved in 55.0 g of ethanol, and purified water was further added to prepare a total volume of 100 mL of the pest repellent composition. This was filled in a container with a pressure-accumulation pump-type spray head.
害虫忌避効果確認試験では、密閉可能な開口部を備えたボックスにアカイエカの雌成虫２０匹を放ち、害虫忌避液剤（害虫忌避組成物）を手の甲に約１ｍＬ塗布し塗り延ばした被験者の片腕を開口部からボックス内に挿入し、被験者の片腕に付着したアカイエカの数（ｎ１）をカウントした。また、ブランクとして、同条件のボックス内に害虫忌避液剤を塗布していない被験者の片腕を挿入し、同様に被験者の片腕に付着したアカイエカの数（ｎ０）をカウントした。そして、アカイエカの忌避率を（ｎ０－ｎ１）／ｎ０〔％〕として算出した。忌避率の算出は、害虫忌避液剤の使用開始から２時間後、４時間後、６時間後、及び８時間後について行った。実施例１～１４、及び比較例１～７における害虫忌避効果確認試験の結果（忌避率）を表１に示す。 In the pest repellent effect confirmation test, 20 adult female Culex pipiens were released into a box with a sealable opening, and about 1 mL of a pest repellent solution (pest repellent composition) was applied to the back of the hand to open one arm of the subject. It was inserted into the box from the part, and the number of Culex pipiens (n 1 ) attached to one arm of the subject was counted. Further, as a blank, one arm of the subject to which the pest repellent solution was not applied was inserted into the box under the same conditions, and the number of Culex pipiens (n 0 ) attached to one arm of the subject was similarly counted. Then, the repellent rate of Culex pipiens was calculated as (n 0 − n 1 ) / n 0 [%]. The repellent rate was calculated 2 hours, 4 hours, 6 hours, and 8 hours after the start of use of the pest repellent. Table 1 shows the results (repellent rate) of the pest repellent effect confirmation test in Examples 1 to 14 and Comparative Examples 1 to 7.
害虫忌避効果確認試験の結果より、実施例１～１４、及び比較例１～７の害虫忌避液剤は、何れも使用開始から４時間後までは、９０％以上の忌避率を示し、十分な忌避効果が認められた。 From the results of the pest repellent effect confirmation test, the pest repellents of Examples 1 to 14 and Comparative Examples 1 to 7 showed a repellent rate of 90% or more until 4 hours after the start of use, and were sufficient repellent. The effect was recognized.
しかしながら、使用開始から６時間後に、実施例１～３、５～９、１２～１４の害虫忌避液剤と、比較例１、２、４～６の害虫忌避液剤との忌避率に差が生じるようになった。具体的には、実施例１の害虫忌避液剤、及び比較例１の害虫忌避液剤は、何れも害虫忌避成分として７．０ｇのイカリジンを含有するが、使用開始から６時間後に、実施例１では９５％と高い忌避率を示したのに対し、比較例１では８０％まで忌避率が低下した。実施例２、３、５、６、１２、１３、１４の害虫忌避液剤、及び比較例２の害虫忌避液剤は、何れも害虫忌避成分として５．０ｇのイカリジンを含有するが、使用開始から６時間後に、実施例２、３、５、６、１２、１３、１４では８５％以上の忌避率を示したのに対し、比較例２では８０％まで忌避率が低下した。なお、実施例３と実施例１２との比較、及び実施例１３と実施例１４との比較から、イカリジンに対する忌避増強成分の配合量を１０倍に増加すると、より長時間に亘って高い忌避率を維持できることが確認された。実施例７の害虫忌避液剤、及び比較例４の害虫忌避液剤は、何れも害虫忌避成分として５．０ｇのＩＲ３５３５を含有するが、使用開始から６時間後に、実施例７では９０％と高い忌避率を示したのに対し、比較例４では８０％まで忌避率が低下した。実施例８の害虫忌避液剤、及び比較例５の害虫忌避液剤は、何れも害虫忌避成分として１５．０ｇのＩＲ３５３５を含有するが、使用開始から６時間後に、実施例８では１００％の忌避率が維持されているのに対し、比較例５では９０％まで忌避率が低下した。実施例９の害虫忌避液剤、及び比較例６の害虫忌避液剤は、何れも害虫忌避成分として１０．０ｇのディートを含有するが、使用開始から６時間後に、実施例９では９０％と高い忌避率を示したのに対し、比較例６では７０％まで忌避率が低下した。 However, 6 hours after the start of use, there is a difference in the repellent rate between the pest repellents of Examples 1 to 3, 5 to 9, 12 to 14 and the pest repellents of Comparative Examples 1, 2, 4 to 6. Became. Specifically, the pest repellent of Example 1 and the pest repellent of Comparative Example 1 both contain 7.0 g of icaridin as a pest repellent component, but 6 hours after the start of use, in Example 1. While the repellent rate was as high as 95%, the repellent rate decreased to 80% in Comparative Example 1. The pest repellents of Examples 2, 3, 5, 6, 12, 13, and 14 and the pest repellents of Comparative Example 2 both contain 5.0 g of icaridin as a pest repellent component, but 6 from the start of use. After hours, Examples 2, 3, 5, 6, 12, 13, and 14 showed a repellent rate of 85% or more, whereas Comparative Example 2 showed a repellent rate of 80%. From the comparison between Example 3 and Example 12 and the comparison between Example 13 and Example 14, when the amount of the repellent enhancing component for icaridin is increased 10 times, the repellent rate is higher over a longer period of time. It was confirmed that it can be maintained. The pest repellent of Example 7 and the pest repellent of Comparative Example 4 both contain 5.0 g of IR3535 as a pest repellent component, but 6 hours after the start of use, the repellent is as high as 90% in Example 7. While the rate was shown, the repellent rate decreased to 80% in Comparative Example 4. The pest repellent of Example 8 and the pest repellent of Comparative Example 5 both contain 15.0 g of IR3535 as a pest repellent component, but 6 hours after the start of use, the repellent rate of 100% in Example 8 In Comparative Example 5, the repellent rate decreased to 90%. The pest repellent of Example 9 and the pest repellent of Comparative Example 6 both contain 10.0 g of deet as a pest repellent component, but 6 hours after the start of use, the repellent is as high as 90% in Example 9. While the rate was shown, the repellent rate decreased to 70% in Comparative Example 6.
また、実施例４、１１の害虫忌避液剤、及び比較例３の害虫忌避液剤は、何れも害虫忌避成分として１５．０ｇのイカリジンを含有し、使用開始から６時間後までは、忌避率に差が見られなかったが、使用開始から８時間後に、実施例４、１１では９０％と高い忌避率を示したのに対し、比較例３では８０％まで忌避率が低下した。実施例１０の害虫忌避液剤、及び比較例７の害虫忌避液剤は、何れも害虫忌避成分として３０．０ｇのディートを含有し、使用開始から６時間後までは、忌避率に差が見られなかったが、使用開始から８時間後に、実施例１０では９０％と高い忌避率を示したのに対し、比較例７では８０％まで忌避率が低下した。 Further, the pest repellents of Examples 4 and 11 and the pest repellents of Comparative Example 3 both contained 15.0 g of icaridin as a pest repellent component, and the repellent rate was different from the start of use until 6 hours later. However, 8 hours after the start of use, Examples 4 and 11 showed a high repellent rate of 90%, whereas Comparative Example 3 showed a high repellent rate of 80%. The pest repellent of Example 10 and the pest repellent of Comparative Example 7 both contained 30.0 g of deet as a pest repellent component, and there was no difference in the repellent rate until 6 hours after the start of use. However, 8 hours after the start of use, Example 10 showed a high repellent rate of 90%, whereas Comparative Example 7 showed a high repellent rate of 80%.
このように、同種の害虫忌避成分を同量含有する組み合わせにおいて、忌避増強成分として冷感香料を含有する実施例１～１４の害虫忌避液剤は、忌避増強成分として冷感香料を含有していない比較例１～７の害虫忌避液剤に比べて、使用開始から６時間後以降も高い忌避率を維持することが示された。 As described above, in the combination containing the same amount of the same kind of pest repellent component, the pest repellent liquids of Examples 1 to 14 containing the cooling fragrance as the repellent enhancing component do not contain the cooling sensation fragrance as the repellent enhancing component. It was shown that a high repellent rate was maintained even after 6 hours from the start of use as compared with the pest repellents of Comparative Examples 1 to 7.
〔刺咬被害防止効果確認試験〕
ハチに対する刺咬被害防止効果を確認するため、実施例６、１０の害虫忌避液剤を使用して、刺咬被害防止効果確認試験を実施した。また、比較のため、それぞれ実施例６、１０と同種の害虫忌避成分を同量含有する比較例２、７を使用し、同様の試験を実施した。
[Bite damage prevention effect confirmation test]
In order to confirm the effect of preventing bite damage on bees, a test for confirming the effect of preventing bite damage was carried out using the pest repellents of Examples 6 and 10. Further, for comparison, Comparative Examples 2 and 7 containing the same amount of the same kind of pest repellent component as Examples 6 and 10 were used, and the same test was carried out.
刺咬被害防止効果確認試験では、２０ｃｍ２のレーヨン／ポリエステル製布地に、害虫忌避液剤をスプレーして害虫忌避成分及び忌避増強成分を含浸させ、これを１ｍ３のガラス箱の底面中央に置き、供試検体とした。供試検体は、実施例６、１０、及び比較例２、７のそれぞれについて、薬剤処理後２時間、４時間の２種を準備した。上記の供試検体上に、炭酸麻酔したフタモンアシナガバチ雌成虫を１匹置き、麻酔から覚醒した後の行動を観察した。ハチが供試検体上で、盛んに羽ばたき行動を行う、もしくはその場から飛び立とうとするといった、忌避行動を行った回数を１０分間記録した。実施例６、１０、及び比較例２、７に使用した各種成分とその配合比（質量比）、並びに刺咬被害防止効果確認試験の結果を表２に示す。 In the bite damage prevention effect confirmation test, a 20 cm 2 rayon / polyester fabric was sprayed with a pest repellent liquid to impregnate it with a pest repellent component and a repellent enhancer component, and this was placed in the center of the bottom surface of a 1 m 3 glass box. It was used as a test sample. Two types of test samples were prepared for Examples 6 and 10 and Comparative Examples 2 and 7 for 2 hours and 4 hours after the drug treatment. One adult female paper wasp, which was anesthetized with carbonic acid, was placed on the above-mentioned test specimen, and the behavior after awakening from the anesthesia was observed. The number of repellent behaviors of the bee, such as actively flapping its wings or trying to take off from the spot, was recorded for 10 minutes. Table 2 shows the various components used in Examples 6, 10 and Comparative Examples 2 and 7, their compounding ratio (mass ratio), and the results of the bite damage prevention effect confirmation test.
刺咬被害防止効果確認試験の結果より、実施例６、１０、及び比較例２、７の害虫忌避液剤は、同種の害虫忌避成分を同量含有する組み合わせにおいて、薬剤処理から２時間後では忌避行動の回数に違いは見られなかった。しかしながら、薬剤処理から４時間後では、実施例６、１０の害虫忌避液剤は、比較例２、７の害虫忌避液剤に比べて、忌避行動の回数が多く観察された。 From the results of the bite damage prevention effect confirmation test, the pest repellents of Examples 6, 10 and Comparative Examples 2 and 7 were repelled 2 hours after the drug treatment in a combination containing the same amount of the same kind of pest repellent component. There was no difference in the number of actions. However, 4 hours after the drug treatment, the pest repellents of Examples 6 and 10 were observed to have a larger number of repellent actions than the pest repellents of Comparative Examples 2 and 7.
このように、忌避増強成分として冷感香料を含有する実施例６、１０の害虫忌避液剤は、忌避増強成分として冷感香料を含有していない比較例２、７の害虫忌避液剤に比べて、ハチに対する忌避効果が高く、実施例６、１０の害虫忌避液剤により、ハチに対する優れた刺咬被害防止効果が得られることが確認された。 As described above, the pest repellents of Examples 6 and 10 containing a cooling sensation as a repellent enhancing component are compared with the pest repellents of Comparative Examples 2 and 7 which do not contain a cooling sensation as a repellent enhancing component. It was confirmed that the repellent effect on bees is high, and that the pest repellents of Examples 6 and 10 have an excellent anti-bite damage effect on bees.
本発明の害虫忌避組成物、及び害虫忌避液剤は、ハチ類、蚊類、蚋、ユスリカ類、ハエ類、コバエ類、チョウバエ類、イガ類などの害虫を忌避するために使用されるものであり、例えば、人の皮膚に塗布する虫除け剤、ペットや家畜の表皮に塗布する虫除け剤、衣類等の繊維製品にスプレーするスプレー剤として利用可能である。 The pest repellent composition and the insect repellent of the present invention are used to repel pests such as bees, mosquitoes, silkworms, yusurikas, flies, flies, butterfly flies, and squid. For example, it can be used as an insect repellent applied to human skin, an insect repellent applied to the epidermis of pets and livestock, and a spray agent to be sprayed on textile products such as clothing.
Claims (5)
忌避増強成分としての冷感香料と、
を含む飛翔害虫忌避組成物を含む飛翔害虫忌避液剤を容器に封入してなるスプレー製品であって、
前記害虫忌避成分は、ディート、３－（Ｎ－ｎ－ブチル－Ｎ－アセチル）アミノプロピオン酸エチルエステル、イカリジン、及びｐ－メンタン－３，８－ジオールからなる群から選択される一つであり、
前記飛翔害虫忌避液剤における前記害虫忌避成分の濃度は、５ｗ／ｖ％以上であり、
前記害虫忌避成分と前記忌避増強成分との配合比が、５：１～１５００：１（質量比）に設定されているスプレー製品（但し、前記容器に噴射剤が封入されている場合を除く）。 Pest repellent ingredients and
Cooling fragrance as a repellent ingredient,
A spray product in which a flying pest repellent liquid containing a flying pest repellent composition containing is sealed in a container.
The pest repellent component is one selected from the group consisting of DEET, 3- (Nn-butyl-N-acetyl) aminopropionate ethyl ester, icaridin, and p-menthane-3,8-diol. ,
The concentration of the pest repellent component in the flying pest repellent is 5 w / v% or more.
A spray product in which the blending ratio of the pest repellent component and the repellent enhancing component is set to 5: 1 to 1500: 1 (mass ratio) (except when the propellant is sealed in the container). ..
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