JP2021535229A - ポリ(2−アルキル−2−オキサゾリン)を有するポリオレフィン配合物 - Google Patents
ポリ(2−アルキル−2−オキサゾリン)を有するポリオレフィン配合物 Download PDFInfo
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- JP2021535229A JP2021535229A JP2020568665A JP2020568665A JP2021535229A JP 2021535229 A JP2021535229 A JP 2021535229A JP 2020568665 A JP2020568665 A JP 2020568665A JP 2020568665 A JP2020568665 A JP 2020568665A JP 2021535229 A JP2021535229 A JP 2021535229A
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- Prior art keywords
- alkyl
- oxazoline
- poly
- weight
- polyolefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 139
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 124
- 238000009472 formulation Methods 0.000 title claims abstract description 98
- 229920001577 copolymer Polymers 0.000 claims abstract description 134
- 150000001336 alkenes Chemical class 0.000 claims abstract description 40
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 36
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000005977 Ethylene Substances 0.000 claims description 58
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 57
- 150000001451 organic peroxides Chemical class 0.000 claims description 57
- -1 thio compound Chemical class 0.000 claims description 45
- 229920001519 homopolymer Polymers 0.000 claims description 40
- 240000005572 Syzygium cordatum Species 0.000 claims description 37
- 235000006650 Syzygium cordatum Nutrition 0.000 claims description 37
- 150000001875 compounds Chemical class 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 30
- 239000004020 conductor Substances 0.000 claims description 28
- 239000000654 additive Substances 0.000 claims description 24
- 239000008188 pellet Substances 0.000 claims description 23
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 22
- 239000004711 α-olefin Substances 0.000 claims description 22
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 21
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 18
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 18
- 238000010998 test method Methods 0.000 claims description 17
- 239000006229 carbon black Substances 0.000 claims description 16
- 230000000996 additive effect Effects 0.000 claims description 12
- 150000001412 amines Chemical class 0.000 claims description 12
- 239000000155 melt Substances 0.000 claims description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 12
- 239000004615 ingredient Substances 0.000 claims description 11
- 229920001684 low density polyethylene Polymers 0.000 claims description 11
- 239000004702 low-density polyethylene Substances 0.000 claims description 11
- 239000002105 nanoparticle Substances 0.000 claims description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 10
- 229910000077 silane Inorganic materials 0.000 claims description 10
- 125000003342 alkenyl group Chemical group 0.000 claims description 9
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229920005638 polyethylene monopolymer Polymers 0.000 claims description 7
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 239000004606 Fillers/Extenders Substances 0.000 claims description 5
- 239000002667 nucleating agent Substances 0.000 claims description 5
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 5
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 4
- 230000005611 electricity Effects 0.000 claims description 4
- 230000015556 catabolic process Effects 0.000 claims description 2
- 238000006731 degradation reaction Methods 0.000 claims description 2
- 229920003020 cross-linked polyethylene Polymers 0.000 claims 1
- 239000004703 cross-linked polyethylene Substances 0.000 claims 1
- 238000010586 diagram Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 description 64
- 239000000047 product Substances 0.000 description 64
- 239000010410 layer Substances 0.000 description 34
- 229920000642 polymer Polymers 0.000 description 26
- 235000019241 carbon black Nutrition 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 14
- 238000012360 testing method Methods 0.000 description 14
- NYEZZYQZRQDLEH-UHFFFAOYSA-N 2-ethyl-4,5-dihydro-1,3-oxazole Chemical compound CCC1=NCCO1 NYEZZYQZRQDLEH-UHFFFAOYSA-N 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 11
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 description 10
- 239000012861 aquazol Substances 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 238000004132 cross linking Methods 0.000 description 10
- 150000001993 dienes Chemical class 0.000 description 10
- 229920006187 aquazol Polymers 0.000 description 9
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229960003742 phenol Drugs 0.000 description 9
- 229920002554 vinyl polymer Polymers 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 8
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 230000005540 biological transmission Effects 0.000 description 7
- 150000007942 carboxylates Chemical class 0.000 description 7
- 238000007598 dipping method Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 150000002978 peroxides Chemical class 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000012752 auxiliary agent Substances 0.000 description 6
- 150000001733 carboxylic acid esters Chemical class 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000005038 ethylene vinyl acetate Substances 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 238000007655 standard test method Methods 0.000 description 6
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 5
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 5
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920001903 high density polyethylene Polymers 0.000 description 5
- 239000004700 high-density polyethylene Substances 0.000 description 5
- 238000007654 immersion Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 5
- 239000002356 single layer Substances 0.000 description 5
- 125000006736 (C6-C20) aryl group Chemical group 0.000 description 4
- XYXJKPCGSGVSBO-UHFFFAOYSA-N 1,3,5-tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C)=C1CN1C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C1=O XYXJKPCGSGVSBO-UHFFFAOYSA-N 0.000 description 4
- MQWCQFCZUNBTCM-UHFFFAOYSA-N 2-tert-butyl-6-(3-tert-butyl-2-hydroxy-5-methylphenyl)sulfanyl-4-methylphenol Chemical compound CC(C)(C)C1=CC(C)=CC(SC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O MQWCQFCZUNBTCM-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 4
- 229920002538 Polyethylene Glycol 20000 Polymers 0.000 description 4
- 239000007983 Tris buffer Substances 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 4
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 238000007142 ring opening reaction Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZOKCNEIWFQCSCM-UHFFFAOYSA-N (2-methyl-4-phenylpent-4-en-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)CC(=C)C1=CC=CC=C1 ZOKCNEIWFQCSCM-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000002656 Distearyl thiodipropionate Substances 0.000 description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 229910002808 Si–O–Si Inorganic materials 0.000 description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000000304 alkynyl group Chemical group 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000012656 cationic ring opening polymerization Methods 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 235000019305 distearyl thiodipropionate Nutrition 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 3
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 3
- 229920000768 polyamine Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 2
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 2
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 2
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
- VFBJXXJYHWLXRM-UHFFFAOYSA-N 2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylsulfanyl]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCSCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 VFBJXXJYHWLXRM-UHFFFAOYSA-N 0.000 description 2
- JJRDRFZYKKFYMO-UHFFFAOYSA-N 2-methyl-2-(2-methylbutan-2-ylperoxy)butane Chemical compound CCC(C)(C)OOC(C)(C)CC JJRDRFZYKKFYMO-UHFFFAOYSA-N 0.000 description 2
- GUXJXWKCUUWCLX-UHFFFAOYSA-N 2-methyl-2-oxazoline Chemical compound CC1=NCCO1 GUXJXWKCUUWCLX-UHFFFAOYSA-N 0.000 description 2
- GXCJLVVUIVSLOQ-UHFFFAOYSA-N 2-propyl-4,5-dihydro-1,3-oxazole Chemical compound CCCC1=NCCO1 GXCJLVVUIVSLOQ-UHFFFAOYSA-N 0.000 description 2
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 2
- UJAWGGOCYUPCPS-UHFFFAOYSA-N 4-(2-phenylpropan-2-yl)-n-[4-(2-phenylpropan-2-yl)phenyl]aniline Chemical compound C=1C=C(NC=2C=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C=CC=1C(C)(C)C1=CC=CC=C1 UJAWGGOCYUPCPS-UHFFFAOYSA-N 0.000 description 2
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- KVOZXXSUSRZIKD-UHFFFAOYSA-N Prop-2-enylcyclohexane Chemical compound C=CCC1CCCCC1 KVOZXXSUSRZIKD-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 229910052729 chemical element Inorganic materials 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000012718 coordination polymerization Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- 229920000359 diblock copolymer Polymers 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- HEAMQYHBJQWOSS-UHFFFAOYSA-N ethene;oct-1-ene Chemical compound C=C.CCCCCCC=C HEAMQYHBJQWOSS-UHFFFAOYSA-N 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
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- 229910052700 potassium Inorganic materials 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
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- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
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- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- PLCFYBDYBCOLSP-UHFFFAOYSA-N tris(prop-2-enyl) 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound C=CCOC(=O)CC(O)(CC(=O)OCC=C)C(=O)OCC=C PLCFYBDYBCOLSP-UHFFFAOYSA-N 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
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- 238000004073 vulcanization Methods 0.000 description 1
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0233—Polyamines derived from (poly)oxazolines, (poly)oxazines or having pendant acyl groups
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/14—Peroxides
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
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- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
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- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
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- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
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- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
少なくとも1つ。各発生において独立して1つ以上。例は、1〜10、あるいは1〜5、あるいは1〜3、あるいは2〜10、あるいは2〜5、あるいは2〜3、あるいは1、あるいは2、あるいは3である。
ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物(ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)含有配合物または本発明の配合物)は、異なる方法で作製することができる。例えば、(A)エチレン系(コ)ポリマーの溶融物を、(B)PAO(コ)ポリマーおよび成分(C)酸化防止剤、およびいずれかの任意選択の成分(例えば、成分(D)〜(L)のうちの任意のゼロ、1つ以上)と混合して、ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物を、成分(A)、(B)、(C)、およびいずれかの任意選択の成分の混合物として得る。混合には、調合、混練、または押出が含まれ得る。混合を促進するために、1つ以上の成分(例えば、(B)、(C)、添加剤(D)、(E)、(F)など)が、(A)の一部への添加剤マスターバッチの形態で、または(A)以外のキャリア樹脂への添加剤の分散物として提供されてもよい。キャリア樹脂は、ポリプロピレンポリマーであってもよい。(D)有機過酸化物は、代替的に、成分(A)、(B)、(C)、およびいずれかの任意選択の成分のブレンドのペレットの表面を(D)有機過酸化物でコーティングすることを含む、吸収、射出、または浸漬方法によって添加されてもよい。吸収、注入、または浸漬は、約20℃〜100℃の温度で0.1〜100時間、例えば、60℃〜80℃で0.1〜24時間実施することができる。いずれの(D)有機過酸化物も大幅な分解温度を受けない限り、より高い温度が、吸収、射出、または浸漬に使用され得る。所望ならば、ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物は、貯蔵温度(例えば、23℃)に冷却し、1時間、1週間、1ヶ月、またはそれ以上の時間にわたって貯蔵し得る。ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物は、照射硬化または有機過酸化物/熱硬化によって、架橋され得る。
成分
架橋ポリオレフィン生成物(本発明の生成物)は、ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物の硬化中に形成されたC−C結合架橋を含有するネットワーク状ポリオレフィン樹脂を含有する。架橋ポリオレフィン生成物は、(D)有機過酸化物の存在下で、成分(A)、(B)、(C)、および任意選択の(G)アルケニル官能性補助剤をカップリングすることによって作製される。代替的に、架橋ポリオレフィン生成物は、(D)有機過酸化物の非存在下で、成分(A)、(B)、(C)、および任意選択の(G)を照射硬化させることによって作製されてもよい。架橋ポリオレフィン生成物はまた、(D)有機過酸化物の反応のアルコール生成物などの硬化副生成物を含んでもよい。ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物が、いずれかの他の任意選択の添加剤(E)、(F)、および(H)〜(L)のうちの1つ以上をさらに含有するとき、架橋ポリオレフィン生成物はまた、添加剤(複数可)、または硬化中にそれから形成される反応副生成物を含有し得る。架橋ポリオレフィン生成物は、分割固体形態または連続形態であってもよい。連続形態は、成形部品(例えばブロー成形部品)または押出部品(例えば絶縁導電体の絶縁層)であってもよい。
絶縁導電体は、絶縁層で覆われた導電性コアを含む。導電性コアは、中実または撚り合わされたもの(例えば、ワイヤの束)であってもよい。いくつかの絶縁導電体はまた、半導電性層(複数可)および/または保護ジャケット(例えば、巻線、テープ、もしくはシース)などの1つ以上の追加の要素を含有し得る。例は、低電圧(「LV」、0キロボルト(kV)超5kV未満)、中電圧(「MV」、5〜69kV未満)、高電圧(「HV」、69〜230kV)、および超高電圧(「EHV」、230kV超)の送電/配電用途に使用するものを含む、被覆金属ワイヤおよび電力ケーブルである。電力ケーブルの評価では、規格および/またはIEC試験方法を使用することができる。
ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物の調製方法1。有機過酸化物(D)を含まないポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物の調製実施形態。ローター速度を最長4分間、毎分10回転(rpm)に設定して、ペレットとして成分(A)を140℃のBrabender内部ミキサーに供給する。得られた溶融物に、成分(B)および(C)を供給して、本質的に成分(A)、(B)、および(C)からなる第1の本発明のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物を得る。第1の本発明のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物に、いずれかの非過酸化物の任意選択の添加剤(E)〜(L)を添加し、140℃、45rpmで、4分間混合して、第2の本発明のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物を、(A)、(B)、(C)、および任意の(E)〜(L)の均一な分散物として得た。その第2の本発明のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物を用いてペレット調製方法1を進める。
架橋時間(T90)試験方法(MDR:180℃でML(N−m)、MDR:180℃でMH−ML(N−m)):ASTM D5289−12、ローターレス硬化計を使用したゴム特性加硫の標準試験方法。以下の手順を使用して、6グラムのコールドプレス試験試料のトルクを測定する。トルクの変化を監視しながら、0.5度のアーク振動で20分間、180℃で、可動ダイレオメーター(MDR)機器MDR2000(Alpha Technologies)内で、Brabender混合ボウルから直接得られた試験試料を加熱する。測定された最小トルク値をデシニュートンメートル(dN−m)で表される「ML」として指定する。硬化または架橋が進行すると、測定されたトルク値が増加し、最終的に最大トルク値に達する。最大または最高の測定トルク値をdN−mで表される「MH」として指定する。他のすべてが等しい場合、MHトルク値が大きいほど、架橋の程度が大きくなる。T90架橋時間を、MH引くMLの差(MH−ML)の90%、すなわちMLからMHの経路の90%に等しいトルク値を達成するのに必要な分数として決定する。T90架橋時間が短いほど、すなわちトルク値がMLからMHへの経路の90%になるのが早いほど、試験試料の硬化速度は速くなる。逆に、T90架橋時間が長いほど、すなわちトルク値がMLからMHへの経路の90%を得るのにかかる時間が長くなるほど、試験試料の硬化速度は遅くなる。ポンド−インチ(lb.−in.)で測定され、ニュートン−メートル(N−m)に変換され、1.00lb.−in.=0.113N−mである。
Claims (13)
- ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物であって、59.99〜99.94重量パーセント(重量%)の(A)オレフィン系(コ)ポリマー、0.05〜20.0重量%の(B)ポリ(2−アルキル−2−オキサゾリン)(コ)ポリマー、0.01〜1.5重量%の(C)酸化防止剤、および0.00〜3.0重量%の(D)有機過酸化物を含み、但し(A)の重量%=100.00重量%−(B)の重量%−(C)の重量%−(D)の重量%−存在する場合すべての他の任意選択の成分の重量%、である、配合物。
- 前記(A)オレフィン系(コ)ポリマーが、(i)エチレン系(コ)ポリマー、プロピレン系(コ)ポリマー、またはそれらの任意の2つ以上の組み合わせ、または(ii)ポリエチレンホモポリマー、エチレン/アルファ−オレフィンコポリマー、エチレン/不飽和カルボン酸エステルコポリマー、エチレン/オレフィン官能性加水分解性シランコポリマー、またはそれらの任意の2つ以上の組み合わせである、請求項1に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物。
- 前記(B)ポリ(2−アルキル−2−オキサゾリン)(コ)ポリマーが、ポリ(2−アルキル−2−オキサゾリン)ホモポリマー、ポリ(2−アルキル−2−オキサゾリン)コポリマー、またはそれらの任意の2つ以上の組み合わせである、請求項1または2に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物
- 前記(C)酸化防止剤が、ヒンダードフェノール、ホスファイト、ホスホナイト、チオ化合物、抗酸化アミン、またはそれらの任意の2つ以上の組み合わせである、請求項1〜3のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物。
- 前記ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物が、80.50〜99.70重量%の前記(A)オレフィン系(コ)ポリマーと、0.1〜15.0重量%の前記(B)ポリ(2−アルキル−2−オキサゾリン)(コ)ポリマーと、0.10〜1.5重量%の前記(C)酸化防止剤と、0.1〜3重量%の(D)有機過酸化物と、を含み、但し、前記配合物は帯電防止剤およびカーボンブラックを含んでいない、請求項1〜4のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物。
- 任意選択の添加剤(E)〜(L)、すなわち、(E)安定剤(例えば、紫外(UV)線に関連する分解を阻害する化合物)、(F)スコーチ遅延剤、(G)アルケニル官能性助剤、(H)核剤、(I)加工助剤、(J)エキステンダー油、(K)ナノ粒子、および(L)カーボンブラックから選択される少なくとも1つの添加剤をさらに含む、請求項1〜5のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物。
- (i)ASTM D6097を使用した水トリー成長試験方法に従って測定したときの水トリー長(WTL)の増加が10%未満であり、(ii)散逸率試験方法に従って測定したときの散逸率が0.30%未満であるか、または(i)および(ii)の両方であることを特徴とする、請求項1〜6のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物。
- 前記(A)オレフィン系(コ)ポリマーが、1−ブテン、1−ヘキセン、または1−オクテンから誘導されたコモノマー単位を含有する低密度ポリエチレンであり、前記(B)ポリ(2−アルキル−2−オキサゾリン)(コ)ポリマーが、1モルあたり10,000〜40,000グラムの重量平均分子量(Mw)を有するポリ(2−アルキル−2−オキサゾリン)ホモポリマーであり、前記(C)酸化防止剤が、ヒンダードフェノール、チオ化合物、またはヒンダードフェノールとチオ化合物との組み合わせであり、前記(D)有機過酸化物が、ジクミルペルオキシドである、成分(A)〜(D)および(E)安定剤を含む、請求項1〜7のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物。
- 請求項1〜8のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物を作製する方法であって、前記方法が、前記(B)ポリ(2−アルキル−2−オキサゾリン)(コ)ポリマーおよび(C)酸化防止剤を、前記(A)オレフィン系(コ)ポリマーの溶融物に混合して、成分(A)、(B)、および(C)を含む溶融ブレンドを得ることと、任意選択で、前記溶融ブレンドを押し出して、成分(A)、(B)、および(C)を含む押出物を得ることと、任意選択で、前記押出物をペレット化して、成分(A)、(B)、および(C)を含むペレットを得ることと、任意選択で、(D)有機過酸化物を、前記溶融ブレンド、前記押出物、または前記ペレットに添加して、前記ポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物を得ることと、を含む、方法。
- 請求項1〜8のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物を硬化させた生成物である、架橋ポリオレフィン生成物。
- 請求項1〜8のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物、請求項9に記載の方法によって作製されたポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物、または請求項10に記載の架橋ポリオレフィン生成物の成形形態を含む、製造物品。
- 導電性コアと、前記導電性コアを少なくとも部分的に被覆する絶縁層と、を含む絶縁導電体であって、前記絶縁層の少なくとも一部が、請求項1〜8のいずれか一項に記載のポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物、請求項9に記載の方法によって作製されたポリオレフィンとポリ(2−アルキル−2−オキサゾリン)との配合物、または請求項10に記載の架橋ポリエチレン生成物を含む、絶縁導電体。
- 電気を伝導する方法であって、前記方法が、請求項12に記載の絶縁導電体の前記導電性コア全体に電圧を印加して、前記導電性コアを通る電気の流れを発生させることを含む、方法。
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JP7209019B2 (ja) | 2023-01-19 |
TW202000772A (zh) | 2020-01-01 |
CN112166151A (zh) | 2021-01-01 |
CA3107125A1 (en) | 2020-01-02 |
KR20210027361A (ko) | 2021-03-10 |
US11939455B2 (en) | 2024-03-26 |
US20210221983A1 (en) | 2021-07-22 |
EP3814419A1 (en) | 2021-05-05 |
MX2020012820A (es) | 2021-02-16 |
TWI721458B (zh) | 2021-03-11 |
CN112166151B (zh) | 2023-09-08 |
WO2020000341A1 (en) | 2020-01-02 |
EP3814419A4 (en) | 2022-01-19 |
KR102628199B1 (ko) | 2024-01-24 |
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