JP2021522394A - 顆粒又は粉末及びその製造方法 - Google Patents
顆粒又は粉末及びその製造方法 Download PDFInfo
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- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 1
- WFACTXCBWPYESL-UHFFFAOYSA-N acetonitrile;4-methylmorpholine Chemical compound CC#N.CN1CCOCC1 WFACTXCBWPYESL-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910001508 alkali metal halide Inorganic materials 0.000 description 1
- 150000008045 alkali metal halides Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 150000001565 benzotriazoles Chemical class 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 108010005774 beta-Galactosidase Proteins 0.000 description 1
- 102000005936 beta-Galactosidase Human genes 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- BRXCDHOLJPJLLT-UHFFFAOYSA-N butane-2-sulfonic acid Chemical compound CCC(C)S(O)(=O)=O BRXCDHOLJPJLLT-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-O carboxymethyl-[3-(dodecanoylamino)propyl]-dimethylazanium Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC(O)=O MRUAUOIMASANKQ-UHFFFAOYSA-O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- VDQQXEISLMTGAB-UHFFFAOYSA-N chloramine T Chemical compound [Na+].CC1=CC=C(S(=O)(=O)[N-]Cl)C=C1 VDQQXEISLMTGAB-UHFFFAOYSA-N 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical group CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 1
- 229940073507 cocamidopropyl betaine Drugs 0.000 description 1
- 229940031728 cocamidopropylamine oxide Drugs 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- QUQFTIVBFKLPCL-UHFFFAOYSA-L copper;2-amino-3-[(2-amino-2-carboxylatoethyl)disulfanyl]propanoate Chemical compound [Cu+2].[O-]C(=O)C(N)CSSCC(N)C([O-])=O QUQFTIVBFKLPCL-UHFFFAOYSA-L 0.000 description 1
- 229940097362 cyclodextrins Drugs 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229920000359 diblock copolymer Polymers 0.000 description 1
- 229940042400 direct acting antivirals phosphonic acid derivative Drugs 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 108010093305 exopolygalacturonase Proteins 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229940029339 inulin Drugs 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- CPJRRXSHAYUTGL-UHFFFAOYSA-N isopentenyl alcohol Chemical compound CC(=C)CCO CPJRRXSHAYUTGL-UHFFFAOYSA-N 0.000 description 1
- 238000007561 laser diffraction method Methods 0.000 description 1
- 229940075468 lauramidopropyl betaine Drugs 0.000 description 1
- 229940048866 lauramine oxide Drugs 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- NNNSKJSUQWKSAM-UHFFFAOYSA-L magnesium;dichlorate Chemical compound [Mg+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O NNNSKJSUQWKSAM-UHFFFAOYSA-L 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 150000002772 monosaccharides Chemical class 0.000 description 1
- 229920006030 multiblock copolymer Polymers 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229960001639 penicillamine Drugs 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 229940127557 pharmaceutical product Drugs 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 150000003007 phosphonic acid derivatives Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000885 poly(2-vinylpyridine) Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- IFIDXBCRSWOUSB-UHFFFAOYSA-M potassium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate Chemical compound [K+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-M 0.000 description 1
- 238000004094 preconcentration Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
- POSICDHOUBKJKP-UHFFFAOYSA-N prop-2-enoxybenzene Chemical compound C=CCOC1=CC=CC=C1 POSICDHOUBKJKP-UHFFFAOYSA-N 0.000 description 1
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical compound CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- MSFGZHUJTJBYFA-UHFFFAOYSA-M sodium dichloroisocyanurate Chemical compound [Na+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O MSFGZHUJTJBYFA-UHFFFAOYSA-M 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 235000019351 sodium silicates Nutrition 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical class CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- ZTWTYVWXUKTLCP-UHFFFAOYSA-N vinylphosphonic acid Chemical compound OP(O)(=O)C=C ZTWTYVWXUKTLCP-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- SRWMQSFFRFWREA-UHFFFAOYSA-M zinc formate Chemical compound [Zn+2].[O-]C=O SRWMQSFFRFWREA-UHFFFAOYSA-M 0.000 description 1
- 239000011670 zinc gluconate Substances 0.000 description 1
- 235000011478 zinc gluconate Nutrition 0.000 description 1
- 229960000306 zinc gluconate Drugs 0.000 description 1
- 239000011576 zinc lactate Substances 0.000 description 1
- 235000000193 zinc lactate Nutrition 0.000 description 1
- 229940050168 zinc lactate Drugs 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/02—Preparation in the form of powder by spray drying
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents ; Methods for using cleaning compositions one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C11D2111/14—
Abstract
【選択図】なし
Description
(a)
(A)一般式(Ia)
[CH3-CH(COO)-N(CH2-COO)2]M3-xHx (Ia)
[式中、Mは、同じ又は異なるアルカリ金属陽イオン及びアンモニウムから選択され、xは、0.01から1.0までの範囲にある]、
又は(Ib)
[OOC-CH2CH2-CH(COO)-N(CH2-COO)2]M4-xHx (Ib)
[式中、Mは、上に定義された通りであり、式(Ib)中のxは、0.01から2.0までの範囲にある]
で表される少なくとも1種のキレート化剤と、
(B)少なくとも1種のポリマーであって、
(B1)平均分子量Mwが1,000から20,000g/モルの範囲にあるポリアスパルテート、並びに
(B2)コポリマー形態で
(α)エチレン性不飽和モノ又はジカルボン酸の少なくとも1種のエステル、及び
(β)少なくとも1種のエチレン性不飽和N含有モノマー
を含むコポリマー
から選択される少なくとも1種のポリマーと
の水溶液又は水性スラリーを用意するステップと、
(b)前記溶液又はスラリーを噴霧乾燥又は造粒するステップと
を含む方法に関する。
[CH3-CH(COO)-N(CH2-COO)2]M3-xHx (Ia)
[式中、Mは、同じ又は異なるアンモニウム及びアルカリ金属陽イオン、例えばリチウム、ナトリウム、カリウム、ルビジウム、セシウムの陽イオン、及び以上のうちの少なくとも2つの組合せから選択され、アンモニウムはアルキルで置換されていてもよいが、非置換アンモニウムNH4 +が好ましく、アルカリ金属陽イオンの好ましい例は、ナトリウム及びカリウム並びにナトリウム及びカリウムの組合せであり、一般式(Ia)で表される化合物において、全てのMが同じであり、それらが全てNaであることがさらに好ましく;
式(Ia)中のxは、0.01から1.0まで、好ましくは0.015から0.2の範囲にある]、
又は(Ib)
[OOC-CH2CH2-CH(COO)-N(CH2-COO)2]M4-xHx (Ib)
[式中、Mは、上に定義された通りであり、式(Ib)中のxは、0.01から2.0まで、好ましくは0.015から1.0の範囲にある]
で表される少なくとも1種のキレート化剤の水溶液又は水性スラリーを用意することを含む。
一般式(Ia)で表されるキレート化剤が好ましい。
(B1)平均分子量Mwが1,000から20,000g/モルの範囲にあるポリアスパルテート、並びに
(B2)コポリマー形態で
(α)以下コモノマー(α)とも称される、エチレン性不飽和モノ又はジカルボン酸の少なくとも1種のエステル、及び
(β)以下コモノマー(β)とも称される、少なくとも1種のエチレン性不飽和N含有モノマー
を含むコポリマー
から選択される。好ましいコモノマー(β)は、pH値とは独立した陽イオン性のコモノマーである、いわゆる永久陽イオン性電荷を有するエチレン性不飽和N含有モノマーである。
(1)アスパラギン酸の熱重縮合、及びそれに続く中間体ポリスクシンイミドのアルカリ加水分解;
(2)酸触媒、例えばリン酸、硫酸又はメタンスルホン酸の存在下でのアスパラギン酸の熱重縮合、及びそれに続く中間体ポリスクシンイミドのアルカリ加水分解;
(3)アンモニア又はアンモニウム塩の存在下での無水マレイン酸の重合、及びそれに続く中間体ポリスクシンイミドのアルカリ加水分解。
CH2=C(R1)-CO-O-R2
式中、R1は、水素及びメチルからであり、
R2は、
C1〜C4アルキル、例えばメチル、エチル、n-プロピル、イソプロピル、n-ブチル、イソブチル、sec-ブチル、及びtert-ブチル、並びに以上のうちの少なくとも2つの組合せから選択され、メチル及びエチル並びにその組合せが好ましく、C1〜C4アルキルはメチルであることがさらに好ましく、
2-ヒドロキシエチル及び3-ヒドロキシプロピル、並びに
(AO)yH又は(AO)y-C1〜C4アルキルであり、yは、1から100までの範囲にあり、AOは、同じ又は異なるC2〜C4アルキレンオキシドから選択され、好ましくはCH2-CH2-O、(CH2)3-O、(CH2)4-O、CH2CH(CH3)-O、CH(CH3)-CH2-O-及びCH2CH(n-C3H7)-Oから選択される。AOの最も好ましい例は、CH2-CH2-O(「EO」)である。
R1は、水素又はメチルであり、
Y1は、酸素又はN-Hであり、
A1は、C2〜C4アルキレン、例えば-CH2-CH2-、-(CH2)3-又は-(CH2)4-から選択される。CH2-CH2-及び-(CH2)3-が好ましい。
R2は、異なり又は好ましくは同じであり、ベンジル及びn-C1〜C4アルキル、例えばメチル、エチル、n-プロピル、又はn-ブチルから選択され、好ましくはそれらが同じで、全てメチルである。
X-は、ハロゲンイオン、例えばヨウ素イオン、臭素イオン、特に塩素イオンから、またモノC1〜C4アルキル硫酸イオン及び硫酸イオンから選択される。モノC1〜C4アルキル硫酸イオンの例は、メチル硫酸イオン、エチル硫酸イオン、イソプロピル硫酸イオン及びn-ブチル硫酸イオン、好ましくはメチル硫酸イオン及びエチル硫酸イオンである。X-が硫酸イオンとして選択される場合、X-は、2分の1当量の硫酸イオンである。
(A)一般式(Ia)で表される少なくとも1種のキレート化剤を含有する。
[CH3-CH(COO)-N(CH2-COO)2]M3-xHx (Ia)
式中、Mは、同じ又は異なるアルカリ金属陽イオン及びアンモニウム、例えばリチウム、ナトリウム、カリウム、ルビジウム、セシウムの陽イオン、及び以上のうちの少なくとも2つの組合せから選択され、アンモニウムはアルキルで置換されていてもよいが、非置換アンモニウムNH4 +が好ましく、アルカリ金属陽イオンの好ましい例は、ナトリウム及びカリウム並びにナトリウム及びカリウムの組合せであり、一般式(Ia)で表される化合物において、全てのMが同じであり、それらが全てNaであることがさらに好ましい。
[OOC-CH2CH2-CH(COO)-N(CH2-COO)2]M4-xHx (Ib)
式中、Mは、上に定義された通りであり、式(Ib)中のxは、0.01から2.0まで、好ましくは0.015から1.0の範囲にある。
(B)少なくとも1種のポリマーであって、
(B1)平均分子量Mwが1,000から20,000g/モルの範囲にあるポリアスパルテート、並びに
(B2)コポリマー形態で
(α)エチレン性不飽和モノ又はジカルボン酸の少なくとも1種のエステル、及び
(β)少なくとも1種のエチレン性不飽和N-含有モノマー
を含むコポリマー
から選択される少なくとも1種のポリマー
を含有する。
CH2=C(R1)-CO-O-R2
式中、R1は、水素及びメチルからであり、
R2は、
C1〜C4アルキル、例えばメチル、エチル、n-プロピル、イソプロピル、n-ブチル、イソブチル、sec-ブチル、及びtert-ブチル、並びに以上のうちの少なくとも2つの組合せから選択され、メチル及びエチル並びにその組合せが好ましく、C1〜C4アルキルはメチルであることがさらに好ましく、
2-ヒドロキシエチル及び3-ヒドロキシプロピル、並びに
(AO)yH又は(AO)y-C1〜C4アルキルであり、yは、1から100までの範囲であり、AOは、同じ又は異なるC2〜C4アルキレンオキシドから選択され、好ましくはCH2-CH2-O、(CH2)3-O、(CH2)4-O、CH2CH(CH3)-O、CH(CH3)-CH2-O-及びCH2CH(n-C3H7)-Oから選択される。AOの最も好ましい例は、CH2-CH2-O(「EO」)である。
R1は、水素又はメチルであり、
Y1は、酸素又はN-Hであり、
A1は、C2〜C4アルキレン、例えば-CH2-CH2-、-(CH2)3-又は-(CH2)4-から選択される。CH2-CH2-及び-(CH2)3-が好ましい。
R2は、異なり又は好ましくは同じであり、ベンジル及びn-C1〜C4アルキル、例えばメチル、エチル、n-プロピル、又はn-ブチルから選択され、好ましくはそれらが同じで、全てメチルである。
X-は、ハロゲンイオン、例えばヨウ素イオン、臭素イオン、特に塩素イオンから、またモノC1〜C4アルキル硫酸イオン及び硫酸イオンから選択される。モノC1〜C4アルキル硫酸イオンの例は、メチル硫酸イオン、エチル硫酸イオン、イソプロピル硫酸イオン及びn-ブチル硫酸イオン、好ましくはメチル硫酸イオン及びエチル硫酸イオンである。X-が硫酸イオンとして選択される場合、X-は、2分の1当量の硫酸イオンである。
R2は、同じ又は異なり、水素及び直鎖C1〜C10アルキルから選択され、好ましくはそれぞれの場合に同じであり、エチル、特に好ましくは、水素又はメチルであり、
R3は、分枝又は直鎖C8〜C22アルキル、例えば、n-C8H17、n-C10H21、n-C12H25、n-C14H29、n-C16H33、又はn-C18H37から選択され、
R4は、C1〜C10アルキル、メチル、エチル、n-プロピル、イソプロピル、n-ブチル、イソブチル、sec-ブチル、tert-ブチル、n-ペンチル、イソペンチル、sec-ペンチル、ネオペンチル、1,2-ジメチルプロピル、イソアミル、n-ヘキシル、イソヘキシル、sec-ヘキシル、n-ヘプチル、n-オクチル、2-エチルヘキシル、n-ノニル、n-デシル又はイソデシルから選択され、
変数e及びfは、eとfの合計が少なくとも1であり、0から300の範囲にあり、好ましくは3から50の範囲にある。好ましくは、eが1から100までの範囲にあり、fが0から30までの範囲にある。
R2は、同じ又は異なり、水素及び直鎖C1〜C4アルキルから選択され、好ましくはそれぞれの場合に同じであり、エチルであり、特に好ましくは水素又はメチルであり、
R5は、分枝又は直鎖C6〜C20アルキル、特にn-C8H17、n-C10H21、n-C12H25、n-C13H27、n-C15H31、n-C14H29、n-C16H33、n-C18H37から選択され、
aは、0から10、好ましくは1から6までの範囲にある数であり、
bは、1から80、好ましくは4から20までの範囲にある数であり、
dは、0から50、好ましくは4から25までの範囲にある数である。
R2は、同じ又は異なり、水素及び直鎖C1〜C10アルキルから選択され、好ましくはそれぞれの場合に同じであり、エチル、特に好ましくは水素又はメチルであり、
R3は、分枝又は直鎖C8〜C22アルキル、例えばイソ-C11H23、イソ-C13H27、n-C8H17、n-C10H21、n-C12H25、n-C14H29、n-C16H33又はn-C18H37から選択され、
R5は、C6〜C20アルキル、例えばn-ヘキシル、イソヘキシル、sec-ヘキシル、n-ヘプチル、n-オクチル、2-エチルヘキシル、n-ノニル、n-デシル、イソデシル、n-ドデシル、n-テトラデシル、n-ヘキサデシル、及びn-オクタデシルから選択される。
R6は、C1〜C4アルキル、特にエチル、n-プロピル、又はイソプロピルであり、
R7は、-(CH2)2-R6であり、
G1は、4個から6個の炭素原子を有する単糖、特にグルコース及びキシロースから選択され、
yは、1.1から4の範囲にあり、yは平均値である。
EOは、エチレンオキシド、CH2CH2-Oであり、
R8は、分枝又は直鎖C8〜C18アルキルから選択され、R5は、上記の通り定義されており、
A3Oは、プロピレンオキシド及びブチレンオキシドから選択され、
wは、15から70、好ましくは30から50の範囲にある数であり、
w1及びw3は、1から5の範囲にある数であり、
w2は、13から35の範囲にある数である。
R9R10R11N→O (IX)
式中、R9、R10、及びR11は、脂肪族、脂環式、又はC2〜C4アルキレンC10〜C20アルキルアミド部分からそれぞれ独立に選択される。好ましくは、R9は、C8〜C20アルキル又はC2〜C4アルキレンC10〜C20アルキルアミドから選択され、R10及びR11は共にメチルである。
5リットルの撹拌フラスコに、1,170gの脱イオン水を充填し、40℃まで加熱した。668.5gのL-アラニン(99.2重量%、7.44molを表し、98%を超えるeeを有する)を添加した。得られたスラリーに、390.0gの50重量%水酸化ナトリウム水溶液(4.88mol)を30分間にわたり添加した。添加中に、温度が60℃まで上昇した。水酸化ナトリウムの添加完了後、スラリーを60℃で30分間撹拌した。透明溶液を得た。
供給原料1: 69.1g(0.51モル)のメタクリル酸2-ヒドロキシエチル(α-1)
供給原料2: 402g(0.91モル)の(3-メタクリルアミドプロピル)トリメチルアンモニウムクロリド(β.1-1)(「MAPTAC」)の50重量%水溶液
供給原料3: 112gの2,2’-アゾビス(2-メチルプロピオンアミジン)の5重量%水溶液
噴霧造粒を、ラボ用造粒機(ジグザグ型空気分級機を付属したVario3インサートを備えるGlatt LabSystem)内で行った。
II.1.1 噴霧溶液SL.1の製造
容器に、14.63kgの(A.1)の40重量%水溶液及び507gのコポリマー(B2.1)の水溶液を充填した。そのようにして得られた溶液SL.1を撹拌し、50℃まで加熱し、次いで噴霧造粒を施した。
造粒機に、0.9kgの固体MGDA-Na3粒子(残留水分:12%)及び600gのMGDA-Na3の粉砕顆粒を充填した。顆粒は、ハンマミル(Kinetatica Polymix PX-MFL 90D)を4000rpm(1分当たりの回転速度)、2mmメッシュで使用して粉砕した。165から170℃の温度の空気を200Nm3/時間で底部から造粒機内に導入することにより、固体MGDA-Na3を流動化した。流動層内に底部から二流体ノズルを通して(パラメータ:霧化空気の絶対圧力:5bar)、6.2kg/時間のSL.1(溶液の温度:50℃)を噴霧することにより、SL.1を導入した。顆粒が形成され、流動層中の固形物の表面温度に対応する層温度は95から100℃であった。
II.2.1 比較噴霧溶液C-SL.2の製造
容器に、14.63kgのMGDA-Na3の40重量%水溶液及び507gのコポリマー(B2.1)の30重量%水溶液を充填した。そのようにして得られた溶液C-SL.2を撹拌し、50℃まで加熱し、次いで噴霧造粒を施した。
造粒機に、実施例II.1.2.の造粒の最後に造粒機に残存していた1.5kgの固体顆粒を充填した。165から170℃の温度の空気を200Nm3/時間で底部から造粒機内に導入することにより、固体MGDA-Na3を流動化した。流動層内に底部から二流体ノズルを通して(パラメータ:霧化空気の絶対圧力:5bar)、1時間あたり6.3kgのSL.2(溶液の温度:50℃)を噴霧することにより、上述の溶液SL.2を導入した。
造粒プロセスの開始後、実施例II.1.2のプロトコルに原則的に従ったが、溶液C-SL.2を使用した。比較顆粒Gr.2を得た。
好ましい自動皿洗い製剤の例は、表1に従って選択できる。
40%の有効成分MGDA及び2.5%の(B2.1)の有効成分ポリマーを含有する2種の100g溶液を作製した。
Claims (14)
- 顆粒又は粉末を製造する方法であって、
(a)
(A)一般式(Ia)
[CH3-CH(COO)-N(CH2-COO)2]M3-xHx (Ia)
[式中、Mは、同じ又は異なるアルカリ金属陽イオン及びアンモニウムから選択され、xは、0.01から1.0までの範囲にある]、
又は(Ib)
[OOC-CH2CH2-CH(COO)-N(CH2-COO)2]M4-xHx (Ib)
[式中、Mは、上に定義された通りであり、式(Ib)中のxは、0.01から2.0までの範囲にある]
で表される少なくとも1種のキレート化剤と、
(B)少なくとも1種のポリマーであって、
(B1)平均分子量Mwが1,000から20,000g/モルの範囲にあるポリアスパルテート、並びに
(B2)コポリマー形態で
(α)エチレン性不飽和モノ又はジカルボン酸の少なくとも1種のエステル、及び
(β)少なくとも1種のエチレン性不飽和N含有モノマー
を含むコポリマー
から選択される少なくとも1種のポリマーと
の水溶液又は水性スラリーを用意するステップと、
(b)前記溶液又はスラリーを噴霧乾燥又は造粒するステップと
を含む方法。 - ステップ(a)で用意される前記水性スラリー又は水溶液が、30から65重量%までの範囲の濃度のキレート化剤(A)を有する、請求項1に記載の方法。
- ステップ(b)が、流動層又は噴流層内で行われる、請求項1又は2に記載の方法。
- ステップ(b)において、ガス注入温度が少なくとも120℃である、請求項1から3のいずれか1項に記載の方法。
- ステップ(a)で用意される前記水性スラリー又は水溶液が、100:1から1:10の範囲のキレート化剤(A)とポリマー(B)との重量比を有する、請求項1から4のいずれか1項に記載の方法。
- 前記流動層中の粒子が、100から800μmまでの範囲の平均直径(D50)を有する、請求項1から5のいずれか1項に記載の方法。
- ステップ(b)において噴霧造粒を施される水性スラリーが、シリカ、ケイ酸塩、及びポリマー(B)以外の有機(コ)ポリマーから選択される少なくとも1種の添加剤をさらに含有する、請求項1から6のいずれか1項に記載の方法。
- ポリマー(B2)が、2,000から200,000g/モルまでの範囲の平均分子量Mwを有する、請求項1から7のいずれか1項に記載の方法。
- (A)一般式(Ia)
[CH3-CH(COO)-N(CH2-COO)2]M3-xHx (Ia)
[式中、Mは、同じ又は異なるアルカリ金属陽イオン及びアンモニウムから選択され、xは、0.01から1.0までの範囲にある]、
又は(Ib)
[OOC-CH2CH2-CH(COO)-N(CH2-COO)2]M4-xHx (Ib)
[式中、Mは、上に定義された通りであり、式(Ib)中のxは、0.01から2.0までの範囲にある]
で表される少なくとも1種のキレート化剤と、
(B)少なくとも1種のポリマーであって、
(B1)平均分子量Mwが1,000から20,000g/モルの範囲にあるポリアスパルテート、並びに
(B2)コポリマー形態で
(α)エチレン性不飽和モノ-又はジカルボン酸の少なくとも1種のエステル、及び
(β)少なくとも1種のエチレン性不飽和N含有モノマー
を含むコポリマー
から選択される少なくとも1種のポリマーと
を含有する、顆粒又は粉末。 - 250から1,250μmまでの範囲の平均直径(D50)を有する、請求項9に記載の顆粒。
- 5から100μmまでの範囲の平均直径(D50)を有する、請求項9に記載の粉末。
- ポリマー(B2)が、2,000から200,000g/モルまでの範囲の平均分子量Mwを有する、請求項9から11のいずれか1項に記載の粉末又は顆粒。
- 硬質表面洗浄剤又は洗濯洗剤の製造のための、請求項9から10若しくは12のいずれか1項に記載の顆粒、又は請求項9若しくは11から12のいずれか1項に記載の粉末の使用。
- 前記硬質表面洗浄剤が、自動皿洗い洗剤である、請求項13に記載の使用。
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US20120004147A1 (en) * | 2008-12-29 | 2012-01-05 | Akzo Nobel N.V. | Coated particles of a chelating agent |
JP2017505854A (ja) * | 2014-02-13 | 2017-02-23 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 粉末及び顆粒、この粉末及び顆粒の製造方法、並びに、その使用方法 |
EP3138895A1 (de) * | 2015-09-02 | 2017-03-08 | Basf Se | Partikel, ihre verwendung als oder zur herstellung von geschirrspülmitteln und ihre herstellung |
WO2017220308A1 (en) * | 2016-06-20 | 2017-12-28 | Basf Se | Powders and granules and process for making such powders and granules |
US20180010072A1 (en) * | 2016-07-08 | 2018-01-11 | The Procter & Gamble Company | Process for making a particle |
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EP0678572A1 (en) * | 1994-04-20 | 1995-10-25 | The Procter & Gamble Company | Detergent powder compositions |
US5837663A (en) | 1996-12-23 | 1998-11-17 | Lever Brothers Company, Division Of Conopco, Inc. | Machine dishwashing tablets containing a peracid |
DE19819187A1 (de) | 1998-04-30 | 1999-11-11 | Henkel Kgaa | Festes maschinelles Geschirrspülmittel mit Phosphat und kristallinen schichtförmigen Silikaten |
DE102005047833A1 (de) * | 2005-10-05 | 2007-04-19 | Basf Ag | Verfahren zur Herstellung von granulären oder pulverförmigen Waschmittelzusammensetzungen |
EP1803801A1 (de) * | 2006-01-03 | 2007-07-04 | Basf Aktiengesellschaft | Mischpulver oder Mischgranulat auf Basis von Glutaminsäure-N,N-diessigsäure und ihren Salzen |
EP2399981A1 (en) * | 2010-06-28 | 2011-12-28 | Akzo Nobel Chemicals International B.V. | Particles of a glumatic acid N,N-diacetate chelating agent coated with poly vinyl alcohol PVOH |
KR101884618B1 (ko) * | 2011-10-19 | 2018-08-02 | 바스프 에스이 | 제형, 식기세척 세제로서의 또는 이를 제조하기 위한 이의 용도, 및 이의 제조 |
US10519097B2 (en) | 2015-05-13 | 2019-12-31 | Basf Se | Process for making mixtures of chelating agents |
KR20180027490A (ko) * | 2015-07-09 | 2018-03-14 | 바스프 에스이 | 식기 세척 방법 |
EP3467085A1 (en) * | 2017-10-05 | 2019-04-10 | The Procter & Gamble Company | Dishwashing cleaning composition |
ES2914836T3 (es) * | 2018-02-23 | 2022-06-16 | Unilever Ip Holdings B V | Composiciones sólidas que comprenden aminopolicarboxilato |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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US20120004147A1 (en) * | 2008-12-29 | 2012-01-05 | Akzo Nobel N.V. | Coated particles of a chelating agent |
JP2017505854A (ja) * | 2014-02-13 | 2017-02-23 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 粉末及び顆粒、この粉末及び顆粒の製造方法、並びに、その使用方法 |
EP3138895A1 (de) * | 2015-09-02 | 2017-03-08 | Basf Se | Partikel, ihre verwendung als oder zur herstellung von geschirrspülmitteln und ihre herstellung |
WO2017220308A1 (en) * | 2016-06-20 | 2017-12-28 | Basf Se | Powders and granules and process for making such powders and granules |
US20180010072A1 (en) * | 2016-07-08 | 2018-01-11 | The Procter & Gamble Company | Process for making a particle |
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WO2019211170A8 (en) | 2020-01-16 |
WO2019211170A1 (en) | 2019-11-07 |
BR112020021865A2 (pt) | 2021-01-26 |
BR112020021865B1 (pt) | 2023-03-14 |
EP3788128B1 (en) | 2024-04-24 |
US20210179978A1 (en) | 2021-06-17 |
JP2024023351A (ja) | 2024-02-21 |
EP3788128A1 (en) | 2021-03-10 |
CN112074593B (zh) | 2022-08-30 |
CN112074593A (zh) | 2020-12-11 |
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