JP2021167366A - Method of manufacturing glue - Google Patents

Method of manufacturing glue Download PDF

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JP2021167366A
JP2021167366A JP2020070231A JP2020070231A JP2021167366A JP 2021167366 A JP2021167366 A JP 2021167366A JP 2020070231 A JP2020070231 A JP 2020070231A JP 2020070231 A JP2020070231 A JP 2020070231A JP 2021167366 A JP2021167366 A JP 2021167366A
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glue
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shaved
skin
hair
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JP7216429B2 (en
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健太郎 宇▲高▼
Kentaro Udaka
典子 早川
Noriko Hayakawa
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National Institutes for Cultural Heritage
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Abstract

To provide a method of manufacturing glue which is light-colored glue of high purity more stably with a smaller workload although the method is based upon classic glue before recent times which uses no agent.SOLUTION: There is provided a method of manufacturing glue from rawhide which consists of subcutaneous tissue, a cutis layer and an epidermal layer, and has many hairs grown from the epidermal layer, and the method has the processes of: fleshing the reverse surface of the rawhide to remove the subcutaneous tissue; shaving the hairs grown on the top surface of the rawhide; performing a heat treatment to apply hot water or steam to the top surface of the shaved hide to harden and make brittle the epidermal layer; removing the epidermal layer and hairs from the top surface of the shaved hide after the heat treatment; and extracting glue from the obtained processed hide consisting of the cutis layer with hot water.SELECTED DRAWING: Figure 1

Description

本発明は、膠の製造方法に関する。 The present invention relates to a method for producing glue.

膠は動物の皮や骨、角などから作られる伝統的材料であり、古来書画や工芸の制作及び修復などに広く活用されてきた。主成分はゼラチンというタンパク質であり、その他に原料や抽出溶媒などに由来する油脂や灰分などの不純物を若干量含んでいる。 Glue is a traditional material made from animal skins, bones, and horns, and has been widely used in the production and restoration of ancient calligraphy and crafts. The main component is a protein called gelatin, which also contains a small amount of impurities such as fats and oils and ash derived from raw materials and extraction solvents.

膠は基本的に、水を加えて溶解され液状(ゾル状態)で用いられる。伝統的東洋絵画や日本画の制作において膠は、まず顔料を水にとくにあたって分散剤(界面活性剤)として作用する。次いで乾燥や低温化が進むに従い、分子間の結合が進んでゼリー状に凝固(ゲル化)し、紙や布帛などの基底材上に顔料を保持する仮止め剤として作用する。そして最終的な乾燥後の絵具層においては顔料を基底材に固定する接着剤として作用する。 Glue is basically dissolved by adding water and used in a liquid state (sol state). In the production of traditional oriental paintings and Japanese paintings, glue first acts as a dispersant (surfactant) when the pigment is dissolved in water. Then, as drying and lowering the temperature progress, the bonds between the molecules proceed and solidify (gel) into a jelly, which acts as a temporary fixing agent for holding the pigment on a base material such as paper or cloth. Then, in the final dried paint layer, it acts as an adhesive for fixing the pigment to the base material.

原皮(毛付きの牛生皮)の一例を図1に示す。図1に示す原皮は、皮下組織と、真皮層と、表皮層とからなり、表皮層から多数の毛が生えており、それらの毛の毛根は、真皮層の中間部まで達している。真皮層は、「コラーゲン」という線維状のタンパク質がその大部分を占めており、加熱によりこれが分解され、主にゼラチンからなる膠を生じる。表皮層及び毛は、「ケラチン」という線維状のタンパク質を主成分とし、コラーゲンとは分解される条件が異なる。表皮層や毛には暗色の垢や泥などが付着している場合が多く、水による洗浄のみでこれを充分に除去することは大きい作業量を要し、また困難である。また毛や表皮層はそれら自体が暗色である場合が多い。したがって、これらに由来する成分が混入した場合には、膠の暗色化が生じる。そのため、明色な膠を安定的かつ効率的に得るためには、皮下組織、表皮層及び毛を全て除去して、真皮層のみを残すことが有効である。 An example of rawhide (cow rawhide with hair) is shown in FIG. The raw skin shown in FIG. 1 is composed of a subcutaneous tissue, a dermis layer, and an epidermis layer, and a large number of hairs grow from the epidermis layer, and the hair roots of these hairs reach the middle part of the dermis layer. The dermis layer is dominated by a fibrous protein called "collagen," which is broken down by heating to produce glue, mainly composed of gelatin. The epidermis layer and hair are mainly composed of a fibrous protein called "keratin", and the conditions under which they are decomposed are different from those of collagen. Dark-colored dirt and mud are often attached to the epidermis layer and hair, and it is difficult and requires a large amount of work to sufficiently remove them only by washing with water. In addition, the hair and epidermis layer are often dark in themselves. Therefore, when the components derived from these are mixed, the glue is darkened. Therefore, in order to obtain bright glue stably and efficiently, it is effective to remove all the subcutaneous tissue, the epidermis layer and the hair, leaving only the dermis layer.

膠は、洋膠、和膠、古典的膠に大別される。洋膠は一般に、主にクロム鞣し革屑を原料として、石灰浸漬、硫酸浸漬による脱クロム、さらに石灰添加などを経て熱水中で抽出され、強度の濾過処理や減圧濃縮の後、凝固や乾燥などを経て作られる。これに対して和膠は一般に、石灰処理などによって脱毛された未鞣しの皮を原料とし、また抽出後の濾過処理が軽度であるなどの点で洋膠と異なり、近年日本画制作などにおいて広く使用されている。しかし、その原皮の脱毛や抽出前処理は、石灰や硫化化合物を用いた西洋由来の近代的手法が主体となっており、また抽出後に適宜消泡剤や防腐剤、漂白剤などが加えられるなど、近代以前の膠とは原料も製法も大きく変化している。 Glue is roughly divided into Western glue, Japanese glue, and classical glue. In general, samak is mainly made from chrome tanned leather scraps, dechromized by lime immersion, sulfuric acid immersion, and further lime addition, and then extracted in hot water. After intense filtration and vacuum concentration, coagulation and drying are performed. It is made through such things. On the other hand, Japanese glue is generally made from untanned skin that has been depilated by lime treatment, and is different from Western glue in that it is lightly filtered after extraction. in use. However, the hair removal and pre-extraction treatment of the raw hide is mainly based on modern Western-derived methods using lime and sulfide compounds, and defoamers, preservatives, bleaching agents, etc. are added as appropriate after extraction. , The raw materials and manufacturing method have changed significantly from the pre-modern glue.

古典的膠は近代以前の方法に依拠した材料であり、原皮裏面のフレッシング(皮下組織についての切除等除去)の後、川晒し(川漬け)によって脱毛された(毛を抜いた)川晒し脱毛皮や、物理的に剃毛された(毛を刈り取られた)剃毛皮、または鹿角や魚鱗などを原料として、水などによる洗浄の後、熱水中で抽出される。すなわち、近代以後の製法と異なり、原料の除毛等下処理や抽出前後の各工程において石灰や酸その他薬剤が使用されていない。またそのため、ゼラチン中のアミノ酸残基アスパラギンやグルタミンにおける側鎖の置換が比較的軽度で、中性から弱酸性域の等イオン点を示すものが多い。これらのうち、特に牛剃毛生皮原料からは乾燥状態で明色かつ不光沢となる古典的膠を得ることが可能である。またそうした特性を備えた古典的膠は、書画制作や修復などに使用した際に顔料の発色担保にも効果的である。 Classical glue is a material that relies on pre-modern methods, and after freshening the underside of the raw skin (removal of the subcutaneous tissue, etc.), the hair was removed by river bleaching (river pickling). The skin, physically shaved (hair-cut) shaved fur, deer horns, fish scales, etc. are used as raw materials, washed with water, etc., and then extracted in hot water. That is, unlike the manufacturing method after modern times, lime, acid and other chemicals are not used in each process before and after pretreatment such as hair removal of raw materials and extraction. Therefore, the substitution of side chains in the amino acid residues asparagine and glutamine in gelatin is relatively mild, and many of them exhibit isoionic points in the neutral to weakly acidic range. Of these, it is possible to obtain a classic glue that becomes light-colored and matte in the dry state, especially from the rawhide rawhide for cow shaving. In addition, classical glue with such characteristics is also effective in ensuring the color development of pigments when used for calligraphic works and restoration.

しかしフレッシングと剃毛のみによって原料を処理した従来の古典的膠では、時折偶発的に、製造工程において毛や表皮層に由来する泥垢や微細な組織屑など暗色の成分が膠に混入し製品の暗色化が起きるという問題があった。従来の剃毛や水による洗浄のみでは原料処理に大きな作業量を要し、また膠の暗色化を時折偶発的に引き起こす原因部位である毛や表皮層を充分に除去することが極めて困難であった。 However, with traditional classical glue, which is made from raw materials only by freshening and shaving, the glue occasionally accidentally mixes dark components such as dirt and fine tissue debris from the hair and epidermal layers into the glue. There was a problem that darkening occurred. Conventional shaving and washing with water alone require a large amount of work to process the raw materials, and it is extremely difficult to sufficiently remove the hair and epidermis layer, which are the causative sites that occasionally cause the glue to darken accidentally. rice field.

従って本発明の目的は、薬剤を使用しない近代以前の古典的膠の製法に基づきながら、より小さい作業量でまたより安定的に純度の高い明色な膠を製造する方法を提供することである。 Therefore, an object of the present invention is to provide a method for producing a light-colored glue having a higher purity and with a smaller amount of work, while being based on a pre-modern classical glue manufacturing method that does not use a drug. ..

上記課題に鑑み鋭意研究の結果、本発明者らは、原皮の表面に生えている毛を剃毛した後、その表面に熱水を当てる熱処理を行なって表皮層を硬化・脆弱化させ、熱処理した表面から表皮層と毛を除去することにより、小さい作業量で安定的に明色な膠を製造することができることを発見し、本発明に想到した。 As a result of diligent research in view of the above problems, the present inventors shave the hair growing on the surface of the raw skin, and then perform a heat treatment of applying hot water to the surface to harden and weaken the epidermis layer, and heat-treat the hair. By removing the epidermis layer and hair from the surface, it was discovered that a light-colored glue can be stably produced with a small amount of work, and the present invention was conceived.

本発明の膠の製造方法は、皮下組織と、真皮層と、表皮層とからなり、表皮層から多数の毛が生えている原皮から膠を製造する方法であって、原皮の裏面をフレッシングして皮下組織を除去する工程と、原皮の表面に生えている毛を剃毛する工程と、得られた剃毛皮の表面に熱水を当てる熱処理を行なって表皮層を硬化・脆弱化させ、熱処理した剃毛皮の表面から表皮層と毛を除去する工程と、得られた真皮層からなる加工皮から膠を熱水により抽出する工程とを有することを特徴とする。 The method for producing glue of the present invention is a method for producing glue from a raw skin which is composed of a subcutaneous tissue, a dermis layer, and an epidermis layer and has many hairs growing from the epidermis layer, and freshens the back surface of the raw skin. The process of removing the subcutaneous tissue, the process of shaving the hair growing on the surface of the dermis, and the heat treatment of applying hot water to the surface of the obtained dermis are performed to harden and weaken the epidermis layer, and the heat treatment is performed. It is characterized by having a step of removing the epidermis layer and hair from the surface of the shaved fur, and a step of extracting glue from the processed dermis composed of the obtained dermis layer with hot water.

前記熱処理工程において、前記剃毛皮の表面に水を供給した後、その上に熱鏝を当てて前記水を加熱させるのが好ましい。 In the heat treatment step, it is preferable to supply water to the surface of the shaved fur and then apply a hot trowel on the water to heat the water.

前記熱処理工程における熱水の温度が50 〜 150 ℃であるのが好ましい。 The temperature of hot water in the heat treatment step is preferably 50 to 150 ° C.

前記剃毛工程において、前記原皮の表面に短く刈り取られた毛が残留するように剃毛するのが好ましい。 In the shaving step, it is preferable to shave so that shortly cut hair remains on the surface of the raw skin.

前記除去工程を高圧水洗浄により行なうのが好ましい。 It is preferable that the removal step is performed by high-pressure water washing.

得られた加工皮の表裏両面をフレッシングする工程をさらに有するのが好ましい。 It is preferable to further have a step of freshening both the front and back surfaces of the obtained processed leather.

得られた加工皮を洗浄した後に前記抽出工程を行なうのが好ましい。 It is preferable to carry out the extraction step after washing the obtained processed skin.

本発明によれば、薬剤を使用しない近代以前の古典的膠の製法に基づきながら、小さい作業量で安定的に明色な膠を製造することができる。 According to the present invention, it is possible to stably produce bright-colored glue with a small amount of work, based on the pre-modern classical glue manufacturing method that does not use chemicals.

原皮の一例を示す概略図である。It is the schematic which shows an example of the raw skin. 皮下組織を除去した原皮を示す概略図である。It is the schematic which shows the raw skin which removed the subcutaneous tissue. 剃毛した原皮を示す概略図である。It is the schematic which shows the shaved raw skin. 剃毛皮の熱処理の一例を示す概略図である。It is the schematic which shows an example of the heat treatment of a shaved fur. 熱処理後の剃毛皮を示す概略図である。It is the schematic which shows the shaved fur after heat treatment. 高圧水洗浄後の加工皮を示す概略図である。It is the schematic which shows the processed skin after washing with high pressure water. 実施例2で製造した膠を示す写真である。It is a photograph which shows the glue produced in Example 2.

本発明の一実施態様による製造方法は、(1) 原皮として毛付きの牛生皮を使用し、(2) 原皮を洗浄し、(3) 原皮の外縁及び末端部位を切除し、(4) 原皮の裏面をフレッシングし、(5) 原皮の表面を剃毛し、(6) 剃毛した原皮を洗浄し、(7) 得られた剃毛皮の表面に熱処理を施し、(8) 熱処理した剃毛皮の表面を高圧水洗浄して表皮層と毛根を除去し、(9) 得られた加工皮の表裏両面をフレッシングして残留組織屑等を除去し、(10) 加工皮を洗浄し、(11) 加工皮から膠を熱水により抽出する工程を有する。各工程について、図1に示す原皮を参照して以下詳細に説明する。 In the production method according to one embodiment of the present invention, (1) raw cowhide with hair is used as the raw hide, (2) the raw hide is washed, (3) the outer edge and the terminal portion of the raw hide are excised, and (4) the raw hide. The back side of the fur is freshened, (5) the surface of the raw skin is shaved, (6) the shaved raw skin is washed, (7) the surface of the obtained shaved fur is heat-treated, and (8) the heat-treated shaved fur is treated. The surface of the skin was washed with high-pressure water to remove the epidermis layer and hair roots. ) It has a process of extracting glue from processed skin with hot water. Each step will be described in detail below with reference to the raw hide shown in FIG.

(1) 原皮
原皮としては、膠の原料となる真皮層が多くあり、流通量が多く入手が容易な牛の生皮が好ましい。しかし、本発明の製造方法に用いる原皮は、これに限らず、猪、鹿、兎等の、膠の原料として使用されるその他の動物種の皮を用いても良い。
(1) Rawhide As the rawhide, there is a large amount of dermis layer, which is a raw material for glue, and a rawhide of cattle, which has a large amount of distribution and is easily available, is preferable. However, the raw skin used in the production method of the present invention is not limited to this, and skins of other animal species used as raw materials for glue, such as wild boar, deer, and rabbit, may be used.

(2) 洗浄
原皮を洗浄しても良い。原皮の洗浄方法は、原皮と水を皮革用ドラム(回転撹拌器)に入れ、撹拌して洗浄することが挙げられる。牛原皮の表裏面や毛の間にゴミや汚れが付着している場合があり、洗浄により除去するのが望ましい。
(2) Washing The raw skin may be washed. Examples of the method for cleaning the raw leather include putting the raw leather and water in a leather drum (rotary stirrer) and stirring the raw leather for cleaning. Dirt and dirt may adhere to the front and back surfaces of the cow hide and between the hairs, and it is desirable to remove it by washing.

(3) 切除
原皮に尻尾、脚及び腹の部分が付いている場合は、尻尾、脚及び腹は切除しても良い。膠の原料となる真皮層は原皮の後背部分が最も厚く、安定的かつ効率的に明色な膠を得るためには、原皮の後背部分以外の部分を切除するのが望ましい。
(3) Excision If the raw skin has a tail, legs and abdomen, the tail, legs and abdomen may be excised. The dermis layer, which is the raw material of glue, has the thickest back part of the dermis, and it is desirable to excise the part other than the back part of the dermis in order to obtain a stable and efficient bright-colored glue.

(4) フレッシング
原皮の裏面をフレッシングする。「フレッシング」とは、剥皮のときに皮の肉面に残存した皮下結合組織、脂肪、肉等(図1の皮下組織に相当する。)を除去することである。それにより、図2に示すように、裏面の表面から皮下組織が除去される。フレッシングは、一般に用いられる方法で行なうことができ、フレッシングマシン(皮の肉面から皮下組織等を削りとるため皮革加工において一般に用いられる機械)や、刃物を用いることができる。
(4) Freshing Fresh the back side of the raw leather. “Freshing” is to remove subcutaneous connective tissue, fat, meat, etc. (corresponding to the subcutaneous tissue in FIG. 1) remaining on the flesh surface of the skin at the time of peeling. As a result, as shown in FIG. 2, the subcutaneous tissue is removed from the front surface of the back surface. The freshing can be performed by a commonly used method, and a freshing machine (a machine generally used in leather processing for scraping the subcutaneous tissue or the like from the flesh surface of the skin) or a knife can be used.

(5) 剃毛
原皮の表面(表皮層の表面)から生えている多数の毛を剃る。剃毛する方法は特に限定されないが、フレッシングマシンや刃物、あるいはバリカン等の理容器具を用いるのが好ましい。図3に示すように、毛が表皮層の表面からごく短く(例えば、0.5 〜10 mm程度)残すように剃毛するのが望ましい。それにより、後述する熱処理を効果的かつ安定的に行なうことができる。
(5) Shaving A large number of hairs growing from the surface of the raw skin (the surface of the epidermis layer) are shaved. The method of shaving is not particularly limited, but it is preferable to use a freshening machine, a knife, or a hair clipper or the like. As shown in FIG. 3, it is desirable to shave the hair so that it remains very short (for example, about 0.5 to 10 mm) from the surface of the epidermal layer. As a result, the heat treatment described later can be effectively and stably performed.

(6) 洗浄
剃り落とした毛等を除去するために、剃毛した原皮(剃毛皮)を再び洗浄しても良い。洗浄方法は、流水を用いて皮を洗浄する方法が挙げられる。
(6) Washing The shaved raw skin (shaved fur) may be washed again in order to remove the shaved hair and the like. Examples of the washing method include a method of washing the skin with running water.

(7) 熱処理
剃毛皮の表面に熱水を当てる熱処理を施す。剃毛皮の表面に熱水を当てることにより、表皮層のケラチン等のタンパク質が熱で変性して凝固・脆弱化等する。剃毛皮の表面にのみ熱水を当てることにより、剃毛皮の表皮層を選択的に熱変性させることができる。すなわち、表皮層が熱変性により硬化・脆弱化する一方、表皮層の下の真皮層は生で柔らかいままとなる。そのため、硬化・脆弱化した表皮層は後述する高圧水洗浄により破壊・除去することが容易となるが、表皮層の下の真皮層は破砕が困難なままである。それにより、高圧水洗浄により硬化・脆弱化した表皮層のみを破壊・除去することが可能となる。
(7) Heat treatment Heat treatment is performed by applying hot water to the surface of the shaved fur. When hot water is applied to the surface of the shaved fur, proteins such as keratin in the epidermis layer are denatured by heat to coagulate and weaken. By applying hot water only to the surface of the shaved fur, the epidermal layer of the shaved fur can be selectively heat-denatured. That is, while the epidermis layer is hardened and weakened by heat denaturation, the dermis layer below the epidermis layer remains raw and soft. Therefore, the hardened / fragile epidermis layer can be easily destroyed / removed by high-pressure water washing described later, but the dermis layer below the epidermis layer remains difficult to crush. As a result, it is possible to destroy / remove only the epidermis layer that has been hardened / fragile by high-pressure water washing.

図1に示すように、真皮層の表皮層側の部分に毛根組織を有し、それらの毛根から毛が伸びており、表皮層を貫いて皮表面に毛が生えている。表皮層を破壊・除去することにより、毛根組織を含めた毛全体の露出部分が増えるため、高圧水洗浄により剃毛皮の表面の毛を毛根組織も含めて除去することが容易になる。従って、熱処理により表皮層を硬化・脆弱化させることにより、真皮層を残しつつ、表皮層と毛根組織を含めた毛を除去することができる。 As shown in FIG. 1, it has hair root tissue in the portion of the dermis layer on the epidermis layer side, hair grows from those hair roots, and hair grows on the skin surface through the epidermis layer. By destroying and removing the epidermis layer, the exposed portion of the entire hair including the hair root tissue increases, so that it becomes easy to remove the hair on the surface of the shaved fur including the hair root tissue by high-pressure water washing. Therefore, by hardening and weakening the epidermis layer by heat treatment, it is possible to remove the hair including the epidermis layer and the hair root tissue while leaving the dermis layer.

熱処理による皮表面からどの程度の深さまで硬化・脆弱化するかは、皮表面に当てる熱水の温度や、熱水を当てる時間によって適宜調節することができる。すなわち、熱処理が不十分であると、表皮層が十分に硬化・脆弱化しないため、高圧水洗浄により表皮層や毛が除去しきれず、残存してしまう。また熱処理が過度であると、表皮層の下の真皮層まで硬化・脆弱化するため、高圧水洗浄により真皮層の表皮層に近い部分まで削れてしまう。高圧水洗浄により真皮層の一部が除去されたとしても、表皮層や毛が残存するよりは望ましく、熱処理は、真皮層の表皮層の近くの部分が硬化・脆弱化するまで行なっても良い。 The depth of hardening and fragility from the skin surface due to heat treatment can be appropriately adjusted by the temperature of the hot water applied to the skin surface and the time of application of the hot water. That is, if the heat treatment is insufficient, the epidermis layer is not sufficiently hardened and weakened, so that the epidermis layer and hair cannot be completely removed by high-pressure water washing and remain. Further, if the heat treatment is excessive, the dermis layer below the epidermis layer is hardened and weakened, so that the portion of the dermis layer close to the epidermis layer is scraped by high-pressure water washing. Even if a part of the dermis layer is removed by high-pressure water washing, it is preferable that the epidermis layer and hair remain, and the heat treatment may be performed until the portion of the dermis layer near the epidermis layer is hardened and weakened. ..

熱水の温度は50 〜 150 ℃程度であるのが好ましい。熱水の温度がこの範囲内であれば、適切な時間熱処理を行なうことにより、真皮層内部まで熱変性が進むことなく、剃毛皮の表面の表皮層を熱変性させることができる。熱水の温度は80 〜 120 ℃程度であるのがより好ましい。 The temperature of hot water is preferably about 50 to 150 ° C. When the temperature of the hot water is within this range, the epidermis layer on the surface of the shaved fur can be heat-denatured without the heat denaturation proceeding to the inside of the dermis layer by performing the heat treatment for an appropriate time. The temperature of hot water is more preferably about 80 to 120 ° C.

熱処理の時間は、熱水の温度と原皮の種類や高圧水洗浄の水温によって適宜設定するものである。熱水の温度が100 ℃程度であるときは、高圧水洗浄の水温が20 ℃程度では熱処理の時間は40 〜 150 秒であるのが好ましく、高圧水洗浄の水温が10 ℃程度では熱処理の時間は50 〜 180 秒であるのが好ましい。熱処理の時間がこの範囲であれば、剃毛皮の表面の表皮層のみを適切に熱変性させることができる。 The heat treatment time is appropriately set according to the temperature of hot water, the type of raw skin, and the water temperature of high-pressure water washing. When the temperature of hot water is about 100 ° C, the heat treatment time is preferably 40 to 150 seconds when the water temperature of high-pressure water washing is about 20 ° C, and the heat treatment time when the water temperature of high-pressure water washing is about 10 ° C. Is preferably 50 to 180 seconds. If the heat treatment time is within this range, only the epidermal layer on the surface of the shaved fur can be appropriately heat-denatured.

熱水を当てる方法としては、熱水を剃毛皮の表面に直接当てても良いが、剃毛皮の表面に水を供給した後、水を加熱して熱水にしても良い。その際、加熱した水が一部水蒸気になっていても良い。加熱方法としては、図4に示すように、供給した水に熱鏝を当てて加熱させる方法が挙げられる。短く剃り残された多数の毛の間に適量の水が含まれた状態にした上で、熱鏝を当てることにより、毛中に含まれる水が熱せられ、またその一部は蒸気化する。 As a method of applying hot water, hot water may be applied directly to the surface of the shaved fur, but after supplying water to the surface of the shaved fur, the water may be heated to make hot water. At that time, the heated water may be partially turned into steam. As a heating method, as shown in FIG. 4, a method of applying a hot trowel to the supplied water to heat it can be mentioned. A proper amount of water is contained between a large number of hairs left unshaved, and then a hot trowel is applied to heat the water contained in the hairs, and a part of the hairs is vaporized.

(8) 高圧水洗浄
熱処理した剃毛皮の表面を高圧水洗浄して表皮層と毛根を除去する。「高圧水洗浄」とは、高圧水洗浄器を用いて高圧の水を吹き付けることにより、その衝撃力により表面の付着物を粉砕剥離することを言う。熱処理した剃毛皮は、図5に示すように、表皮層が硬化・脆弱化している。そのため、図6に示すように、高圧水洗浄により毛根組織を含む表皮層を破壊・除去することができる。
(8) High-pressure water washing The surface of the heat-treated shaved fur is washed with high-pressure water to remove the epidermis layer and hair roots. "High-pressure water cleaning" means that by spraying high-pressure water using a high-pressure water washer, the deposits on the surface are crushed and peeled off by the impact force. As shown in FIG. 5, the skin layer of the heat-treated shaved fur is hardened and weakened. Therefore, as shown in FIG. 6, the epidermis layer including the hair root tissue can be destroyed and removed by high-pressure water washing.

高圧水洗浄の水温は特に限定されず、常温の水を用いることができる。皮の腐敗等の劣化を抑制することを考慮すると、低温であることが望ましく、1〜 10 ℃程度であるのが好ましい。また環境温度等に応じて、熱処理の時間等を適宜調節し得る。 The water temperature for high-pressure water washing is not particularly limited, and normal temperature water can be used. Considering the suppression of deterioration such as putrefaction of the skin, it is desirable that the temperature is low, and the temperature is preferably about 1 to 10 ° C. Further, the heat treatment time and the like can be appropriately adjusted according to the environmental temperature and the like.

このように本発明では、剃毛皮の表面に熱水を当てる熱処理を施しているので、剃毛皮の表面を高圧水洗浄することにより毛根組織までも含めて表皮層を除去するという画期的な技術的効果が得られる。従来の古典的膠の製法では除毛後の洗浄処理に大きな作業量を要していたが、本発明の方法では、高圧水洗浄で毛根組織までも除去できるため、作業時間も大幅に抑え、また製品汚濁因子を大幅に低減することができる。 As described above, in the present invention, since the surface of the shaved fur is heat-treated by applying hot water, the surface of the shaved fur is washed with high-pressure water to remove the epidermis layer including the hair root tissue, which is epoch-making. A technical effect can be obtained. In the conventional classical glue manufacturing method, a large amount of work is required for the washing process after hair removal, but in the method of the present invention, even the hair root tissue can be removed by high-pressure water washing, so that the working time is greatly reduced. In addition, product pollution factors can be significantly reduced.

本実施態様では、熱処理した剃毛皮の表面から表皮層と毛根を除去する方法として高圧水洗浄を挙げたが、本発明はこれに限らず、熱処理により硬化・脆弱化した表皮層を除去することが可能な方法であれば適宜選択できる。例えば、硬化・脆弱化した表皮層を刃物や皮革用機械などで削り取っても良い。 In the present embodiment, high-pressure water washing is mentioned as a method for removing the epidermis layer and hair roots from the surface of the heat-treated shaved fur, but the present invention is not limited to this, and the epidermis layer hardened and weakened by the heat treatment is removed. Any method that can be used can be selected as appropriate. For example, the hardened / weakened epidermis layer may be scraped off with a knife or a leather machine.

(9) フレッシング
高圧水洗浄した加工皮の表裏両面に再度フレッシングを行なって、残留する表面の組織屑や裏面の皮下組織を除去しても良い。それにより、さらに純度の高い真皮層からなる加工皮が得られる。
(9) Freshing You may re-fresh both the front and back surfaces of the processed skin washed with high-pressure water to remove residual tissue debris on the front surface and subcutaneous tissue on the back surface. As a result, a processed dermis composed of a dermis layer having a higher purity can be obtained.

(10) 洗浄
フレッシングした後、再び洗浄しても良い。洗浄方法は、流水を用いて皮を洗浄する方法が挙げられる。
(10) Washing After freshening, it may be washed again. Examples of the washing method include a method of washing the skin with running water.

(11) 抽出
得られた真皮層からなる加工皮から、ゼラチンを主成分とする膠を熱水により抽出する。抽出方法は、通常用いられている膠の抽出方法を適用できる。
(11) Extraction From the obtained processed dermis composed of the dermis layer, gelatin-based glue is extracted with hot water. As the extraction method, a commonly used glue extraction method can be applied.

得られた膠を必要に応じて濃縮や濾過を行なった後、凝固させる。凝固した膠を裁断した後乾燥し、所望の固形膠が得られる。 The obtained glue is concentrated and filtered as necessary, and then coagulated. The solidified glue is cut and then dried to obtain the desired solid glue.

以下実施例により本発明を具体的に説明するが、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be specifically described with reference to Examples, but the present invention is not limited thereto.

実施例1
原皮として毛付きの黒毛牛生皮を使用し、下記の各処理を順に行なって原皮から皮下組織、表皮層及び毛根を除去し、各工程での様子を観察した。温度測定は、AD-5616放射温度計(A&D Company, Limited)を用いて行なった。
Example 1
Using black beef rawhide with hair as the rawhide, the subcutaneous tissue, epidermis layer and hair root were removed from the rawhide by performing each of the following treatments in order, and the state in each step was observed. The temperature was measured using an AD-5616 radiation thermometer (A & D Company, Limited).

[1. 洗浄]
毛付きの黒毛牛生皮と水を皮革用ドラム(回転撹拌器)に入れ、10 分間程度撹拌し洗浄を行なった。原皮は国産黒毛種成牛由来であって、同日朝に食肉処理場で剥皮されたばかりの新鮮なものを使用した。
[1. Cleaning]
Rawhide with hair and water were placed in a leather drum (rotary stirrer) and stirred for about 10 minutes for washing. The raw hide was derived from domestic Japanese Black cattle, and the fresh one that had just been peeled at the slaughterhouse on the morning of the same day was used.

[2. 外縁及び末端部位の切除]
原皮より尻尾、脚及び腹の部分を切除した。該処理により、元の原皮の30 重量%程度を切除した。
[2. Resection of outer edge and end site]
The tail, legs and abdomen were excised from the raw skin. By this treatment, about 30% by weight of the original raw hide was excised.

[3. 皮下組織の除去]
フレッシングマシンを用いて、原皮の裏面の皮下組織等の除去を行なった。該処理において、工程2の処理後の原皮から30 重量%程度をさらに除去した。即ち、元の原皮から延べ50 重量%程度が除去された。フレッシング工程時の原皮の表面温度及び作業室床温度は19 ℃程度であった。
[3. Removal of subcutaneous tissue]
The subcutaneous tissue on the back surface of the raw skin was removed using a freshening machine. In the treatment, about 30% by weight was further removed from the raw hide after the treatment in step 2. That is, a total of about 50% by weight was removed from the original raw hide. The surface temperature of the raw leather and the floor temperature of the work room during the freshing process were about 19 ° C.

[4. 剃毛]
バリカンを用いて剃毛処理を行なった。毛が表皮層の表面から4 mm程度残るように剃毛した。
[4. Shaving]
A shaving treatment was performed using a hair clipper. The hair was shaved so that about 4 mm remained from the surface of the epidermal layer.

[5. 洗浄]
流水を用いて皮を洗浄し、工程4で剃り落とした毛等を除去した。水温は19 ℃程度であった。
[5. Cleaning]
The skin was washed with running water to remove hair and the like shaved off in step 4. The water temperature was about 19 ° C.

[6. 熱処理]
剃毛処理を行なった剃毛皮について、表皮層の熱処理を下記(i)〜(v) の各条件で行なった。なお100 ℃以上の過剰な昇温を防ぐため、該処理は、皮表面に短く残された毛中に適量の水が含まれた状態で行なった。
[6. Heat treatment]
For the shaved fur that had been shaved, the epidermis layer was heat-treated under the following conditions (i) to (v). In order to prevent an excessive temperature rise of 100 ° C. or higher, the treatment was carried out with an appropriate amount of water contained in the hair left short on the skin surface.

剃毛皮の表面を上にして作業台に載せ、その上から120 〜160 ℃程度の皮革用熱鏝(重量13 kg,長さ36 cm,幅22 cm)を載置した。該熱鏝は温度調整不能で、またこれを載置すると皮表面温度は即時100 ℃程度となることから、熱処理の程度は、熱鏝を皮表面上に載置する時間の長短によって調整した。下記の単位時間ごとに、熱鏝を熱鏝幅(22 cm)の半分ずつ、即ち11 cmずつ、横にずらしてゆく方法で処理を行なった。したがって、皮表面各箇所における加熱時間は熱鏝載置単位時間の2倍である。なお該処理直前の皮表面温度は20 ℃程度であった。
(i) 熱鏝載置単位時間:70 秒/ 加熱時間:140 秒
熱鏝を離した直後の皮表面温度は100 ℃程度で、その後60 ℃程度までは急激に降下した。該処理後、表皮層のみ硬化・脆弱化していた。
(ii) 熱鏝載置単位時間:15 秒/ 加熱時間:30 秒
該熱処理後も表皮層が柔らかいままで、熱変性が不十分である様子が窺われた。熱鏝を離した瞬間の皮表面温度は100 ℃近くあったが、その後温度降下が急速であった。
(iii) 熱鏝載置単位時間:120 秒/ 加熱時間:240 秒
該熱処理によって表皮層が硬化・脆弱化し、また面方向に収縮し厚みが増した。またその関係で引きつりによる皺が生じ、熱鏝による作業の継続がやや煩雑化した。熱鏝を離した瞬間の皮表面温度は100 ℃程度で、かつその後の温度降下が緩慢で、80 ℃以上が暫く維持された。
(iv) 熱鏝載置単位時間:35 秒/ 加熱時間:70 秒
熱鏝を離した瞬間の皮表面温度は100 ℃近くで、その後温度は比較的速やかに降下した。該処理後、表皮層のみ硬化・脆弱化していた。
(v) 熱鏝載置単位時間:0 秒/ 加熱時間:0 秒
比較のため、熱処理を全く行なわなかった。
The surface of the shaved fur was placed on the work table, and a hot trowel for leather (weight 13 kg, length 36 cm, width 22 cm) at about 120 to 160 ° C was placed on it. Since the temperature of the hot trowel cannot be adjusted and the skin surface temperature immediately becomes about 100 ° C. when the hot trowel is placed, the degree of heat treatment is adjusted by the length of time for placing the hot trowel on the skin surface. The treatment was performed by shifting the trowel laterally by half the width of the trowel (22 cm), that is, by 11 cm for each of the following unit times. Therefore, the heating time at each part of the skin surface is twice the unit time for placing the trowel. The skin surface temperature immediately before the treatment was about 20 ° C.
(i) Heat trowel placement unit time: 70 seconds / Heating time: 140 seconds The skin surface temperature immediately after the heat trowel was released was about 100 ° C, and then dropped sharply to about 60 ° C. After the treatment, only the epidermis layer was hardened and weakened.
(ii) Heat treatment unit time: 15 seconds / Heating time: 30 seconds It was observed that the epidermis layer remained soft even after the heat treatment, and the heat denaturation was insufficient. The skin surface temperature at the moment when the hot trowel was released was close to 100 ° C, but the temperature dropped rapidly thereafter.
(iii) Heat trowel placement unit time: 120 seconds / heating time: 240 seconds The heat treatment hardened and weakened the epidermis layer, and also shrunk in the plane direction to increase the thickness. In addition, wrinkles due to dragging occurred due to this relationship, and the continuation of work with a hot trowel became a little complicated. The skin surface temperature at the moment when the hot trowel was released was about 100 ° C, and the temperature drop after that was slow, and it was maintained at 80 ° C or higher for a while.
(iv) Heat iron placement unit time: 35 seconds / Heating time: 70 seconds The skin surface temperature at the moment when the heat iron was released was close to 100 ° C, and then the temperature dropped relatively quickly. After the treatment, only the epidermis layer was hardened and weakened.
(v) Heat trowel placement unit time: 0 seconds / Heating time: 0 seconds For comparison, no heat treatment was performed.

[7. 表皮層の除去]
上記(i)〜(v) の各条件で熱処理を行なった剃毛皮について、高圧水洗浄器を用いて表皮層の除去処理を行なった。なお環境温度は23 ℃程度であった。
(i) 熱鏝載置単位時間:70 秒/ 加熱時間:140 秒
高圧水洗浄の結果、毛根組織を含む表皮層のみを充分に破壊除去できた。
(ii) 熱鏝載置単位時間:15 秒/ 加熱時間:30 秒
高圧水洗浄の結果、皮が柔らかすぎるため表皮層の破壊除去がやや困難であった。一応除去可能ではあったが、高圧水洗浄処理が繰り返し必要で、そのため真皮層まで一部損傷してしまうことがあった。またその結果、後述の工程8において皮の一部が裂けてしまった。
(iii) 熱鏝載置単位時間:120 秒/ 加熱時間:240 秒
高圧水洗浄の結果、表皮層を充分に破壊除去できたが、真皮層内部まで熱変性が進み硬化・脆弱化が進んでいたため、高圧水洗浄によって真皮層まで一部損傷し穴が開いてしまうことがあった。このことから、やはり熱処理は表皮層のみについて選択的に行ない、真皮層は生のままにしておくことが望ましいことが改めて確認された。またしたがって、熱鏝を使用する代わりに皮をまるごと熱湯に浸漬するといった方法は不適であると思われる。
(iv) 熱鏝載置単位時間:35 秒/ 加熱時間:70 秒
高圧水洗浄の結果、表皮層を充分に破壊除去できた。条件(i) よりも熱処理所要時間が短く済む点において、本条件のほうが効率的である。ただし、当該実施例以前に環境温度10 ℃程度の冬期に該熱処理条件を試行した際には、高圧水洗浄工程において表皮除去が困難で、そうした低温環境下ではより高強度の熱処理(熱鏝載置単位時間70 秒程度)が必要であった。
(v) 熱鏝載置単位時間:0 秒/ 加熱時間:0 秒
高圧水洗浄の結果、毛については概ね除去できたが、表皮層及びその中の毛根組織は殆ど除去することができず皮表面に残留した。
[7. Removal of epidermis layer]
The epidermis layer was removed from the shaved fur that had been heat-treated under each of the above conditions (i) to (v) using a high-pressure water washer. The environmental temperature was about 23 ° C.
(i) Heat iron placement unit time: 70 seconds / Heating time: 140 seconds As a result of high-pressure water washing, only the epidermis layer including the hair root tissue was sufficiently destroyed and removed.
(ii) Heat iron placement unit time: 15 seconds / Heating time: 30 seconds As a result of high-pressure water washing, it was somewhat difficult to destroy and remove the epidermis layer because the skin was too soft. Although it was possible to remove it, it was necessary to repeatedly wash it with high-pressure water, which sometimes damaged the dermis layer. As a result, a part of the skin was torn in step 8 described later.
(iii) Heat iron placement unit time: 120 seconds / Heating time: 240 seconds As a result of high-pressure water washing, the epidermis layer was sufficiently destroyed and removed, but heat denaturation progressed to the inside of the dermis layer and hardening and weakening progressed. Therefore, high-pressure water washing sometimes damaged the dermis layer and opened holes. From this, it was reconfirmed that it is desirable to selectively perform the heat treatment only on the epidermis layer and leave the dermis layer raw. Therefore, instead of using a hot trowel, the method of immersing the whole skin in boiling water seems to be unsuitable.
(iv) Heat iron placement unit time: 35 seconds / Heating time: 70 seconds As a result of high-pressure water washing, the epidermis layer was sufficiently destroyed and removed. This condition is more efficient in that the time required for heat treatment is shorter than that of condition (i). However, when the heat treatment conditions were tried in winter with an environmental temperature of about 10 ° C before the example, it was difficult to remove the epidermis in the high-pressure water washing process, and in such a low temperature environment, a higher-strength heat treatment (heat treatment). A unit time of about 70 seconds) was required.
(v) Heat iron placement unit time: 0 seconds / Heating time: 0 seconds As a result of high-pressure water washing, most of the hair could be removed, but the epidermis layer and the hair root tissue in it could hardly be removed, and the skin. Remained on the surface.

[8. 残留組織屑等の除去]
フレッシングマシンを用いて皮表裏両面に一度ずつ処理を行ない、表面の組織屑及び裏面の皮下組織を除去した。
[8. Removal of residual tissue waste, etc.]
Both the front and back surfaces of the skin were treated once using a freshing machine to remove tissue debris on the front surface and subcutaneous tissue on the back surface.

[9. 洗浄]
皮裏面に短時間の高圧水洗浄を行ない、汚れ等を除去した。
[9. Cleaning]
The back surface of the skin was washed with high-pressure water for a short time to remove dirt and the like.

以上の通り、工程6において表皮層のみを選択的に熱変性させることが、工程7における毛根組織を含む表皮層の破壊除去に極めて効果的であった。本実施例では、100 ℃程度、熱鏝載置単位時間15 秒/ 加熱時間30 秒の条件でも効果はあるがやや不十分で、より長い処理が望ましい。一方、100 ℃程度、熱鏝載置単位時間120 秒/ 加熱時間240 秒の条件では真皮層まで熱変性してしまい、処理過剰であった。20 ℃程度の環境下では、100 ℃程度、熱鏝載置単位時間35 秒/ 加熱時間70 秒の条件及び熱鏝載置単位時間70 秒/ 加熱時間140 秒の条件で課題が良好に達成され、また特に効率面において熱鏝載置単位時間35 秒 / 加熱時間70 秒の条件がより好ましい。ただし10 ℃程度の環境下では、100 ℃程度、熱鏝載置単位時間35 秒/ 加熱時間70 秒の条件ではやや不十分で、熱鏝載置単位時間70 秒 / 加熱時間140 秒程度の処理が好ましい場合もあった。 As described above, selectively heat-denaturing only the epidermis layer in step 6 was extremely effective in destroying and removing the epidermis layer including the hair root tissue in step 7. In this example, the effect is effective even under the conditions of about 100 ° C. and the heating time of 15 seconds / heating time of 30 seconds, but a longer treatment is desirable. On the other hand, under the conditions of about 100 ° C, a heating iron placement unit time of 120 seconds / heating time of 240 seconds, the dermis layer was thermally denatured, resulting in excessive treatment. In an environment of about 20 ° C, the task was successfully achieved under the conditions of about 100 ° C, hot iron mounting unit time 35 seconds / heating time 70 seconds, and hot iron mounting unit time 70 seconds / heating time 140 seconds. In particular, in terms of efficiency, the condition of heating iron placement unit time of 35 seconds / heating time of 70 seconds is more preferable. However, in an environment of about 10 ° C, the conditions of about 100 ° C and a heating time of 35 seconds / heating time of 70 seconds are somewhat insufficient, and processing with a heating iron placing unit time of about 70 seconds / heating time of about 140 seconds. Was preferred in some cases.

上記の通り、本発明の技術的特徴は、工程6の熱処理により表皮層のみを選択的に熱変性させ、硬化及び柔軟性低下、脆弱化させることにより、次の工程7における高圧水洗浄により毛根組織を含む表皮層の破壊除去を可能にする点にある。本実施例では、載置すると皮表面温度が即時100 ℃程度となる皮革用熱鏝を用いたため、加熱時間によっては本発明の効果が得られない場合もあったが、本発明の加熱時間は本実施例の範囲に限定されず、熱水の温度や使用する加熱器具に応じて適宜設定可能である。 As described above, the technical feature of the present invention is that only the epidermis layer is selectively heat-modified by the heat treatment in step 6 to cure, reduce flexibility, and weaken the hair roots by high-pressure water washing in the next step 7. The point is that it enables destruction and removal of the epidermal layer including tissues. In this embodiment, since a heat iron for leather whose skin surface temperature becomes about 100 ° C immediately when placed is used, the effect of the present invention may not be obtained depending on the heating time, but the heating time of the present invention is It is not limited to the range of this embodiment, and can be appropriately set according to the temperature of hot water and the heating equipment used.

実施例2
原皮として毛付きの黒毛牛生皮を使用し、下記の各条件で膠を製造した。
(1) 原皮を剃毛し、原皮の裏表両面をフレッシングし、洗浄した後、得られた加工皮から膠を熱水で抽出した(抽出温度:90 ℃,単位抽出時間:6 時間, 抽出番手:1)。
(2) 工程(1) で膠を抽出したあとの残渣を原料とし、再び抽出した(抽出温度:90 ℃,単位抽出時間:6 時間, 抽出番手:2)。
(3) 工程(2) で膠を抽出したあとの残渣を原料とし、さらに抽出した(抽出温度:90 ℃,単位抽出時間:6 時間, 抽出番手:3)。
(4) 工程(1) と同条件で膠を製造した。
(5) 実施例1の条件(i) の方法で製造した加工皮から膠を熱水で抽出した(抽出温度:90 ℃,単位抽出時間:6 時間, 抽出番手:1)。
(6) 工程(5) で膠を抽出したあとの残渣を原料とし、再び抽出した(抽出温度:90 ℃,単位抽出時間:6 時間, 抽出番手:2)。
(7) 工程(6) で膠を抽出したあとの残渣を原料とし、さらに抽出した(抽出温度:90 ℃,単位抽出時間:6 時間, 抽出番手:3)。
(8) 実施例1の条件(i) の方法で製造した加工皮から膠を熱水で抽出した(抽出温度:80 ℃,単位抽出時間:48 時間, 抽出番手:1)。
※ 抽出溶媒は、おいしい水天然水六甲(アサヒ飲料株式会社,硬度:約40 mg/L,pH 約7)を膠に対し100 重量%用いた。
※ 各膠を抽出後、化繊紙05TH-12(廣瀬製紙株式会社製, ポリエステル製不織布, 12 g/m2)を8枚重ねてステンレス製笊上に置いたものを通して濾し、濾液を均一に撹拌した後、ポリプロピレン製容器にて10 ℃で凝固させた。その後、205 × 8 × 8 mm程度の角棒状に裁断し、ポリプロピレン製棚上に並べて10 ℃で送風乾燥し、固形膠を製造した。
Example 2
Black beef rawhide with hair was used as the rawhide, and glue was produced under each of the following conditions.
(1) After shaving the raw skin, freshening both the front and back sides of the raw skin, and washing, the glue was extracted from the obtained processed skin with hot water (extraction temperature: 90 ° C, unit extraction time: 6 hours, extraction count). : 1).
(2) The residue after extracting glue in step (1) was used as a raw material and extracted again (extraction temperature: 90 ° C, unit extraction time: 6 hours, extraction count: 2).
(3) The residue after extracting glue in step (2) was used as a raw material for further extraction (extraction temperature: 90 ° C, unit extraction time: 6 hours, extraction count: 3).
(4) Glue was produced under the same conditions as in step (1).
(5) Glue was extracted with hot water from the processed skin produced by the method of condition (i) of Example 1 (extraction temperature: 90 ° C., unit extraction time: 6 hours, extraction count: 1).
(6) The residue after extracting glue in step (5) was used as a raw material and extracted again (extraction temperature: 90 ° C, unit extraction time: 6 hours, extraction count: 2).
(7) The residue after extracting glue in step (6) was used as a raw material for further extraction (extraction temperature: 90 ° C, unit extraction time: 6 hours, extraction count: 3).
(8) Glue was extracted with hot water from the processed skin produced by the method of condition (i) of Example 1 (extraction temperature: 80 ° C., unit extraction time: 48 hours, extraction count: 1).
* As the extraction solvent, 100% by weight of delicious water natural water Rokko (Asahi Soft Drinks Co., Ltd., hardness: about 40 mg / L, pH about 7) was used.
* After extracting each glue, 8 sheets of synthetic fiber paper 05TH-12 (manufactured by Hirose Paper Co., Ltd., polyester non-woven fabric, 12 g / m 2 ) are stacked and filtered through a stainless steel container, and the filtrate is stirred uniformly. After that, it was solidified at 10 ° C in a polypropylene container. Then, it was cut into a square bar of about 205 × 8 × 8 mm, arranged on a polypropylene shelf, and air-dried at 10 ° C. to produce solid glue.

上記条件(1)〜(8) で製造した膠の写真を図7に示す。従来の条件(1)〜(4) で製造した膠は、条件(1)〜(3) で製造した膠は毛や表皮組織の溶出等により暗色となった。条件(4) で製造した膠は問題なく明色に仕上がったが、同じ条件(1)で製造した膠との比較から分かるように、製造の安定性(品質の再現性)に課題があった。本発明の条件(5)〜(8) で製造した膠は、全て問題なく明色に仕上っており、より高い安定性をもって小さい作業量で明色の膠を調製することが可能になった。 A photograph of glue produced under the above conditions (1) to (8) is shown in FIG. The glue produced under the conventional conditions (1) to (4) became darker due to the elution of hair and epidermal tissue. The glue manufactured under condition (4) was finished in bright color without any problem, but as can be seen from the comparison with the glue manufactured under the same condition (1), there was a problem with manufacturing stability (quality reproducibility). .. All the glues produced under the conditions (5) to (8) of the present invention were finished in light color without any problem, and it became possible to prepare light color glue with higher stability and a small amount of work.

Claims (7)

皮下組織と、真皮層と、表皮層とからなり、表皮層から多数の毛が生えている原皮から膠を製造する方法であって、
原皮の裏面をフレッシングして皮下組織を除去する工程と、
原皮の表面に生えている毛を剃毛する工程と、
得られた剃毛皮の表面に熱水を当てて熱処理を行なって表皮層を硬化・脆弱化させる工程と、
熱処理した剃毛皮の表面から表皮層と毛を除去する工程と、
得られた真皮層からなる加工皮から膠を熱水により抽出する工程とを有することを特徴とする膠の製造方法。
It is a method of producing glue from the raw skin, which consists of the subcutaneous tissue, the dermis layer, and the epidermis layer, and has many hairs growing from the epidermis layer.
The process of freshening the back surface of the raw skin to remove the subcutaneous tissue,
The process of shaving the hair growing on the surface of the raw skin,
The process of applying hot water to the surface of the obtained shaved fur and heat-treating it to harden and weaken the epidermis layer.
The process of removing the epidermis layer and hair from the surface of the heat-treated shaved fur,
A method for producing glue, which comprises a step of extracting glue with hot water from the processed dermis composed of the obtained dermis layer.
請求項1に記載の膠の製造方法において、前記熱処理工程において、前記剃毛皮の表面に水を供給した後、その上に熱鏝を当てて前記水を加熱させることを特徴とする膠の製造方法。 The method for producing glue according to claim 1, wherein in the heat treatment step, water is supplied to the surface of the shaved fur, and then a hot iron is applied thereto to heat the water. Method. 請求項1又は2に記載の膠の製造方法において、前記熱処理工程における熱水の温度が50 〜 150 ℃であることを特徴とする膠の製造方法。 The method for producing glue according to claim 1 or 2, wherein the temperature of hot water in the heat treatment step is 50 to 150 ° C. 請求項1〜3のいずれかに記載の膠の製造方法において、前記剃毛工程において、前記原皮の表面に短く刈り取られた毛が残留するように剃毛することを特徴とする膠の製造方法。 The method for producing glue according to any one of claims 1 to 3, wherein in the shaving step, shaving is performed so that shortly cut hair remains on the surface of the raw skin. .. 請求項1〜4のいずれかに記載の膠の製造方法において、前記除去工程を高圧水洗浄により行なうことを特徴とする膠の製造方法。 The method for producing glue according to any one of claims 1 to 4, wherein the removing step is performed by high-pressure water washing. 請求項1〜5のいずれかに記載の膠の製造方法において、熱処理した剃毛皮の表裏両面をフレッシングする工程をさらに有することを特徴とする膠の製造方法。 The method for producing glue according to any one of claims 1 to 5, further comprising a step of freshening both the front and back surfaces of the heat-treated shaved fur. 請求項1〜6のいずれかに記載の膠の製造方法において、得られた加工皮を洗浄した後に前記抽出工程を行なうことを特徴とする膠の製造方法。 The method for producing glue according to any one of claims 1 to 6, wherein the extraction step is performed after washing the obtained processed skin.
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4222741A (en) * 1979-03-09 1980-09-16 Dubuque Packing Company Method of processing mechanically removed porcine skins for ultimate gelatin or leather production
JP2001234128A (en) * 1999-12-07 2001-08-28 Ed Geistlich Soehne Ag Fuer Chemische Industrie Method for manufacturing collagenous film from pig skin

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4222741A (en) * 1979-03-09 1980-09-16 Dubuque Packing Company Method of processing mechanically removed porcine skins for ultimate gelatin or leather production
JP2001234128A (en) * 1999-12-07 2001-08-28 Ed Geistlich Soehne Ag Fuer Chemische Industrie Method for manufacturing collagenous film from pig skin

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