JP2021149102A - 光散乱感光性樹脂組成物、カラーフィルタ、及び画像表示装置 - Google Patents
光散乱感光性樹脂組成物、カラーフィルタ、及び画像表示装置 Download PDFInfo
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- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- LYXOWKPVTCPORE-UHFFFAOYSA-N phenyl-(4-phenylphenyl)methanone Chemical compound C=1C=C(C=2C=CC=CC=2)C=CC=1C(=O)C1=CC=CC=C1 LYXOWKPVTCPORE-UHFFFAOYSA-N 0.000 description 1
- OTYNBGDFCPCPOU-UHFFFAOYSA-N phosphane sulfane Chemical compound S.P[H] OTYNBGDFCPCPOU-UHFFFAOYSA-N 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 125000004591 piperonyl group Chemical group C(C1=CC=2OCOC2C=C1)* 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- SUXIKHBBPQWLHO-UHFFFAOYSA-N trihydroxy-(8-methylnonyl)-(8-methyl-1-phenylnonyl)-lambda5-phosphane Chemical compound CC(C)CCCCCCCP(O)(O)(O)C(CCCCCCC(C)C)C1=CC=CC=C1 SUXIKHBBPQWLHO-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F20/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/133509—Filters, e.g. light shielding masks
- G02F1/133514—Colour filters
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0005—Production of optical devices or components in so far as characterised by the lithographic processes or materials used therefor
- G03F7/0007—Filters, e.g. additive colour filters; Components for display devices
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
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- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/032—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with binders
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
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Abstract
Description
光散乱画素層を形成するための感光性樹脂組成物であって、
前記感光性樹脂組成物は、散乱粒子、アルカリ可溶性樹脂、光重合性化合物、光重合開始剤、及び溶剤を含み、
前記感光性樹脂組成物から形成される光散乱画素層は、表面粗さが50Å以上である感光性樹脂組成物を提供する。
Ra及びRbは、それぞれ独立して、水素又はメチルである。
前記感光性樹脂組成物から形成される光散乱画素層は表面粗さが50Å以上である感光性樹脂組成物に関する。
本発明の一実施形態において、前記散乱粒子は、光源から放出された光の経路を増加させて全体的な光効率を高める役割をする。
本発明において、前記散乱粒子は金属酸化物を含む。
一方、本発明の感光性樹脂組成物は硬化時に青色光源によって青色画素の役割を遂行するのに用いられ得るものであり、前記散乱粒子以外の着色剤を含む場合、光源から発光する青色光の透過効率が低下するという問題点が生じることがある。
前記アルカリ可溶性樹脂は、光や熱の作用による反応性及びアルカリ溶解性を有し、散乱粒子をはじめとした固形分の分散媒として作用し、結着樹脂の機能を遂行する。
Ra及びRbは、それぞれ独立して、水素又はメチルである。
本発明の感光性樹脂組成物に含有される光重合性化合物は、光及び後述する光重合開始剤の作用で重合することができる化合物であって、単官能単量体、2官能単量体、その他の多官能単量体などが挙げられる。
本発明の一実施形態において、前記光重合開始剤としては、感光性樹脂組成物に一般的に用いられる光重合開始剤を用いてよい。
チオキサントン系化合物としては、2−イソプロピルチオキサントン、2,4−ジエチルチオキサントン、2,4−ジクロロチオキサントン、1−クロロ−4−プロポキシチオキサントンなどが挙げられる。
ベンゾイン系化合物としては、ベンゾインメチルエーテル、ベンゾインエチルエーテル、ベンゾインイソプロピルエーテル、ベンゾインイソブチルエーテル、ベンジルジメチルケタルなどが挙げられる。
本発明の一実施形態において、前記溶剤(E)は、感光性樹脂組成物が適当な粘性を有し、且つ残りの成分を容易に溶解させ得るものであればその種類は特に制限されず、感光性樹脂組成物の分野で用いられている各種の有機溶剤を用いてよい。
本発明の一実施形態に係る感光性樹脂組成物は、前記の成分の他、必要に応じて添加剤(F)をさらに含んでよい。
本発明の一実施形態は、上述した感光性樹脂組成物から形成される光散乱画素層に関する。
以下、本発明に係る感光性樹脂組成物を用いたパターン形成方法について詳しく説明する。
具体的に、前記感光性樹脂組成物を、何も塗布されていないガラス基板またはSiNx(保護膜)が500〜1,500Åの厚さで塗布されているガラス基板上にスピン塗布、スリット塗布などの好適な方法にて2.0〜3.4μmの厚さで塗布する。塗布後はカラーフィルタに必要なパターンを形成するように光を照射する。光の照射後、塗布層をアルカリ現像液で処理すると塗布層の非照射部分が溶解しカラーフィルタに必要なパターンが形成される。このような過程を必要なR、G、B色の数だけ繰り返し行うことで、所望のパターンを有するカラーフィルタを得ることができる。また、前記過程で、現像によって得られた画像パターンをさらに加熱し、または活性線照射などによって硬化させることで耐クラック性や耐溶剤性などをさらに向上させることができる。
本発明に係るカラーフィルタは、通常の液晶表示装置(LCD)だけでなく、電界発光表示装置(EL)、プラズマ表示装置(PDP)、電界放出表示装置(FED)、有機発光素子(OLED)、量子ドット発光ダイオード(Quantum Dot Light−Emitting Diode、QLED)などの各種の画像表示装置に適用可能である。
撹拌機、温度計、還流冷却管、滴下ロート及び窒素導入管を備えたフラスコを準備し、さらに、N−ベンジルマレイミド5モル%、シクロヘキシルメタクリレート15モル%、メチルメタクリレート5モル%、ロジンメタクリレート20モル%、及びアクリル酸55モル%からなる単量体100重量部に、プロピレングリコールモノメチルエーテルアセテート(以下、PGMEAともいう)40重量部を投入した後、撹拌・混合してモノマー滴下ロートを準備し、n−ドデカンジオール6重量部、PGMEA 24重量部を入れて撹拌・混合して連鎖移動剤滴下ロートを準備した。
次いで、フラスコにPGMEA 395重量部を導入し、フラスコ内の雰囲気を空気から窒素に置換した後、撹拌しながらフラスコの温度を90℃まで昇温した。次いで、モノマー及び連鎖移動剤の、滴下ロートからの滴下を開始した。滴下は90℃を維持しながらそれぞれ2時間進行し、1時間後に110℃に昇温して、3時間維持した後、ガス導入管を導入させて、酸素/窒素=5/95(v/v)の混合ガスのバブリングを開始した。
次いで、前記単量体100モル%に対してグリシジルメタクリレート45モル%、2,2’−メチレンビス(4−メチル−6−t−ブチルフェノール)0.4重量部、トリエチルアミン0.8重量部をフラスコ内に投入し、110℃で6時間反応を続け、その後、室温まで冷却して、重量平均分子量11,100、固形分基準酸価70mgKOH/gのアルカリ可溶性樹脂を得た。
撹拌機、温度計、還流冷却管、滴下ロート及び窒素導入管を備えたフラスコを準備し、さらに、N−ベンジルマレイミド10モル%、シクロヘキシルメタクリレート25モル%、メチルメタクリレート5モル%、ロジンメタクリレート25モル%及びアクリル酸35モル%からなる単量体100重量部に、プロピレングリコールモノメチルエーテルアセテート(以下、PGMEAともいう)40重量部を投入した後、撹拌・混合してモノマー滴下ロートを準備し、n−ドデカンジオール6重量部、PGMEA 24重量部を入れて撹拌・混合して連鎖移動剤滴下ロートを準備した。
次いで、前記単量体100モル%に対してグリシジルメタクリレート30モル%、2,2’−メチレンビス(4−メチル−6−t−ブチルフェノール)0.4重量部、トリエチルアミン0.8重量部をフラスコ内に投入し、110℃で6時間反応を続け、その後、室温まで冷却して、重量平均分子量11,600、固形分基準酸価50mgKOH/gのアルカリ可溶性樹脂を得た。
撹拌機、温度計、還流冷却管、滴下ロート及び窒素導入管を備えたフラスコを準備し、さらに、N−ベンジルマレイミド5モル%、シクロヘキシルメタクリレート25モル%、メチルメタクリレート5モル%、ロジンメタクリレート40モル%及びアクリル酸25モル%からなる単量体100重量部に、プロピレングリコールモノメチルエーテルアセテート(以下、PGMEAともいう)40重量部を投入した後、撹拌・混合してモノマー滴下ロートを準備し、n−ドデカンジオール6重量部、PGMEA 24重量部を入れて撹拌・混合して連鎖移動剤滴下ロートを準備した。
次いで、前記単量体100モル%に対してグリシジルメタクリレート15モル%、2,2’−メチレンビス(4−メチル−6−t−ブチルフェノール)0.4重量部、トリエチルアミン0.8重量部をフラスコ内に投入し、110℃で6時間反応を続け、その後、室温まで冷却して、重量平均分子量11,500、固形分基準酸価62mgKOH/gのアルカリ可溶性樹脂を得た。
撹拌機、温度計、還流冷却管、滴下ロート及び窒素導入管を備えたフラスコを準備し、さらに、N−ベンジルマレイミド5モル%、シクロヘキシルメタクリレート5モル%、メチルメタクリレート10モル%、ロジンメタクリレート10モル%及びアクリル酸70モル%からなる単量体100重量部に、プロピレングリコールモノメチルエーテルアセテート(以下、PGMEAともいう)40重量部を投入した後、撹拌・混合してモノマー滴下ロートを準備し、n−ドデカンジオール6重量部、PGMEA 24重量部を入れて撹拌・混合して連鎖移動剤滴下ロートを準備した。
下記表1の組成にてそれぞれの成分を混合して感光性樹脂組成物を製造した(重量%)。
(B−1)アルカリ可溶性樹脂:合成例1
(B−2)アルカリ可溶性樹脂:合成例2
(B−3)アルカリ可溶性樹脂:合成例3
(B−4)アルカリ可溶性樹脂:合成例4
(C−1)光重合性化合物:ジペンタエリトリトールヘキサアクリレート(Kayarad DPHA、日本化薬社製)
(D−1)光重合開始剤:Irgacure OXE01(BASF社製)、λmax:327nm
(D−2)光重合開始剤:NCI−831(ADEKA社),λmax:365nm
(F−1)酸化防止剤:Sumilizer GP(住友化学社製)
(F−2)エポキシ樹脂:ESCN 195XL(住友化学社製)
(F−3)レベリング剤:F−554(DIC社製)
(E−1)溶剤:プロピレングリコールモノメチルエーテルアセテート(PGMEA)
実験例:
前記実施例及び比較例で製造された感光性樹脂組成物を用いて下記のように光散乱画素層を製造し、このときの表面粗さ及び青色光源に対する輝度を下記のような方法にて測定し、その結果を下記の表2に表した。
前記実施例及び比較例で製造された感光性樹脂組成物を用いて光散乱画素層基板を製造した。すなわち、前記感光性樹脂組成物のそれぞれをスピンコーティング法にてガラス基板上に塗布した後、加熱板上に載置し、100℃の温度で3分間維持して溶剤を除去し、塗膜を形成させた。
表面粗さ測定器としてDEKTAK(Veeco社製)装備を用いて前記光散乱画素層の表面粗さ(surface roughness)を測定した(単位:Å)。
前記実施例及び比較例で製造された感光性樹脂組成物を用いて製造された光散乱画素層基板の基板面に青色発光素子を配置した後、輝度測定器(CAS 140 CT、Instrument System社製)を用いて青色光源に対する輝度を測定した。当該輝度は、光散乱画素層基板なしに青色光源だけを載置し測定時の輝度値を100%にし、これに対する相対的な値にして求めた。
したがって、本発明の実質的な範囲は、特許請求の範囲とその等価物によって定義されると言えよう。
Claims (11)
- 光散乱画素層を形成するための感光性樹脂組成物であって、
当該感光性樹脂組成物は、散乱粒子、アルカリ可溶性樹脂、光重合性化合物、光重合開始剤、及び溶剤を含み、
当該感光性樹脂組成物から形成される光散乱画素層は表面粗さが50Å以上である、感光性樹脂組成物。 - 当該感光性樹脂組成物から形成される光散乱画素層は、10μm厚さを基準に光源に対して輝度が60%以上である、請求項1に記載の感光性樹脂組成物。
- 前記光源は青色光源である、請求項2に記載の感光性樹脂組成物。
- 前記青色光源の波長は380nm〜530nmの範囲である、請求項3に記載の感光性樹脂組成物。
- 前記アルカリ可溶性樹脂は、グリシジル(メタ)アクリレート由来の置換基を有し、前記グリシジル(メタ)アクリレート由来の置換基を有する繰り返し単位が前記アルカリ可溶性樹脂を構成する繰り返し単位の全体100モル%に対し、10〜50モル%の量で含まれたものである、請求項1に記載の感光性樹脂組成物。
- 前記光重合開始剤は、360nm以下の波長で最大吸収波長(λmax)を有するものである、請求項1に記載の感光性樹脂組成物。
- 請求項1〜8のいずれか一項に記載の感光性樹脂組成物から形成される光散乱画素層。
- 請求項9に記載の光散乱画素層を含むカラーフィルタ。
- 請求項10に記載のカラーフィルタが備えられたことを特徴とする画像表示装置。
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