JP2020523217A - 付加製造において有用な光重合性樹脂のブロッキング基 - Google Patents
付加製造において有用な光重合性樹脂のブロッキング基 Download PDFInfo
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- JP2020523217A JP2020523217A JP2019565564A JP2019565564A JP2020523217A JP 2020523217 A JP2020523217 A JP 2020523217A JP 2019565564 A JP2019565564 A JP 2019565564A JP 2019565564 A JP2019565564 A JP 2019565564A JP 2020523217 A JP2020523217 A JP 2020523217A
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- Prior art keywords
- component
- block
- polymerizable liquid
- reactive component
- weight percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/0037—Production of three-dimensional images
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
- B29C64/129—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/188—Processes of additive manufacturing involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/30—Auxiliary operations or equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/02—Thermal after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0002—Condition, form or state of moulded material or of the material to be shaped monomers or prepolymers
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Optics & Photonics (AREA)
- Mechanical Engineering (AREA)
- General Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022211476A JP2023055693A (ja) | 2017-06-08 | 2022-12-28 | 付加製造において有用な光重合性樹脂のブロッキング基 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762516893P | 2017-06-08 | 2017-06-08 | |
| US62/516,893 | 2017-06-08 | ||
| PCT/US2018/036441 WO2018226943A1 (en) | 2017-06-08 | 2018-06-07 | Blocking groups for light polymerizable resins useful in additive manufacturing |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022211476A Division JP2023055693A (ja) | 2017-06-08 | 2022-12-28 | 付加製造において有用な光重合性樹脂のブロッキング基 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2020523217A true JP2020523217A (ja) | 2020-08-06 |
| JP2020523217A5 JP2020523217A5 (https=) | 2021-07-26 |
Family
ID=62779048
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019565564A Pending JP2020523217A (ja) | 2017-06-08 | 2018-06-07 | 付加製造において有用な光重合性樹脂のブロッキング基 |
| JP2022211476A Pending JP2023055693A (ja) | 2017-06-08 | 2022-12-28 | 付加製造において有用な光重合性樹脂のブロッキング基 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2022211476A Pending JP2023055693A (ja) | 2017-06-08 | 2022-12-28 | 付加製造において有用な光重合性樹脂のブロッキング基 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US11226559B2 (https=) |
| EP (1) | EP3635487A1 (https=) |
| JP (2) | JP2020523217A (https=) |
| CN (1) | CN110582725A (https=) |
| WO (1) | WO2018226943A1 (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019168807A1 (en) | 2018-03-02 | 2019-09-06 | Carbon, Inc. | Sustainable additive manufacturing resins and methods of recycling |
| US12162975B2 (en) | 2018-07-27 | 2024-12-10 | Carbon, Inc. | Branched reactive blocked prepolymers for additive manufacturing |
| WO2020055609A1 (en) | 2018-09-13 | 2020-03-19 | Carbon, Inc. | Reversible thermosets for additive manufacturing |
| WO2020131675A1 (en) * | 2018-12-21 | 2020-06-25 | Carbon, Inc. | Energy absorbing dual cure polyurethane elastomers for additive manufacturing |
| US11840023B2 (en) * | 2019-08-30 | 2023-12-12 | Carbon, Inc. | Mutliphysics model for inverse warping of data file in preparation for additive manufacturing |
| WO2021146237A1 (en) * | 2020-01-17 | 2021-07-22 | Carbon, Inc. | Chemical recycling of additively manufactured objects |
| WO2021173785A1 (en) * | 2020-02-28 | 2021-09-02 | Carbon, Inc. | One part moisture curable resins for additive manufacturing |
| WO2021183741A1 (en) | 2020-03-12 | 2021-09-16 | Carbon, Inc. | Partially reversible thermosets useful for recycling |
| CN115668057B (zh) * | 2020-05-27 | 2025-09-02 | 富士胶片株式会社 | 转印膜、层叠体的制造方法及封端异氰酸酯化合物 |
| CN113321925B (zh) * | 2021-06-10 | 2022-08-12 | 珠海赛纳三维科技有限公司 | 3d打印用组合物及其制备方法、3d打印方法、装置 |
| CN113388075B (zh) * | 2021-06-11 | 2023-03-24 | 珠海赛纳三维科技有限公司 | 一种3d打印用组合物、3d打印方法、装置 |
| WO2022266331A1 (en) | 2021-06-16 | 2022-12-22 | Carbon, Inc. | Methods for surface coating additively manufactured objects |
| US11884000B2 (en) * | 2021-08-27 | 2024-01-30 | Carbon, Inc. | One part, catalyst containing, moisture curable dual cure resins for additive manufacturing |
| CN113929869B (zh) * | 2021-11-29 | 2022-08-16 | 四川大学 | 双组份3d打印用聚脲材料以及3d打印聚脲制品的方法 |
| WO2023244739A1 (en) * | 2022-06-15 | 2023-12-21 | Cmc Materials Llc | Dual-cure resin for preparing chemical mechanical polishing pads |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0860742A1 (en) * | 1997-02-25 | 1998-08-26 | E.I. Du Pont De Nemours And Company | Flexible, flame-retardant, photoimageable composition for coating printing circuits |
| US20040052966A1 (en) * | 2001-03-29 | 2004-03-18 | Guido Wilke | Aqueous dispersions, which can be hardened thermally and by using actinic radiation, method for the production thereof and their use |
| JP2004341278A (ja) * | 2003-05-16 | 2004-12-02 | Toyo Ink Mfg Co Ltd | 活性エネルギー線硬化性着色組成物 |
| US20050090620A1 (en) * | 2003-10-27 | 2005-04-28 | Grace Scott A. | Acrylate-functional blocked polyisocyanate resin for UV/thermally curable coatings |
| US20130102943A1 (en) * | 2009-09-08 | 2013-04-25 | Schoeller Textil Ag | Reloadable finishes for textiles and formulations for loading such finishes |
| WO2015200173A1 (en) * | 2014-06-23 | 2015-12-30 | Carbon3D, Inc. | Methods of producing three-dimensional objects from materials having multiple mechanisms of hardening |
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| US3213058A (en) | 1960-12-19 | 1965-10-19 | American Cyanamid Co | Polymers reacted with benzotriazole uv absorbers |
| US3694389A (en) | 1970-08-06 | 1972-09-26 | Rohm & Haas | Thermosetting coatings based on oxime-blocked isocyanates |
| US5236637A (en) | 1984-08-08 | 1993-08-17 | 3D Systems, Inc. | Method of and apparatus for production of three dimensional objects by stereolithography |
| US4785075A (en) | 1987-07-27 | 1988-11-15 | Interez, Inc. | Metal acetylacetonate/alkylphenol curing catalyst for polycyanate esters of polyhydric phenols |
| US5158858A (en) | 1990-07-05 | 1992-10-27 | E. I. Du Pont De Nemours And Company | Solid imaging system using differential tension elastomeric film |
| US5122441A (en) | 1990-10-29 | 1992-06-16 | E. I. Du Pont De Nemours And Company | Method for fabricating an integral three-dimensional object from layers of a photoformable composition |
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| US6380285B1 (en) | 2000-02-01 | 2002-04-30 | Ciba Specialty Chemicals Corporation | Bloom-resistant benzotriazole UV absorbers and compositions stabilized therewith |
| GB2361005B (en) | 2000-04-04 | 2002-08-14 | Ciba Sc Holding Ag | Synergistic mixtures of uv-absorbers in polyolefins |
| DE10119817A1 (de) | 2001-04-23 | 2002-10-24 | Envision Technologies Gmbh | Vorrichtung und Verfahren für die zerstörungsfreie Trennung ausgehärteter Materialschichten von einer planen Bauebene |
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| RU2414471C2 (ru) | 2005-02-02 | 2011-03-20 | Циба Спешиалти Кемикэлз Холдинг Инк. | Бензотриазоловые поглотители уф-лучей со смещенным в длинноволновую область спектром поглощения и их применение |
| US7892474B2 (en) | 2006-11-15 | 2011-02-22 | Envisiontec Gmbh | Continuous generative process for producing a three-dimensional object |
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| CN102575051B (zh) * | 2009-08-21 | 2015-04-22 | 路博润高级材料公司 | 水解稳定的聚氨酯纳米复合材料 |
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| US20180229436A1 (en) * | 2015-09-04 | 2018-08-16 | Carbon3D, Inc. | Methods of Making Three Dimensional Objects from Dual Cure Resins with Supported Second Cure |
| JP2017052177A (ja) * | 2015-09-09 | 2017-03-16 | 富士ゼロックス株式会社 | 三次元造形物の製造方法、三次元造形用支持材、三次元造形用支持材カートリッジ、及び三次元造形用組成物セット |
-
2018
- 2018-06-07 US US16/615,446 patent/US11226559B2/en active Active
- 2018-06-07 EP EP18735062.4A patent/EP3635487A1/en not_active Withdrawn
- 2018-06-07 JP JP2019565564A patent/JP2020523217A/ja active Pending
- 2018-06-07 CN CN201880021466.6A patent/CN110582725A/zh active Pending
- 2018-06-07 WO PCT/US2018/036441 patent/WO2018226943A1/en not_active Ceased
-
2021
- 2021-12-03 US US17/457,481 patent/US20220091504A1/en not_active Abandoned
-
2022
- 2022-12-28 JP JP2022211476A patent/JP2023055693A/ja active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0860742A1 (en) * | 1997-02-25 | 1998-08-26 | E.I. Du Pont De Nemours And Company | Flexible, flame-retardant, photoimageable composition for coating printing circuits |
| US20040052966A1 (en) * | 2001-03-29 | 2004-03-18 | Guido Wilke | Aqueous dispersions, which can be hardened thermally and by using actinic radiation, method for the production thereof and their use |
| JP2004341278A (ja) * | 2003-05-16 | 2004-12-02 | Toyo Ink Mfg Co Ltd | 活性エネルギー線硬化性着色組成物 |
| US20050090620A1 (en) * | 2003-10-27 | 2005-04-28 | Grace Scott A. | Acrylate-functional blocked polyisocyanate resin for UV/thermally curable coatings |
| US20130102943A1 (en) * | 2009-09-08 | 2013-04-25 | Schoeller Textil Ag | Reloadable finishes for textiles and formulations for loading such finishes |
| WO2015200173A1 (en) * | 2014-06-23 | 2015-12-30 | Carbon3D, Inc. | Methods of producing three-dimensional objects from materials having multiple mechanisms of hardening |
| WO2015200179A1 (en) * | 2014-06-23 | 2015-12-30 | Carbon3D, Inc. | Methods of producing polyurethane three-dimensional objects from materials having multiple mechanisms of hardening |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3635487A1 (en) | 2020-04-15 |
| CN110582725A (zh) | 2019-12-17 |
| US20220091504A1 (en) | 2022-03-24 |
| JP2023055693A (ja) | 2023-04-18 |
| WO2018226943A1 (en) | 2018-12-13 |
| US11226559B2 (en) | 2022-01-18 |
| US20200174367A1 (en) | 2020-06-04 |
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