JP2019514825A - メタノール分解による水素または合成ガスの製造方法 - Google Patents
メタノール分解による水素または合成ガスの製造方法 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B6/00—Heating by electric, magnetic or electromagnetic fields
- H05B6/02—Induction heating
- H05B6/22—Furnaces without an endless core
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00139—Controlling the temperature using electromagnetic heating
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
- C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
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- C—CHEMISTRY; METALLURGY
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0855—Methods of heating the process for making hydrogen or synthesis gas by electromagnetic heating
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1217—Alcohols
- C01B2203/1223—Methanol
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- Engineering & Computer Science (AREA)
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- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Description
CH3OH <−−−−−> CO+2H2
反応は適度な温度、すなわち、200〜400℃、好ましくは、200〜350℃で行われる。
CH3OH −−−−> CO+2H2
CH3OH+H2O <−−−−−> 3H2+CO2
CH3OH <−−−−−> 2H2+CO
CO+H2O <−−−−−> CO2+H2
Claims (10)
- メタノール分解により水素または合成ガスを製造する方法であって、メタノールが、以下に示す吸熱反応において水素と一酸化炭素とに触媒的に分解され、
CH3OH −> CO+2H2
前記反応は、反応ゾーンにおいて直接誘導加熱を伴う反応器内で行われる、上記の方法。 - 前記加熱が、反応器内に配置された金属コイルに交流電流を通すことによって得られる、請求項1に記載の方法。
- 前記触媒が、Cu/ZnOのようなCuを含む、請求項1または2に記載の方法。
- 前記金属コイルが銅線である、請求項2または3に記載の方法。
- 前記コイルが絶縁されていなく、それによって触媒と電気的に接触する、請求項4に記載の方法。
- 前記加熱が、触媒活性相で含浸した酸化物でコーティングされている、強磁性構造体の形状の誘導加熱された触媒ハードウェアを用いて得られる、請求項1に記載の方法。
- 前記強磁性構造体が、Fe−CrまたはAI−Ni−Co合金の金属からなる、請求項6に記載の方法。
- 前記強磁性構造体上にコーティングされた酸化物が、A1、Zrおよび/またはCeを含む組み合わせからなる酸化物である、請求項6または7に記載の方法。
- 前記酸化物の表面をメタノール分解に適した触媒相で含浸させている、請求項8に記載の方法。
- 前記触媒相がCu/ZnOのようなCuを含む、請求項9に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA201600242 | 2016-04-26 | ||
DKPA201600242 | 2016-04-26 | ||
PCT/EP2017/059594 WO2017186612A1 (en) | 2016-04-26 | 2017-04-24 | A process for producing hydrogen or syngas by methanol cracking |
Publications (2)
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JP2019514825A true JP2019514825A (ja) | 2019-06-06 |
JP7041636B2 JP7041636B2 (ja) | 2022-03-24 |
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Application Number | Title | Priority Date | Filing Date |
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JP2018555478A Active JP7041636B2 (ja) | 2016-04-26 | 2017-04-24 | メタノール分解による水素または合成ガスの製造方法 |
Country Status (5)
Country | Link |
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US (1) | US11059719B2 (ja) |
EP (1) | EP3448804B1 (ja) |
JP (1) | JP7041636B2 (ja) |
CN (1) | CN109071216B (ja) |
WO (1) | WO2017186612A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2019514901A (ja) * | 2016-04-26 | 2019-06-06 | ハルドール・トプサー・アクチエゼルスカベット | ニトリルの合成方法 |
JP2021014397A (ja) * | 2019-07-11 | 2021-02-12 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | 二水素製造器 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20210113983A1 (en) * | 2018-05-31 | 2021-04-22 | Haldor Topsøe A/S | Endothermic reactions heated by resistance heating |
EP3574991A1 (en) | 2018-05-31 | 2019-12-04 | Haldor Topsøe A/S | Steam reforming heated by resistance heating |
CN114555220A (zh) * | 2019-10-01 | 2022-05-27 | 托普索公司 | 由甲醇按需制氢 |
JP2022550815A (ja) * | 2019-10-01 | 2022-12-05 | トプソー・アクチエゼルスカベット | メタノールからオンデマンド合成ガス |
CN115141099A (zh) * | 2021-03-31 | 2022-10-04 | 中国石油天然气集团有限公司 | 甲基丙烯酸甲酯的生产装置和工艺 |
CN114772552A (zh) * | 2022-03-23 | 2022-07-22 | 浙江浙能技术研究院有限公司 | 一种化学链甲烷重整制氢的结构化氧载体及制备方法 |
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JPH09286603A (ja) * | 1996-04-24 | 1997-11-04 | Mitsubishi Gas Chem Co Inc | 一酸化炭素及び水素の混合ガスの製造法 |
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JP2011245475A (ja) * | 2010-04-28 | 2011-12-08 | Nippon Seisen Co Ltd | 水素化反応/脱水素化反応用のワイヤー触媒、ワイヤー触媒成形品、及びそれらの製造方法 |
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- 2017-04-24 US US16/087,943 patent/US11059719B2/en active Active
- 2017-04-24 EP EP17718549.3A patent/EP3448804B1/en active Active
- 2017-04-24 JP JP2018555478A patent/JP7041636B2/ja active Active
- 2017-04-24 WO PCT/EP2017/059594 patent/WO2017186612A1/en active Application Filing
- 2017-04-24 CN CN201780025276.7A patent/CN109071216B/zh active Active
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JPH09286603A (ja) * | 1996-04-24 | 1997-11-04 | Mitsubishi Gas Chem Co Inc | 一酸化炭素及び水素の混合ガスの製造法 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2019514901A (ja) * | 2016-04-26 | 2019-06-06 | ハルドール・トプサー・アクチエゼルスカベット | ニトリルの合成方法 |
JP7050695B2 (ja) | 2016-04-26 | 2022-04-08 | ハルドール・トプサー・アクチエゼルスカベット | ニトリルの合成方法 |
JP2021014397A (ja) * | 2019-07-11 | 2021-02-12 | コミッサリア ア レネルジー アトミーク エ オ ゼネルジ ザルタナテイヴ | 二水素製造器 |
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JP7041636B2 (ja) | 2022-03-24 |
US11059719B2 (en) | 2021-07-13 |
EP3448804B1 (en) | 2021-08-18 |
US20190112187A1 (en) | 2019-04-18 |
EP3448804A1 (en) | 2019-03-06 |
CN109071216B (zh) | 2022-04-26 |
WO2017186612A1 (en) | 2017-11-02 |
CN109071216A (zh) | 2018-12-21 |
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