JP2018537546A5 - - Google Patents
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- Publication number
- JP2018537546A5 JP2018537546A5 JP2018515840A JP2018515840A JP2018537546A5 JP 2018537546 A5 JP2018537546 A5 JP 2018537546A5 JP 2018515840 A JP2018515840 A JP 2018515840A JP 2018515840 A JP2018515840 A JP 2018515840A JP 2018537546 A5 JP2018537546 A5 JP 2018537546A5
- Authority
- JP
- Japan
- Prior art keywords
- substituted
- metathesis catalyst
- olefin metathesis
- unsubstituted
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims 12
- 238000005865 alkene metathesis reaction Methods 0.000 claims 10
- 239000002184 metal Substances 0.000 claims 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 10
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 8
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 claims 7
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- 125000005842 heteroatom Chemical group 0.000 claims 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 4
- 239000003446 ligand Substances 0.000 claims 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- -1 phenylindenylidene Chemical group 0.000 claims 4
- 238000007152 ring opening metathesis polymerisation reaction Methods 0.000 claims 3
- 125000001424 substituent group Chemical group 0.000 claims 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 2
- 125000004172 4-methoxyphenyl group Chemical group [H]C1=C([H])C(OC([H])([H])[H])=C([H])C([H])=C1* 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 125000004404 heteroalkyl group Chemical group 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 125000005538 phosphinite group Chemical group 0.000 claims 2
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims 2
- 239000011342 resin composition Substances 0.000 claims 2
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920002554 vinyl polymer Chemical group 0.000 claims 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 150000004820 halides Chemical class 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 125000001072 heteroaryl group Chemical group 0.000 claims 1
- 238000005649 metathesis reaction Methods 0.000 claims 1
- 125000003518 norbornenyl group Chemical class C12(C=CC(CC1)C2)* 0.000 claims 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021181172A JP7810545B2 (ja) | 2015-09-24 | 2021-11-05 | 金属カルベンオレフィンメタセシス触媒 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562222989P | 2015-09-24 | 2015-09-24 | |
| US62/222,989 | 2015-09-24 | ||
| PCT/US2016/053288 WO2017053690A1 (en) | 2015-09-24 | 2016-09-23 | Metal carbene olefin metathesis catalysts |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021181172A Division JP7810545B2 (ja) | 2015-09-24 | 2021-11-05 | 金属カルベンオレフィンメタセシス触媒 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018537546A JP2018537546A (ja) | 2018-12-20 |
| JP2018537546A5 true JP2018537546A5 (enExample) | 2021-02-25 |
| JP7013370B2 JP7013370B2 (ja) | 2022-01-31 |
Family
ID=58387388
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018515840A Active JP7013370B2 (ja) | 2015-09-24 | 2016-09-23 | 金属カルベンオレフィンメタセシス触媒 |
| JP2021181172A Active JP7810545B2 (ja) | 2015-09-24 | 2021-11-05 | 金属カルベンオレフィンメタセシス触媒 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021181172A Active JP7810545B2 (ja) | 2015-09-24 | 2021-11-05 | 金属カルベンオレフィンメタセシス触媒 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10501488B2 (enExample) |
| EP (1) | EP3353187B1 (enExample) |
| JP (2) | JP7013370B2 (enExample) |
| KR (1) | KR20180059489A (enExample) |
| CN (2) | CN113307830A (enExample) |
| BR (1) | BR112018005823A2 (enExample) |
| CA (1) | CA2999864A1 (enExample) |
| MX (1) | MX2018003639A (enExample) |
| PL (1) | PL3353187T3 (enExample) |
| WO (1) | WO2017053690A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10501488B2 (en) * | 2015-09-24 | 2019-12-10 | Umicore Ag & Co. Kg | Metal carbene olefin metathesis catalysts |
| KR102670566B1 (ko) * | 2019-01-18 | 2024-05-31 | 광주과학기술원 | 루테늄 착화합물, 이의 제조를 위한 리간드 및 이의 용도 |
| WO2020214399A2 (en) * | 2019-03-28 | 2020-10-22 | University Of Florida Research Foundation, Inc. | High temperature bulk metathesis polymerization |
| US20240199671A1 (en) * | 2021-03-25 | 2024-06-20 | Sigma-Aldrich Co. Llc | Novel ferrocene-based unsymmetrical ligands bearing bulky di(adamantly)phosphino motif and their metal catalysts |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4899005A (en) | 1987-11-19 | 1990-02-06 | The B. F. Goodrich Company | Method for preparing cycloolefin copolymers with improved heat stability |
| US5204427A (en) | 1989-11-01 | 1993-04-20 | Nippon Zeon Co., Ltd. | Method of making ring-opened polynorbornene polymers using pot life extending agents |
| TW350851B (en) | 1995-01-31 | 1999-01-21 | Ciba Sc Holding Ag | Polymerizable composition and process for the preparation of network polymer |
| US5728785A (en) | 1995-07-07 | 1998-03-17 | California Institute Of Technology | Romp polymerization in the presence of peroxide crosslinking agents to form high-density crosslinked polymers |
| US5939504A (en) | 1995-12-07 | 1999-08-17 | Advanced Polymer Technologies | Method for extending the pot life of an olefin metathesis polymerization reaction |
| CA2280268C (en) * | 1997-03-06 | 2007-11-20 | Ciba Specialty Chemicals Holding Inc. | New catalysts |
| DE19815275B4 (de) | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| DE69941219D1 (de) | 1998-09-10 | 2009-09-17 | Univ New Orleans Foundation | Katalysatorkomplex mit phenylindenyliden-ligand |
| DE19902439A1 (de) | 1999-01-22 | 2000-08-03 | Aventis Res & Tech Gmbh & Co | Homo- und heterobimetallische Alkylidenkomplexe des Rutheniums mit N-heterocyclischen Carbenliganden und deren Anwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| EP1196455B1 (en) | 1999-02-05 | 2008-01-16 | Materia, Inc. | Metathesis-active adhesion agents and methods for enhancing polymer adhesion to surfaces |
| US7329758B1 (en) | 1999-05-24 | 2008-02-12 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
| US6436476B1 (en) | 2000-02-14 | 2002-08-20 | Owens Corning Fiberglas Technology, Inc. | Polyolefin fiber-reinforced composites using a fiber coating composition compatible with romp catalysts |
| WO2002076613A1 (en) | 2001-03-23 | 2002-10-03 | California Institute Of Technology | High activity metal carbene metathesis catalysts generated using a thermally activated n-heterocyclic carbene precursor |
| US6838489B2 (en) | 2001-03-23 | 2005-01-04 | Cymetech, Llc | High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor |
| US6884859B2 (en) | 2001-08-29 | 2005-04-26 | California Institute Of Technology | Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms |
| MXPA05000866A (es) | 2002-07-23 | 2005-04-19 | Ppg Ind Ohio Inc | Composiciones de encolado de fibras de vidrio, fibras de vidrio encoladas, y compuestos de poliolefina. |
| AU2005228434A1 (en) * | 2004-03-29 | 2005-10-13 | California Institute Of Technology | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
| DE102006008520A1 (de) | 2006-02-22 | 2007-08-23 | Lanxess Deutschland Gmbh | Neue Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| CN101594937B (zh) * | 2006-11-21 | 2014-04-30 | 加州理工学院 | 含有亚噻唑-2-基配体的烯烃复分解反应引发剂 |
| BRPI0814994A2 (pt) | 2007-08-09 | 2015-02-03 | Elevance Renewable Sciences | Métodos químicos para tratamento de uma matéria-prima de metátese |
| EP2147721A1 (de) * | 2008-07-08 | 2010-01-27 | Lanxess Deutschland GmbH | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| GB201004732D0 (en) | 2010-03-22 | 2010-05-05 | Univ Aberdeen | Ruthenium complexes for use in olefin metathesis |
| US9597674B2 (en) * | 2011-01-14 | 2017-03-21 | California Institute Of Technology | Z-selective olefin metathesis catalysts and their synthetic procedure |
| IN2014DN00290A (enExample) | 2011-06-17 | 2015-06-05 | Materia Inc | |
| GB201116719D0 (en) | 2011-09-28 | 2011-11-09 | Univ St Andrews | Ruthenium polymerisation catalysts |
| EP2639219B1 (en) * | 2012-03-14 | 2016-08-10 | Umicore AG & Co. KG | Ruthenium-based metathesis catalysts and precursors for their preparation |
| US9728235B2 (en) * | 2012-07-17 | 2017-08-08 | SK Hynix Inc. | Semiconductor device and semiconductor memory device |
| CN105229040B (zh) * | 2013-02-27 | 2017-05-31 | 马特里亚公司 | 金属卡宾烯烃易位双催化剂组合物 |
| CN104371044B (zh) * | 2013-12-19 | 2016-09-21 | 上海克琴化工科技有限公司 | 一种钌金属催化剂的制备及其在开环易位聚合反应中的应用 |
| US10633484B2 (en) * | 2014-01-10 | 2020-04-28 | Materia, Inc. | Method and composition for improving adhesion of metathesis compositions to substrates |
| US10501488B2 (en) * | 2015-09-24 | 2019-12-10 | Umicore Ag & Co. Kg | Metal carbene olefin metathesis catalysts |
-
2016
- 2016-09-23 US US15/762,918 patent/US10501488B2/en active Active
- 2016-09-23 MX MX2018003639A patent/MX2018003639A/es unknown
- 2016-09-23 WO PCT/US2016/053288 patent/WO2017053690A1/en not_active Ceased
- 2016-09-23 PL PL16849676T patent/PL3353187T3/pl unknown
- 2016-09-23 EP EP16849676.8A patent/EP3353187B1/en active Active
- 2016-09-23 CA CA2999864A patent/CA2999864A1/en not_active Abandoned
- 2016-09-23 KR KR1020187011391A patent/KR20180059489A/ko not_active Withdrawn
- 2016-09-23 BR BR112018005823-8A patent/BR112018005823A2/en not_active Application Discontinuation
- 2016-09-23 CN CN202110611820.4A patent/CN113307830A/zh active Pending
- 2016-09-23 JP JP2018515840A patent/JP7013370B2/ja active Active
- 2016-09-23 CN CN201680055546.4A patent/CN108779134B/zh active Active
-
2021
- 2021-11-05 JP JP2021181172A patent/JP7810545B2/ja active Active