CN108779134B - 金属卡宾烯烃易位催化剂 - Google Patents
金属卡宾烯烃易位催化剂 Download PDFInfo
- Publication number
- CN108779134B CN108779134B CN201680055546.4A CN201680055546A CN108779134B CN 108779134 B CN108779134 B CN 108779134B CN 201680055546 A CN201680055546 A CN 201680055546A CN 108779134 B CN108779134 B CN 108779134B
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- China
- Prior art keywords
- substituted
- alkyl
- aryl
- phenyl
- trans
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3324—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from norbornene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
- C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
- C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/41—Organometallic coupling reactions
- C08G2261/418—Ring opening metathesis polymerisation [ROMP]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
- Catalysts (AREA)
- Polymerization Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110611820.4A CN113307830A (zh) | 2015-09-24 | 2016-09-23 | 金属卡宾烯烃易位催化剂 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562222989P | 2015-09-24 | 2015-09-24 | |
| US62/222,989 | 2015-09-24 | ||
| PCT/US2016/053288 WO2017053690A1 (en) | 2015-09-24 | 2016-09-23 | Metal carbene olefin metathesis catalysts |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110611820.4A Division CN113307830A (zh) | 2015-09-24 | 2016-09-23 | 金属卡宾烯烃易位催化剂 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108779134A CN108779134A (zh) | 2018-11-09 |
| CN108779134B true CN108779134B (zh) | 2023-10-03 |
Family
ID=58387388
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680055546.4A Active CN108779134B (zh) | 2015-09-24 | 2016-09-23 | 金属卡宾烯烃易位催化剂 |
| CN202110611820.4A Pending CN113307830A (zh) | 2015-09-24 | 2016-09-23 | 金属卡宾烯烃易位催化剂 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110611820.4A Pending CN113307830A (zh) | 2015-09-24 | 2016-09-23 | 金属卡宾烯烃易位催化剂 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US10501488B2 (enExample) |
| EP (1) | EP3353187B1 (enExample) |
| JP (2) | JP7013370B2 (enExample) |
| KR (1) | KR20180059489A (enExample) |
| CN (2) | CN108779134B (enExample) |
| BR (1) | BR112018005823A2 (enExample) |
| CA (1) | CA2999864A1 (enExample) |
| MX (1) | MX2018003639A (enExample) |
| PL (1) | PL3353187T3 (enExample) |
| WO (1) | WO2017053690A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113307830A (zh) * | 2015-09-24 | 2021-08-27 | 优美科股份公司及两合公司 | 金属卡宾烯烃易位催化剂 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102670566B1 (ko) * | 2019-01-18 | 2024-05-31 | 광주과학기술원 | 루테늄 착화합물, 이의 제조를 위한 리간드 및 이의 용도 |
| WO2020214399A2 (en) * | 2019-03-28 | 2020-10-22 | University Of Florida Research Foundation, Inc. | High temperature bulk metathesis polymerization |
| CN115819724A (zh) * | 2022-12-27 | 2023-03-21 | 上海中化科技有限公司 | 环氧-环烯烃树脂组合物、热固性树脂材料及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013045876A1 (en) * | 2011-09-28 | 2013-04-04 | University Court Of The University Of St Andrews | Ruthenium polymerisation catalysts |
| WO2014134333A1 (en) * | 2013-02-27 | 2014-09-04 | Materia, Inc. | Metal carbene olefin metathesis two catalyst composition |
| WO2015106210A1 (en) * | 2014-01-10 | 2015-07-16 | Materia, Inc. | Method and composition for improving adhesion of metathesis compositions to substrates |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4899005A (en) | 1987-11-19 | 1990-02-06 | The B. F. Goodrich Company | Method for preparing cycloolefin copolymers with improved heat stability |
| US5204427A (en) | 1989-11-01 | 1993-04-20 | Nippon Zeon Co., Ltd. | Method of making ring-opened polynorbornene polymers using pot life extending agents |
| TW350851B (en) | 1995-01-31 | 1999-01-21 | Ciba Sc Holding Ag | Polymerizable composition and process for the preparation of network polymer |
| US5728785A (en) | 1995-07-07 | 1998-03-17 | California Institute Of Technology | Romp polymerization in the presence of peroxide crosslinking agents to form high-density crosslinked polymers |
| US5939504A (en) | 1995-12-07 | 1999-08-17 | Advanced Polymer Technologies | Method for extending the pot life of an olefin metathesis polymerization reaction |
| WO1998039346A1 (en) * | 1997-03-06 | 1998-09-11 | Ciba Specialty Chemicals Holding Inc. | New catalysts |
| DE19815275B4 (de) | 1998-04-06 | 2009-06-25 | Evonik Degussa Gmbh | Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| DE69941219D1 (de) | 1998-09-10 | 2009-09-17 | Univ New Orleans Foundation | Katalysatorkomplex mit phenylindenyliden-ligand |
| DE19902439A1 (de) | 1999-01-22 | 2000-08-03 | Aventis Res & Tech Gmbh & Co | Homo- und heterobimetallische Alkylidenkomplexe des Rutheniums mit N-heterocyclischen Carbenliganden und deren Anwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese |
| JP2002536468A (ja) | 1999-02-05 | 2002-10-29 | マテリア インコーポレイテッド | 表面へのポリマー接着を増強するためのメタセシス活性接着剤及び方法 |
| US7329758B1 (en) | 1999-05-24 | 2008-02-12 | California Institute Of Technology | Imidazolidine-based metal carbene metathesis catalysts |
| US6436476B1 (en) | 2000-02-14 | 2002-08-20 | Owens Corning Fiberglas Technology, Inc. | Polyolefin fiber-reinforced composites using a fiber coating composition compatible with romp catalysts |
| US6838489B2 (en) | 2001-03-23 | 2005-01-04 | Cymetech, Llc | High activity metal carbene metathesis catalysts generated using a thermally activated N-heterocyclic carbene precursor |
| JP4402354B2 (ja) | 2001-03-23 | 2010-01-20 | カリフォルニア インスティチュート オブ テクノロジー | 熱活性化n−複素環カルベン前駆体の使用により生成される高活性金属カルベンメタセシス触媒 |
| EP2251360B1 (en) | 2001-08-29 | 2013-07-31 | California Institute of Technology | Ring-opening metathesis polymerization of bridged bicyclic and polycyclic olefins containing two or more heteroatoms |
| AU2003252128A1 (en) | 2002-07-23 | 2004-02-09 | Ppg Industries Ohio, Inc. | Glass fiber sizing compositions, sized glass fibers, and polyolefin composites |
| WO2005094345A2 (en) * | 2004-03-29 | 2005-10-13 | California Institute Of Technology | Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand |
| DE102006008520A1 (de) | 2006-02-22 | 2007-08-23 | Lanxess Deutschland Gmbh | Neue Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| EP2104566B1 (en) * | 2006-11-21 | 2016-01-27 | California Institute Of Technology | Olefin metathesis initiators bearing thiazol-2-ylidene ligands |
| BRPI0814994A2 (pt) * | 2007-08-09 | 2015-02-03 | Elevance Renewable Sciences | Métodos químicos para tratamento de uma matéria-prima de metátese |
| EP2147721A1 (de) | 2008-07-08 | 2010-01-27 | Lanxess Deutschland GmbH | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
| GB201004732D0 (en) | 2010-03-22 | 2010-05-05 | Univ Aberdeen | Ruthenium complexes for use in olefin metathesis |
| PL2663398T3 (pl) * | 2011-01-14 | 2019-01-31 | California Institute Of Technology | Katalizatory Z-selektywnej metatezy olefin i sposób ich syntezy |
| BR112013032369B1 (pt) | 2011-06-17 | 2021-08-24 | Materia, Inc | Composição de resina, método para melhorar a adesão da referida composição de resina e uso de pelo menos um promotor de adesão |
| EP2639219B1 (en) * | 2012-03-14 | 2016-08-10 | Umicore AG & Co. KG | Ruthenium-based metathesis catalysts and precursors for their preparation |
| US9728235B2 (en) * | 2012-07-17 | 2017-08-08 | SK Hynix Inc. | Semiconductor device and semiconductor memory device |
| CN104371044B (zh) * | 2013-12-19 | 2016-09-21 | 上海克琴化工科技有限公司 | 一种钌金属催化剂的制备及其在开环易位聚合反应中的应用 |
| CN108779134B (zh) * | 2015-09-24 | 2023-10-03 | 优美科股份公司及两合公司 | 金属卡宾烯烃易位催化剂 |
-
2016
- 2016-09-23 CN CN201680055546.4A patent/CN108779134B/zh active Active
- 2016-09-23 EP EP16849676.8A patent/EP3353187B1/en active Active
- 2016-09-23 CN CN202110611820.4A patent/CN113307830A/zh active Pending
- 2016-09-23 BR BR112018005823A patent/BR112018005823A2/pt not_active Application Discontinuation
- 2016-09-23 MX MX2018003639A patent/MX2018003639A/es unknown
- 2016-09-23 JP JP2018515840A patent/JP7013370B2/ja active Active
- 2016-09-23 WO PCT/US2016/053288 patent/WO2017053690A1/en not_active Ceased
- 2016-09-23 CA CA2999864A patent/CA2999864A1/en not_active Abandoned
- 2016-09-23 PL PL16849676T patent/PL3353187T3/pl unknown
- 2016-09-23 US US15/762,918 patent/US10501488B2/en active Active
- 2016-09-23 KR KR1020187011391A patent/KR20180059489A/ko not_active Withdrawn
-
2021
- 2021-11-05 JP JP2021181172A patent/JP2022010098A/ja active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013045876A1 (en) * | 2011-09-28 | 2013-04-04 | University Court Of The University Of St Andrews | Ruthenium polymerisation catalysts |
| WO2014134333A1 (en) * | 2013-02-27 | 2014-09-04 | Materia, Inc. | Metal carbene olefin metathesis two catalyst composition |
| WO2015106210A1 (en) * | 2014-01-10 | 2015-07-16 | Materia, Inc. | Method and composition for improving adhesion of metathesis compositions to substrates |
Non-Patent Citations (1)
| Title |
|---|
| Synthesis, Structure, and Activity of Enhanced Initiators for Olefin Metathesis;Jennifer A. Love et al.,;《J.Am.Chem.Soc.》;20020626;第125卷;第10103-10109页,参见第10105页图2化合物5 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113307830A (zh) * | 2015-09-24 | 2021-08-27 | 优美科股份公司及两合公司 | 金属卡宾烯烃易位催化剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2018003639A (es) | 2019-04-25 |
| CN108779134A (zh) | 2018-11-09 |
| CN113307830A (zh) | 2021-08-27 |
| BR112018005823A2 (pt) | 2018-10-16 |
| EP3353187A4 (en) | 2019-05-01 |
| CA2999864A1 (en) | 2017-03-30 |
| EP3353187B1 (en) | 2021-07-21 |
| JP2018537546A (ja) | 2018-12-20 |
| US20180265532A1 (en) | 2018-09-20 |
| US10501488B2 (en) | 2019-12-10 |
| JP7013370B2 (ja) | 2022-01-31 |
| KR20180059489A (ko) | 2018-06-04 |
| JP2022010098A (ja) | 2022-01-14 |
| EP3353187A1 (en) | 2018-08-01 |
| PL3353187T3 (pl) | 2021-11-22 |
| WO2017053690A1 (en) | 2017-03-30 |
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| GR01 | Patent grant | ||
| GR01 | Patent grant |