JP2018519374A - 生分解性炭化水素流体の製造方法 - Google Patents
生分解性炭化水素流体の製造方法 Download PDFInfo
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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Abstract
Description
−圧力:80〜150バール、好ましくは90〜120バール
−温度:120〜160℃、好ましくは150〜160℃
−液空間速度(LHSV):0.4〜3、好ましくは0.5〜0.8
−水素処理率は供給物の200Nm3/トンまで。
−混合量(合計量)が80〜98%の、C15イソパラフィンおよびC16イソパラフィン;または、
−混合量が80〜98%の、C16イソパラフィン、C17イソパラフィンおよびC18イソパラフィン;または、
−混合量が80〜98%の、C17イソパラフィンおよびC18イソパラフィン;
を含む。
−流体は、3%未満、好ましくは1%未満、より好ましくは約0%のCquatとして表される炭素を含む;
−流体は、20%未満、好ましくは18%未満、より好ましくは15%未満の飽和CHで表される炭素を含む;
−流体は、40%を超え、好ましくは50%を超え、より好ましくは60%を超える飽和CH2で表される炭素を含む;
−流体は、30%未満、好ましくは28%未満、より好ましくは25%未満の飽和CH3で表される炭素を含む;
−流体は、20%未満、好ましくは18%未満、より好ましくは15%未満の長鎖CH3で表される炭素を含む;
−流体は、15%未満、好ましくは10%未満、より好ましくは9%未満の短鎖CH3で表される炭素を含む。
供給原料または単に供給物は、バイオマスで実施されるように、以降は「HDO/ISO」と称する水素化脱酸素後の異性化処理の結果である供給物である。
HDO/ISOから生じた供給原料は次いで水素化される。供給原料はオプションで予備分留することができる。
−圧力:50〜160バール、好ましくは80〜150バール、最も好ましくは90〜120バール;
−温度:80〜180℃、好ましくは120〜160℃、最も好ましくは150〜160℃;
−液空間速度(LHSV):0.2〜5hr−1、好ましくは0.4〜3hr−1、最も好ましくは0.5〜0.8hr−1;
−水素処理率:上記条件に適合し、供給物の200Nm3/トンまでとすることができる。
本発明の流体は、以降は単に「改良流体」と称するが、アニリン点または溶解力、分子量、蒸気圧、粘度、乾燥が重要であるシステムのための定義された蒸発条件、および定義された表面張力の点で優れた特性を有する。
−混合量が80〜98%のC15イソパラフィンおよびC16イソパラフィン;または、
−混合量が80〜98%のC16イソパラフィン、C17イソパラフィンおよびC18イソパラフィン;または、
−混合量が80〜98%のC17イソパラフィンおよびC18イソパラフィン。
−30〜70%のC15イソパラフィンおよび30〜70%のC16イソパラフィン、好ましくは40〜60%のC15イソパラフィンおよび35〜55%のC16イソパラフィン;
−5〜25%のC15イソパラフィン、30〜70%のC16イソパラフィンおよび10〜40%のC17イソパラフィン、好ましくは8〜15%のC15イソパラフィン、40〜60%のC16イソパラフィンおよび15〜25%のC17イソパラフィン;
−5〜30%のC17イソパラフィンおよび70〜95%のC18イソパラフィン、好ましくは10〜25%のC17イソパラフィンおよび70〜90%のC18イソパラフィン。
NEXBTL供給原料(イソアルカン)である供給原料を、本発明の方法において使用した。水素化のための以下の条件を使用した。
Claims (17)
- 100〜400℃の範囲の沸点を有し、95重量%を超えるイソパラフィンを含み、100重量ppm未満の芳香族を含む流体の製造方法であって、95重量%を超える水素化脱酸素化および異性化された炭化水素バイオマス原料を含む供給物を、80〜180℃の温度で、50〜160バールの圧力で、0.2〜5hr−1の液空間速度で、および、200Nm3/トンまでの供給物の水素処理率で触媒的に水素化するステップを含む、方法。
- 水素化条件は、
−圧力:80〜150バール、好ましくは90〜120バールであり、
−温度:120〜160℃、好ましくは150〜160℃であり、
−液空間速度(LHSV):0.4〜3、好ましくは0.5〜0.8であり、
−水素処理率は供給物の200Nm3/トンまで、
である請求項1に記載の方法。 - 前記供給物は、98%を超え、好ましくは99%を超える水素化脱酸素化および異性化された炭化水素バイオマス原料を含み、より好ましくは水素化脱酸素化および異性化された炭化水素バイオマス原料からなる、請求項1または2に記載の方法。
- 前記バイオマスは、植物油、植物油のエステルまたは植物油のトリグリセリドであり、有利には、前記供給物はNEXBTL供給物である、請求項1〜3のいずれか一項に記載の方法。
- (i)分留ステップは、前記水素化ステップの前、若しくは前記水素化ステップの後、若しくはその両方で実施され、または(ii)前記方法は、好ましくは3つの別個の反応器において3つの水素化段階を含み、または(iii)(i)および(ii)の両方である、請求項1〜4のいずれか一項に記載の方法。
- 前記流体は、150〜400℃、好ましくは200〜400℃、特に220〜340℃、有利には250℃超340℃以下の沸点を有し、および/または80℃未満、好ましくは60℃未満、有利には40〜50℃の沸点範囲を有する、請求項1〜5のいずれか一項に記載の方法。
- 前記流体は、50重量ppm未満、好ましくは20重量ppm未満の芳香族を含む、請求項1〜6のいずれか一項に記載の方法。
- 前記流体は、3重量%未満、好ましくは1重量%未満、有利には50重量ppm未満のナフテンを含む、請求項1〜7のいずれか一項に記載の方法。
- 前記流体は、98重量%を超えるイソパラフィンを含む、請求項1〜8のいずれか一項に記載の方法。
- 前記流体は、イソパラフィン対n−パラフィンの比が少なくとも12:1、好ましくは少なくとも15:1、より好ましくは少なくとも20:1である、請求項1〜9のいずれか一項に記載の方法。
- 前記流体は、イソパラフィンとして14〜18個の炭素原子を含む分子を95重量%超含み、好ましくは、C15イソパラフィン、C16イソパラフィン、C17イソパラフィン、C18イソパラフィンおよびそれらの2種以上の混合物からなる群から選択されるイソパラフィンを、60〜95重量%、より好ましくは80〜98重量%含む、請求項1〜10のいずれか一項に記載の方法。
- 前記流体は、
−混合量が80〜98%のC15イソパラフィンおよびC16イソパラフィン、または、
−混合量が80〜98%のC16イソパラフィン、C17イソパラフィンおよびC18イソパラフィン、または、
−混合量が80〜98%のC17イソパラフィンおよびC18イソパラフィン、
を含む、請求項1〜11のいずれか一項に記載の方法。 - 前記流体は以下の特徴の1つ以上、好ましくは全てを示す、請求項1〜12のいずれか一項に記載の方法:
−前記流体は、3%未満、好ましくは1%未満、より好ましくは約0%のCquatとして表される炭素を含む、
−前記流体は、20%未満、好ましくは18%未満、より好ましくは15%未満の飽和CHとして表される炭素を含む、
−前記流体は、40%を超え、好ましくは50%を超え、より好ましくは60%を超える飽和CH2として表される炭素を含み、
−前記流体は、30%未満、好ましくは28%未満、より好ましくは25%未満の飽和CH3として表される炭素を含む、
−流体は、20%未満、好ましくは18%未満、より好ましくは15%未満の長鎖CH3として表される炭素を含む、
−流体は、15%未満、好ましくは10%未満、より好ましくは9%未満の短鎖CH3として表される炭素を含む。 - 前記流体は、OECD基準306にしたがって測定される28日での生分解性が少なくとも60%、好ましくは少なくとも70%、より好ましくは少なくとも75%、有利には少なくとも80%である、請求項1〜13のいずれか一項に記載の方法。
- 前記流体は、バイオカーボン含有量が少なくとも95%、好ましくは少なくとも97%、より好ましくは少なくとも98%、さらにより好ましくは約100%である、請求項1〜14のいずれか一項に記載の方法。
- 100〜400℃の範囲の沸点および80℃未満の沸点範囲を有する流体であって、前記流体は、95重量%を超えるイソパラフィンおよび3重量%未満のナフテンを含み、イソパラフィン対n−パラフィンの比が少なくとも12:1であり、OECD基準306にしたがって測定される28日での生分解性が少なくとも60%であり、バイオカーボン含有量が少なくとも95重量%であり、100重量ppm未満の芳香族を含み、30%未満の飽和CH3として表される炭素を含む、流体。
- 請求項6〜15のいずれか一項に記載の特性を有する、請求項16に記載の流体。
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Application Number | Title | Priority Date | Filing Date |
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JP2017559870A Ceased JP2018519374A (ja) | 2015-05-20 | 2016-05-20 | 生分解性炭化水素流体の製造方法 |
Country Status (11)
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US (1) | US10435634B2 (ja) |
EP (2) | EP3095838A1 (ja) |
JP (1) | JP2018519374A (ja) |
KR (1) | KR20180009759A (ja) |
CN (1) | CN107690469B (ja) |
AU (1) | AU2016265462A1 (ja) |
BR (1) | BR112017024507A2 (ja) |
CA (1) | CA2985887A1 (ja) |
IL (1) | IL255642A (ja) |
RU (1) | RU2716823C2 (ja) |
WO (1) | WO2016185046A1 (ja) |
Cited By (1)
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JP2021508724A (ja) * | 2017-12-29 | 2021-03-11 | ネステ オサケ ユキチュア ユルキネン | 溶媒としての使用のための、再生可能な高度にイソパラフィン化された蒸留物 |
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FR3143625A1 (fr) | 2022-12-19 | 2024-06-21 | Totalenergies Onetech | Composition de carburant comprenant une base renouvelable, un ester d’acide gras et un additif polysiloxane |
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- 2016-05-20 AU AU2016265462A patent/AU2016265462A1/en not_active Abandoned
- 2016-05-20 CN CN201680031725.4A patent/CN107690469B/zh not_active Expired - Fee Related
- 2016-05-20 JP JP2017559870A patent/JP2018519374A/ja not_active Ceased
- 2016-05-20 US US15/574,569 patent/US10435634B2/en not_active Expired - Fee Related
- 2016-05-20 BR BR112017024507A patent/BR112017024507A2/pt not_active Application Discontinuation
- 2016-05-20 EP EP16724051.4A patent/EP3298107A1/en not_active Withdrawn
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- 2016-05-20 WO PCT/EP2016/061504 patent/WO2016185046A1/en active Application Filing
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2017
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2021508724A (ja) * | 2017-12-29 | 2021-03-11 | ネステ オサケ ユキチュア ユルキネン | 溶媒としての使用のための、再生可能な高度にイソパラフィン化された蒸留物 |
JP7304865B2 (ja) | 2017-12-29 | 2023-07-07 | ネステ オサケ ユキチュア ユルキネン | 溶媒としての使用のための、再生可能な高度にイソパラフィン化された蒸留物 |
Also Published As
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RU2017141915A3 (ja) | 2019-09-23 |
US10435634B2 (en) | 2019-10-08 |
CN107690469A (zh) | 2018-02-13 |
EP3095838A1 (en) | 2016-11-23 |
RU2017141915A (ru) | 2019-06-20 |
CA2985887A1 (en) | 2016-11-24 |
EP3298107A1 (en) | 2018-03-28 |
AU2016265462A1 (en) | 2017-12-21 |
US20180148656A1 (en) | 2018-05-31 |
RU2716823C2 (ru) | 2020-03-17 |
CN107690469B (zh) | 2021-06-29 |
WO2016185046A1 (en) | 2016-11-24 |
IL255642A (en) | 2018-01-31 |
KR20180009759A (ko) | 2018-01-29 |
BR112017024507A2 (pt) | 2018-07-24 |
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