JP2018505832A - 銅含有導電性ストリップを備えたガラス基材 - Google Patents
銅含有導電性ストリップを備えたガラス基材 Download PDFInfo
- Publication number
- JP2018505832A JP2018505832A JP2017532158A JP2017532158A JP2018505832A JP 2018505832 A JP2018505832 A JP 2018505832A JP 2017532158 A JP2017532158 A JP 2017532158A JP 2017532158 A JP2017532158 A JP 2017532158A JP 2018505832 A JP2018505832 A JP 2018505832A
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- JP
- Japan
- Prior art keywords
- strip
- copper
- glazing
- silver
- paste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 79
- 239000010949 copper Substances 0.000 title claims abstract description 79
- 239000011521 glass Substances 0.000 title claims abstract description 42
- 239000000758 substrate Substances 0.000 title description 5
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 58
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910052709 silver Inorganic materials 0.000 claims abstract description 54
- 239000004332 silver Substances 0.000 claims abstract description 54
- 239000000203 mixture Substances 0.000 claims abstract description 36
- 230000001681 protective effect Effects 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims description 15
- 238000000151 deposition Methods 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000010304 firing Methods 0.000 claims description 9
- 238000007650 screen-printing Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 235000013305 food Nutrition 0.000 claims description 3
- 230000006698 induction Effects 0.000 claims description 3
- 238000007639 printing Methods 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 2
- 239000004020 conductor Substances 0.000 claims 1
- 238000009304 pastoral farming Methods 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000003570 air Substances 0.000 description 3
- 239000005340 laminated glass Substances 0.000 description 3
- 229910052596 spinel Inorganic materials 0.000 description 3
- 239000011029 spinel Substances 0.000 description 3
- 239000005341 toughened glass Substances 0.000 description 3
- 238000004320 controlled atmosphere Methods 0.000 description 2
- 239000001023 inorganic pigment Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003985 ceramic capacitor Substances 0.000 description 1
- ZTXONRUJVYXVTJ-UHFFFAOYSA-N chromium copper Chemical compound [Cr][Cu][Cr] ZTXONRUJVYXVTJ-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- HPDFFVBPXCTEDN-UHFFFAOYSA-N copper manganese Chemical compound [Mn].[Cu] HPDFFVBPXCTEDN-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
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- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
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- B32B17/10165—Functional features of the laminated safety glass or glazing
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- B32B17/10385—Laminated safety glass or glazing containing metal wires for ohmic resistance heating
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- C03C17/3673—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having electrical properties specially adapted for use in heating devices for rear window of vehicles
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/84—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
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- H—ELECTRICITY
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- H—ELECTRICITY
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- H05K1/02—Details
- H05K1/09—Use of materials for the conductive, e.g. metallic pattern
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
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- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
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-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/011—Heaters using laterally extending conductive material as connecting means
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
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- H05B2203/013—Heaters using resistive films or coatings
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/016—Heaters using particular connecting means
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2203/00—Aspects relating to Ohmic resistive heating covered by group H05B3/00
- H05B2203/017—Manufacturing methods or apparatus for heaters
-
- H—ELECTRICITY
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- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
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- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/12—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using thick film techniques, e.g. printing techniques to apply the conductive material or similar techniques for applying conductive paste or ink patterns
- H05K3/1275—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using thick film techniques, e.g. printing techniques to apply the conductive material or similar techniques for applying conductive paste or ink patterns by other printing techniques, e.g. letterpress printing, intaglio printing, lithographic printing, offset printing
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Composite Materials (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
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Abstract
Description
・ストリップを形成するためガラス板の面のうちの少なくとも一方のものの少なくとも一部分に銀ペーストの層を被着させる工程、
・別のストリップを形成するため銅ペーストの層を被着させる工程、
その際、これらの被着の工程は2つの層の間に少なくとも1つの接触ゾーンが存在するように行い、その後、
・銅ペーストの層の全体を覆って保護エナメル層を被着させる工程、及び、
・被着させた層の全てを空気中において550℃と700℃の間の温度で2〜10分間焼成する工程、
を含む。
Claims (15)
- 抵抗ストリップと集電体ストリップとからなる電気ネットワークを面のうちの一方に備えた少なくとも1枚のガラス板を含むグレージングであって、一方の面のうちの少なくとも一部分は、銀ペーストを含む導電性組成物から得られた少なくとも1つのストリップを含み、該ストリップは、銅ペーストを含む導電性組成物から得られた別のストリップと接触しており、銅ペーストを含む導電性組成物から得られた該別のストリップは、保護エナメル層で完全に覆われていることを特徴とする、グレージング。
- 銅ペーストを含む導電性組成物から得られたストリップの末端において銅ストリップと銀ストリップとの接触がなされていることを特徴とする、請求項1記載のグレージング。
- 銅ストリップが銀ストリップを部分的に覆っていることを特徴とする、請求項1又は2記載のグレージング。
- 銀ストリップが銅ストリップを部分的に覆っていることを特徴とする、請求項1又は2記載のグレージング。
- 銅ストリップ及び/又は銀ストリップがガラス板の上に被着させたエナメル層の上に位置していることを特徴とする、請求項1〜4の1つに記載のグレージング。
- 銅ベースの導電性組成物が70重量%と90重量%の間の銅粉末と15重量%未満のガラスフリットを含むことを特徴とする、請求項5記載のグレージング。
- 銅ペーストを含むストリップの、焼成後に測定した厚さが5μmと50μmの間、好ましくは5μmと30μmの間であることを特徴とする、請求項1〜6の1つに記載のグレージング。
- 銅ストリップを覆う保護エナメル層の、焼成後に測定した厚さが5μmと40μmの間、好ましくは10μmと30μmの間であることを特徴とする、請求項1〜7の1つに記載のグレージング。
- 少なくとも1つの面のうちの一部分が、銅ペーストをベースとする導電性組成物から得られそして保護エナメル層で覆われた集電体ストリップ及び/又は抵抗ストリップを含むことを特徴とする、請求項1〜8の1つに記載のグレージング。
- 銅の抵抗ストリップがガラス板の上に直接被着され、そして顔料を含まない保護エナメル層で覆われていることを特徴とする、請求項9記載のグレージング。
- 請求項1〜10の1つに記載のグレージングを製造するための方法であって、
・ストリップを形成するためガラス板の面のうちの少なくとも一方のものに銀ペーストの層を被着させる工程、
・別のストリップを形成するため銅ペーストの層を被着させる工程、
その際、これらの被着の工程は2つの層の間に少なくとも1つの接触ゾーンが存在するように行い、その後、
・銅ペーストの層の全体を覆って保護エナメル層を被着させる工程、及び、
・被着させた層の全てを空気中において550℃と700℃の間の温度で2〜10分間焼成する工程、
を含むことを特徴とする、グレージング製造方法。 - 被着させる工程のうちの少なくとも一方をスクリーン印刷により行うことを特徴とする、請求項11記載の方法。
- 被着させる工程のうちの少なくとも一方をデジタル印刷により行うことを特徴とする、請求項11記載の方法。
- 銅ペースト及び/又は銀ペーストの層を被着させる工程を実施するガラス板の面上にエナメル層を被着させる事前の工程を含むことを特徴とする、請求項11〜13の1つに記載の方法。
- 請求項1〜10の1つに記載のグレージングを含む、加熱フロントガラス、レインセンサー、アンテナ、輻射加熱装置、誘導ホブ、食品加温装置、又は太陽電池集電体。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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FR1462758A FR3030493B1 (fr) | 2014-12-18 | 2014-12-18 | Substrat en verre muni de bandes conductrices a base de cuivre |
FR1462758 | 2014-12-18 | ||
PCT/FR2015/053508 WO2016097579A1 (fr) | 2014-12-18 | 2015-12-15 | Substrat en verre muni de bandes conductrices a base de cuivre |
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JP2018505832A true JP2018505832A (ja) | 2018-03-01 |
JP6701197B2 JP6701197B2 (ja) | 2020-05-27 |
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JP2017532158A Active JP6701197B2 (ja) | 2014-12-18 | 2015-12-15 | 銅含有導電性ストリップを備えたガラス基材 |
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US (1) | US11510288B2 (ja) |
EP (1) | EP3233480B1 (ja) |
JP (1) | JP6701197B2 (ja) |
KR (1) | KR20170095967A (ja) |
CN (1) | CN105934416B (ja) |
BR (1) | BR112017010688B1 (ja) |
CA (1) | CA2967172A1 (ja) |
EA (1) | EA034949B1 (ja) |
ES (1) | ES2726681T3 (ja) |
FR (1) | FR3030493B1 (ja) |
MX (1) | MX2017007920A (ja) |
PL (1) | PL3233480T3 (ja) |
PT (1) | PT3233480T (ja) |
TR (1) | TR201907248T4 (ja) |
WO (1) | WO2016097579A1 (ja) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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FR3054771B1 (fr) * | 2016-07-27 | 2020-11-06 | Saint Gobain | Vitrage muni d'un dispositif conducteur electrique avec zones de soudure ameliorees |
WO2019064738A1 (ja) * | 2017-09-29 | 2019-04-04 | 株式会社村田製作所 | 導電性ペースト、ガラス物品、及びガラス物品の製造方法 |
WO2020019120A1 (zh) * | 2018-07-23 | 2020-01-30 | 湖北中烟工业有限责任公司 | 一种陶瓷发热体及其制备方法和用途 |
CN110450480B (zh) * | 2019-08-29 | 2024-01-02 | 邢台秉润玻璃技术有限公司 | 电磁屏蔽式防弹玻璃 |
FR3103809B1 (fr) * | 2019-11-29 | 2022-05-27 | Saint Gobain | Procédé d’obtention de vitrages munis de motifs électroconducteurs |
DE102022109687A1 (de) | 2022-04-21 | 2023-10-26 | Irlbacher Blickpunkt Glas Gmbh | Abdeckung aus Glas mit einer Beschichtung zur Enteisung |
Family Cites Families (16)
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US2777044A (en) * | 1951-12-15 | 1957-01-08 | Pittsburgh Plate Glass Co | Electrical heating device |
US3813519A (en) * | 1964-11-09 | 1974-05-28 | Saint Gobain | Electrically heated glass window |
FR1544718A (fr) * | 1966-08-08 | 1968-11-08 | Triplex Safety Glass Co | Procédé pour appliquer au moins un conducteur électrique à un corps vitreux mauvais conducteur |
FR2188025B1 (ja) * | 1972-06-01 | 1974-07-26 | Saint Gobain Pont A Mousson | |
US4450346A (en) | 1981-05-14 | 1984-05-22 | Ford Motor Company | Electric heater plate |
FR2509947A1 (fr) * | 1981-07-15 | 1983-01-21 | Saint Gobain Vitrage | Vitrage chauffant electrique |
US4637862A (en) * | 1985-12-16 | 1987-01-20 | General Motors Corporation | Wire-glass composite and method of making same |
US5902505A (en) * | 1988-04-04 | 1999-05-11 | Ppg Industries, Inc. | Heat load reduction windshield |
US5911899A (en) * | 1995-06-15 | 1999-06-15 | Mitsui Chemicals, Inc. | Corrosion-proof transparent heater panels and preparation process thereof |
DE19844046C2 (de) * | 1998-09-25 | 2001-08-23 | Schott Glas | Mehrscheibenisolierglas |
FR2841432A1 (fr) * | 2002-06-20 | 2003-12-26 | Saint Gobain | Procede de fabrication de motifs electroconducteurs sur un substrat transparent et substrat obtenu |
WO2005068385A1 (fr) * | 2003-12-19 | 2005-07-28 | Saint-Gobain Glass France | Procede de fabrication de motifs electroconducteurs sur un substrat transparent et substrat obtenu |
GB0512077D0 (en) | 2005-06-14 | 2005-07-20 | Pilkington Plc | Glazing |
CN201397399Y (zh) * | 2009-05-25 | 2010-02-03 | 林嘉宏 | 银镜 |
CN201542190U (zh) * | 2009-12-09 | 2010-08-11 | 唐远贵 | 电热式防雾银镜 |
EP2405708A1 (de) * | 2010-07-07 | 2012-01-11 | Saint-Gobain Glass France | Transparente Scheibe mit heizbarer Beschichtung |
-
2014
- 2014-12-18 FR FR1462758A patent/FR3030493B1/fr not_active Expired - Fee Related
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- 2015-12-15 PT PT15821123T patent/PT3233480T/pt unknown
- 2015-12-15 KR KR1020177019435A patent/KR20170095967A/ko not_active Application Discontinuation
- 2015-12-15 JP JP2017532158A patent/JP6701197B2/ja active Active
- 2015-12-15 TR TR2019/07248T patent/TR201907248T4/tr unknown
- 2015-12-15 BR BR112017010688-4A patent/BR112017010688B1/pt not_active IP Right Cessation
- 2015-12-15 EA EA201791368A patent/EA034949B1/ru not_active IP Right Cessation
- 2015-12-15 CA CA2967172A patent/CA2967172A1/fr not_active Abandoned
- 2015-12-15 WO PCT/FR2015/053508 patent/WO2016097579A1/fr active Application Filing
- 2015-12-15 EP EP15821123.5A patent/EP3233480B1/fr active Active
- 2015-12-15 CN CN201580002466.8A patent/CN105934416B/zh active Active
- 2015-12-15 US US15/536,837 patent/US11510288B2/en active Active
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Publication number | Publication date |
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CN105934416B (zh) | 2019-06-07 |
EA034949B1 (ru) | 2020-04-09 |
JP6701197B2 (ja) | 2020-05-27 |
TR201907248T4 (tr) | 2019-06-21 |
EP3233480B1 (fr) | 2019-02-20 |
CN105934416A (zh) | 2016-09-07 |
PL3233480T3 (pl) | 2019-09-30 |
ES2726681T3 (es) | 2019-10-08 |
FR3030493B1 (fr) | 2016-12-30 |
FR3030493A1 (fr) | 2016-06-24 |
KR20170095967A (ko) | 2017-08-23 |
US20170347403A1 (en) | 2017-11-30 |
CA2967172A1 (fr) | 2016-06-23 |
BR112017010688A2 (pt) | 2018-02-14 |
WO2016097579A1 (fr) | 2016-06-23 |
EP3233480A1 (fr) | 2017-10-25 |
US11510288B2 (en) | 2022-11-22 |
EA201791368A1 (ru) | 2017-10-31 |
MX2017007920A (es) | 2017-09-05 |
PT3233480T (pt) | 2019-05-28 |
BR112017010688B1 (pt) | 2022-03-15 |
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