JP2018131393A - Aqueous make-up cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an aqueous make-up cosmetic that gives a uniform cosmetic film, includes a brilliant powder with excellent glossy feeling and cosmetic persistence, and prevents the brilliant powder from peeling off upon physical contact (secondary adhesion prevention).SOLUTION: An aqueous make-up cosmetic contains (A) water-soluble polysaccharide, (B) specific silicone phosphoric acid triester, (C) water, and (D) brilliant powder.SELECTED DRAWING: None

Description

  The present invention relates to a makeup cosmetic, and more specifically, by containing a water-soluble polysaccharide, a silicone phosphate triester, water, and a glitter powder, the gloss feeling of the glitter powder in a uniform cosmetic film. The present invention relates to a water-based makeup cosmetic that is excellent in makeup persistence and that the glittering powder is difficult to peel off due to physical contact (less effect of secondary adhesion).

  Makeup cosmetics are required to have a high pearly luster for application to the eyelids and cheeks, shading, and producing a cosmetic effect. Aqueous makeup cosmetics containing glitter powder in a base formed with a gel using water and an aqueous gelling agent can produce a glossy and watery feeling with transparency. Is preferred. Aqueous makeup cosmetics are composed of an aqueous gelling agent, powder, water, etc., and in order to improve the feeling of use and functionality required for cosmetics, studies have been made on dosage forms and ingredients.

  For example, in order to obtain glossiness of pearl powder, a technique (Patent Document 1) using a water-based thickening / gelling agent such as gellan gum or an alkyl acrylate copolymer polymer emulsion and pearly luster powder, or a uniform cosmetic film Technology that uses gellan gum and glycerin to enhance the properties (Patent Document 2), Technology that uses a specific fluorine-containing copolymer to obtain a makeup film with a pearly luster powder and a uniform cosmetic film (Patent Document 3), etc. Has been studied.

JP-A-2005-97148 JP 2004-292375 A JP 2012-193148 A

  However, since these cosmetics are water-based, they tend to lack makeup, especially glittering powders with large particle sizes are peeled off with sweat, peeled off when touched with fingers, and eyeshadows. It wasn't satisfactory for a long-lasting makeup, such as transferring it when blinking. Moreover, in the technique (patent document 2) containing gellan gum and glycerin, the dispersibility to an aqueous system is good, and a uniform makeup film is obtained, but it is weak against sweat and a satisfactory makeup cannot be obtained. With the technology (Patent Document 3) containing a specific fluorine-containing copolymer, a flexible and uniform decorative film can be obtained, and the durability of the glittering powder can be improved. Transfer resistance against physical contact (secondary adhesion) A sufficient effect was not obtained for the “less effect”.

  In view of the above circumstances, the present invention is a uniform decorative film, excellent in glossiness and makeup durability of the glitter powder, and the glitter powder is difficult to peel off against physical contact (secondary adhesion-less effect). It is an object to provide an aqueous makeup cosmetic.

  The inventors of the present invention can enhance the long-lasting effect by including an ingredient having a high affinity for the skin and a low tackiness in an aqueous makeup cosmetic using a water-soluble polysaccharide. As a result of examining the inclusion of various components, the inclusion of a specific silicone phosphate triester has high adhesion to the skin and is less sticky to the surface (tackiness). The present invention has been completed by finding that a decorative film that does not easily peel off by simple contact can be produced.

That is, the present invention provides the following components (A) to (D);
(A) Water-soluble polysaccharide (B) Formula (1)
(In the formula, each R 1 independently represents an alkyl group having 1 to 4 carbon atoms, and R 2 may have at least one selected from —O— and —CO—. Water-based makeup containing a silicone phosphoric acid triester (C) water (D) glittering powder represented by 7 represents a divalent hydrocarbon group of 7 and n represents any integer of 5 to 40) It provides cosmetics.

  The water-based makeup cosmetic is provided with a content of the component (B) of 0.05 to 10% by mass.

  The water-based makeup cosmetics having a content of the component (A) of 0.1 to 5% by mass are provided.

  The water-based makeup cosmetics having a content of the component (D) of 0.1 to 60% by mass are provided.

  Provided is the aqueous makeup cosmetic wherein the mass ratio of the component (A) and the component (B) is (A) / (B) = 0.1-10.

  The content makeup ratio of the said component (B) and the said component (D) provides the said water-based makeup cosmetics whose (B) / (D) = 0.01-0.5.

  The water-based makeup cosmetics in which the water-soluble polysaccharide of the component (A) is gellan gum are provided.

  The present invention is a uniform cosmetic film, excellent in glossiness and makeup durability of the glitter powder, and the glitter powder is difficult to peel off against physical contact (secondary adhesion-less effect). Is to provide.

  The present invention will be described in detail below. In the present specification, “to” means a range including numerical values before and after.

  The component (A) water-soluble polysaccharide used in the present invention is a polysaccharide that forms an elastic gel by swelling with water. Examples of water-soluble polysaccharides include gellan gum, pectin, agar powder, alginic acid, carrageenan, hyaluronic acid, and salts thereof, and these can be used alone or in combination of two or more. In particular, gellan gum is preferable because it has low tackiness and easily develops a secondary adhesion-less effect. Gellan gum includes deacylated gellan gum and native gellan gum, both of which can be suitably used. Commercially available products include Kelcogel, Kelcogel LT100, Kelcogel HM (manufactured by Dainippon Sumitomo Pharma Co., Ltd.), Genipectin LM-104AS-J (CP Kelco), Inagar Agar UP-37CS (Ina Food Industry Co., Ltd.), Kimika Argin I3-150 (manufactured by Kimika Co., Ltd.) and the like can be mentioned, and these can be used alone or in combination.

  The content of the component (A) used in the present invention is not particularly limited, but it is 0.1 to 5 from the viewpoint of being able to form a uniform decorative film and a gel with good glossiness of the glittering powder. The content is preferably mass% (hereinafter simply referred to as “%”), more preferably 0.2 to 2%.

  The silicone phosphate triester of component (B) in the present invention is represented by the following general formula (1)

It is represented by
In the formula, each R 1 independently represents an alkyl group having 1 to 4 carbon atoms, and R may have at least one selected from —O— and —CO—. In which n represents an integer of 5 to 40.

Examples of the “alkyl group having 1 to 4 carbon atoms” in R1 include methyl group, ethyl group, n-propyl group, i-propyl group, n-butyl group, s-butyl group, i-butyl group, and t-butyl group. Is mentioned. Of these, methyl is preferred as R1.
“Divalent hydrocarbon group having 2 to 7 carbon atoms” of “Divalent hydrocarbon group having 2 to 7 carbon atoms which may have at least one selected from —O— and —CO—” in R Examples of "" include ethylene chain, propylene chain, methylethylene chain, butylene chain, 1,2-dimethylethylene chain, pentylene chain, 1-methylbutylene chain, 2-methylbutylene chain, hexylene chain, heptylene chain and the like.

The “C2-C7 divalent hydrocarbon group having at least one selected from —O— and —CO—” has one or more of —O— or —CO—. For example, -CH2-O- (CH2) 2-,-(CH2) 2-O- (CH2) 2-,-(CH2) 3-O- (CH2) 2-,-(CH2) 4- O- (CH2) 2-,-(CH2) 2-O (CH2) 2-O- (CH2) 2-,-(CH2) 2-O- (CH2) 4-,-(CH2) 2-O- (CH2) 5-,-(CH2) 3-O-CH2-, -CH2-CO- (CH2) 2-,-(CH2) 2-CO- (CH2) 2-,-(CH2) 3-CO- (CH2) 2-,-(CH2) 4-CO- (CH2) 2-,-(CH2) 2-CO- (CH2) 4-,-(CH2) 2-CO- (CH2) -, - (CH2) 3-CO-CH2-, and the like.
Among these, “(C 2) 2 divalent hydrocarbon group optionally having at least one selected from —O— and —CO—” is — (CH 2) 3 O (CH 2) 2. -Is preferred.

  Specific examples of silicone phosphate triesters include the following. However, n is an integer in any one of 5-40. These can be used singly or in a mixture of two or more.

  The silicone phosphate triester of the present invention can be produced, for example, by the method shown in the following reaction formula (refer to JP2011-173852A).

(Wherein R1, R and n are the same as defined in the above formula (I)).

One-terminal carbinol-modified silicone represented by the formula (IV) is reacted with phosphorus oxychloride represented by the formula (V) in the presence of a base in a solvent.
As a solvent used in carrying out the above reaction, polar solvents such as tetrahydrofuran, dimethyl sulfoxide, N, N-dimethylformamide, acetone, diethyl ether and acetonitrile can be used.
Examples of the base include alkylamines such as diethylamine and triethylamine, heterocyclic amines such as piperazine and imidazole, quaternary ammonium salts such as benzyltriethylammonium chloride and methyltrioctylammonium chloride, n-butyllithium, lithium diisopropylamide and the like. Organic metals can be used.
The reaction temperature is usually about 25 ° C. to 50 ° C., and the reaction time is usually about 2 hours to 20 hours, although it varies depending on the silicone chain length.

  By the above reaction, a silicone phosphate triester represented by the formula (I) is obtained. As a by-product, a silicone phosphate diester represented by the following formula (II), represented by the following formula (III): Silicon phosphate monoester is produced.

(Wherein R1, R and n are the same as defined in the above formula (I)).

(Wherein R1, R and n are the same as defined in the above formula (I)).

  Although these by-products can be used as a silicone phosphate ester mixture, the product is purified by a conventional method to obtain substantially only the silicone phosphate triester represented by the formula (I). May be used.

  In the present invention, the content mass ratio of the silicone phosphate triester represented by the formula (I), the silicone phosphate diester represented by the formula (II), and the silicone phosphate monoester represented by the formula (III) is Although the silicone phosphate triester represented by the formula (I) is not particularly limited as long as it has an effect, the silicone phosphate represented by the formula (I) is preferably used with respect to a total of 100 parts of the silicone phosphate ester mixture. 60 to 100 parts by mass of the acid triester, 0 to 35 parts by mass of the silicone phosphoric diester represented by the formula (II), and 0 to 5 parts by mass of the silicone phosphoric monoester represented by the formula (III) It is.

  The content of the silicone phosphate triester of component (B) used in the present invention is not particularly limited, but the adhesiveness of the cosmetic base material, particularly the glitter powder, to the skin is increased and the surface tackiness is increased. Is preferably 0.05 to 10%, more preferably 0.1 to 10%, and particularly preferably 0.5 to 10% from the viewpoint of being excellent in the secondary adhesion-less effect.

  The water of component (C) used in the present invention is not particularly limited, and examples thereof include ordinary water, purified water, hot spring water, deep water, lavender water, rose water, orange flower water, and the like. Can be used.

  Although content of the component (C) in this invention is not specifically limited, From a viewpoint that the effect of this invention is more excellent, 30 to 90% is preferable and it is more preferable that it is 40 to 90%.

  The glitter powder of component (D) used in the present invention is not particularly limited as long as it is a glitter powder commonly used in cosmetics. For example, mica, sericite, synthetic mica, synthetic sericite, Body powders such as aluminum silicate, magnesium silicate, magnesium aluminum silicate, cleaved talc, plate-like anhydrous silicic acid, plate-like aluminum oxide, plate-like kaolin, plate-like boron nitride, plate-like titanium oxide, plate-like cellulose, Mica titanium, bismuth oxychloride, organic pigment-treated mica titanium, titanium dioxide coated mica, titanium dioxide coated synthetic phlogopite, titanium dioxide coated bismuth oxychloride, iron oxide mica titanium, bituminized mica titanium, carmine treated mica titanium, fish scale foil, Titanium dioxide coated glass powder, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terf Rate polyolefin laminated film powder, bright powders of the resin laminate powder such as powder of polyethylene terephthalate polymethyl methacrylate laminated film and the like, may be used in combination of two or more thereof. Among these, glittering powders based on mica, synthetic mica, and glass powder are preferable because of their good gloss. These components (D) are 1 compound such as fluorine compound, silicone compound, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant, etc. You may surface-treat using seed | species or 2 or more types.

  The average particle diameter of the component (D) used in the present invention is not particularly limited, but is preferably 20 to 400 μm, more preferably 30 to 200 μm from the standpoint of superior glossiness. More preferred. Further, the aspect ratio is preferably 30 or more, and more preferably 50 or more. In the present invention, the average particle diameter means an average value (average of 50% integrated volume) of powder width and length measured in a dispersion state in water using a laser diffraction / scattering particle size distribution measuring apparatus. Particle size value).

  The content of the component (D) is not particularly limited, but is preferably 0.1 to 60% from the viewpoint that a sufficient cosmetic effect is obtained and a decorative film having a watery and high gloss feeling is obtained. -40% is more preferable.

  The component (D) in the present invention preferably contains a water- and oil-repellent treated product from the viewpoint of makeup sustainability, and may be from the viewpoint of cosmetic stability. Examples of the water / oil repellent treatment include perfluoroalkyl phosphate diethanolamine salt and perfluorooctyltriethoxysilane. When the water- and oil-repellent-treated product is included, the content thereof is preferably 15% or more in the component (D), and more preferably 30% or more.

  The content ratio by mass of the component (A) and the component (B) in the present invention is not particularly limited, but (A) / (B) = 0. It is preferable that it is 1-10, and it is more preferable that it is 0.15-5.

  In addition, the mass ratio of the component (B) and the component (D) in the present invention is not particularly limited, but from the viewpoint of being excellent in the glossiness of the glittering powder and the secondary adhesion-less effect, (B) / ( D) = 0.01 to 0.5 is preferable, and 0.02 to 0.3 is more preferable.

  In addition to the above components (A) to (D), the aqueous makeup cosmetic of the present invention includes components, oily components, powders and powders that are usually used in cosmetics as long as the effects of the present invention are not hindered. The effects of the present invention include surfactants, film forming agents, aqueous components, UV absorbers, moisturizers, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, and fragrances for body dispersion and feel adjustment. Can be appropriately contained within a range not impairing the above.

Oily components include hydrocarbons, oils and fats, waxes, hardened oils, ester oils, regardless of the origin, such as animal oils, vegetable oils, synthetic oils, and solid oils, semisolid oils, liquid oils, etc. , Fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents, oil-soluble resins, volatile oils and the like.
Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, montan wax, fisher trops wax, molasses, olive oil, castor oil, mink oil, macadamia Oils such as peanut oil, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, jojoba oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diisostearate Polyglyceryl acid, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol fat Acid esters, esters such as N-lauroyl-L-glutamate di (cholesteryl, behenyl, octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and other higher alcohols, methylphenyl poly Silicones such as siloxane and fluorine-modified organopolysiloxane, fluorinated oils such as perfluorodecane, perfluorooctane and perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin octoate , Dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, coconut oil Fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid, calcium stearate and other oily gelling agents, hydrogenated rosin acid pentaerythrityl, specific alkyl acrylate Volatilization of oil-soluble resins such as methylpolysiloxane esters, hydrocarbon oils such as light liquid isoparaffin and isododecane, silicones such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyltrimethicone, and low polymerization degree dimethylpolysiloxane Oily agents and the like.

  The powders other than the component (D) are particularly in the form of spindles, needles, fibers, spheres, etc., fumes, fine particles, particle sizes such as pigment grades, porous, non-porous particle structures, etc. Without being limited, inorganic powders, composite powders and the like can be mentioned. Specifically, inorganic powders such as aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, talc, kaolin, silica, silicon carbide, magnesium stearate, zinc stearate, N-acyl lysine, nylon, etc. Organic powders, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen, ultramarine blue, red rose, red 201, Organic pigment powder such as red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401, red 3, red 104, red 106, Zirconium, barium or aluminum such as orange 205, yellow 4, yellow 5, green 3, blue 1 Organic pigment powders or even aluminum powder over key such as gold powder, include metal powders such as silver, it can be used more than those one or. In addition, these powders may be used singly or in combination of two or more, and by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a surfactant, fats and oils, etc. It may be surface-treated.

  As the surfactant contained for the purpose of improving the dispersibility of the powder, any surfactant that is generally used in cosmetics can be used. Nonionic surfactants and anionic surfactants can be used. , Cationic surfactants, amphoteric surfactants and the like. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sucrose fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified Examples thereof include organopolysiloxane, polyether-modified organopolysiloxane, and lecithin.

  Examples of the film forming agent include alkyl acrylate polymers, alkyl methacrylate polymers, and alkyl methacrylate copolymers.

  The aqueous component may be any component that is soluble in water, for example, lower alcohols such as ethyl alcohol and butyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and polyethylene glycol. Glycerols such as glycerin, diglycerin and polyglycerin.

  Examples of the water-soluble polymer include synthetic compounds such as carboxyvinyl polymer, alkyl-added carboxyvinyl polymer, and sodium polyacrylate. Other moisturizing agents such as protein, collagen, elastin, keratin and the like can also be contained.

  Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., antiseptics such as paraoxybenzoic acid esters, phenoxyethanol, 1 , 2-pentanediol and the like.

  The aqueous makeup cosmetic of the present invention is not particularly limited, but can be applied to eye color, face color, cheek color, eyeliner and the like, and examples of the shape include solid, cream, gel, and liquid. Among them, a solid gel shape having no fluidity is preferred from one having a viscosity of 50,000 mm 2 / s or more. Appearance can be used as transparent, translucent and opaque cosmetics.

  The aqueous makeup cosmetic of the present invention is a cosmetic having water as the component (C) as a continuous phase, and is not particularly limited. However, the content of the oily component is preferably less than 50%, and less than 30%. More preferably, it is more preferably less than 10% from the viewpoint that the effect of the present invention is more exerted. Although it does not specifically limit as a dosage form, The oil-in-water type | mold and the aqueous type | mold without an emulsification process are mentioned. Among these, the aqueous type in which the content of the oil component is less than 1% is particularly preferable from the viewpoint that the effects of the present invention are more remarkably exhibited.

  Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

A synthesis example of the silicone phosphate triester of component (B) in the present invention is shown below.
[Synthesis Example 1]
265 g of carbinol-modified silicone (formula 2) and 136 g of tetrahydrofuran were mixed and cooled to -40 ° C. After adding 200 ml of lithium diisopropylamide (LDA) (1 mol / THF solution) dropwise and reacting for 90 minutes, 7.8 g of phosphorus oxychloride (formula 1) was added and allowed to react for 1 hour. After raising the temperature to 25 ° C. and further aging for 2 hours, 42 g of concentrated hydrochloric acid was added to terminate the reaction. The mixture containing silicone phosphate triester was obtained by washing with methanol and distilling off the solvent. The composition ratio of the obtained mixture was determined by 31P-NMR measurement to be 92% for the formula (I) as the triester, 1% for the formula (II) as the diester, and 7% by-product containing polyphosphoric acid. %Met.

[Prescription example]
The mixture containing the silicone phosphate triester produced in the above production example was used in the following formulation. Therefore, in the following examples, for example, “product of Synthesis Example 1” means a mixture containing the silicone phosphate triester obtained in Synthesis Example 1.

Examples 1 to 8 and Comparative Examples 1 to 5: Eye color (aqueous gel)
Prepare eye colors of the formulation shown in Table 1, a. Uniformity of decorative film, b. Pearl luster, c. Makeup persistence, d. The secondary adhesion-less effect was evaluated by the following method. The results are shown in Table 1.

(Production method)
A. The components (1) to (5) are uniformly heated and swollen with a part of the component (20).
B. Add the remainder of (6) to (19) and (20) to A and mix uniformly.
C. B was filled in a container to obtain an eye color (aqueous gel).

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
a. Uniformity of decorative film b. Glossiness of pearl c. Makeup persistence For each of the items a to c, a use test was conducted by 20 professional panels for each sample. Each panel person uses each eye color of Examples 1 to 8 and Comparative Examples 1 to 5 with a finger, evaluates it according to the following absolute evaluation criteria in 7 levels, and gives a score from the total score of all panel members The average value was calculated and judged according to the following criteria. Whether the cosmetic film is applied evenly after the eye color is used, and whether the gloss of pearl is high, a. Uniformity of decorative film, b. The glossiness of pearl was evaluated. For makeup persistence, each sample was applied, and after having a normal life on the panel, it was evaluated whether the makeup film was broken by tears or sweat after 6 hours.

Absolute Evaluation Criteria (Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad

Judgment criteria (judgment): (average score)
◎: 5 points or more ○: 3.5 points or more to less than 5 points △: 2 points or more to less than 3.5 points ×: Less than 2 points

d. Secondary adhesion-less effect 0.2 g of each sample was applied to artificial leather A (manufactured by Beaulux) with 2 cm square fingers and dried for 3 minutes, and then another artificial leather B was pressed with a load of 50 gwt for 10 seconds. Transfer resistance (secondary adhesion-less effect) at the time of peeling was evaluated by calculating a color difference ΔE before and after transfer of the artificial leather B using a color difference meter (CM-700d, manufactured by Konica Minolta Co., Ltd.). Judgment was made according to the criteria.
Judgment criteria (judgment): (Evaluation)
: ΔE <1.0
○: 1.0 ≦ ΔE <3.0
Δ: 3.0 ≦ ΔE <5.0
×: 5.0 <ΔE

As is clear from the results in Table 1, the aqueous eye colors of Examples 1 to 8 of the present invention were more uniform than the Comparative Examples 1 to 5, the uniformity of the cosmetic film, the pearly luster, the makeup persistence, and the secondary adhesion less. It was excellent in all of the effects. On the other hand, Comparative Example 1 containing a carboxyvinyl polymer, which is an aqueous gelling agent, instead of component (A) is not sufficient in pearl luster and has a poor adhesion to the skin. The film was not uniform, and the makeup persistence and secondary adhesion-less effect were poor. Comparative Example 2 containing no component (B), Comparative Example 3 containing dimethicone instead of Component (B), and Comparative Example 4 containing trioleyl phosphate have poor dispersibility. Therefore, the makeup film is not uniform and the adhesion to the skin is inferior, so the secondary adhesion-less effect is not sufficient. In Comparative Example 5 containing the vinyl acetate copolymer emulsion, although the adhesion of the cosmetic to the skin was improved, the surface tackiness was also increased, and the secondary adhesion-less effect was poor.

Example 9 Blusher (aqueous solid gel)
(Ingredient) (%)
1. Deacylated gellan gum 0.6
2. Water remaining amount 3. Triethanolamine 0.1
4). EDTA-2Na 0.05
5. Dibutylene glycol 15
6). Lecithin 0.2
7). Polyoxyethylene sorbitan monooleate 0.15
8). Talc 2
9. Perfluorooctyltriethoxysilane 5% treated yellow iron oxide 0.2
10. Perfluorooctyltriethoxysilane 5% black iron oxide 0.02
11. Perfluorooctyltriethoxysilane 5% treated bengara 0.1
12 Perfluoroalkyl phosphate diethanolamine 5% treated Titanium oxide 0.05
13. Synthetic phlogopite * 9 14
14 Perfluoroalkyl phosphate diethanolamine salt 3% treatment Titanium oxide coated mica * 10 10
15. Silicone 2% treated titanium oxide coated synthetic phlogopite * 11 1
16. Product of Synthesis Example 1 2

* 9: PDM-10L (Topy Industries, Ltd.)
* 10: FLAMENCO RED 420C (manufactured by BASF) treated with 3% perfluoroalkyl phosphate diethanolamine salt * 11: HELIOS R100S (S) (manufactured by Topy Industries)
(Production method)
A. Ingredient (1) is uniformly swollen with part of ingredient (2).
B. Ingredients (3) to (12) are uniformly dispersed.
C. Add B and components (13) to (16) to A and mix uniformly.
D. C was filled into a container to obtain blusher (aqueous gel).
The blusher of Example 6 was excellent in all of the uniformity of the cosmetic film, the glossiness of the pearl, the makeup persistence, and the effect of preventing secondary adhesion.

Example 10 Foundation (oil-in-water solid gel)
(Ingredient) (%)
1. Pectin * 12 0.5
2. 2. Purified water remaining amount L-Arginine 0.1
4). EDTA-2Na 0.05
5. Calcium chloride 0.03
6). Phenoxyethanol 0.3
7.1,3-Butylene glycol 15
8). Polyoxyethylene polyoxypropylene glycol * 13 0.3
9. Sodium polyoxyethylene alkyl ether phosphate 0.3
10. Dimethylpolysiloxane 2% treated talc 3.5
11. Dimethylpolysiloxane 2% treated yellow iron oxide 1.5
12 Dimethylpolysiloxane 2% black iron oxide 0.1
13. Dimethylpolysiloxane 2% treated bengara 0.1
14 Dimethylpolysiloxane 2% treated plate-like titanium oxide 7
15. Dimethylpolysiloxane 2% treated mica titanium * 14 10
16. Product of Synthesis Example 1 0.5
17. Glycerol monostearate 1.5
18. Cetanol 1.5
19. Liquid paraffin 1
20. Squalane 2
21. Glyceryl trioctanoate 3
22. Dipentaerythritol tetra 12-hydroxystearic acid sesquistearic acid hemirosin ester 0.5
23. Dimethylpolysiloxane (20CS) 0.5
24. Alkyl acrylate / styrene copolymer emulsion * 15 3
* 12: GENU pectin LM-104AS-J (manufactured by Sankisha)
* 13: Unilube 70DP-950B (Nippon Yushi Co., Ltd.)
* 14: Timilon Super Gold (MERCK) treated with 2% dimethylpolysiloxane * 15: Iodosol GH41F (Axon Nobel)
(Production method)
A. Ingredient (1) is uniformly swollen with ingredient (2).
B. Ingredients (3) to (16) are uniformly dispersed.
C. Components (17) to (23) are dissolved by heating at 70 ° C.
D. A and B are mixed, and C is added thereto to emulsify.
E. Add component (24) to D and mix.
F. E was heated and dissolved, filled into a container, and then cooled to room temperature to obtain a gel-like foundation.
The gel-like foundation of Example 6 was excellent in all of the uniformity of the cosmetic film, makeup persistence, and secondary adhesion-less effect.

Example 11 Base (oil-in-water cream))
(Ingredient) (%)
1. Agar * 2 0.3
2. Locust bean gum 0.1
3. Xanthan gum 0.1
4. 1,2-pentylene glycol 5
5.1,3-Butylene glycol 5
6). Purified water Residual amount 7. 2-Amino-2-methyl-1-propanol 0.3
8). EDTA-2Na 0.05
9. Product of Synthesis Example 1 0.1
10. Methyl paraoxybenzoate 0.1
11. Sodium polyoxyethylene alkyl ether phosphate 0.3
12 Dimethylpolysiloxane 2% treated talc 3.5
13. Dimethylpolysiloxane 2% treated yellow iron oxide 1.5
14 Dimethylpolysiloxane 2% black iron oxide 0.1
15. Dimethylpolysiloxane 2% treated bengara 0.1
16. Dimethylpolysiloxane 2% treated plate-like titanium oxide 7
17. Bengala-coated mica titanium * 16 7
18. Polyglyceryl monostearate 1.5
19. Cetanol 1.5
20. Polyoxyethylene (60) hydrogenated castor oil 1
21. Squalane 3
22. Glyceryl trioctanoate 5
23. Glyceryl monostearate 0.5
24. Dimethylpolysiloxane (100CS) 0.5
25. Vaseline 0.5
* 16CLOISNE ROUGE FLAMBE (BASF)
(Production method)
A. Components (1) to (3) and (7) to (11) are uniformly swollen with a part of components (4), (5), and (6).
B. Components (18) to (25) are dissolved by heating at 70 ° C.
C. Components (12) to (17) are uniformly dispersed in the remainder of component (6).
D. B is added to C and emulsified.
E. Add A and component (6) to D and mix.
F. After E was melt-filled in the container, it was cooled to room temperature to obtain a gel-like substrate.
The gel-like substrate of Example 7 was excellent in all of the uniformity of the decorative film, the glossiness of pearl, the makeup durability, and the effect of preventing secondary adhesion.

Example 12 Eyeliner (aqueous liquid)
(Ingredient) (%)
1. Native gellan gum * 1 0.1
2. 2. Purified water remaining amount EDTA-2Na 0.05
4). Triethanolamine 0.1
5.1,3-Butylene glycol 15
6). Lecithin 0.2
7). Polyoxyethylene sorbitan monooleate 0.15
8). Sericite 2
9. Plate cellulose 2
10. Perfluorooctyltriethoxysilane 3% treated black iron oxide 5
11. Titanium oxide coated borosilicate * 17 5
12 Black iron oxide coated mica * 18 20
13. Product of Synthesis Example 1 10
* 17: Metashine MT1080RS (manufactured by Nippon Sheet Glass Co., Ltd.)
* 18: COLORONA MICA BLACK (Merck)

(Production method)
A. Ingredient (1) is uniformly swollen with ingredient (2).
B. Ingredients (3) to (10) are uniformly dispersed.
C. Add B and components (11) to (13) to A and mix uniformly.
D. C was filled into a container to obtain an eyeliner (aqueous gel).
The eyeliner of Example 8 was excellent in all of the uniformity of the decorative film, the glossiness of the pearl, the makeup persistence, and the secondary adhesion-less effect.

Claims (7)

The following components (A) to (D);
(A) Water-soluble polysaccharide (B) Formula (1)
(In the formula, each R 1 independently represents an alkyl group having 1 to 4 carbon atoms, and R 2 may have at least one selected from —O— and —CO—. Water-based makeup containing a silicone phosphoric acid triester (C) water (D) glittering powder represented by 7 represents a divalent hydrocarbon group of 7 and n represents any integer of 5 to 40) Cosmetics.   The aqueous makeup cosmetic according to claim 1, wherein the content of the component (B) is 0.05 to 10% by mass.   The aqueous makeup cosmetic according to claim 1 or 2, wherein the content of the component (A) is 0.1 to 5% by mass.   The content of the said component (D) is 0.1-60 mass%, The aqueous makeup cosmetics in any one of Claims 1-3.   The aqueous makeup cosmetic according to any one of claims 1 to 4, wherein a content mass ratio of the component (A) and the component (B) is (A) / (B) = 0.1 to 10.   The aqueous makeup cosmetic according to any one of claims 1 to 5, wherein a content ratio by mass of the component (B) and the component (D) is (B) / (D) = 0.01 to 0.5. .   The aqueous makeup cosmetic according to any one of claims 1 to 6, wherein the water-soluble polysaccharide of the component (A) is gellan gum.