JP6822866B2 - Aqueous makeup cosmetics - Google Patents

Description

The present invention relates to a make-up cosmetic, and more specifically, by containing a water-soluble polysaccharide, tripropylene glycol, water, and a plate-like powder, there is no feeling of dryness over time, and the skin is familiar and flexible. It relates to a water-based make-up cosmetic having an excellent cosmetic effect, which is finished as a cosmetic film.

Makeup cosmetics are required to be applied to the eyelids and cheeks to add shadows and have a high makeup effect. Aqueous make-up cosmetics, which form a gel using water and an aqueous gelling agent, are popular in the market because they can produce a transparent luster and wateriness. Aqueous make-up cosmetics are composed of an aqueous gelling agent, powder, and water, and the content of dosage forms and ingredients has been examined in order to improve the usability and functionality required for cosmetics.

In addition, in order to obtain a fresh feeling of use and an effect of excellent familiarity with the skin, a technique using a water-soluble surfactant (Patent Document 1) and a feeling of firmness of the skin after application drying (feeling of dryness over time) can be obtained. A technique using gellan gum, a cation, glycerin, and a powder for improvement (Patent Document 2) is being studied.

Japanese Unexamined Patent Publication No. 2006-315973 Japanese Unexamined Patent Publication No. 2004-292375

However, in the technique of Patent Document 1 using a water-soluble surfactant, a feeling of dryness may be felt when water evaporates over time, and when the cosmetic film dries, the film loses its flexibility and moves such as blinking. There was also a problem that the cosmetic film was peeled off. Further, in the technique of Patent Document 2 using gellan gum, cations, glycerin, and powder, if the content of glycerin is increased in order to further reduce the feeling of dryness over time, the skin becomes less familiar and the film becomes softer. It also tended to be inferior in sex. Further, when a powder such as a plate-like powder is contained in an aqueous make-up cosmetic, the flexibility of the decorative film after drying tends to decrease. Therefore, with the conventional technology, it is not possible to embody a water-based make-up cosmetic containing a plate-like powder that has excellent skin compatibility but does not feel dry over time and has excellent flexibility of the cosmetic film after drying. It was difficult.

In view of the above circumstances, it is an object of the present invention to provide an aqueous make-up cosmetic that does not feel dry over time, has a flexible film, and is familiar to the skin.

By using a polyhydric alcohol having a larger number of carbon atoms than glycerin in a water-based make-up cosmetic using a water-soluble polysaccharide and having a watery feel, the present inventors have excellent dryness over time. We found that it fits well on the skin, and examined the content of various components. As a result, by using tripropylene glycol, there was no feeling of dryness over time, and even if it contained plate-like powder, it was flexible. The present invention has been completed by finding that a certain cosmetic film is finished and the skin fits well when used.

That is, the present invention describes the following components (A) to (D);
(A) Containing at least one water-soluble polysaccharide (B) tripropylene glycol (C) water (D) plate-like powder selected from the group consisting of gellan gum, pectin, agar, alginic acid, and carrageenan .
The content mass ratio of the component (A) to the component (B) is (A) / (B) = 0.01 to 5.
It provides water-based make-up cosmetics.

It provides the aqueous make-up cosmetic in which the component (A) is gellan gum.

The present invention provides the aqueous make-up cosmetic having a content of the component (B) of 0.1 to 30% by mass.

It provides the aqueous make-up cosmetics in which the content mass ratio of the component (B) to the component (D) is (B) / (D) = 0.001 to 1.5.

The present invention provides a water-based make-up cosmetic that does not feel dry over time, is finished in a flexible makeup film, and has good skin compatibility.

The figure which showed the flexibility evaluation (coating film evaluation) result of the film of Example 1, Comparative Example 2, and Comparative Example 4.

Hereinafter, the present invention will be described in detail. In addition, in this specification, "~" means the range including the numerical values before and after it.

The component (A) water-soluble polysaccharide used in the present invention is a polysaccharide that forms an elastic gel when swollen with water. The water-soluble polysaccharide is not particularly limited, and examples thereof include gellan gum, pectin, agar, alginic acid, carrageenan, hyaluronic acid, and salts thereof, and one or a combination of two or more of these can be used. Among these, it is more preferable to use gellan gum because it is more excellent in elasticity and the like. Gellan gum includes deacylated gellan gum and native gellan gum, both of which can be preferably used.

Commercially available products include Kerkogel, Kerkogel LT100, Kerkogel HM (manufactured by Sumitomo Dainippon Pharma), Genupectin LM-104AS-J (manufactured by CP Kerco), Ina Agar UP-37CS (manufactured by Ina Food Industry Co., Ltd.), and Kimika Argin. Examples thereof include I3-150 (manufactured by Kimika Co., Ltd.), and one or more of these can be used in combination.

The content of the component (A) used in the present invention is not particularly limited, but is 0.1 to 5% by mass (hereinafter, simply referred to as "%") from the viewpoint of obtaining a gel having a good elasticity. Is preferable, and more preferably 0.2 to 2%.

The component (B) tripropylene glycol used in the present invention is a polyhydric alcohol composed of a trimer of propylene glycol, and is represented by the following general formula (1).
H (OCH2CH (CH3)) noH (1)
(In the formula, n is 3 on average)
In INCI names (International Nomenclature Cosmetic Ingredient labeling names), it is represented by tripropylene glycol or PPG-3. The component (B) has a higher affinity with the oil agent than that of the dimer, and can give a more moisturizing feeling. Examples of commercially available products include Nieuport PP-200 (manufactured by Sanyo Chemical Industries, Ltd.) and tripropylene glycol (manufactured by Asahi Glass Co., Ltd.).

The content of the component (B) in the present invention is not particularly limited, but 0.1 to 30% is preferable in that it does not feel dry over time, is excellent in the flexibility of the cosmetic film, and the like. When it is 2 to 15%, it is more preferable in that it does not feel dry over time, has good compatibility with the skin, and is excellent in the flexibility of the cosmetic film.

The water of the component (C) used in the present invention is not particularly limited, and examples thereof include normal water, purified water, hot spring water, deep water, lavender water, rose water, orange flower water, and the like, and one or more kinds. Can be used.

The content of the component (C) in the present invention is not particularly limited, but is preferably 30 to 90%, more preferably 40 to 90%, from the viewpoint of being superior in wateriness and elasticity.

The plate-like powder of the component (D) used in the present invention is not particularly limited as long as it is a plate-like powder usually used in cosmetics, and is, for example, mica, serisite, synthetic gold mica, or synthetic serisite. , Aluminum silicate, Magnesium silicate, Aluminum magnesium silicate, Mica talc, Plate-shaped anhydrous silicic acid, Plate-shaped aluminum oxide, Plate-shaped kaolin, Plate-shaped boron nitride, Plate-shaped titanium oxide, Plate-shaped cellulose and other constitutional powders , Mica titanium, oxychloride bismuth, organic pigment treated mica titanium, titanium dioxide coated mica, titanium dioxide coated synthetic gold mica, titanium dioxide coated oxychloride bismus, iron oxide mica titanium oxide, dark blue treated mica titanium, carmine treated mica titanium, fish scale foil , Titanium dioxide coated glass powder, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethylmethacrylate laminated film powder, and other resin laminated powders, and one or two of these. The above can be used in combination. Among these, it is more preferable to use mica, synthetic phlogopite, mica titanium or the like because it is superior in gloss height. These plate-like powders include fluorine-based compounds, silicone-based compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes, waxes, surfactants, etc. The surface treatment may be performed using seeds or two or more kinds.

The average particle size of the component (D) used in the present invention is not particularly limited, but from the viewpoint of being superior in gloss height, it is preferable to use a component (D) of 5 to 400 μm, and a component (D) of 15 to 300 μm is preferably used. More preferred. The aspect ratio is preferably 30 or more, and more preferably 50 or more. In the present invention, the average particle size is the average value (average of 50% of integrated volume) of the width and length of the powder measured in the dispersed state in water using a laser diffraction / scattering type particle size distribution measuring device. Particle size value).

The content of the component (D) is not particularly limited, but is 0.1 from the viewpoint that a cosmetic effect such as sufficient luster and pearliness can be obtained, and a watery and highly glossy cosmetic film can be obtained. It is preferably ~ 60%, more preferably 5-40%.

When the component (D) in the present invention contains a water-repellent and oil-repellent treated component, it is more preferable in terms of long-lasting makeup, and it is also good in terms of stability of the cosmetic. Examples of the water- and oil-repellent treatment include perfluoroalkyl phosphate diethanolamine salt and perfluorooctyltriethoxysilane. When a water-repellent or oil-repellent treated product is included, the content of the component (D) is preferably 15% or more, and more preferably 30% or more.

The content-mass ratio of the component (A) to the component (B) in the present invention is not particularly limited, but from the viewpoint of being superior in the elasticity of the cosmetic and the good compatibility with the skin, (A) / (B) = 0. It is preferably 01 to 5, more preferably 0.02 to 0.5.

The content mass ratio of the component (A) to the component (D) in the present invention is not particularly limited, but (A) / (D) from the viewpoint of obtaining a glossy film without impairing the elasticity of the gel. = 0.005 to 5, more preferably 0.01 to 0.1.

The mass ratio of the component (B) to the component (D) in the present invention is not particularly limited, but is excellent from the viewpoint of forming a flexible and glossy film that is familiar to the skin and does not have a dry feeling. (B) / (D) = 0.001 to 1.5, more preferably 0.004 to 0.3.

In addition to the above ingredients (A) to (D), the aqueous make-up cosmetic of the present invention contains ingredients, oily ingredients, powders, and powders normally used in cosmetics as long as the effects of the present invention are not impaired. Effects of the present invention such as surfactants, film-forming agents, aqueous components, ultraviolet absorbers, moisturizers, anti-fading agents, antioxidants, defoamers, beauty ingredients, preservatives, fragrances, etc. for body dispersion and feel adjustment. Can be appropriately contained within a range that does not impair.

The oily components include hydrocarbons, fats and oils, waxes, hardened oils, ester oils, regardless of the origin of animal oils, vegetable oils, synthetic oils, etc., and the properties of solid oils, semi-solid oils, liquid oils, etc. , Fatty acids, higher alcohols, silicone oils, fluorooils, lanolin derivatives, oil-based gelling agents, oil-soluble resins, volatile oils and the like.
Specifically, hydrocarbons such as liquid paraffin, squalane, vaseline, paraffin wax, ceresin wax, microcrystallin wax, ethylenepropylene copolymer, montan wax, fishertropus wax, mokurou, olive oil, castor oil, mink oil, macadamia. Fats and oils such as nut oil, waxes such as beeswax, carnauba wax, candelilla wax, gay wax, jojoba oil, cetylisooctane, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diisosteare Esters such as polyglyceryl acid, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, di-lauroyl-L-glutamate (cholesteryl behenyl octyldodecyl), Higher alcohols such as stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol, silicones such as methylphenylpolysiloxane and fluorine-modified organopolysiloxane, perfluorodecane, perfluorooctane, perfluoropolyether. Fluorine oils such as lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin octanate, dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, coconut oil fatty acid Oil-based gelling agents such as dextrin, (palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid, calcium stearate, pentaerythrityl hydrogenated loginate, specific alkylmethylmethylacrylate acrylate Oil-soluble resins such as siloxane esters, light fluid isoparaffins, hydrocarbon oils such as isododecane, volatile oils such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyltrimethicone, silicones such as low-polymerization dimethylpolysiloxane And so on.

As the powder other than the component (D), the powder has a spindle-like shape, a needle-like shape, a fibrous shape, a spherical shape, etc. Examples thereof include, but are not limited to, inorganic powders and composite powders. Specifically, inorganic powders such as aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, kaolin, silica and silicon carbide, and organic powders such as magnesium stearate, zinc stearate, N-acyllysine and nylon. White inorganic pigments such as body, titanium oxide, zinc oxide, cerium oxide, barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, dark blue, ultramarine, red iron oxide, red 201, red 202 Organic pigment powders such as No., Red No. 205, Red No. 226, Red No. 228, Orange No. 203, Orange No. 204, Blue No. 404, Yellow No. 401, Red No. 3, Red No. 104, Red No. 106, Orange No. 205 Organic pigment powders such as zinc oxide, barium or aluminum lake, such as No., Yellow No. 4, Yellow No. 5, Green No. 3, and Blue No. 1, or metal powders such as aluminum powder, gold powder, and silver powder can be mentioned. Can be used alone or in combination of two or more. Further, these powders may be one kind or a composite of two or more kinds, and may be used by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a surfactant, an oil or fat, a hydrocarbon, or the like. It may be surface-treated.

As the surfactant contained for the purpose of improving the dispersibility of the powder, any surfactant generally used in cosmetics can be used, and a nonionic surfactant and an anionic surfactant can be used. , Cationic surfactant, amphoteric surfactant and the like. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sucrose fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified. Examples thereof include organopolysiloxane, polyether-modified organopolysiloxane, and lecithin.

Examples of the film forming agent include an alkyl acrylate polymer, an alkyl methacrylate polymer, and an alkyl methacrylate copolymer.

The aqueous component may be any component that is soluble in water, for example, lower alcohols such as ethyl alcohol and butyl alcohol, and glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol and polyethylene glycol. , Glycerin, diglycerin, polyglycerin and other glycerols and the like.

Examples of the water-soluble polymer include synthetic polymers such as a carboxyvinyl polymer, an alkyl-added carboxyvinyl polymer, and sodium polyacrylate. It can also contain other moisturizers such as protein, collagen, elastin and keratin.

Examples of UV absorbers include benzophenone, PABA, silicic acid, salicylic acid, 4-tert-butyl-4'-methoxydibenzoylmethane, oxybenzone, etc., and moisturizers include, for example, protein, mucopolysaccharide, collagen. , Elastin, keratin, etc. Antioxidants such as α-tocopherol, ascorbic acid, beauty ingredients such as vitamins, anti-inflammatory agents, crude drugs, etc. Preservatives, for example, paraoxybenzoic acid ester, phenoxyethanol, 1 , 2-Pentanediol and the like.

The water-based makeup cosmetic of the present invention is not particularly limited, but can be applied to eye color, face color, cheek color, eyeliner and the like, and examples of the shape include solid type, cream type, gel type and liquid type. Of these, a fluid having a viscosity of 50,000 mm2 / s or more is preferable to a solid gel having no fluidity. The appearance can be used as transparent, translucent, and opaque cosmetics.

The aqueous make-up cosmetic of the present invention is a cosmetic having the water component (C) as a continuous phase, and is not particularly limited, but the content of the oily component is preferably less than 50%, preferably less than 30%. It is more preferable, and it is more preferable that it is less than 10% from the viewpoint that the effect of the present invention is more exhibited. The dosage form is not particularly limited, and examples thereof include an oil-in-water type and an aqueous type having no emulsification step. Among these, the aqueous type having an oily component content of less than 1% is particularly preferable from the viewpoint that the effect of the present invention is more remarkablely exhibited.

Hereinafter, the present invention will be described in detail with reference to examples. It should be noted that these do not limit the present invention in any way.

Examples 1-8 and Comparative Examples 1-7: Eye color (water-based gel)
Prepare eye colors of the formulations shown in Table 1 and a. Membrane flexibility, b. No feeling of dryness, c. Feeling of elasticity, d. Good skin compatibility, e. Membrane gloss, f. The flexibility of the film (evaluation of the coating film) was evaluated by the following method. The results are shown in Table 1.

(Production method)
A. After the components (1) to (4) are moistened with the component (10), a part of the component (11) is uniformly heated and swollen.
B. Add the rest of (5) to (9) and (11) and (12) to (14) to A and mix them uniformly.
C. B was filled in a container to obtain an eye color (water-based gel).

(Evaluation method)
The following evaluation items were evaluated by the following methods.

(Evaluation item)
Membrane flexibility (sensory evaluation)
b. No feeling of dryness c. Feeling of elasticity d. Good familiarity with the skin e. Feeling of gloss of the film A to e were tested for use by 20 specialized panels for each sample. Each person in the panel uses each eye color of Examples 1 to 8 and Comparative Examples 1 to 7 with his / her finger, evaluates and gives a score in 7 stages according to the following absolute evaluation criteria, and gives a score for each sample from the total score of all the panels. The average value was calculated and judged according to the following criteria. After applying each sample and letting the panel live a normal life, 6 hours later, check whether the cosmetic film is cracked or peeled off, or whether there is a feeling of dryness. It was evaluated as the flexibility of the film and b. the lack of dryness. Whether or not the sample filled in the container had a feeling of elasticity when taken with a finger was evaluated as c. Feeling of elasticity, and whether or not the sample taken in a finger was applied to the skin was evaluated as d. Goodness of skin familiarity. The gloss height of the finished cosmetic film was evaluated as the glossiness of the e. film.

Absolute evaluation criteria (score): (evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad

Judgment criteria (judgment): (average score)
◎: 5 points or more ○: 3.5 points or more and less than 5 points △: 1 point or more and less than 3.5 points ×: less than 1 point

(Evaluation item)
f. Film flexibility (coating film evaluation)
The flexibility of the membrane was also evaluated using artificial skin. The same amount of each eye color of Examples 1 to 8 and Comparative Examples 1 to 7 is applied to the artificial skin of urethane resin (Bioskin Black (manufactured by Beaulux), thickness 5 mm) with a finger, dried, and then dried. The work of bending the artificial skin 90 degrees in the medial horizontal direction was repeated 5 times to substitute for the movement of the skin.

Judgment criteria (judgment): (evaluation)
◎: Residual rate of decorative film at the bent part is 80% or more ○: Residual rate of the decorative film at the bent part is 50% or more and less than 80% Δ: Residual rate of the decorative film at the bent part is 20% or more and less than 50% ×: The residual rate of the decorative film at the bent part is less than 20%

As is clear from the results in Table 1, the water-based eye colors of Examples 1 to 8 of the present invention have film flexibility, lack of dryness, elasticity, good skin compatibility, and film as compared with Comparative Examples 1 to 7. It was excellent in all of the glossiness of.
On the contrary,
Comparative Example 1 in which dipropylene glycol was used instead of the component (B), Comparative Example 2 in which glycerin was used, and Comparative Example 3 in which the amount of 1,3-butylene glycol was increased lacked the flexibility of the film and was familiar to the skin. It was bad. In Comparative Example 4 in which the component (B) was not used, the feeling of dryness over time, the flexibility of the film, and the good compatibility with the skin were inferior. In Comparative Example 6 in which a carboxyvinyl polymer, which is an aqueous gelling agent, was used instead of the component (A), the elasticity was lost, and the film's flexibility, moisturizing feeling, and good skin compatibility were also satisfactory. I couldn't get it. In Comparative Example 7 in which the component (D) was not used, the skin did not fit well and the film did not feel glossy.
Further, regarding the flexibility of the film (evaluation of the coating film), when each decorative film was observed, as shown in FIG. 1, in Example 1, 80% or more of the decorative film remained at the bent portion. In contrast to the judgment, in Comparative Example 2 in which glycerin was used instead of the component (B) of the present invention, 50% remained and Δ-judgment, and in Comparative Example 4 containing no component (B), the residual rate. It was observed that was less than 20% and was judged as x. From this result, it was confirmed that the eye color of the example formed a flexible cosmetic film.

Example 9 Blush (water-based solid gel)
(Ingredient) (%)
1. 1. Native gellan gum 0.5
2.1,3-butylene glycol 3
3. 3. Remaining amount of purified water 4. Disodium edetate 0.06
5. Tripropylene glycol * 5 5
6. Perfluorooctyltriethoxysilane 5% treated iron oxide 0.2
7. Perfluorooctyltriethoxysilane 5% treated black iron oxide 0.02
8. Perfluorooctyltriethoxysilane 5% treated Bengala 0.1
9. Perfluoroalkyl Phosphate Ester Diethanolamine Salt 5% Treatment Titanium Oxide 0.05
10. Synthetic phlogopite * 10 20
11. Perfluoroalkyl Phosphate Ester Diethanolamine Salt 3% Treatment Titanium Oxide Coated Mica * 11 10
* 11: FLAMENCO ULTRA SPARKLE 4500 with an average particle size of 50 μm (manufactured by BASF) treated with 3% perfluorooctyltriethoxysilane (manufacturing method).
A. After the component (1) is moistened with the component (2), a part of the component (3) is uniformly heated and swollen.
B. The components (4) to (9) and the rest of the component (3) are uniformly dispersed.
C. Add B and components (10) and (11) to A and mix them uniformly.
D. C was filled in a container to obtain a blusher (water-based gel).
The blusher of this example was excellent in all of the flexibility of the film, the lack of dryness, the elasticity, the good familiarity with the skin, and the glossiness of the film.

Example 10 Foundation (oil-in-water solid gel)
(Ingredient) (%)
1. 1. Native gellan gum 0.5
2.1,3-butylene glycol 15
3. 3. Remaining amount of purified water 4. Disodium edetate 0.06
5. Tripropylene glycol * 5 5
6. L-Arginine 0.3
7. Calcium chloride 0.03
8. Phenoxyethanol 0.3
9. Polyoxyethylene polyoxypropylene glycol * 12 0.3
10. Polyoxyethylene alkyl ether sodium phosphate 0.3
11. Dimethylpolysiloxane 2% treated talc 3.5
12. Dimethylpolysiloxane 2% treated iron oxide 1.5
13. Dimethylpolysiloxane 2% treated black iron oxide 0.1
14. Didimethylpolysiloxane 2% treated Bengala 0.1
15. Dimethylpolysiloxane 2% treated plate-shaped titanium oxide 7
16. 2% treated dimethylpolysiloxane Barium sulphate plate 3
17. Synthetic phlogopite * 10 5
18. Glycerin monostearate 1.5
19. Cetanol 1.5
20. Liquid paraffin 1
21. Squalan 2
22. Glyceryl trioctanoate 3
23. Dipentaerythrit Tetra 12-Hydroxystearate Sesquistearate Hemirosin Ester 0.5
24. Dimethylpolysiloxane (20CS) 0.5
25. Alkylate acrylate / styrene copolymer emulsion 3
* 12: Unilube 70DP-950B (manufactured by NOF CORPORATION)
(Production method)
A. After the component (1) is moistened with the component (2), a part of the component (3) is uniformly heated and swollen.
B. The rest of the components (4) to (17) and the component (3) are uniformly dispersed.
C. Ingredients (18) to (24) are heated and dissolved at 70 ° C.
D. A and B are mixed, and C is added thereto to emulsify.
E. Component (25) is added to D and mixed.
F. E was heated and dissolved, filled in a container, and then cooled to room temperature to obtain a gel-like foundation.
The gel-like foundation of this example was excellent in all of the flexibility of the film, the lack of dryness, the elasticity, the good compatibility with the skin, and the glossiness of the film.

Example 11 Base (oil-in-water cream))
(Ingredient) (%)
1. 1. Native Gellan 0.3
2. 2. Locust bean gum 0.1
3. 3. Xanthan gum 0.1
4. Tripropylene glycol * 5 5
5. Purified water remaining amount 6.2-amino-2-methyl-1-propanol 0.3
7. Disodium edetate 0.05
8. Calcium chloride 0.03
9. Methyl paraoxybenzoate 0.1
10. Polyoxyethylene alkyl ether sodium phosphate 0.3
11. Dimethylpolysiloxane 2% treated talc 3.5
12. Dimethylpolysiloxane 2% treated iron oxide 1.5
13. Dimethylpolysiloxane 2% treated black iron oxide 0.1
14. Didimethylpolysiloxane 2% treated Bengala 0.1
15. Dimethylpolysiloxane 2% treated plate-shaped titanium oxide 7
16. Synthetic phlogopite * 10 4
17. Polyglyceryl monostearate 1.5
18. Cetanol 1.5
19. Polyoxyethylene (60) hardened castor oil 1
20. Squalene 3
21. Glyceryl trioctanoate 5
22. Glyceryl monostearate 0.5
23. Dimethylpolysiloxane (100CS) 0.5
24. Vaseline 0.5
(Production method)
A. The components (1) to (3) and (6) to (10) are uniformly heated and swollen with a part of the components (4) and (5).
B. Ingredients (17) to (24) are heated and dissolved at 70 ° C.
C. The rest of the component (5) and the components (11) to (16) are uniformly dispersed.
D. B is added to C to emulsify.
E. Add A to D and mix.
F. After E was melt-filled in a container, it was cooled to room temperature to obtain a gel-like substrate.
The gel-like substrate of this example was excellent in all of the flexibility of the film, the lack of dryness, the elasticity, the good compatibility with the skin, and the glossiness of the film.

Example 12 Eyeliner (water-based liquid)
(Ingredient) (%)
1. 1. Native gellan gum 0.1
2.1,3-butylene glycol 15
3. 3. Remaining amount of purified water 4. Disodium edetate 0.05
5. Tripropylene glycol * 5 5
6. Triethanolamine 0.1
7. Lecithin 0.2
8. Sericite 2
9. Plate-shaped cellulose 2
10. Perfluorooctyltriethoxysilane 3% treated black iron oxide 5
11. Synthetic phlogopite * 10 5
12. Black iron oxide coated mica * 13 20
* 13: COLORONA MICA BLACK (manufactured by Merck & Co., Ltd.)
(Production method)
A. After the component (1) is moistened with the component (2), a part of the component (3) is uniformly heated and swollen.
B. The components (4) to (10) and the rest of the component (3) are uniformly dispersed.
C. Add B and components (11) to (12) to A and mix them uniformly.
D. C was filled in a container to obtain an eyeliner (water-based gel).
The eyeliner of this example was excellent in all of the flexibility of the film, the lack of dryness, the elasticity, the good compatibility with the skin, and the glossiness of the film.

Example 13 Mascara (water-based paste)
(Ingredient) (%)
1. 1. Native gellan gum * 1 0.2
2.1,3-butylene glycol 3
3. 3. Remaining amount of purified water 4. Tripropylene glycol * 5 5
5. Ethanol 15
6. L-Arginine 0.1
7. Disodium edetate 0.05
8. Lecithin 0.2
9. Cleavage talc 2
10. Perfluorooctyltriethoxysilane 3% treated black iron oxide 0.5
11. Perfluoroalkyl Phosphate Ester Diethanolamine Salt 3% Treatment Titanium Oxide Coated Mica * 112
12. Perfluoroalkyl Phosphate Ester Diethanolamine Salt 3% Treatment Titanium Oxide Coated Synthetic Phlogopite * 14 3
13. Perfluoroalkyl Phosphate Ester Diethanolamine Salt 2% Treatment Titanium Oxide Coated Glass Powder * 125
14. (PET / Al / Epoxy resin) Laminate * 13 3
(Production method)
A. After the component (1) is moistened with the component (2), a part of the component (3) is uniformly heated and swollen.
B. The rest of the component (3) and the components (8) to (10) are uniformly dispersed.
C. Add B and components (4) to (7) and (11) to (14) to A and mix them uniformly.
D. C was filled in a container to obtain mascara (water-based paste).
The mascara of this example was excellent in all of the flexibility of the film, the lack of dryness, the elasticity, the good familiarity with the skin, and the glossiness of the film.

Example 14 Eye color base (water-based solid gel)
(Ingredient) (%)
1. 1. Native gellan gum 0.5
2.1,3-butylene glycol 3
3. 3. Remaining amount of purified water 4. Triethanolamine 1
5. Phenylbenzimizosulfonic acid 2
6. Tripropylene glycol * 5 5
7. Dipropylene glycol 15
8. Ethanol 5
9. Perfluorooctyltriethoxysilane 3% treated black iron oxide 0.5
10. Perfluorooctyltriethoxysilane 3% treated Titanium oxide coated mica * 112
11. Methyl Hydrogen Polysiloxane 3% Treatment Titanium Oxide Coated Phlogopite * 14 3
12. Hyaluronic acid 5
13. Novara extract 0.1
14. Licorice extract 0.1
15. Yokuinin extract 0.1
(Production method)
A. After the component (1) is moistened with the component (2), a part of the component (3) is uniformly heated and swollen.
B. The rest of the component (3) and the components (4) and (5) are uniformly mixed and dissolved.
C. Add B and components (6) to (15) to A and mix them uniformly.
D. C was filled in a container to obtain an eye color base (water-based solid gel).
The eye color base of this example was excellent in all of the flexibility of the film, the lack of dryness, the elasticity, the good familiarity with the skin, and the glossiness of the film.

Claims (4)

The following components (A) to (D);
(A) Containing at least one water-soluble polysaccharide (B) tripropylene glycol (C) water (D) plate-like powder selected from the group consisting of gellan gum, pectin, agar, alginic acid, and carrageenan .
The content mass ratio of the component (A) to the component (B) is (A) / (B) = 0.01 to 5.
Aqueous makeup cosmetics. Wherein component (A) is gellan gum, an aqueous makeup cosmetic according to claim 1. The content of the component (B) is 0.1 to 30 wt%, aqueous makeup cosmetic according to claim 1 or 2. Content weight ratio of the component (B) and the component (D) is, (B) / (D) = 0.001 to 1.5 is, an aqueous makeup according to any one of claims 1 to 3 Up cosmetics.