JP2017516680A5 - - Google Patents
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- Publication number
- JP2017516680A5 JP2017516680A5 JP2016561670A JP2016561670A JP2017516680A5 JP 2017516680 A5 JP2017516680 A5 JP 2017516680A5 JP 2016561670 A JP2016561670 A JP 2016561670A JP 2016561670 A JP2016561670 A JP 2016561670A JP 2017516680 A5 JP2017516680 A5 JP 2017516680A5
- Authority
- JP
- Japan
- Prior art keywords
- powder
- thermoplastic polymer
- spherical
- ultrafine
- polyetherimide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000843 powder Substances 0.000 claims 33
- 229920001169 thermoplastic Polymers 0.000 claims 14
- 239000000203 mixture Substances 0.000 claims 13
- 239000004697 Polyetherimide Substances 0.000 claims 7
- 238000000034 method Methods 0.000 claims 7
- 239000002245 particle Substances 0.000 claims 7
- 229920001601 polyetherimide Polymers 0.000 claims 7
- 230000009477 glass transition Effects 0.000 claims 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 6
- 239000002861 polymer material Substances 0.000 claims 5
- 239000002904 solvent Substances 0.000 claims 5
- 239000000839 emulsion Substances 0.000 claims 4
- 239000002002 slurry Substances 0.000 claims 4
- 239000004094 surface-active agent Substances 0.000 claims 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 230000001804 emulsifying effect Effects 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 238000002156 mixing Methods 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 239000005995 Aluminium silicate Substances 0.000 claims 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims 1
- 241001244373 Carex spissa Species 0.000 claims 1
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 235000012211 aluminium silicate Nutrition 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000003945 anionic surfactant Substances 0.000 claims 1
- 229960000892 attapulgite Drugs 0.000 claims 1
- 230000002902 bimodal effect Effects 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 239000000378 calcium silicate Substances 0.000 claims 1
- 229910052918 calcium silicate Inorganic materials 0.000 claims 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 239000003093 cationic surfactant Substances 0.000 claims 1
- 239000000356 contaminant Substances 0.000 claims 1
- 239000008367 deionised water Substances 0.000 claims 1
- 229910021641 deionized water Inorganic materials 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 229910021485 fumed silica Inorganic materials 0.000 claims 1
- 230000004927 fusion Effects 0.000 claims 1
- 239000011521 glass Substances 0.000 claims 1
- -1 glassy oxide Chemical compound 0.000 claims 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims 1
- 239000000391 magnesium silicate Substances 0.000 claims 1
- 229910052919 magnesium silicate Inorganic materials 0.000 claims 1
- 235000019792 magnesium silicate Nutrition 0.000 claims 1
- 239000010445 mica Substances 0.000 claims 1
- 229910052618 mica group Inorganic materials 0.000 claims 1
- 239000002736 nonionic surfactant Substances 0.000 claims 1
- 229910052625 palygorskite Inorganic materials 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 229920002492 poly(sulfone) Polymers 0.000 claims 1
- 229960004029 silicic acid Drugs 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 239000004416 thermosoftening plastic Substances 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461976110P | 2014-04-07 | 2014-04-07 | |
| US61/976,110 | 2014-04-07 | ||
| PCT/US2015/024452 WO2015157148A1 (en) | 2014-04-07 | 2015-04-06 | Powder bed fusing thermoplastic polymers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2017516680A JP2017516680A (ja) | 2017-06-22 |
| JP2017516680A5 true JP2017516680A5 (OSRAM) | 2017-08-03 |
Family
ID=52988471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016561670A Pending JP2017516680A (ja) | 2014-04-07 | 2015-04-06 | 粉末床溶融結合する熱可塑性ポリマー |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10669437B2 (OSRAM) |
| EP (1) | EP3129210B1 (OSRAM) |
| JP (1) | JP2017516680A (OSRAM) |
| KR (1) | KR102322827B1 (OSRAM) |
| CN (1) | CN106170506A (OSRAM) |
| WO (1) | WO2015157148A1 (OSRAM) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10364341B2 (en) * | 2015-04-08 | 2019-07-30 | Arevo, Inc. | Method and apparatus for 3d printing of nano-filler/polymer composites |
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| KR20180050322A (ko) | 2015-09-04 | 2018-05-14 | 사빅 글로벌 테크놀러지스 비.브이. | 분말 조성물, 이 분말 조성물로부터의 물품 및 코팅 제조 방법, 및 이로부터 제조된 물품 |
| WO2017040893A1 (en) * | 2015-09-04 | 2017-03-09 | Sabic Global Technologies B.V. | Powder compositions, method of preparing articles and coatings from the powder compositions, and articles prepared therefrom |
| KR20180094002A (ko) * | 2015-12-11 | 2018-08-22 | 디에스엠 아이피 어셋츠 비.브이. | 3d 인쇄 방법 |
| US10987735B2 (en) | 2015-12-16 | 2021-04-27 | 6K Inc. | Spheroidal titanium metallic powders with custom microstructures |
| EP3389862B1 (en) | 2015-12-16 | 2023-12-06 | 6K Inc. | Method of producing spheroidal dehydrogenated titanium alloy particles |
| CN105504814B (zh) * | 2015-12-25 | 2018-08-24 | 成都新柯力化工科技有限公司 | 一种用于三维打印的聚苯砜组合物及其制备方法 |
| CN105504813A (zh) * | 2015-12-25 | 2016-04-20 | 成都新柯力化工科技有限公司 | 一种用于3d打印的球形聚苯硫醚粉末材料及其制备方法 |
| CN105504815A (zh) * | 2015-12-30 | 2016-04-20 | 成都新柯力化工科技有限公司 | 一种3d打印用聚砜柔性粉体及其制备方法 |
| KR102099577B1 (ko) | 2016-04-15 | 2020-04-10 | 휴렛-팩커드 디벨롭먼트 컴퍼니, 엘.피. | 복합 미립자 빌드(build) 재료 |
| US10315409B2 (en) * | 2016-07-20 | 2019-06-11 | Xerox Corporation | Method of selective laser sintering |
| US10649355B2 (en) | 2016-07-20 | 2020-05-12 | Xerox Corporation | Method of making a polymer composite |
| EP3559094B1 (en) * | 2016-12-23 | 2023-12-13 | SHPP Global Technologies B.V. | Polyetherimide powders for additive manufacturing |
| KR102650520B1 (ko) * | 2017-01-19 | 2024-03-25 | 에스케이이노베이션 주식회사 | 산출 지표를 이용한 폐수처리제 투입량 산출 방법 및 폐수 처리 장치 |
| DE102017206963A1 (de) | 2017-04-25 | 2018-10-25 | Eos Gmbh Electro Optical Systems | Verfahren zur Herstellung eines dreidimensionalen Objekts |
| US11141913B2 (en) | 2017-09-22 | 2021-10-12 | Shpp Global Technologies B.V. | Composition and method for powder bed fusion |
| EP3684861B1 (en) * | 2017-11-30 | 2023-12-27 | Hewlett-Packard Development Company, L.P. | 3d-printed articles |
| JP6547014B1 (ja) * | 2018-01-23 | 2019-07-17 | ダイキン工業株式会社 | 造形用粉末 |
| WO2019182568A1 (en) | 2018-03-20 | 2019-09-26 | Hewlett-Packard Development Company, L.P. | Compositions for printing |
| DE102018108001A1 (de) * | 2018-04-05 | 2019-10-10 | Lean Plastics Technologies GmbH | Verfahren und Vorrichtung zur Herstellung von kugelförmigen Polymerpartikeln und deren Verwendung |
| KR102202980B1 (ko) * | 2018-04-27 | 2021-01-14 | 다이킨 고교 가부시키가이샤 | 조형용 분말 |
| KR102740027B1 (ko) * | 2018-05-17 | 2024-12-06 | 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 | 폴리이미드파우더 조성물 |
| CA3104080A1 (en) | 2018-06-19 | 2019-12-26 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| US10619032B2 (en) | 2018-09-18 | 2020-04-14 | Hexcel Corporation | Polymer powder and method of preparing the same |
| US11597805B2 (en) | 2019-04-10 | 2023-03-07 | Xerox Corporation | Method for producing sulfone polymer micro-particles for SLS 3D printing |
| US11611130B2 (en) | 2019-04-30 | 2023-03-21 | 6K Inc. | Lithium lanthanum zirconium oxide (LLZO) powder |
| KR20220002998A (ko) | 2019-04-30 | 2022-01-07 | 6케이 인크. | 기계적으로 합금된 분말 공급원료 |
| EP3741792A1 (en) | 2019-05-23 | 2020-11-25 | SABIC Global Technologies B.V. | Method of forming semicrystalline polyetherimide, and polyetherimide-containing composition |
| EP3996899B1 (en) | 2019-07-31 | 2023-08-30 | SHPP Global Technologies B.V. | Powder bed fusion material and method |
| EP4004112B1 (en) * | 2019-07-31 | 2023-08-30 | SHPP Global Technologies B.V. | Material and method for powder bed fusion |
| CN114651031B (zh) * | 2019-11-08 | 2025-02-25 | 北卡罗来纳-查佩尔山大学 | 反应性聚酰胺酰亚胺寡聚物、方法及制品 |
| AU2020400980A1 (en) | 2019-11-18 | 2022-03-31 | 6K Inc. | Unique feedstocks for spherical powders and methods of manufacturing |
| US11590568B2 (en) | 2019-12-19 | 2023-02-28 | 6K Inc. | Process for producing spheroidized powder from feedstock materials |
| US12122873B2 (en) | 2020-03-03 | 2024-10-22 | Jabil Inc. | Producing semi-crystalline pulverulent polycarbonate and use thereof in additive manufacturing |
| US11634546B2 (en) | 2020-03-03 | 2023-04-25 | Jabil Inc. | Producing semi-crystalline pulverulent polycarbonate and use thereof in additive manufacturing |
| CN111302718B (zh) * | 2020-04-01 | 2022-09-09 | 同济大学 | 一种利用商品混凝土现场调配为3d打印混凝土的方法 |
| CA3180426A1 (en) | 2020-06-25 | 2021-12-30 | Richard K. Holman | Microcomposite alloy structure |
| EP4165957A4 (en) | 2020-09-24 | 2024-07-24 | 6K Inc. | SYSTEMS, DEVICES AND METHODS FOR STARTING PLASMA |
| CA3196653A1 (en) | 2020-10-30 | 2022-05-05 | Sunil Bhalchandra BADWE | Systems and methods for synthesis of spheroidized metal powders |
| CN116711095A (zh) | 2021-01-11 | 2023-09-05 | 6K有限公司 | 使用微波等离子体处理用于回收锂离子阴极材料的方法和系统 |
| WO2022212291A1 (en) | 2021-03-31 | 2022-10-06 | 6K Inc. | Systems and methods for additive manufacturing of metal nitride ceramics |
| US12031046B2 (en) | 2021-07-22 | 2024-07-09 | Braskem America, Inc. | Polypropylene polymers for powder bed fusion based additive manufacturing |
| US11859103B2 (en) * | 2021-09-24 | 2024-01-02 | Xerox Corporation | Polymer particles and related additive manufacturing methods |
| CN113817227B (zh) * | 2021-10-26 | 2022-06-28 | 中国科学院兰州化学物理研究所 | 聚醚酰亚胺-凹凸棒石-碳纤维杂化材料及其制备方法、改性uhmwpe及其制备方法 |
| WO2023211780A1 (en) * | 2022-04-25 | 2023-11-02 | Jabil Inc. | Spherical particles for additive manufacturing |
| US12261023B2 (en) | 2022-05-23 | 2025-03-25 | 6K Inc. | Microwave plasma apparatus and methods for processing materials using an interior liner |
| US12040162B2 (en) | 2022-06-09 | 2024-07-16 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing an upstream swirl module and composite gas flows |
| US12094688B2 (en) | 2022-08-25 | 2024-09-17 | 6K Inc. | Plasma apparatus and methods for processing feed material utilizing a powder ingress preventor (PIP) |
| US12195338B2 (en) | 2022-12-15 | 2025-01-14 | 6K Inc. | Systems, methods, and device for pyrolysis of methane in a microwave plasma for hydrogen and structured carbon powder production |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4404350A (en) | 1982-07-07 | 1983-09-13 | General Electric Company | Silicone-imide copolymers and method for making |
| US4690997A (en) | 1984-01-26 | 1987-09-01 | General Electric Company | Flame retardant wire coating compositions |
| US4603194A (en) * | 1984-11-30 | 1986-07-29 | General Electric Company | Isolation of polymer resin from organic solution |
| US5296062A (en) | 1986-10-17 | 1994-03-22 | The Board Of Regents, The University Of Texas System | Multiple material systems for selective beam sintering |
| US4944817A (en) | 1986-10-17 | 1990-07-31 | Board Of Regents, The University Of Texas System | Multiple material systems for selective beam sintering |
| US4808686A (en) | 1987-06-18 | 1989-02-28 | General Electric Company | Silicone-polyimides, and method for making |
| US5204055A (en) | 1989-12-08 | 1993-04-20 | Massachusetts Institute Of Technology | Three-dimensional printing techniques |
| US5165994A (en) * | 1990-06-05 | 1992-11-24 | University Of Delaware | Spontaneous equilbrium surfactant vesicles |
| US5385780A (en) | 1990-12-05 | 1995-01-31 | The B. F. Goodrich Company | Sinterable mass of polymer powder having resistance to caking and method of preparing the mass |
| US5648450A (en) | 1992-11-23 | 1997-07-15 | Dtm Corporation | Sinterable semi-crystalline powder and near-fully dense article formed therein |
| US5527877A (en) | 1992-11-23 | 1996-06-18 | Dtm Corporation | Sinterable semi-crystalline powder and near-fully dense article formed therewith |
| US5342919A (en) | 1992-11-23 | 1994-08-30 | Dtm Corporation | Sinterable semi-crystalline powder and near-fully dense article formed therewith |
| US5304329A (en) | 1992-11-23 | 1994-04-19 | The B. F. Goodrich Company | Method of recovering recyclable unsintered powder from the part bed of a selective laser-sintering machine |
| US5516697A (en) | 1993-08-26 | 1996-05-14 | Ferrosensor, Inc. | Biosensor for detecting iron |
| US5817206A (en) * | 1996-02-07 | 1998-10-06 | Dtm Corporation | Selective laser sintering of polymer powder of controlled particle size distribution |
| US6110411A (en) * | 1997-03-18 | 2000-08-29 | Clausen; Christian Henning | Laser sinterable thermoplastic powder |
| SE509088C2 (sv) | 1997-04-30 | 1998-12-07 | Ralf Larsson | Sätt och anordning för framställning av volymkroppar |
| US6322728B1 (en) * | 1998-07-10 | 2001-11-27 | Jeneric/Pentron, Inc. | Mass production of dental restorations by solid free-form fabrication methods |
| US6589471B1 (en) | 1999-10-26 | 2003-07-08 | University Of Southern California | Selective inhibition of bonding of power particles for layered fabrication of 3-D objects |
| US6489372B1 (en) * | 1999-12-23 | 2002-12-03 | General Electric Company | Polycarbonate isolation through homogenization devolatization |
| EP1459871B1 (de) | 2003-03-15 | 2011-04-06 | Evonik Degussa GmbH | Verfahren und Vorrichtung zur Herstellung von dreidimensionalen Objekten mittels Mikrowellenstrahlung sowie dadurch hergestellter Formkörper |
| DE102006015791A1 (de) * | 2006-04-01 | 2007-10-04 | Degussa Gmbh | Polymerpulver, Verfahren zur Herstellung und Verwendung eines solchen Pulvers und Formkörper daraus |
| JP5288361B2 (ja) | 2006-09-26 | 2013-09-11 | 住化エンビロサイエンス株式会社 | 球状ポリアミド粒子の製造方法 |
| US20080122141A1 (en) * | 2006-11-29 | 2008-05-29 | Bryan Bedal | Sinterable Powder |
| WO2009014718A1 (en) * | 2007-07-24 | 2009-01-29 | Porex Corporation | Porous laser sintered articles |
| KR101294925B1 (ko) * | 2008-05-21 | 2013-08-08 | 도레이 카부시키가이샤 | 중합체 미립자의 제조 방법 |
| FR2960878B1 (fr) * | 2010-06-07 | 2012-07-27 | Centre Nat Rech Scient | Nouvelles dispersions aqueuses stables de nanoparticules de polymeres thermoplastiques haute performance et leurs utilisations comme agents filmifiants |
| US9469734B2 (en) * | 2011-03-25 | 2016-10-18 | Sabic Global Technologies B.V. | Fast dissolving polyimide powders |
| GB201108455D0 (en) | 2011-05-20 | 2011-07-06 | Eads Uk Ltd | Polymer additive layer muanfacturing |
| US9181395B2 (en) | 2013-03-15 | 2015-11-10 | Sabic Global Technologies B.V. | Optimized emulsion drying process for making micronized polyetherimide polymers |
| US20140272430A1 (en) * | 2013-03-15 | 2014-09-18 | Sabic Innovative Plastics Ip B.V. | Process of making dispersed polyetherimide micronized particles and process of coating and further forming of these particles products made therefrom |
-
2015
- 2015-04-06 KR KR1020167026459A patent/KR102322827B1/ko active Active
- 2015-04-06 US US15/302,272 patent/US10669437B2/en active Active
- 2015-04-06 CN CN201580018653.5A patent/CN106170506A/zh active Pending
- 2015-04-06 WO PCT/US2015/024452 patent/WO2015157148A1/en not_active Ceased
- 2015-04-06 EP EP15717365.9A patent/EP3129210B1/en not_active Not-in-force
- 2015-04-06 JP JP2016561670A patent/JP2017516680A/ja active Pending
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