JP2017512630A5 - - Google Patents
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- Publication number
- JP2017512630A5 JP2017512630A5 JP2016554465A JP2016554465A JP2017512630A5 JP 2017512630 A5 JP2017512630 A5 JP 2017512630A5 JP 2016554465 A JP2016554465 A JP 2016554465A JP 2016554465 A JP2016554465 A JP 2016554465A JP 2017512630 A5 JP2017512630 A5 JP 2017512630A5
- Authority
- JP
- Japan
- Prior art keywords
- iron
- organic compound
- zeolite
- mixture
- sapo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 30
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims 15
- 229910052742 iron Inorganic materials 0.000 claims 14
- 238000000034 method Methods 0.000 claims 12
- 150000002894 organic compounds Chemical class 0.000 claims 12
- 229910021536 Zeolite Inorganic materials 0.000 claims 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims 10
- 239000010457 zeolite Substances 0.000 claims 10
- 239000000203 mixture Substances 0.000 claims 7
- 239000002808 molecular sieve Substances 0.000 claims 7
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 6
- 239000007789 gas Substances 0.000 claims 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- 238000010531 catalytic reduction reaction Methods 0.000 claims 4
- 238000005470 impregnation Methods 0.000 claims 4
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 claims 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 3
- 230000032683 aging Effects 0.000 claims 3
- 239000004202 carbamide Substances 0.000 claims 3
- 229910001657 ferrierite group Inorganic materials 0.000 claims 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims 2
- 239000002211 L-ascorbic acid Substances 0.000 claims 2
- 235000000069 L-ascorbic acid Nutrition 0.000 claims 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims 2
- 229930006000 Sucrose Natural products 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 2
- 229960005070 ascorbic acid Drugs 0.000 claims 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 2
- 235000015165 citric acid Nutrition 0.000 claims 2
- 239000008103 glucose Substances 0.000 claims 2
- 238000005342 ion exchange Methods 0.000 claims 2
- 239000007791 liquid phase Substances 0.000 claims 2
- 238000002156 mixing Methods 0.000 claims 2
- 235000006408 oxalic acid Nutrition 0.000 claims 2
- 238000006722 reduction reaction Methods 0.000 claims 2
- 239000007790 solid phase Substances 0.000 claims 2
- 238000001694 spray drying Methods 0.000 claims 2
- 239000005720 sucrose Substances 0.000 claims 2
- 150000005621 tetraalkylammonium salts Chemical class 0.000 claims 2
- 125000005270 trialkylamine group Chemical group 0.000 claims 2
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 claims 1
- CGVPYAREDIUBOY-UHFFFAOYSA-K 2-hydroxypropane-1,2,3-tricarboxylate;iron(2+) Chemical compound [Fe+2].[Fe+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O CGVPYAREDIUBOY-UHFFFAOYSA-K 0.000 claims 1
- 238000001669 Mossbauer spectrum Methods 0.000 claims 1
- JGIBNXVWKYGFLY-UHFFFAOYSA-M [NH4+].C(C(=O)[O-])(=O)[O-].[Fe+] Chemical compound [NH4+].C(C(=O)[O-])(=O)[O-].[Fe+] JGIBNXVWKYGFLY-UHFFFAOYSA-M 0.000 claims 1
- WLZUXSFXGDGPPF-UHFFFAOYSA-L [O-]S([O-])(=O)=O.N.[Fe+2].[Fe+2] Chemical compound [O-]S([O-])(=O)=O.N.[Fe+2].[Fe+2] WLZUXSFXGDGPPF-UHFFFAOYSA-L 0.000 claims 1
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical group C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 claims 1
- 229910001573 adamantine Inorganic materials 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 150000002505 iron Chemical class 0.000 claims 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims 1
- 229910000358 iron sulfate Inorganic materials 0.000 claims 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims 1
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- -1 nitrogen-containing compound Chemical class 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 claims 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 claims 1
- BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 claims 1
- SEACXNRNJAXIBM-UHFFFAOYSA-N triethyl(methyl)azanium Chemical class CC[N+](C)(CC)CC SEACXNRNJAXIBM-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461946075P | 2014-02-28 | 2014-02-28 | |
| US61/946,075 | 2014-02-28 | ||
| PCT/GB2015/050579 WO2015128668A1 (en) | 2014-02-28 | 2015-02-27 | Scr catalysts having improved low temperature performance, and methods of making and using the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2017512630A JP2017512630A (ja) | 2017-05-25 |
| JP2017512630A5 true JP2017512630A5 (https=) | 2018-04-12 |
Family
ID=52627529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016554465A Pending JP2017512630A (ja) | 2014-02-28 | 2015-02-27 | 低温性能が改善されたｓｃｒ触媒及びその製造ならびに使用方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20150246345A1 (https=) |
| EP (1) | EP3110548A1 (https=) |
| JP (1) | JP2017512630A (https=) |
| KR (1) | KR20160127108A (https=) |
| CN (1) | CN106029227A (https=) |
| DE (1) | DE112015001008T5 (https=) |
| GB (1) | GB2543166A (https=) |
| RU (1) | RU2016138282A (https=) |
| WO (1) | WO2015128668A1 (https=) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2537206A (en) * | 2015-01-29 | 2016-10-12 | Johnson Matthey Plc | Direct incorporation of iron complexes into SAPO-34 (CHA) type materials |
| US10513439B2 (en) | 2015-08-13 | 2019-12-24 | Tosoh Corporation | Method for producing AEI zeolite |
| US10710059B2 (en) | 2015-12-22 | 2020-07-14 | Basf Corporation | Process for preparing iron(III)-exchanged zeolite composition |
| GB2551871A (en) | 2016-04-22 | 2018-01-03 | Johnson Matthey Plc | STA-18, A new member of the SFW family of molecular sieve zeotypes, methods of preparation and use |
| BR112018072038A2 (pt) | 2016-04-28 | 2019-02-12 | Johnson Matthey Plc | peneira molecular sta-20, catalisador, artigo catalisador, métodos para sintetizar uma peneira molecular, para tratar um gás de escape e para converter metanol em uma olefina, e, composição |
| EP3494089A4 (en) | 2016-08-05 | 2020-09-16 | BASF Corporation | SELECTIVE CATALYTIC REDUCTION ARTICLES AND SYSTEMS |
| TWI619539B (zh) | 2016-10-14 | 2018-04-01 | 財團法人工業技術研究院 | 淨化含氮氧化物氣體的組成物及裝置 |
| KR101879695B1 (ko) * | 2016-12-02 | 2018-07-18 | 희성촉매 주식회사 | 2가 구리 이온들을 특정비율로 담지한 제올라이트, 이의 제조방법 및 이를 포함하는 촉매조성물 |
| CN110392607A (zh) * | 2017-03-13 | 2019-10-29 | 三菱化学株式会社 | 过渡金属负载沸石和其制造方法以及氮氧化物净化用催化剂和其使用方法 |
| CN107262145B (zh) * | 2017-07-24 | 2020-11-27 | 安徽纳蓝环保科技有限公司 | 一种沸石碳氢吸附重整催化剂的制备方法 |
| CN108212208B (zh) * | 2018-04-03 | 2020-08-25 | 兰州理工大学 | 一种atn型铁基磷酸铝分子筛催化剂的制备方法 |
| FR3081340B1 (fr) * | 2018-05-24 | 2020-06-26 | IFP Energies Nouvelles | Catalyseur comprenant un melange d'une zeolithe de type structural afx et d'une zeolithe de type structural bea et au moins un metal de transition pour la reduction selective de nox |
| BR112021013873A2 (pt) * | 2019-01-18 | 2021-09-14 | Cummins Emission Solutions Inc. | Catalisadores de rcs tratados com resistência ao enxofre melhorada |
| CN109999895B (zh) * | 2019-04-16 | 2021-06-29 | 上海交通大学 | 一种低温催化去除氮氧化物的催化剂及其制备方法 |
| CN110833831B (zh) * | 2019-11-07 | 2022-11-01 | 上海纳米技术及应用国家工程研究中心有限公司 | 铬钴基一氧化氮常温常压催化剂的制备方法及其产品和应用 |
| KR102528565B1 (ko) | 2020-02-27 | 2023-05-04 | 한국화학연구원 | 잔류염소 제거방법 및 그 방법에 의한 질소산화물 저감용 촉매 |
| EP3919165B1 (en) * | 2020-06-03 | 2025-08-13 | Johnson Matthey Public Limited Company | Method for forming a catalyst article |
| CN114345402B (zh) * | 2021-08-30 | 2024-09-17 | 武汉科技大学 | 一种铁基分子筛催化剂的制备方法 |
| CN121001962A (zh) * | 2023-05-12 | 2025-11-21 | 东曹株式会社 | 含铁fer型沸石及其制造方法 |
| KR20260038236A (ko) | 2023-06-06 | 2026-03-18 | 바스프 코포레이션 | 배기 가스의 처리를 위한 Fe 함유 제올라이트 재료를 포함하는 촉매 재료 |
| CN116786135B (zh) * | 2023-08-18 | 2024-01-02 | 四川大学 | 氧化锰矿烟气脱硫尾渣资源化制备低温脱硝催化剂的方法 |
| CN120004287A (zh) * | 2025-04-18 | 2025-05-16 | 长春理工大学 | 一种Cu-SSZ-13分子筛制备方法和分子筛的应用 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4255349A (en) * | 1978-12-18 | 1981-03-10 | Mobil Oil Corporation | Conversion of synthesis gas with iron-containing catalyst |
| EP0756891A1 (en) * | 1995-07-26 | 1997-02-05 | Corning Incorporated | Iron zeolite for conversion of NOx |
| US6033641A (en) * | 1996-04-18 | 2000-03-07 | University Of Pittsburgh Of The Comonwealth System Of Higher Education | Catalyst for purifying the exhaust gas from the combustion in an engine or gas turbines and method of making and using the same |
| FR2789911B1 (fr) | 1999-02-18 | 2001-05-04 | Grande Paroisse Sa | Procede pour abattre simultanement les oxydes nitriques et le protoxyde d'azote dans les gaz qui en contiennent |
| BRPI0810133B1 (pt) * | 2007-04-26 | 2023-01-17 | Johnson Matthey Public Limited Company | Método para converter óxidos de nitrogênio de um gás em nitrogênio, sistema de escapamento para um motor de combustão interna de queima pobre veicular, e, aparelho |
| WO2008143762A2 (en) * | 2007-05-15 | 2008-11-27 | Corning Incorporated | Catalyst body and methods |
| CN101827654B (zh) * | 2007-08-13 | 2013-11-06 | Pq公司 | 含铁铝硅酸盐沸石及其制备和使用方法 |
| EP2296790B1 (de) * | 2008-05-07 | 2018-03-14 | Umicore AG & Co. KG | Verfahren zur verminderung von stickoxiden in kohlenwasserstoffhaltigen abgasen unter verwendung eines scr-katalysators auf basis eines molekularsiebes |
| US8841105B2 (en) * | 2009-03-27 | 2014-09-23 | National University Corporation Okayama University | Organic-inorganic composite material and process for producing same |
| JP5573453B2 (ja) * | 2010-07-21 | 2014-08-20 | 三菱樹脂株式会社 | 窒素酸化物浄化用触媒及びその製造方法 |
| US20120134916A1 (en) * | 2011-02-28 | 2012-05-31 | Fedeyko Joseph M | High-temperature scr catalyst |
| US20120251422A1 (en) * | 2011-04-04 | 2012-10-04 | Pq Corporation | Fe-SAPO-34 CATALYST AND METHODS OF MAKING AND USING THE SAME |
-
2015
- 2015-02-27 WO PCT/GB2015/050579 patent/WO2015128668A1/en not_active Ceased
- 2015-02-27 KR KR1020167026799A patent/KR20160127108A/ko not_active Withdrawn
- 2015-02-27 RU RU2016138282A patent/RU2016138282A/ru not_active Application Discontinuation
- 2015-02-27 CN CN201580010629.7A patent/CN106029227A/zh active Pending
- 2015-02-27 US US14/633,658 patent/US20150246345A1/en not_active Abandoned
- 2015-02-27 GB GB1616359.4A patent/GB2543166A/en not_active Withdrawn
- 2015-02-27 DE DE112015001008.4T patent/DE112015001008T5/de not_active Withdrawn
- 2015-02-27 JP JP2016554465A patent/JP2017512630A/ja active Pending
- 2015-02-27 EP EP15708040.9A patent/EP3110548A1/en not_active Withdrawn
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