JP2017508852A - 改質されたエラストマー表面 - Google Patents
改質されたエラストマー表面 Download PDFInfo
- Publication number
- JP2017508852A JP2017508852A JP2016558644A JP2016558644A JP2017508852A JP 2017508852 A JP2017508852 A JP 2017508852A JP 2016558644 A JP2016558644 A JP 2016558644A JP 2016558644 A JP2016558644 A JP 2016558644A JP 2017508852 A JP2017508852 A JP 2017508852A
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- Prior art keywords
- polymerizable composition
- elastomer
- component
- membrane
- pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000034 method Methods 0.000 claims abstract description 109
- 150000001875 compounds Chemical class 0.000 claims abstract description 60
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 56
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- 239000003999 initiator Substances 0.000 claims abstract description 33
- 150000003254 radicals Chemical class 0.000 claims abstract description 27
- 150000001412 amines Chemical class 0.000 claims abstract description 25
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 14
- 239000012528 membrane Substances 0.000 claims description 136
- 229920001971 elastomer Polymers 0.000 claims description 109
- 239000000806 elastomer Substances 0.000 claims description 105
- 229920001296 polysiloxane Polymers 0.000 claims description 64
- 239000000047 product Substances 0.000 claims description 38
- 239000007789 gas Substances 0.000 claims description 33
- 239000007788 liquid Substances 0.000 claims description 23
- 230000037303 wrinkles Effects 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 14
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 229910052796 boron Inorganic materials 0.000 claims description 7
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- 239000003431 cross linking reagent Substances 0.000 claims description 7
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- 150000008064 anhydrides Chemical class 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
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- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 claims description 3
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 claims 1
- -1 methylenedioxy, ethylenedioxy Chemical group 0.000 description 46
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- 125000004432 carbon atom Chemical group C* 0.000 description 18
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- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 9
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- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 8
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 8
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
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- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 238000004611 spectroscopical analysis Methods 0.000 description 5
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 4
- MPIAGWXWVAHQBB-UHFFFAOYSA-N [3-prop-2-enoyloxy-2-[[3-prop-2-enoyloxy-2,2-bis(prop-2-enoyloxymethyl)propoxy]methyl]-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical class C=CC(=O)OCC(COC(=O)C=C)(COC(=O)C=C)COCC(COC(=O)C=C)(COC(=O)C=C)COC(=O)C=C MPIAGWXWVAHQBB-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 125000000753 cycloalkyl group Chemical group 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 125000000623 heterocyclic group Chemical group 0.000 description 4
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- 125000004433 nitrogen atom Chemical group N* 0.000 description 4
- 125000000962 organic group Chemical group 0.000 description 4
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- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- KQQUVPYTQZDZAE-UHFFFAOYSA-N 3-methoxypropan-1-amine;triethylborane Chemical compound COCCCN.CCB(CC)CC KQQUVPYTQZDZAE-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
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- 150000001299 aldehydes Chemical class 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
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- 125000005842 heteroatom Chemical group 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 230000000977 initiatory effect Effects 0.000 description 3
- 239000002184 metal Chemical class 0.000 description 3
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- 229920000728 polyester Polymers 0.000 description 3
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
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- 229940096522 trimethylolpropane triacrylate Drugs 0.000 description 3
- LZWFXVJBIZIHCH-UHFFFAOYSA-N 1-Ethenylhexyl butanoate Chemical class CCCCCC(C=C)OC(=O)CCC LZWFXVJBIZIHCH-UHFFFAOYSA-N 0.000 description 2
- OFHHDSQXFXLTKC-UHFFFAOYSA-N 10-undecenal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 description 2
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical class C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 description 2
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 2
- JMWGZSWSTCGVLX-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;2-methylprop-2-enoic acid Chemical class CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O.CCC(CO)(CO)CO JMWGZSWSTCGVLX-UHFFFAOYSA-N 0.000 description 2
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
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- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 2
- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 description 2
- JUDXBRVLWDGRBC-UHFFFAOYSA-N [2-(hydroxymethyl)-3-(2-methylprop-2-enoyloxy)-2-(2-methylprop-2-enoyloxymethyl)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(CO)(COC(=O)C(C)=C)COC(=O)C(C)=C JUDXBRVLWDGRBC-UHFFFAOYSA-N 0.000 description 2
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- KGBBDBRJXGILTQ-UHFFFAOYSA-N [3-(2-methylprop-2-enoyloxy)-2,2-bis(2-methylprop-2-enoyloxymethyl)propyl] 2-methylprop-2-enoate Chemical class CC(=C)C(=O)OCC(COC(=O)C(C)=C)(COC(=O)C(C)=C)COC(=O)C(C)=C KGBBDBRJXGILTQ-UHFFFAOYSA-N 0.000 description 2
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- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 2
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- XQBXAEVGRNAIBS-UHFFFAOYSA-N propane-1,1-diamine;triethylborane Chemical group CCC(N)N.CCB(CC)CC XQBXAEVGRNAIBS-UHFFFAOYSA-N 0.000 description 2
- IJUCBZFJEAVADL-UHFFFAOYSA-N propane-1,3-diamine;triethylborane Chemical compound NCCCN.CCB(CC)CC IJUCBZFJEAVADL-UHFFFAOYSA-N 0.000 description 2
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- YUPAWYWJNZDARM-UHFFFAOYSA-N tri(butan-2-yl)borane Chemical compound CCC(C)B(C(C)CC)C(C)CC YUPAWYWJNZDARM-UHFFFAOYSA-N 0.000 description 2
- CMHHITPYCHHOGT-UHFFFAOYSA-N tributylborane Chemical compound CCCCB(CCCC)CCCC CMHHITPYCHHOGT-UHFFFAOYSA-N 0.000 description 2
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- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- XVZMLSWFBPLMEA-UHFFFAOYSA-N trimethoxy(2-pyridin-2-ylethyl)silane Chemical compound CO[Si](OC)(OC)CCC1=CC=CC=N1 XVZMLSWFBPLMEA-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- WXRGABKACDFXMG-UHFFFAOYSA-N trimethylborane Chemical compound CB(C)C WXRGABKACDFXMG-UHFFFAOYSA-N 0.000 description 1
- 125000003960 triphenylenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C3=CC=CC=C3C12)* 0.000 description 1
- 210000005239 tubule Anatomy 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
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Abstract
Description
エラストマー表面を改質する方法
機械的な変形
構成成分A、1種以上のフリーラジカル重合性モノマー
構成成分B、1種以上の有機ボラン−有機窒素フリーラジカル開始剤。
構成成分C、1つ以上のアミン反応性化合物。
膜。
供給混合物中の構成成分の分離方法
実施例1.回転楕円体様の特徴を備えるパターン
実施例2.連続した平行な正弦波様の特徴を備えるパターン
実施例3.
実施例4a〜g.回転楕円体型の特徴を備えるパターン
実施例6.シリコーンゴム管の内側表面改質
実施例7.シリコーンゴム管の内側表面改質
実施例8.シリコーンゴム中空糸膜モジュールの(仮想的)内側表面改質
実施例9.シリコーン中空糸膜モジュールの(仮想的)使用
実施例10.シリコーン中空糸膜モジュールの(仮想的)使用
追加の実施形態
A)フリーラジカル重合性モノマー;
B)有機ボラン−有機窒素フリーラジカル開始剤;及び
C)アミン反応性化合物、を含む重合性組成物と、オルガノポリシロキサンを含むエラストマー表面の少なくとも一部分と、を接触させること、
重合性組成物を少なくとも部分的に重合させて、エラストマー表面上に重合性組成物の重合生成物を提供すること、を含む。
エラストマー表面の少なくとも一部分と、構成成分A及びBとを接触させること;及び
続いてエラストマー表面の少なくとも一部分と、構成成分Cとを接触させること、を含む、実施形態1〜3のいずれか1つに記載の方法を提供する。
エラストマー表面の少なくとも一部分と、構成成分A及びCとを接触させること;及び
続いてエラストマー表面の少なくとも一部分と、構成成分Bとを接触させること、を含む、実施形態1〜4のいずれか1つに記載の方法を提供する。
エラストマーが、重合の少なくともある程度の期間中に機械的に変形した状態となるよう、エラストマーにひずみを加えることを更に含み、重合性組成物の重合生成物がパターンを含む、実施形態1〜5のいずれか1つに記載の方法を提供する。
膜の第1面を少なくとも第1の構成成分と第2の構成成分とを含む供給気体混合物又は供給液体混合物と接触させて、膜の第2の面上に透過混合物をもたらし、非透過混合物を表面の第1面上にもたらすことを含み、透過混合物には第1の構成成分が富化されており、非透過混合物には第1の構成成分が含まれておらず、少なくとも膜の第1面又は第2面が実施形態1〜33のいずれか1つに記載の重合性組成物の重合生成物を含むエラストマーを含む、方法を提供する。
オルガノポリシロキサンを含むエラストマー表面の少なくとも一部分と、重合性組成物とを接触させることであって、重合性組成物が、
A)約0.01重量%〜約75重量%の1種以上のジ−、トリ−、テトラ−、ペンタ−、又はヘキサ−エチレン性不飽和架橋剤、及び約25重量%〜約99.9重量%の1種以上のC2〜C10モノエチレン性不飽和モノマーを含む、1種以上のフリーラジカル重合性モノマー、
B)1種以上の有機ボラン重合開始剤、
C)独立してC1〜C20アルカノン酸から選択された1種以上のアミン反応性化合物、及び
1種以上の任意選択的なキャリアフルイド、を含み、構成成分Aは構成成分A、B、及びCの約50重量%〜約99.9重量%であり、構成成分Bは構成成分A、B、及びCの約0.01重量%〜約20重量%であり、構成成分Cは構成成分A、B、及びCの約0.000,01重量%〜約10重量%であり、並びに
重合性組成物を少なくとも部分的に重合させて、エラストマー表面上に重合性組成物の重合生成物を提供すること、を含む、方法を提供する。
エラストマー表面の少なくとも一部分と、重合性組成物とを接触させることであって、重合性組成物が、
A)フリーラジカル重合性モノマー;
B)有機ボラン−有機窒素フリーラジカル開始剤;及び
C)アミン反応性化合物、を含む、接触させること、
重合性組成物を少なくとも部分的に重合させて、エラストマー表面上に金型不使用のパターンを含む重合性組成物の重合生成物を提供すること、を含み、
エラストマーは、重合の少なくともある程度の期間中、機械的に変形している状態である、方法を提供する。
Claims (15)
- エラストマー表面の改質方法であって、
オルガノポリシロキサンを含むエラストマー表面の少なくとも一部分と、重合性組成物とを接触させることであって、前記重合性組成物が、
A)フリーラジカル重合性モノマー;
B)有機ボラン−有機窒素フリーラジカル開始剤;及び
C)アミン反応性化合物、を含む、接触させること、
前記重合性組成物を少なくとも部分的に重合させて、前記エラストマー表面上に前記重合性組成物の重合生成物を提供すること、を含む、方法。 - 前記エラストマーが、前記重合の少なくともある程度の期間中に機械的に変形した状態となるよう、前記エラストマーにひずみを加えることを更に含み、前記重合性組成物の前記重合生成物がパターンを含む、請求項1に記載の方法。
- 前記ひずみが、前記組成物との接触前、前記組成物との接触中、前記組成物との接触後、前記少なくとも部分的な重合前、及び前記少なくとも部分的な重合中、のうちの少なくとも1つの時点で、前記エラストマーに加えられる、請求項1又は2のいずれか一項に記載の方法。
- 前記パターンが金型不使用のパターンを含む、請求項1〜3のいずれか一項に記載の方法。
- 前記パターンが、回転楕円体様の特徴、正弦波様の特徴、しわ、及び平行なしわのうちの少なくとも1つを含む別個のパターンを含む、請求項1〜4のいずれか一項に記載の方法。
- 前記エラストマーが膜を含む、請求項1〜5のいずれか一項に記載の方法。
- 構成成分Aが、少なくとも1つのC2〜C10モノエチレン性不飽和モノマーを含む、請求項1〜6のいずれか一項に記載の方法。
- 構成成分Aが、少なくとも1種の架橋剤、すなわちジ−、トリ−、テトラ−、ペンタ−、又はヘキサ−エチレン性不飽和架橋剤を含む、請求項1〜7のいずれか一項に記載の方法。
- 前記アミン反応性化合物が、鉱酸、ルイス酸、カルボン酸、カルボン酸誘導体、カルボン酸塩、イソシアネート、アルデヒド、エポキシド、酸塩化物、スルホニルクロリド、ヨードニウム塩、無水物、スクシネート、シラン、オルガノシロキサン、及び酸素から選択される、請求項1〜8のいずれか一項に記載の方法。
- 前記重合性組成物が、キャリア液体を更に含む、請求項1〜9のいずれか一項に記載の方法。
- 請求項1〜10のいずれか一項に記載の方法により作製された前記重合生成物。
- 請求項1〜10のいずれか一項に記載の方法により作製された前記重合生成物を含む前記エラストマー。
- 供給混合物中の構成成分を分離する方法であって、
膜の第1面を少なくとも第1の構成成分と第2の構成成分とを含む供給気体混合物又は供給液体混合物と接触させて、前記膜の第2の面上に透過混合物をもたらし、非透過混合物を前記表面の前記第1面上にもたらすことを含み、前記透過混合物には前記第1の構成成分が富化されており、前記非透過混合物には前記第1の構成成分が含まれておらず、少なくとも前記膜の前記第1面又は前記第2面が請求項1〜10のいずれか一項に記載の前記重合性組成物の前記重合生成物を含む前記エラストマーを含む、方法。 - エラストマー表面の改質方法であって、
オルガノポリシロキサンを含むエラストマー表面の少なくとも一部分と、重合性組成物とを接触させることであって、前記重合性組成物が、
A)約0.01重量%〜約75重量%の1種以上のジ−、トリ−、テトラ−、ペンタ−、又はヘキサ−エチレン性不飽和架橋剤、及び約25重量%〜約99.9重量%の1種以上のC2〜C10モノエチレン性不飽和モノマーを含む、1種以上のフリーラジカル重合性モノマー、
B)1種以上の有機ボラン重合開始剤、
C)独立してC1〜C20アルカノン酸から選択された1種以上のアミン反応性化合物、及び
1種以上の任意選択的なキャリアフルイド、を含み、構成成分Aは構成成分A、B、及びCの約50重量%〜約99.9重量%であり、構成成分Bは構成成分A、B、及びCの約0.01重量%〜約20重量%であり、構成成分Cは構成成分A、B、及びCの約0.000,01重量%〜約10重量%であり、並びに
前記重合性組成物を少なくとも部分的に重合させて、前記エラストマー表面上に前記重合性組成物の重合生成物を提供すること、を含む、方法。 - エラストマー表面の改質方法であって、
エラストマー表面の少なくとも一部分と、重合性組成物とを接触させることであって、前記重合性組成物が、
A)フリーラジカル重合性モノマー;
B)有機ボラン−有機窒素フリーラジカル開始剤;及び
C)アミン反応性化合物、を含む、接触させること、
前記重合性組成物を少なくとも部分的に重合させて、前記エラストマー表面上に、金型不使用のパターンを含む前記重合性組成物の重合生成物を提供すること、を含み、
前記エラストマーが、前記重合の少なくともある程度の期間中、機械的に変形している状態である、方法。
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2019049950A1 (ja) * | 2017-09-11 | 2019-03-14 | 東レ・ダウコーニング株式会社 | ラジカル反応性を有するシリコーンエラストマー硬化物およびその用途 |
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EP3588538B1 (en) * | 2017-02-14 | 2024-03-27 | Toshiba Mitsubishi-Electric Industrial Systems Corporation | Method of forming nitride films |
CN114149527B (zh) * | 2021-12-10 | 2023-08-04 | 复旦大学 | 一种在空气氛围中实现可控自由基聚合的方法及其应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006522206A (ja) * | 2003-02-28 | 2006-09-28 | ダウ グローバル テクノロジーズ インコーポレイティド | シロキサン重合性成分を含むアミン有機ボラン錯体開始重合性組成物 |
JP2008527077A (ja) * | 2005-01-04 | 2008-07-24 | ダウ・コーニング・コーポレイション | オルガノボランアミン錯体によって硬化されたシロキサンおよびシラン |
JP2008527105A (ja) * | 2005-01-04 | 2008-07-24 | ダウ・コーニング・コーポレイション | 有機硅素官能基硼素アミン触媒錯体およびこれから調製された硬化可能な組成物 |
JP2008530338A (ja) * | 2005-02-16 | 2008-08-07 | ダウ・コーニング・コーポレイション | ポリマー粒子、および、有機ボランアミン錯体を使用しているカプセル化組成物 |
JP2014500393A (ja) * | 2010-12-27 | 2014-01-09 | ダウ コーニング コーポレーション | 硬化性ケイ酸塩−シロキサン混合マトリックス膜組成物 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1327942C (zh) * | 2004-01-09 | 2007-07-25 | 中国科学院大连化学物理研究所 | 一种复合金属钯膜或合金钯膜及其制备方法 |
EP2026906A2 (en) * | 2006-05-23 | 2009-02-25 | Dow Corning Corporation | Borane catalyst complexes with amide functional polymers and curable compositions made therefrom |
US8501887B2 (en) * | 2008-07-28 | 2013-08-06 | Dow Corning Corporation | Radical polymerizable composition |
WO2010091001A1 (en) * | 2009-02-04 | 2010-08-12 | Dow Corning Corporation | Method of forming a non-random copolymer |
CA2772309C (en) | 2009-08-27 | 2017-11-21 | Mcmaster University | Surface-modifying silicone elastomers |
WO2011049919A1 (en) | 2009-10-23 | 2011-04-28 | Dow Corning Corporation | Hydrophilically-modified silicone compositions |
US9243113B2 (en) * | 2009-10-23 | 2016-01-26 | Dow Corning Corporation | Silicone compositions comprising a swollen silicone gel |
JP2013520531A (ja) | 2010-02-18 | 2013-06-06 | ダウ コーニング コーポレーション | シロキサン表面改質ヒドロゲル及びヒドロゲル微粒子組成物 |
KR101825607B1 (ko) | 2010-02-18 | 2018-02-05 | 다우 코닝 코포레이션 | 표면-개질된 하이드로겔 및 하이드로겔 미세입자 |
US8865266B2 (en) * | 2011-02-16 | 2014-10-21 | Dow Corning Corporation | Method of coating a porous substrate |
WO2012138755A1 (en) * | 2011-04-08 | 2012-10-11 | Dongchan Ahn | Method of preparing gas selective membrane using epoxy-functional siloxanes |
WO2013101943A1 (en) * | 2011-12-27 | 2013-07-04 | Dow Corning Corporation | High free volume siloxane compositions useful as membranes |
WO2014052419A1 (en) * | 2012-09-26 | 2014-04-03 | Dow Corning Corporation | Method of separating a gas using at least one membrane in contact with an organosilicon fluid |
US10022680B2 (en) * | 2013-01-14 | 2018-07-17 | Kraton Polymers U.S. Llc | Anion exchange block copolymers, their manufacture and their use |
-
2014
- 2014-12-11 KR KR1020167026014A patent/KR20160138030A/ko active IP Right Grant
- 2014-12-11 CN CN201480073452.0A patent/CN105916924B/zh not_active Expired - Fee Related
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- 2014-12-11 WO PCT/US2014/069700 patent/WO2015147921A1/en active Application Filing
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- 2014-12-11 EP EP14887683.2A patent/EP3122807B1/en not_active Not-in-force
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006522206A (ja) * | 2003-02-28 | 2006-09-28 | ダウ グローバル テクノロジーズ インコーポレイティド | シロキサン重合性成分を含むアミン有機ボラン錯体開始重合性組成物 |
JP2008527077A (ja) * | 2005-01-04 | 2008-07-24 | ダウ・コーニング・コーポレイション | オルガノボランアミン錯体によって硬化されたシロキサンおよびシラン |
JP2008527105A (ja) * | 2005-01-04 | 2008-07-24 | ダウ・コーニング・コーポレイション | 有機硅素官能基硼素アミン触媒錯体およびこれから調製された硬化可能な組成物 |
JP2008530338A (ja) * | 2005-02-16 | 2008-08-07 | ダウ・コーニング・コーポレイション | ポリマー粒子、および、有機ボランアミン錯体を使用しているカプセル化組成物 |
JP2014500393A (ja) * | 2010-12-27 | 2014-01-09 | ダウ コーニング コーポレーション | 硬化性ケイ酸塩−シロキサン混合マトリックス膜組成物 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019049950A1 (ja) * | 2017-09-11 | 2019-03-14 | 東レ・ダウコーニング株式会社 | ラジカル反応性を有するシリコーンエラストマー硬化物およびその用途 |
JPWO2019049950A1 (ja) * | 2017-09-11 | 2020-11-26 | ダウ・東レ株式会社 | ラジカル反応性を有するシリコーンエラストマー硬化物およびその用途 |
JP7228519B2 (ja) | 2017-09-11 | 2023-02-24 | ダウ・東レ株式会社 | ラジカル反応性を有するシリコーンエラストマー硬化物およびその用途 |
US11981814B2 (en) | 2017-09-11 | 2024-05-14 | Dow Toray Co., Ltd. | Cured silicone elastomer having radical reactivity and use of same |
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