JP2017221152A - Manufacturing method of confectionery using nitrogen water - Google Patents

Manufacturing method of confectionery using nitrogen water Download PDF

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JP2017221152A
JP2017221152A JP2016119903A JP2016119903A JP2017221152A JP 2017221152 A JP2017221152 A JP 2017221152A JP 2016119903 A JP2016119903 A JP 2016119903A JP 2016119903 A JP2016119903 A JP 2016119903A JP 2017221152 A JP2017221152 A JP 2017221152A
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water
nitrogen
confectionery
sweetener
oxygen
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聖子 若山
Seiko Wakayama
聖子 若山
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SHOWA REITO PLANT KK
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Abstract

PROBLEM TO BE SOLVED: To provide a manufacturing method of confectionery with suppressing oxidation and degradation by oxygen dissolved in water without using an oxidization inhibitor.SOLUTION: There is provided a manufacturing method of confectionery with reducing a risk of deterioration by oxidation and microorganism propagation, and nitrogen water with reducing oxygen dissolved amount by dissolving nitrogen gas in water is used as water in materials. When the confectionery is candy, all materials including a sweetener and nitrogen water are mixed, heated and cooled and solidified after boiling and dissolving the sweetener. When the sweetener is saccharide, the nitrogen water of 40 to 90 pts.wt. based on 100 pts.wt. of the saccharide is used, materials is heated, and cooled and solidified after dissolving the saccharide.SELECTED DRAWING: Figure 1

Description

本発明は、窒素水を使用した菓子の製造方法に関する。   The present invention relates to a method for producing a confectionery using nitrogen water.

近年、健康と食に対する関心が高まっている。従来から、酸化した油脂の摂取は健康被害に繋がるものとして避けられる傾向にあったが、近年では油脂に限らず、酸化した食品全般の摂取が老化や様々な病気の原因になる可能性が指摘されている。   In recent years, interest in health and food has increased. Traditionally, the consumption of oxidized fats and oils tended to be avoided as a health hazard, but in recent years, not only fats and oils but also the consumption of oxidized foods in general can cause aging and various diseases. Has been.

食品の酸化は、食品が酸素と結びつくことで起こる。しかし、酸素は空気中に多量に存在し、また、水に溶け込んだ形で水中にも存在している。そのため、食品の酸化を防ぐことは困難であり、酸化防止剤を食品に添加することも多い。   Food oxidation occurs when food is combined with oxygen. However, oxygen is present in a large amount in the air, and is also present in the water in a form dissolved in water. Therefore, it is difficult to prevent the food from being oxidized, and an antioxidant is often added to the food.

空気中の酸素による酸化は、主に食品の表面を酸化させると考えられる。これは、食品の包装等を工夫して、なるべく食品が空気に触れないようにすることによりある程度防ぐことができる。しかし、水に溶け込んだ形で存在している酸素による酸化は、食品自体が水分を含んでいる以上、包装等によって防ぐことはできない。   Oxidation by oxygen in the air is thought to mainly oxidize the food surface. This can be prevented to some extent by devising food packaging and the like so that the food does not touch the air as much as possible. However, oxidation by oxygen existing in a form dissolved in water cannot be prevented by packaging or the like as long as the food itself contains moisture.

特に菓子類は、製造の際に水が使われることが多く、また、材料には粉体や粒体等、細かく比較的均質なものがよく使用されるため、材料が水と接触する表面積が大きいと考えられる。そのため、水に溶け込んだ酸素により材料が酸化する可能性がある。   Especially for confectionery, water is often used in production, and fine and relatively homogeneous materials such as powders and granules are often used for the material, so the surface area where the material comes into contact with water is large. It is considered large. Therefore, there is a possibility that the material is oxidized by oxygen dissolved in water.

また、酸素は酸化の原因となるだけでなく、菌類、好気性細菌類等の繁殖の要因にもなる。カビを含む多くの菌類や好気性細菌類は、生存のために酸素を必要とする。また、菓子類はそれらが繁殖するための栄養も豊富であると考えられる。そのため、水に溶け込んだ酸素が菌類や好気性細菌類の増殖の原因となり、食品の劣化や腐敗を引き起こす可能性がある。   Moreover, oxygen not only causes oxidation but also causes growth of fungi, aerobic bacteria and the like. Many fungi and aerobic bacteria, including mold, require oxygen for survival. Confectionery is also thought to be rich in nutrition for their breeding. For this reason, oxygen dissolved in water may cause the growth of fungi and aerobic bacteria, which may cause food deterioration and spoilage.

特許文献1の酸化抑制組成物及び固形状経口剤若しくは固形状食品では、化学的又は物理的な変質を抑制する酸化抑制組成物及び、それが配合された食品が記載されている。食品には、グミ、飴、チョコレート、チューイングガム、羊羹等の菓子類が含まれる。   In the oxidation inhibitory composition and solid oral preparation or solid food of Patent Document 1, an oxidation inhibitory composition that suppresses chemical or physical alteration and a food containing the same are described. The food includes confectionery such as gummy, candy, chocolate, chewing gum, and sheep candy.

菓子の分野ではないが、特許文献2の漬け汁、漬け汁製造装置及び加工漬け方法では、生鮮食品の酸化、腐敗を防ぐために、通常の水に含まれる酸素を窒素に置換した窒素水又は窒素水を凍結させた窒素氷を用いた保存方法が提示されている。   Although not in the field of confectionery, the pickled juice, pickled juice manufacturing apparatus and processed pickled method disclosed in Patent Document 2 have nitrogen water or nitrogen in which oxygen contained in normal water is replaced with nitrogen in order to prevent the oxidation and decay of fresh food. A storage method using nitrogen ice in which water is frozen is proposed.

特開2013−213001号公報JP 2013-211301 A 特許第4969897号公報Japanese Patent No. 4969897

特許文献1に記載の発明では、空気中の酸素による表面の酸化を抑制することは考慮されているものの、水に溶け込んだ酸素による酸化までは考慮されていない。また、昨今の自然食品の流行により食品添加物を好まない消費者も多く、酸化抑制剤を添加することに対する懸念もある。   In the invention described in Patent Document 1, although suppression of surface oxidation by oxygen in the air is considered, oxidation by oxygen dissolved in water is not considered. In addition, there are many consumers who do not like food additives due to the recent trend of natural foods, and there is concern about adding an oxidation inhibitor.

本発明の目的は、酸化抑制剤を使用せずに、水に溶け込んだ酸素による酸化・劣化を抑制した菓子の製造方法を提供することである。   The objective of this invention is providing the manufacturing method of the confectionery which suppressed the oxidation and deterioration by the oxygen which melt | dissolved in water, without using an oxidation inhibitor.

本発明の態様は、酸化及び微生物繁殖による劣化のリスクを低減させた菓子の製造方法であって、材料中の水は、水に窒素ガスを溶解させて酸素溶存量を低下させた窒素水を使用することを特徴とする。   An aspect of the present invention is a confectionery manufacturing method in which the risk of deterioration due to oxidation and microbial propagation is reduced, and the water in the material is nitrogen water in which the amount of dissolved oxygen is reduced by dissolving nitrogen gas in the water. It is characterized by using.

上記の態様において、前記菓子が飴である場合、甘味料及び窒素水を含む全ての材料を混合し、加温して甘味料を煮溶かした後に冷やし固めることを特徴とする。   Said aspect WHEREIN: When the said confectionery is a candy, all the ingredients containing a sweetener and nitrogen water are mixed, It heats and the sweetener is boiled, It cools and solidifies, It is characterized by the above-mentioned.

上記の態様において、前記甘味料が糖類である場合、100重量部の糖類に対し、40〜90重量部の前記窒素水を使用し、材料を加温して前記糖類を煮溶かした後に冷やし固めることを特徴とする。   In the above aspect, when the sweetener is a saccharide, 40 to 90 parts by weight of the nitrogen water is used with respect to 100 parts by weight of the saccharide, and the material is heated to boil the saccharide and then cooled and hardened. It is characterized by that.

本発明の窒素水を使用した菓子の製造方法によれば、材料中の水に溶存する酸素が極めて少ないため、酸化抑制剤を使用せずに、水に溶け込んだ酸素による酸化及び劣化を抑制することができる。   According to the method for producing confectionery using nitrogen water of the present invention, since oxygen dissolved in water in the material is extremely small, oxidation and deterioration due to oxygen dissolved in water are suppressed without using an oxidation inhibitor. be able to.

図1は、本発明に用いる窒素水の製造システムの構成例の機能を示すブロック図である。FIG. 1 is a block diagram showing functions of a configuration example of a nitrogen water production system used in the present invention.

以下、本発明の実施形態を説明する。なお、括弧内の数字は、後述する図面中の符号であり、参考のために付するものである   Embodiments of the present invention will be described below. The numbers in parentheses are the symbols in the drawings described later, and are attached for reference.

本発明による菓子の製造方法の対象となる菓子には、グミ、飴、チョコレート菓子、チューイングガム、羊羹、ケーキ類等の、材料に水を用いるものが含まれる。飴には、ハードキャンディ、ソフトキャンディ、水飴、キャラメル等が含まれるものとする。   The confectionery targeted by the method for producing a confectionery according to the present invention includes those using water as a material, such as gummi, candy, chocolate confectionery, chewing gum, sheep gourd, cakes and the like. The candy includes hard candy, soft candy, chickenpox, caramel and the like.

菓子の材料としては、主成分である甘味料と窒素水を含む。主成分以外に香料、着色料等の添加物や果汁、乳製品等を製造したい菓子の色、風味等に応じて適宜添加するものとする。菓子に含まれる甘味料は、甘味を有するものであればよい。例えば単糖類、二糖類、オリゴ糖の糖類や、人工甘味料のいずれでもよい。単糖類は例えばグルコース(ブドウ糖)、フルクトース(果糖)があり、二糖類は例えばスクロース(ショ糖、砂糖)、マルトース(麦芽糖)がある。人工甘味料は、例えばキシリトール、エリスリトール等がある。 As a confectionery material, the main ingredients are a sweetener and nitrogen water. In addition to the main components, additives such as fragrances and coloring agents, fruit juices, dairy products and the like should be added as appropriate according to the color, flavor, etc. of the confectionery to be manufactured. The sweetener contained in a confectionery should just have sweetness. For example, monosaccharides, disaccharides, oligosaccharide saccharides, and artificial sweeteners may be used. Examples of monosaccharides include glucose (glucose) and fructose (fructose), and examples of disaccharides include sucrose (sucrose and sugar) and maltose (maltose). Examples of the artificial sweetener include xylitol and erythritol.

窒素水を用いる菓子の基本的な製造方法では、当該菓子の通常の製造方法で用いる材料の水に替えて、窒素水を用いる。窒素水は、水に窒素ガスを溶解させて酸素溶存量を低下させたものである。酸素溶存量の少ない窒素水を用いているので、材料の混合及び加温の過程において材料中のいずれの成分も酸素と結びつくことはなく、材料の特性がそのまま維持されることになる。従って、通常の水を使用した場合に比べて、製造後の菓子の保存性が向上する上、風味なども良好となる。なお、窒素自体は、無味、無臭、無色、無害の不活性ガスであるので、水を窒素水としたことによって他の材料及び完成後の製品の味、香り、色、品質に悪影響を及ぼすことはない。   In the basic method for producing confectionery using nitrogen water, nitrogen water is used in place of the material water used in the usual method for producing the confectionery. Nitrogen water is obtained by dissolving nitrogen gas in water and reducing the amount of dissolved oxygen. Since nitrogen water with a small amount of dissolved oxygen is used, none of the components in the material is combined with oxygen in the process of mixing and heating the material, and the characteristics of the material are maintained as they are. Therefore, compared with the case where normal water is used, the preservability of the confectionery after manufacture is improved and the flavor and the like are also improved. Nitrogen itself is a tasteless, odorless, colorless, harmless inert gas, so the use of nitrogen as water will adversely affect the taste, aroma, color, and quality of other materials and finished products. There is no.

一例として、窒素水を用いる飴の製造方法は、以下の通りである。甘味料及び窒素水を含む全ての材料を混合し、加温して甘味料を煮溶かした後に冷やし固める。甘味料として糖類を使用する場合、好適には100重量部の糖類に対し、40〜90重量部の窒素水を使用する。 As an example, the manufacturing method of the soot using nitrogen water is as follows. All ingredients including sweetener and nitrogen water are mixed, heated to boil the sweetener and then cooled and hardened. When saccharides are used as a sweetener, 40 to 90 parts by weight of nitrogen water is preferably used for 100 parts by weight of saccharides.

図1は、本発明に用いる窒素水の製造システムの構成例の機能を示すブロック図である。
まず、貯水槽4内に原水を充填し、原水に窒素ガスを注入し酸素溶存量を減少させて窒素水とした後、窒素水を取り出して本発明に用いる。
FIG. 1 is a block diagram showing functions of a configuration example of a nitrogen water production system used in the present invention.
First, raw water is filled in the water storage tank 4, and nitrogen gas is injected into the raw water to reduce the amount of dissolved oxygen to form nitrogen water. Then, the nitrogen water is taken out and used in the present invention.

エアコンプレッサ1は、大気を圧縮して窒素ガス抽出機に送るエアコンプレッサ(例えば株式会社日立産機システム製のオイルフリーベビコン(登録商標))である。供給エア圧力が0.5MPa〜0.9MPaのものを用いる。   The air compressor 1 is an air compressor (for example, Oil-free Babycon (registered trademark) manufactured by Hitachi Industrial Equipment Systems Co., Ltd.) that compresses the atmosphere and sends it to a nitrogen gas extractor. A supply air pressure of 0.5 MPa to 0.9 MPa is used.

窒素ガス抽出器2は、ポリイミド中空糸膜からなる窒素分解膜を設けた圧力容器の一端に圧縮空気を取り込み、横の口から酸素Oをパージ(排出)し、圧力容器の多端から窒素ガスを送出する脱気装置である。気体の種類により膜の透過速度が異なることを利用したものである。この脱気装置は、窒素ガス抽出器2と窒素ガス注入器3とを一体的に構成した装置として提供されている(例えば株式会社片山化学工業研究所製の脱気装置「リプレル」(登録商標)) The nitrogen gas extractor 2 takes compressed air into one end of a pressure vessel provided with a nitrogen decomposition membrane made of a polyimide hollow fiber membrane, purges (discharges) oxygen O 2 from a side port, and nitrogen gas from multiple ends of the pressure vessel. It is a deaeration device which sends out. This utilizes the fact that the permeation rate of the membrane differs depending on the type of gas. This deaeration device is provided as a device in which a nitrogen gas extractor 2 and a nitrogen gas injector 3 are integrally formed (for example, a deaeration device “Riprel” (registered trademark) manufactured by Katayama Chemical Industry Laboratory Co., Ltd. ))

窒素ガス注入器3と貯水槽4の間でポンプP2により水を循環させる。窒素ガス注入器3は、例えば、1時間当たり2mの水を透過させ、1リットルあたり1.0mgの酸素溶存量まで酸素を追い出す能力を有する。 Water is circulated between the nitrogen gas injector 3 and the water tank 4 by the pump P2. The nitrogen gas injector 3 has a capability of permeating 2 m 3 of water per hour, for example, and driving out oxygen to a dissolved amount of 1.0 mg per liter.

さらに、図1の窒素水の製造システムにおいて、精製水の製造機構を組み込むことが好適である。例えば、窒素ガス注入器3と貯水槽4の間に不純物除去用の適宜のフィルターを挿入してもよい。これにより精製窒素水を1つのシステムで行うことができる。   Furthermore, it is preferable to incorporate a purified water production mechanism in the nitrogen water production system of FIG. For example, an appropriate filter for removing impurities may be inserted between the nitrogen gas injector 3 and the water tank 4. Thereby, purified nitrogen water can be performed in one system.

通常、水温と酸素溶存量との関係は、例えば次の通りである。
水温(℃) 酸素溶存量DO(mg/L)
0 14.6
10 10.9
20 8.8
Usually, the relationship between water temperature and dissolved oxygen amount is as follows, for example.
Water temperature (° C) Oxygen dissolved amount DO (mg / L)
0 14.6
10 10.9
20 8.8

図1に示したシステムを用いて窒素水の生成試験を行った。
<試験方法>
貯水槽に300リットルの原水(試験のため、水道水で行った)を充填し、エアコンプレッサの供給圧力0.2MPaで3時間半、窒素ガスを注入した。
Using the system shown in FIG. 1, a nitrogen water generation test was conducted.
<Test method>
A water tank was filled with 300 liters of raw water (performed with tap water for the test), and nitrogen gas was injected for 3 and a half hours at an air compressor supply pressure of 0.2 MPa.

<試験結果>
時間 水温(℃) 酸素溶存量DO(mg/L)
開始時 : 8.4 4.99
1時間後 : 9.1 3.13
2時間後 : 9.6 3.02
3時間半後: 9.2 1.36
試験結果が示すように、窒素ガスを水中に注入することにより、水中の酸素溶存量は大きく減少する。
<Test results>
Time Water temperature (° C) Oxygen dissolved amount DO (mg / L)
Starting time: 8.4 4.99
1 hour later: 9.1 3.13
2 hours later: 9.6 3.02
Three and a half hours: 9.2 1.36
As the test results indicate, the amount of dissolved oxygen in water is greatly reduced by injecting nitrogen gas into water.

上記のような窒素水の製造システムを、菓子の製造システムの一部に組み込むことが好適である。それにより、窒素水を製造後、直ちに菓子の他の材料と混合することができ、窒素水中に酸素が再び溶存することが避けられる。別の例として、製造した窒素水を、一旦、密封容器に充填してもよい。その場合、菓子を製造する際には、密封容器を開封後直ちに窒素水を菓子の他の材料と混合し、加温することが好ましい。
以下に、実施例を示す。
It is preferable to incorporate the nitrogen water production system as described above into a part of the confectionery production system. Thereby, after manufacturing the nitrogen water, it can be immediately mixed with other ingredients of the confectionery, and it is avoided that oxygen is dissolved again in the nitrogen water. As another example, the sealed nitrogen container may be once filled with the produced nitrogen water. In that case, when manufacturing a confectionery, it is preferable to mix and heat nitrogen water with other ingredients of a confectionery immediately after opening a sealed container.
Examples are shown below.

<ハードキャンディ>
砂糖100g、塩2.5g、窒素水60gをひとつの鍋に入れ、火にかけて溶かす。120℃になったらカクテル用のブルーキュラソー又はブルーハワイ少々及び、食青少々を加えて混ぜる。165℃になったら濡れ布巾の上に置き、1〜2秒冷ます。その後、型に流し入れて常温で5分置く。その後、冷蔵庫に入れて冷やし固める。
<Hard candy>
Put 100g of sugar, 2.5g of salt, and 60g of nitrogen water in one pan and melt over heat. When the temperature reaches 120 ° C, add a little blue curacao or blue hawaii for cocktail and a little food blue. When it reaches 165 ° C, place it on a wet cloth and let it cool for 1-2 seconds. Then pour into a mold and leave at room temperature for 5 minutes. Then put it in the refrigerator to cool and harden.

本実施例の製造方法によれば、使用する水に溶け込んだ酸素によって酸化したり、微生物が繁殖したりするおそれが低減される。また、この製造方法によって製造した飴は、べたつきや軟化等の経時的な劣化が少なかった。さらに、溶存酸素量との関係は不明であるが、着色料による色の発色がよく、まろやかな風味であった。   According to the manufacturing method of the present embodiment, the risk of oxidation by oxygen dissolved in the water used and the proliferation of microorganisms are reduced. In addition, the soot produced by this production method had little deterioration over time such as stickiness and softening. Furthermore, although the relationship with the amount of dissolved oxygen is unclear, the coloration by the colorant is good and the flavor is mellow.

<生キャラメル>
砂糖150g、全粉乳15g、窒素水135g、バター60gを火にかけ、煮溶かす。沸騰後は弱火にし、焦げないように混ぜながら煮詰める。水分が減り、適度な固さになったら長方形状の型に流し入れ、冷やし固める。固まった後、適当な大きさに切り分ける。
<Raw caramel>
150g of sugar, 15g of whole milk powder, 135g of nitrogen water and 60g of butter are put on fire and melted. After boiling, reduce the heat to a low heat and simmer while mixing so as not to burn. When the water content is reduced to a suitable level, pour into a rectangular mold and cool and harden. After solidifying, cut into appropriate sizes.

バターや全粉乳中の乳脂肪分は酸素に触れることで酸化しやすいが、本実施例の製造方法では、溶存酸素量を低下させた窒素水が使用されるため、材料の酸化が起こり難い。   Milk fat content in butter and whole milk powder is easily oxidized by contact with oxygen, but in the production method of this example, nitrogen water with a reduced amount of dissolved oxygen is used, so that the material is hardly oxidized.

<羊羹>
寒天3gをあらかじめ窒素水に浸して戻しておく。鍋に窒素水100ccを入れ、絞った寒天を煮溶かす。寒天が完全に溶けたら、砂糖100gを加えて溶かす。その後、粒あん300gを少しずつ溶かし、よく混ぜて練り上げる。水分が減り、適度な固さに練り上がったら、長方形状の型に流し入れ、冷やし固める。固まった後、適当な大きさに切り分ける。
<Yotei>
3 g of agar is dipped in nitrogen water in advance. Add 100cc of nitrogen water to the pan and boil the squeezed agar. When the agar is completely dissolved, add 100g of sugar and dissolve. Then, dissolve 300g of bean paste little by little, mix well and knead. When the water is reduced and kneaded to an appropriate hardness, pour into a rectangular mold and cool and harden. After solidifying, cut into appropriate sizes.

<コーヒーゼリー>
インスタントコーヒー大さじ3に窒素水を加熱した熱湯100ccを加え、コーヒー液を作る。鍋に窒素水200ccと砂糖大さじ3を入れて加熱する。砂糖が溶けたらコーヒー液を加え、火から下ろす。粉ゼラチン5gを振り入れて溶かし、適当な型に流し入れ、冷やし固める。
<Coffee jelly>
Add 100 cc of hot water heated with nitrogen water to 3 tablespoons of instant coffee to make coffee. Put 200cc of nitrogen water and 3 tablespoons of sugar in a pan and heat. When the sugar has melted, add coffee and remove from the fire. Sprinkle 5 g of powdered gelatin to melt, pour into a suitable mold, cool and harden.

以上に述べた本発明の実施形態は一例を示したものであり、これら以外にも種々の公知技術を適用した多様な変形形態が可能であり、それらについても本発明に含まれるものとする。   The embodiment of the present invention described above is merely an example, and various modifications other than those described above to which various known techniques are applied are also included in the present invention.

1:エアコンプレッサ
2:窒素ガス抽出機
3:窒素ガス注入器
4:貯水槽
1: Air compressor 2: Nitrogen gas extractor 3: Nitrogen gas injector 4: Water storage tank

Claims (3)

酸化及び微生物繁殖による劣化のリスクを低減させた菓子の製造方法であって、
材料中の水は、水に窒素ガスを溶解させて酸素溶存量を低下させた窒素水を使用することを特徴とする、菓子の製造方法。
A method for producing confectionery that reduces the risk of deterioration due to oxidation and microbial propagation,
A method for producing a confectionery, characterized in that the water in the material is nitrogen water in which nitrogen gas is dissolved in water to reduce the amount of dissolved oxygen.
前記菓子が飴である場合、甘味料及び窒素水を含む全ての材料を混合し、加温して甘味料を煮溶かした後に冷やし固めることを特徴とする、
請求項1に記載の菓子の製造方法。
When the confectionery is a candy, all ingredients including a sweetener and nitrogen water are mixed, heated to boil the sweetener, and then cooled and hardened.
The manufacturing method of the confectionery of Claim 1.
前記甘味料が糖類である場合、100重量部の糖類に対し、40〜90重量部の前記窒素水を使用し、材料を加温して前記糖類を煮溶かした後に冷やし固めることを特徴とする、
請求項2に記載の菓子の製造方法。


When the sweetener is a saccharide, 40 to 90 parts by weight of the nitrogen water is used with respect to 100 parts by weight of the saccharide. ,
The manufacturing method of the confectionery of Claim 2.


JP2016119903A 2016-06-16 2016-06-16 Manufacturing method of confectionery using nitrogen water Pending JP2017221152A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0938660A (en) * 1995-08-01 1997-02-10 Kankyo Kagaku Kogyo Kk Method for removing dissolved oxygen in water and device for removing the same
JP2001131168A (en) * 1999-11-05 2001-05-15 Suntory Ltd Antioxidant and method for producing the same
JP2007135546A (en) * 2005-11-22 2007-06-07 Riken Vitamin Co Ltd Soft candy

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0938660A (en) * 1995-08-01 1997-02-10 Kankyo Kagaku Kogyo Kk Method for removing dissolved oxygen in water and device for removing the same
JP2001131168A (en) * 1999-11-05 2001-05-15 Suntory Ltd Antioxidant and method for producing the same
JP2007135546A (en) * 2005-11-22 2007-06-07 Riken Vitamin Co Ltd Soft candy

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
FOOMA JAPAN 2016国際食品工業展に行ってきました!!- スタッフブログ|三菱重工冷熱[ONLINE], JPN6019000446, 16 June 2016 (2016-06-16), ISSN: 0004070463 *

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