JP2017179318A5 - - Google Patents
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- JP2017179318A5 JP2017179318A5 JP2016082454A JP2016082454A JP2017179318A5 JP 2017179318 A5 JP2017179318 A5 JP 2017179318A5 JP 2016082454 A JP2016082454 A JP 2016082454A JP 2016082454 A JP2016082454 A JP 2016082454A JP 2017179318 A5 JP2017179318 A5 JP 2017179318A5
- Authority
- JP
- Japan
- Prior art keywords
- metal
- suspension
- molding material
- bonded
- collection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012778 molding material Substances 0.000 claims description 439
- 239000002082 metal nanoparticle Substances 0.000 claims description 352
- 239000000725 suspension Substances 0.000 claims description 346
- 150000002894 organic compounds Chemical class 0.000 claims description 224
- 229910052751 metal Inorganic materials 0.000 claims description 215
- 239000002184 metal Substances 0.000 claims description 215
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 162
- -1 metal complex ion Chemical class 0.000 claims description 147
- 238000004519 manufacturing process Methods 0.000 claims description 136
- 239000002105 nanoparticle Substances 0.000 claims description 131
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 124
- 150000002736 metal compounds Chemical class 0.000 claims description 97
- 229920003002 synthetic resin Polymers 0.000 claims description 90
- 239000000057 synthetic resin Substances 0.000 claims description 90
- 238000002844 melting Methods 0.000 claims description 87
- 230000008018 melting Effects 0.000 claims description 87
- 238000009835 boiling Methods 0.000 claims description 79
- 238000000465 moulding Methods 0.000 claims description 76
- 238000000034 method Methods 0.000 claims description 71
- 239000007789 gas Substances 0.000 claims description 66
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 54
- 239000000126 substance Substances 0.000 claims description 41
- 239000000203 mixture Substances 0.000 claims description 39
- 239000007788 liquid Substances 0.000 claims description 38
- 238000010438 heat treatment Methods 0.000 claims description 34
- 230000008016 vaporization Effects 0.000 claims description 28
- 238000011049 filling Methods 0.000 claims description 24
- 150000002500 ions Chemical class 0.000 claims description 22
- 239000013078 crystal Substances 0.000 claims description 21
- 239000006185 dispersion Substances 0.000 claims description 21
- 239000003446 ligand Substances 0.000 claims description 20
- 239000001301 oxygen Substances 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 19
- 229910021645 metal ion Inorganic materials 0.000 claims description 18
- 150000002739 metals Chemical class 0.000 claims description 17
- 238000000197 pyrolysis Methods 0.000 claims description 15
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 14
- 238000001125 extrusion Methods 0.000 claims description 14
- 238000003825 pressing Methods 0.000 claims description 13
- 238000000748 compression moulding Methods 0.000 claims description 12
- 238000001746 injection moulding Methods 0.000 claims description 12
- 238000001721 transfer moulding Methods 0.000 claims description 11
- 238000000071 blow moulding Methods 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 9
- 150000002334 glycols Chemical class 0.000 claims description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 238000003856 thermoforming Methods 0.000 claims description 9
- 230000006835 compression Effects 0.000 claims description 7
- 238000007906 compression Methods 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 230000008878 coupling Effects 0.000 claims description 2
- 238000010168 coupling process Methods 0.000 claims description 2
- 238000005859 coupling reaction Methods 0.000 claims description 2
- 150000001735 carboxylic acids Chemical group 0.000 claims 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 239000008188 pellet Substances 0.000 description 271
- 239000011651 chromium Substances 0.000 description 109
- 229910052804 chromium Inorganic materials 0.000 description 95
- 229920005989 resin Polymers 0.000 description 86
- 239000011347 resin Substances 0.000 description 86
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 85
- 239000010949 copper Substances 0.000 description 75
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 69
- 229910052802 copper Inorganic materials 0.000 description 68
- 239000012298 atmosphere Substances 0.000 description 67
- 229920005992 thermoplastic resin Polymers 0.000 description 65
- 230000009477 glass transition Effects 0.000 description 50
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 45
- 239000002994 raw material Substances 0.000 description 44
- 229920001187 thermosetting polymer Polymers 0.000 description 42
- 239000011248 coating agent Substances 0.000 description 41
- 238000000576 coating method Methods 0.000 description 41
- 239000000463 material Substances 0.000 description 35
- 210000003934 vacuole Anatomy 0.000 description 34
- 239000010410 layer Substances 0.000 description 31
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 26
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 23
- 239000010419 fine particle Substances 0.000 description 22
- 238000012856 packing Methods 0.000 description 22
- 229920000642 polymer Polymers 0.000 description 21
- 239000000047 product Substances 0.000 description 19
- 239000007787 solid Substances 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 18
- 150000001845 chromium compounds Chemical class 0.000 description 18
- 239000011259 mixed solution Substances 0.000 description 17
- 238000006116 polymerization reaction Methods 0.000 description 17
- 229920006127 amorphous resin Polymers 0.000 description 15
- 229910001430 chromium ion Inorganic materials 0.000 description 15
- 239000002245 particle Substances 0.000 description 15
- 239000005749 Copper compound Substances 0.000 description 14
- 150000004671 saturated fatty acids Chemical class 0.000 description 14
- 238000009834 vaporization Methods 0.000 description 14
- 239000002585 base Substances 0.000 description 13
- 150000001880 copper compounds Chemical class 0.000 description 13
- 239000008187 granular material Substances 0.000 description 13
- 239000012299 nitrogen atmosphere Substances 0.000 description 13
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 13
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 238000013459 approach Methods 0.000 description 12
- 150000004699 copper complex Chemical class 0.000 description 12
- 229920006038 crystalline resin Polymers 0.000 description 12
- 239000003317 industrial substance Substances 0.000 description 12
- 230000008569 process Effects 0.000 description 12
- 239000004695 Polyether sulfone Substances 0.000 description 11
- 239000005011 phenolic resin Substances 0.000 description 11
- 229920006393 polyether sulfone Polymers 0.000 description 11
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 10
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 10
- VPONMBLTGNYMND-UHFFFAOYSA-N azane copper(1+) Chemical compound N.N.N.N.[Cu+] VPONMBLTGNYMND-UHFFFAOYSA-N 0.000 description 10
- 239000000460 chlorine Substances 0.000 description 10
- 229910000423 chromium oxide Inorganic materials 0.000 description 10
- 229910001882 dioxygen Inorganic materials 0.000 description 10
- 238000010894 electron beam technology Methods 0.000 description 10
- 239000004800 polyvinyl chloride Substances 0.000 description 10
- 229920000915 polyvinyl chloride Polymers 0.000 description 10
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 9
- 229910002651 NO3 Inorganic materials 0.000 description 9
- 239000003063 flame retardant Substances 0.000 description 9
- POULHZVOKOAJMA-UHFFFAOYSA-N methyl undecanoic acid Natural products CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 9
- 229920000139 polyethylene terephthalate Polymers 0.000 description 9
- 239000005020 polyethylene terephthalate Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 8
- 238000002485 combustion reaction Methods 0.000 description 8
- 229910001431 copper ion Inorganic materials 0.000 description 8
- 229960004643 cupric oxide Drugs 0.000 description 8
- 238000011084 recovery Methods 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 229920000106 Liquid crystal polymer Polymers 0.000 description 7
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- MZQZXSHFWDHNOW-UHFFFAOYSA-N 1-phenylpropane-1,2-diol Chemical compound CC(O)C(O)C1=CC=CC=C1 MZQZXSHFWDHNOW-UHFFFAOYSA-N 0.000 description 6
- 239000005639 Lauric acid Substances 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 230000005484 gravity Effects 0.000 description 6
- 229920001903 high density polyethylene Polymers 0.000 description 6
- 239000004700 high-density polyethylene Substances 0.000 description 6
- 229940070765 laurate Drugs 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 238000004064 recycling Methods 0.000 description 6
- 239000002344 surface layer Substances 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 239000004743 Polypropylene Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 description 5
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 230000036961 partial effect Effects 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 229920006324 polyoxymethylene Polymers 0.000 description 4
- 230000000717 retained effect Effects 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 229920001774 Perfluoroether Polymers 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 229930003836 cresol Natural products 0.000 description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 3
- 150000002484 inorganic compounds Chemical class 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 229920002312 polyamide-imide Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 239000002341 toxic gas Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- 229930182556 Polyacetal Natural products 0.000 description 2
- 239000004962 Polyamide-imide Substances 0.000 description 2
- 239000004697 Polyetherimide Substances 0.000 description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 description 2
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- 230000001133 acceleration Effects 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
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- 239000003513 alkali Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 2
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 2
- 150000004696 coordination complex Chemical group 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002366 halogen compounds Chemical class 0.000 description 2
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- 239000000976 ink Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
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- 125000004430 oxygen atom Chemical group O* 0.000 description 2
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- ZUAURMBNZUCEAF-UHFFFAOYSA-N 2-(2-phenoxyethoxy)ethanol Chemical compound OCCOCCOC1=CC=CC=C1 ZUAURMBNZUCEAF-UHFFFAOYSA-N 0.000 description 1
- MTJGVAJYTOXFJH-UHFFFAOYSA-N 3-aminonaphthalene-1,5-disulfonic acid Chemical compound C1=CC=C(S(O)(=O)=O)C2=CC(N)=CC(S(O)(=O)=O)=C21 MTJGVAJYTOXFJH-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
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- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- FEOSYYULJGIEAC-UHFFFAOYSA-N C(CCCCCCC)[Cu] Chemical compound C(CCCCCCC)[Cu] FEOSYYULJGIEAC-UHFFFAOYSA-N 0.000 description 1
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 1
- 229940126062 Compound A Drugs 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
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| JP6748392B2 (ja) * | 2016-05-18 | 2020-09-02 | 小林 博 | 自己発火せず着火しない性質を持つ透明不燃性シートの製造方法 |
| JP7464952B2 (ja) * | 2018-04-16 | 2024-04-10 | 三菱ケミカル株式会社 | ポリマーｐｔｃ組成物、層状ポリマーｐｔｃ要素、ポリマーｐｔｃ素子、ｐｔｃデバイス、電気装置及び２次電池セル |
| JP7095941B2 (ja) * | 2018-09-17 | 2022-07-05 | 博 小林 | 金属ないしは合金の性質と自己発火せず着火しない不燃性を兼備する熱可塑性エラストマーからなる成形体の成形方法 |
| JP7827436B2 (ja) * | 2021-11-04 | 2026-03-10 | 博 小林 | 可燃性または難燃性の基材または部品を、８４０℃に耐えられる耐熱性と、８４０℃の温度に耐えられる耐火性とを兼備する基材または部品に変える方法 |
| CN118596475B (zh) * | 2024-08-06 | 2024-12-06 | 温州荣力鞋业有限公司 | 一种防粘的胶鞋生产用注塑设备及其使用方法 |
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| JP5142002B2 (ja) * | 2004-05-11 | 2013-02-13 | 日東紡績株式会社 | 透明不燃性シート及びその製造方法 |
| CN103022190A (zh) * | 2011-09-21 | 2013-04-03 | 杜邦公司 | 用于太阳能电池模块的阻燃背板 |
| JP2014201831A (ja) * | 2013-04-08 | 2014-10-27 | 小林 博 | 部品ないしは基材ないしは素材の性質の改質 |
| JP6332942B2 (ja) * | 2013-10-18 | 2018-05-30 | 小林 博 | 部品同士ないしは基材同士からなる被接合体の接合方法 |
| JP6232628B2 (ja) * | 2014-01-06 | 2017-11-22 | 平岡織染株式会社 | 不燃性膜材 |
| JP6618142B2 (ja) * | 2015-10-14 | 2019-12-11 | 小林 博 | 金属ないしは合金の微粒子の集まりで覆われた合成樹脂のペレットの集まりの製造方法と、金属ないしは合金の性質を持つ合成樹脂の成形体の成形方法 |
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