JP2017007872A - 合成ガスの製造方法および装置 - Google Patents
合成ガスの製造方法および装置 Download PDFInfo
- Publication number
- JP2017007872A JP2017007872A JP2015121594A JP2015121594A JP2017007872A JP 2017007872 A JP2017007872 A JP 2017007872A JP 2015121594 A JP2015121594 A JP 2015121594A JP 2015121594 A JP2015121594 A JP 2015121594A JP 2017007872 A JP2017007872 A JP 2017007872A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- biogas
- synthesis gas
- reaction
- reforming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 99
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 97
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 34
- 239000007789 gas Substances 0.000 claims abstract description 173
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 73
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 37
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 36
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 36
- 239000001257 hydrogen Substances 0.000 claims abstract description 36
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 238000006243 chemical reaction Methods 0.000 claims abstract description 33
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 28
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 28
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 28
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 26
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000001301 oxygen Substances 0.000 claims abstract description 17
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 54
- 238000006057 reforming reaction Methods 0.000 claims description 37
- 239000003054 catalyst Substances 0.000 claims description 31
- 238000002407 reforming Methods 0.000 claims description 28
- 238000002485 combustion reaction Methods 0.000 claims description 13
- 239000012535 impurity Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 239000002994 raw material Substances 0.000 abstract description 39
- 238000002203 pretreatment Methods 0.000 abstract 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 57
- 238000000034 method Methods 0.000 description 40
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 30
- 229910052799 carbon Inorganic materials 0.000 description 29
- 239000000203 mixture Substances 0.000 description 17
- 230000000694 effects Effects 0.000 description 14
- 238000000629 steam reforming Methods 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 229910052717 sulfur Inorganic materials 0.000 description 9
- 239000011593 sulfur Substances 0.000 description 9
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 238000006477 desulfuration reaction Methods 0.000 description 7
- 230000023556 desulfurization Effects 0.000 description 7
- 229910001882 dioxygen Inorganic materials 0.000 description 7
- 238000005038 synthesis gas manufacturing Methods 0.000 description 7
- 239000003463 adsorbent Substances 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 239000002028 Biomass Substances 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 5
- 235000019482 Palm oil Nutrition 0.000 description 5
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 5
- 239000002540 palm oil Substances 0.000 description 5
- 239000000446 fuel Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003345 natural gas Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000002551 biofuel Substances 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- -1 shortening Substances 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 239000010796 biological waste Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 235000013310 margarine Nutrition 0.000 description 1
- 239000003264 margarine Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002463 transducing effect Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015121594A JP2017007872A (ja) | 2015-06-17 | 2015-06-17 | 合成ガスの製造方法および装置 |
PCT/JP2016/066110 WO2016203944A1 (ja) | 2015-06-17 | 2016-06-01 | 合成ガスの製造方法および装置 |
PH12017550143A PH12017550143A1 (en) | 2015-06-17 | 2017-12-15 | Synthesis gas production method and apparatus |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015121594A JP2017007872A (ja) | 2015-06-17 | 2015-06-17 | 合成ガスの製造方法および装置 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2017007872A true JP2017007872A (ja) | 2017-01-12 |
JP2017007872A5 JP2017007872A5 (enrdf_load_stackoverflow) | 2017-12-07 |
Family
ID=57545673
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015121594A Pending JP2017007872A (ja) | 2015-06-17 | 2015-06-17 | 合成ガスの製造方法および装置 |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP2017007872A (enrdf_load_stackoverflow) |
PH (1) | PH12017550143A1 (enrdf_load_stackoverflow) |
WO (1) | WO2016203944A1 (enrdf_load_stackoverflow) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180105823A (ko) * | 2017-03-16 | 2018-10-01 | 한국과학기술연구원 | 발열량이 증가된 합성천연가스의 제조방법 및 제조장치 |
JP2021512035A (ja) * | 2017-11-15 | 2021-05-13 | ガス、テクノロジー、インスティチュートGas Technology Institute | メタンおよび他の炭化水素を改質するための貴金属触媒およびプロセス |
JP2022174629A (ja) * | 2021-05-11 | 2022-11-24 | 国立研究開発法人物質・材料研究機構 | バイオガスの二酸化炭素改質触媒、その製造方法、および、それを用いた水素製造装置 |
US11667853B2 (en) | 2017-11-15 | 2023-06-06 | Gti Energy | Processes and systems for reforming of methane and light hydrocarbons to liquid hydrocarbon fuels |
JP2023532938A (ja) * | 2020-07-07 | 2023-08-01 | プロテウム エナジー,エルエルシー | 非メタン炭化水素を変換して、そこから水素ガス及び/又はメタンガスを回収するための方法及びシステム |
US12122962B2 (en) | 2018-09-18 | 2024-10-22 | Gti Energy | Processes and catalysts for reforming of impure methane-containing feeds |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020054063A1 (ja) * | 2018-09-14 | 2020-03-19 | 株式会社 ユーリカ エンジニアリング | 低炭素ft合成油製造用合成ガス製造システム |
CN111547678B (zh) * | 2020-04-08 | 2022-03-25 | 华南农业大学 | 沼气全组分热催化制备甲醇的方法及系统 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002173304A (ja) * | 2000-12-06 | 2002-06-21 | Japan Petroleum Exploration Co Ltd | オートサーマルリホーミングによる合成ガスの製法 |
JP2006096590A (ja) * | 2004-09-28 | 2006-04-13 | Asao Tada | 低級炭化水素の直接分解装置 |
JP2010530878A (ja) * | 2007-06-21 | 2010-09-16 | ユニバーシティ オブ サザン カリフォルニア | メタン又は天然ガスの再改質を用いた二酸化炭素のメタノールへの変換 |
JP2011207740A (ja) * | 2010-03-08 | 2011-10-20 | Air Water Inc | 合成ガス製造方法 |
JP2013533245A (ja) * | 2010-07-09 | 2013-08-22 | ハルドール・トプサー・アクチエゼルスカベット | バイオガスをメタンリッチのガスに転化する方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2875888A1 (en) * | 2011-06-08 | 2012-12-13 | University Of Regina | Sulfur tolerant catalysts for hydrogen production by carbon dioxide reforming of methane-rich gas |
JP6041162B2 (ja) * | 2012-08-01 | 2016-12-07 | 国立大学法人九州大学 | 炭化水素の改質用のペーパー状触媒及びペーパー状触媒配列体並びにペーパー状触媒又はペーパー状触媒配列体を備えた固体酸化物形燃料電池 |
-
2015
- 2015-06-17 JP JP2015121594A patent/JP2017007872A/ja active Pending
-
2016
- 2016-06-01 WO PCT/JP2016/066110 patent/WO2016203944A1/ja active Application Filing
-
2017
- 2017-12-15 PH PH12017550143A patent/PH12017550143A1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002173304A (ja) * | 2000-12-06 | 2002-06-21 | Japan Petroleum Exploration Co Ltd | オートサーマルリホーミングによる合成ガスの製法 |
JP2006096590A (ja) * | 2004-09-28 | 2006-04-13 | Asao Tada | 低級炭化水素の直接分解装置 |
JP2010530878A (ja) * | 2007-06-21 | 2010-09-16 | ユニバーシティ オブ サザン カリフォルニア | メタン又は天然ガスの再改質を用いた二酸化炭素のメタノールへの変換 |
JP2011207740A (ja) * | 2010-03-08 | 2011-10-20 | Air Water Inc | 合成ガス製造方法 |
JP2013533245A (ja) * | 2010-07-09 | 2013-08-22 | ハルドール・トプサー・アクチエゼルスカベット | バイオガスをメタンリッチのガスに転化する方法 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180105823A (ko) * | 2017-03-16 | 2018-10-01 | 한국과학기술연구원 | 발열량이 증가된 합성천연가스의 제조방법 및 제조장치 |
KR102097283B1 (ko) * | 2017-03-16 | 2020-04-06 | 한국과학기술연구원 | 발열량이 증가된 합성천연가스의 제조방법 및 제조장치 |
JP2021512035A (ja) * | 2017-11-15 | 2021-05-13 | ガス、テクノロジー、インスティチュートGas Technology Institute | メタンおよび他の炭化水素を改質するための貴金属触媒およびプロセス |
JP7096887B2 (ja) | 2017-11-15 | 2022-07-06 | ガス、テクノロジー、インスティチュート | メタンおよび他の炭化水素を改質するための貴金属触媒およびプロセス |
JP2022130544A (ja) * | 2017-11-15 | 2022-09-06 | ガス、テクノロジー、インスティチュート | メタンおよび他の炭化水素を改質するための貴金属触媒およびプロセス |
US11667853B2 (en) | 2017-11-15 | 2023-06-06 | Gti Energy | Processes and systems for reforming of methane and light hydrocarbons to liquid hydrocarbon fuels |
JP7629424B2 (ja) | 2017-11-15 | 2025-02-13 | ジーティーアイ エナジー | メタンおよび他の炭化水素を改質するための貴金属触媒およびプロセス |
US12122962B2 (en) | 2018-09-18 | 2024-10-22 | Gti Energy | Processes and catalysts for reforming of impure methane-containing feeds |
JP2023532938A (ja) * | 2020-07-07 | 2023-08-01 | プロテウム エナジー,エルエルシー | 非メタン炭化水素を変換して、そこから水素ガス及び/又はメタンガスを回収するための方法及びシステム |
JP2022174629A (ja) * | 2021-05-11 | 2022-11-24 | 国立研究開発法人物質・材料研究機構 | バイオガスの二酸化炭素改質触媒、その製造方法、および、それを用いた水素製造装置 |
JP7669031B2 (ja) | 2021-05-11 | 2025-04-28 | 国立研究開発法人物質・材料研究機構 | バイオガスの二酸化炭素改質触媒、その製造方法、および、それを用いた水素製造装置 |
Also Published As
Publication number | Publication date |
---|---|
WO2016203944A1 (ja) | 2016-12-22 |
PH12017550143A1 (en) | 2018-06-11 |
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