JP2016506393A5 - - Google Patents
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- Publication number
- JP2016506393A5 JP2016506393A5 JP2015547085A JP2015547085A JP2016506393A5 JP 2016506393 A5 JP2016506393 A5 JP 2016506393A5 JP 2015547085 A JP2015547085 A JP 2015547085A JP 2015547085 A JP2015547085 A JP 2015547085A JP 2016506393 A5 JP2016506393 A5 JP 2016506393A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- alkyl group
- alkyl
- formula
- complex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 11
- 125000003118 aryl group Chemical group 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 229910052741 iridium Inorganic materials 0.000 description 4
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910020366 ClO 4 Inorganic materials 0.000 description 2
- 229910018286 SbF 6 Inorganic materials 0.000 description 2
- HFKJQIJFRMRSKM-UHFFFAOYSA-N [3,5-bis(trifluoromethyl)phenoxy]boronic acid Chemical compound OB(O)OC1=CC(C(F)(F)F)=CC(C(F)(F)F)=C1 HFKJQIJFRMRSKM-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 229940063013 borate ion Drugs 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000013110 organic ligand Substances 0.000 description 2
- -1 perfluorinated sulfonic acid Ions Chemical class 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 125000006713 (C5-C10) cycloalkyl group Chemical group 0.000 description 1
- 125000006705 (C5-C7) cycloalkyl group Chemical group 0.000 description 1
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
- 125000002941 2-furyl group Chemical group O1C([*])=C([H])C([H])=C1[H] 0.000 description 1
- 125000001622 2-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C(*)C([H])=C([H])C2=C1[H] 0.000 description 1
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 150000002503 iridium Chemical class 0.000 description 1
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 1
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12197812.6 | 2012-12-18 | ||
| EP12197812 | 2012-12-18 | ||
| PCT/EP2013/077233 WO2014096098A1 (en) | 2012-12-18 | 2013-12-18 | (6r,10r)-6,10,14-trimetylpentadecan-2-one prepared from 6,10,14-trimetylpentadeca-5,9,13-trien-2-one or 6,10,14-trimetylpentadeca-5,9-dien-2-one |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2016506393A JP2016506393A (ja) | 2016-03-03 |
| JP2016506393A5 true JP2016506393A5 (enExample) | 2019-02-28 |
| JP6582324B2 JP6582324B2 (ja) | 2019-10-02 |
Family
ID=47458691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015547085A Active JP6582324B2 (ja) | 2012-12-18 | 2013-12-18 | ６，１０，１４−トリメチルペンタデカ−５，９，１３−トリエン−２−オンまたは６，１０，１４−トリメチルペンタデカ−５，９−ジエン−２−オンから調製した（６ｒ，１０ｒ）−６，１０，１４−トリメチルペンタデカン−２−オン |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9611200B2 (enExample) |
| EP (1) | EP2935185B1 (enExample) |
| JP (1) | JP6582324B2 (enExample) |
| CN (1) | CN104854071B (enExample) |
| BR (1) | BR112015014423B1 (enExample) |
| EA (1) | EA033302B9 (enExample) |
| MY (1) | MY173272A (enExample) |
| WO (1) | WO2014096098A1 (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014096106A1 (en) * | 2012-12-18 | 2014-06-26 | Dsm Ip Assets B.V. | Using mixtures of e/z isomers to obtain quantitatively specific products by combined asymmetric hydrogenations |
| US9452961B2 (en) * | 2012-12-18 | 2016-09-27 | Dsm Ip Assets B.V. | (6R,10R)-6,10,14-trimetylpentadecan-2-one prepared from 6,10-dimetylundec-5-en-2-one or 6,10-dimetylundeca-5,9-dien-2-one |
| ES2739229T3 (es) * | 2012-12-18 | 2020-01-29 | Dsm Ip Assets Bv | Uso de mezclas de isómeros E/Z para obtener productos cuantitativamente específicos combinando hidrogenación asimétrica e isomerización |
| WO2017098050A1 (en) * | 2015-12-11 | 2017-06-15 | Dsm Ip Assets B.V. | Process for the manufacture of 6,10,14-trimethylpentadecan-2-one, isophytol and alpha-tocopherol |
| BR112022005528A2 (pt) | 2019-09-25 | 2022-06-21 | Bayer Ag | Novos catalisadores de irídio para hidrogenação enantiosseletiva de 1,2-di-hidroquinolinas 4-substituídas |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4028385A (en) | 1974-09-02 | 1977-06-07 | Kuraray Co., Ltd. | Process for preparing stereospecific farnesylacetic acid and ester thereof |
| JPS5132511A (en) * | 1974-09-10 | 1976-03-19 | Kuraray Co | Ritsutaikiseisareta geraniruaseton no seizohoho |
| JPS6036479A (ja) * | 1983-08-08 | 1985-02-25 | Kotobuki Seiyaku Kk | １，３−ジオキサン誘導体、本化合物を有効成分とする抗潰瘍剤及びその製造方法 |
| US5028385A (en) | 1989-04-10 | 1991-07-02 | Baldi Alfonso L | Treatment of metals for coating or activation |
| US5073659A (en) * | 1989-08-22 | 1991-12-17 | Eisai Co., Ltd. | Process for the preparation of terpenes |
| DE59303616D1 (de) * | 1992-04-16 | 1996-10-10 | Hoffmann La Roche | Verfahren zur Herstellung von Isoprenderivaten |
| US5349071A (en) | 1992-11-25 | 1994-09-20 | Loyola University Of Chicago | Process for preparing tertiary alkynols |
| US5955636A (en) | 1996-07-05 | 1999-09-21 | Kuraray Co., Ltd. | Process for producing 6-methyl-3-hepten-2-one and 6-methyl-2-heptanone analogues, and process for producing phyton or isophytol |
| EP0970953B1 (en) | 1998-07-10 | 2004-09-29 | DSM IP Assets B.V. | Manufacture of d,1-alpha-tocopherol |
| DE19840747A1 (de) | 1998-09-07 | 2000-03-09 | Basf Ag | Kontinuierliches Verfahren zur Herstellung von ungesättigten Ketonen |
| KR100880081B1 (ko) | 2001-09-28 | 2009-01-23 | 디에스엠 아이피 어셋츠 비.브이. | 에티닐화 방법 |
| WO2004018400A1 (en) | 2002-08-16 | 2004-03-04 | Dsm Ip Assets B.V. | Ethynylation process |
| CN1968943B (zh) | 2004-06-11 | 2011-08-10 | 帝斯曼知识产权资产管理有限公司 | 生产色满衍生物尤其是α-生育酚及其链烷酸酯的方法 |
| WO2006066863A1 (en) * | 2004-12-22 | 2006-06-29 | Dsm Ip Assets B.V. | Asymmetric hydrogenation of alkennes using chiral iridium complexes |
| EP2522647B1 (en) | 2011-05-10 | 2014-04-30 | DSM IP Assets B.V. | Process of separating chiral isomers of chroman compounds and their derivatives and precursors |
| EP2535323A1 (en) * | 2011-06-14 | 2012-12-19 | DSM IP Assets B.V. | Hydrogenation of ketones having at least a carbon-carbon double bond in the gamma-,delta-position |
| EA028168B1 (ru) * | 2012-12-18 | 2017-10-31 | ДСМ АйПи АССЕТС Б.В. | Эффективный способ асимметричного гидрирования ненасыщенных кетонов и альдегидов с использованием добавок |
| EP2935186B1 (en) * | 2012-12-18 | 2020-03-25 | DSM IP Assets B.V. | Polythiols as cis/trans isomerization catalysts for unsaturated compounds |
| ES2739229T3 (es) * | 2012-12-18 | 2020-01-29 | Dsm Ip Assets Bv | Uso de mezclas de isómeros E/Z para obtener productos cuantitativamente específicos combinando hidrogenación asimétrica e isomerización |
| US9452961B2 (en) * | 2012-12-18 | 2016-09-27 | Dsm Ip Assets B.V. | (6R,10R)-6,10,14-trimetylpentadecan-2-one prepared from 6,10-dimetylundec-5-en-2-one or 6,10-dimetylundeca-5,9-dien-2-one |
| WO2014096106A1 (en) * | 2012-12-18 | 2014-06-26 | Dsm Ip Assets B.V. | Using mixtures of e/z isomers to obtain quantitatively specific products by combined asymmetric hydrogenations |
| EA028190B9 (ru) * | 2012-12-18 | 2017-12-29 | ДСМ АйПи АССЕТС Б.В. | Монооксид азота в качестве катализатора цис/транс-изомеризации ненасыщенных соединений |
-
2013
- 2013-12-18 EP EP13814521.4A patent/EP2935185B1/en active Active
- 2013-12-18 MY MYPI2015701971A patent/MY173272A/en unknown
- 2013-12-18 JP JP2015547085A patent/JP6582324B2/ja active Active
- 2013-12-18 US US14/652,297 patent/US9611200B2/en active Active
- 2013-12-18 CN CN201380065784.XA patent/CN104854071B/zh active Active
- 2013-12-18 WO PCT/EP2013/077233 patent/WO2014096098A1/en not_active Ceased
- 2013-12-18 EA EA201500665A patent/EA033302B9/ru not_active IP Right Cessation
- 2013-12-18 BR BR112015014423-3A patent/BR112015014423B1/pt active IP Right Grant
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