JP2016204282A - Hair treatment agent composition - Google Patents
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- JP2016204282A JP2016204282A JP2015085213A JP2015085213A JP2016204282A JP 2016204282 A JP2016204282 A JP 2016204282A JP 2015085213 A JP2015085213 A JP 2015085213A JP 2015085213 A JP2015085213 A JP 2015085213A JP 2016204282 A JP2016204282 A JP 2016204282A
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- 210000004209 hair Anatomy 0.000 title claims abstract description 86
- 239000000203 mixture Substances 0.000 title claims abstract description 56
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 69
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims abstract description 44
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 32
- -1 organic acid salt Chemical class 0.000 claims abstract description 21
- 150000007524 organic acids Chemical class 0.000 claims abstract description 21
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 16
- 230000002378 acidificating effect Effects 0.000 claims abstract description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 20
- 239000010452 phosphate Substances 0.000 claims description 20
- 235000011007 phosphoric acid Nutrition 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 4
- 235000011054 acetic acid Nutrition 0.000 claims description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 4
- 235000015165 citric acid Nutrition 0.000 claims description 4
- 150000002169 ethanolamines Chemical class 0.000 claims description 4
- 239000001630 malic acid Substances 0.000 claims description 4
- 235000011090 malic acid Nutrition 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical class CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 2
- 230000006378 damage Effects 0.000 abstract description 6
- 150000003016 phosphoric acids Chemical class 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000007864 aqueous solution Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 230000003700 hair damage Effects 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 239000012190 activator Substances 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 5
- ZZTCCAPMZLDHFM-UHFFFAOYSA-N ammonium thioglycolate Chemical compound [NH4+].[O-]C(=O)CS ZZTCCAPMZLDHFM-UHFFFAOYSA-N 0.000 description 4
- 229940075861 ammonium thioglycolate Drugs 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- 229940071127 thioglycolate Drugs 0.000 description 3
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229960003067 cystine Drugs 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000004129 EU approved improving agent Substances 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 206010044625 Trichorrhexis Diseases 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- 230000003752 improving hair Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 210000003491 skin Anatomy 0.000 description 1
- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Abstract
Description
本発明は、毛髪処理剤組成物に関する。 The present invention relates to a hair treatment composition.
従来のパーマネントウエーブ施術は、概して以下のように行われる。まず、還元剤（主剤）としてのチオグリコール酸塩（チオグリコール酸アンモニウム等）と、アルカリ剤としてのアンモニア、モノエタノールアミン、炭酸水素アンモニウム等と、を加えた第１剤を用いて、毛髪の膨潤と共に毛髪中のシスチン結合を開裂する。なお、ウエーブを良好に発現させる観点から、上記第１剤のｐＨは、通常９．６以下のアルカリ性に調整される。次いで、臭素酸塩、過酸化水素などの酸化剤を主成分とする溶液である第２剤で酸化固定する。このように、第１剤と第２剤とを順次用いることで、毛髪に所望の形状を定着させる。 Conventional permanent wave treatment is generally performed as follows. First, using a first agent in which a thioglycolate (such as ammonium thioglycolate) as a reducing agent (main agent) and ammonia, monoethanolamine, ammonium hydrogencarbonate or the like as an alkaline agent is added, With swelling, it cleaves cystine bonds in the hair. The pH of the first agent is usually adjusted to an alkalinity of 9.6 or less from the viewpoint of favorably expressing the wave. Next, it is oxidatively fixed with a second agent which is a solution mainly composed of an oxidizing agent such as bromate or hydrogen peroxide. Thus, the desired shape is fixed to the hair by sequentially using the first agent and the second agent.
アルカリ性の第１剤を作用させると、毛髪の膨潤が大きく、チオグリコール酸塩の還元作用にも影響され、毛表皮の剥離、間充物質の流失などにより毛髪が傷み、ぱさつき、弾力性の消失、滑りの悪化、櫛通りの悪化などと共に、枝毛、切れ毛などの損傷が著しくなるといった問題が生じうる。そこで、チオグリコール酸塩を含むパーマネントウエーブ用剤第１剤に特定の物質を添加することにより、アルカリ性であっても上述した問題を低減する技術が提案されている（例えば、特許文献１参照）。 When the alkaline first agent is applied, the hair swells greatly and is also affected by the reduction action of the thioglycolate, and the hair is damaged by the peeling of the hair epidermis, the loss of the intercalation material, and the skin becomes soft and loses elasticity. In addition to worsening of slippage and worsening of combing, problems such as significant damage to split ends and cut hairs may occur. Then, the technique which reduces the problem mentioned above even if it is alkaline is proposed by adding a specific substance to the permanent wave agent 1st agent containing thioglycolate (for example, refer patent document 1). .
しかしながら、特許文献１に記載のパーマネントウエーブ剤は、アルカリ性であるがゆえ、毛髪の傷みを更に低減する観点から、依然として改善の余地がある。なお、従来、パーマネントウエーブ剤による毛髪の傷みとウエーブの出やすさはトレードオフの関係にある。すなわち、単に従来のパーマネントウエーブ剤のｐＨを低下させる（酸性にする）のみでは、ウエーブのかかりを損ねやすくなる。 However, since the permanent wave agent described in Patent Document 1 is alkaline, there is still room for improvement from the viewpoint of further reducing hair damage. Conventionally, there is a trade-off relationship between hair damage caused by a permanent wave agent and the ease with which the wave appears. That is, simply lowering the pH of a conventional permanent wave agent (making it acidic) tends to impair the application of the wave.
本発明は、上記事情に鑑みてなされたものであり、毛髪の傷みを十分に抑制し、かつ、良好なウエーブを発現できる、酸性ｐＨの条件下で使用可能な毛髪処理剤組成物を提供することを目的とする。 The present invention has been made in view of the above circumstances, and provides a hair treatment composition that can be used under acidic pH conditions that can sufficiently suppress damage to hair and that can express a good wave. For the purpose.
本発明者らは、鋭意研究を重ねた結果、チオグリコール酸を特定の物質と共に使用することで、上記課題を解決できることを見出し、本発明を完成するに至った。 As a result of intensive studies, the present inventors have found that the above problem can be solved by using thioglycolic acid together with a specific substance, and have completed the present invention.
すなわち、本発明は、以下の態様を包含する。
［１］
チオグリコール酸と、有機酸及び／又はリン酸と、有機酸塩及び／又はリン酸塩と、を含み、酸性である、毛髪処理剤組成物。
［２］
前記毛髪処理剤組成物中における前記チオグリコール酸の含有量が、３．０〜７．０質量％である、［１］に記載の毛髪処理剤組成物。
［３］
ｐＨが２．５〜４．７である、［１］又は［２］に記載の毛髪処理剤組成物。
［４］
前記有機酸が、酢酸、プロピオン酸、グリコール酸、乳酸、リンゴ酸、酒石酸及びクエン酸からなる群より選択される少なくとも１つを含む、［１］〜［３］のいずれかに記載の毛髪処理剤組成物。
［５］
前記有機酸塩及び／又はリン酸塩が、ナトリウム塩、カリウム塩、アンモニウム塩、モノエタノールアミン塩、トリエタノールアミン塩及び２−アミノ−２−メチル−１−プロパノール塩からなる群より選択される少なくとも１つを含む、［１］〜［４］のいずれかに記載の毛髪処理剤組成物。
［６］
パーマネントウエーブ剤に用いる、又は、縮毛矯正剤に用いる、［１］〜［５］のいずれかに記載の毛髪処理剤組成物。
［７］
［１］〜［５］のいずれか１項に記載の毛髪処理剤組成物から得られる、パーマネントウエーブ剤。
［８］
［１］〜［５］のいずれか１項に記載の毛髪処理剤組成物から得られる、縮毛矯正剤。
That is, this invention includes the following aspects.
[1]
A hair treatment composition comprising thioglycolic acid, an organic acid and / or phosphoric acid, and an organic acid salt and / or phosphate, which is acidic.
[2]
The hair treatment composition according to [1], wherein a content of the thioglycolic acid in the hair treatment composition is 3.0 to 7.0% by mass.
[3]
The hair treatment composition according to [1] or [2], wherein the pH is 2.5 to 4.7.
[4]
The hair treatment according to any one of [1] to [3], wherein the organic acid includes at least one selected from the group consisting of acetic acid, propionic acid, glycolic acid, lactic acid, malic acid, tartaric acid, and citric acid. Agent composition.
[5]
The organic acid salt and / or phosphate is selected from the group consisting of sodium salt, potassium salt, ammonium salt, monoethanolamine salt, triethanolamine salt and 2-amino-2-methyl-1-propanol salt. The hair treatment composition according to any one of [1] to [4], comprising at least one.
[6]
The hair treatment composition according to any one of [1] to [5], which is used for a permanent wave agent or a hair straightener.
[7]
A permanent wave agent obtained from the hair treatment composition according to any one of [1] to [5].
[8]
A hair straightener obtained from the hair treatment composition according to any one of [1] to [5].
本発明によれば、毛髪の傷みを十分に抑制し、かつ、良好なウエーブを発現できる、酸性ｐＨの条件下で使用可能な毛髪処理剤組成物を提供することが可能となる。 ADVANTAGE OF THE INVENTION According to this invention, it becomes possible to provide the hair treating agent composition which can be used on the conditions of acidic pH which can fully suppress the damage of hair and can express a favorable wave.
以下、本発明を実施するための形態（以下、単に「本実施形態」という。）について詳細に説明する。なお、本実施形態は、本発明を説明するための例示であり、本発明は以下の実施形態のみに限定されない。 Hereinafter, a mode for carrying out the present invention (hereinafter simply referred to as “the present embodiment”) will be described in detail. In addition, this embodiment is an illustration for demonstrating this invention, and this invention is not limited only to the following embodiment.
［毛髪処理剤組成物］
本実施形態の毛髪処理剤組成物は、チオグリコール酸と、有機酸及び／又はリン酸と、有機酸塩及び／又はリン酸塩とを含み、酸性である。このように構成されているため、本実施形態の毛髪処理剤組成物は、酸性ｐＨの条件下で使用されるものであり、毛髪の傷みを十分に抑制することができる。上記に加え、本実施形態の毛髪処理剤組成物は、良好なウエーブを発現することができる。
[Hair treatment composition]
The hair treatment composition of this embodiment contains thioglycolic acid, an organic acid and / or phosphoric acid, and an organic acid salt and / or phosphate, and is acidic. Since it is comprised in this way, the hair-treatment agent composition of this embodiment is used on the conditions of acidic pH, and can fully suppress the damage | wound of hair. In addition to the above, the hair treatment composition of the present embodiment can express a good wave.
［毛髪処理剤組成物の用途］
本実施形態の毛髪処理剤組成物は、例えば、パーマネントウエーブ剤として用いることができる。また、本実施形態の毛髪処理剤組成物は、例えば、縮毛矯正剤として用いることもできる。さらに、本実施形態の毛髪処理剤組成物は、パーマネントウエーブ剤の基材として、又は、縮毛矯正剤の基材として用いることができる。ただし、本実施形態の毛髪処理剤組成物の用途はそれらに限定されない。
[Use of hair treatment composition]
The hair treatment composition of this embodiment can be used, for example, as a permanent wave agent. Moreover, the hair treatment agent composition of this embodiment can also be used as a hair straightener, for example. Furthermore, the hair treatment composition of this embodiment can be used as a base material for permanent wave agents or a base material for hair straighteners. However, the use of the hair treatment composition of this embodiment is not limited to them.
（チオグリコール酸）
本実施形態におけるチオグリコール酸は、少なくとも還元剤として機能する。すなわち、チオグリコール酸が配合されていることにより、毛髪中のシスチン結合を還元して切断することができる。本実施形態において、毛髪処理剤組成物中のチオグリコール酸の含有量は特に限定されないが、好ましくは３．０〜７．０質量％であり、より好ましくは４．０〜７．０質量％である。特に、毛髪処理剤組成物をパーマネントウエーブ剤又は縮毛矯正剤として用いる場合、上述したチオグリコール酸含有量に調整することが好ましい。上記含有量が３．０質量％以上である場合、よりウエーブがかかりやすくなる傾向にあり、上記含有量が７．０質量％以下である場合、毛髪の傷みをより抑制できる傾向にある。
(Thioglycolic acid)
The thioglycolic acid in this embodiment functions at least as a reducing agent. That is, by incorporating thioglycolic acid, the cystine bond in the hair can be reduced and cleaved. In the present embodiment, the content of thioglycolic acid in the hair treatment composition is not particularly limited, but is preferably 3.0 to 7.0% by mass, more preferably 4.0 to 7.0% by mass. It is. In particular, when the hair treatment composition is used as a permanent wave agent or a hair straightener, it is preferably adjusted to the above-described thioglycolic acid content. When the content is 3.0% by mass or more, the wave tends to be more likely to be applied, and when the content is 7.0% by mass or less, hair damage tends to be further suppressed.
（有機酸及び／又はリン酸）
本実施形態における有機酸及び／又はリン酸は、特に限定されず、種々公知のものを使用することができる。有機酸及び／又はリン酸は、少なくとも、後述する有機酸塩及び／又はリン酸塩と併用されることにより、毛髪処理剤組成物のｐＨを安定させるものと考えられる。上記有機酸は、チオグリコール酸の酸解離定数に近い酸解離定数を有するものを選択することが好ましく、すなわち、酢酸、プロピオン酸、グリコール酸、乳酸、リンゴ酸、酒石酸及びクエン酸からなる群より選択される少なくとも１つを含むことが好ましい。同様の観点から、酢酸、リンゴ酸、クエン酸及びリン酸からなる群より選択される少なくとも１つを含むことがより好ましい。なお、上述した有機酸は、それぞれ、１種を単独で又は２種以上を組み合わせて用いることができる。
(Organic acid and / or phosphoric acid)
The organic acid and / or phosphoric acid in the present embodiment is not particularly limited, and various known acids can be used. It is considered that the organic acid and / or phosphoric acid stabilizes the pH of the hair treatment composition by being used in combination with at least the organic acid salt and / or phosphate described later. The organic acid is preferably selected from those having an acid dissociation constant close to that of thioglycolic acid, that is, from the group consisting of acetic acid, propionic acid, glycolic acid, lactic acid, malic acid, tartaric acid and citric acid. It is preferable to include at least one selected. From the same viewpoint, it is more preferable to include at least one selected from the group consisting of acetic acid, malic acid, citric acid and phosphoric acid. In addition, the organic acid mentioned above can be used individually by 1 type or in combination of 2 or more types, respectively.
（有機酸塩及び／又はリン酸塩）
本実施形態における有機酸塩及び／又はリン酸塩は、特に限定されず、種々公知のものを使用することができる。有機酸塩及び／又はリン酸塩は、上述の有機酸及び／又はリン酸と併用されることにより、毛髪処理剤組成物のｐＨを安定させるものと考えられる。中でも、イオン結合強度の観点から、上記有機酸塩及び／又はリン酸塩は、ナトリウム塩、カリウム塩、アンモニウム塩、モノエタノールアミン塩、トリエタノールアミン塩及び２−アミノ−２−メチル−１−プロパノール（ＡＭＰ）塩からなる群より選択される少なくとも１つを含むことが好ましく、ナトリウム塩、カリウム塩及びモノエタノールアミン塩からなる群より選択される少なくとも１つを含むことがより好ましい。なお、上述した有機酸塩及び／又はリン酸塩は、それぞれ、１種を単独で又は２種以上を組み合わせて用いることができる。
(Organic acid salt and / or phosphate)
The organic acid salt and / or phosphate in the present embodiment is not particularly limited, and various known ones can be used. The organic acid salt and / or phosphate is considered to stabilize the pH of the hair treatment composition when used in combination with the above-described organic acid and / or phosphoric acid. Among these, from the viewpoint of ionic bond strength, the organic acid salt and / or phosphate is sodium salt, potassium salt, ammonium salt, monoethanolamine salt, triethanolamine salt and 2-amino-2-methyl-1- It is preferable to include at least one selected from the group consisting of propanol (AMP) salts, and it is more preferable to include at least one selected from the group consisting of sodium salts, potassium salts and monoethanolamine salts. In addition, the organic acid salt and / or phosphate which were mentioned above can be used individually by 1 type or in combination of 2 or more types, respectively.
上述のように、本実施形態の毛髪処理剤組成物は、還元剤たるチオグリコール酸に加えて、有機酸及び／又はリン酸と、有機酸塩及び／又はリン酸塩とを配合している。そのため、毛髪処理剤組成物におけるチオグリコール酸は、そのほとんどが解離ないし中和されておらず、酸の状態で存在し、酸性ｐＨに調整することないし酸性ｐＨを維持することが容易になると考えられる。ただし、上記で説明した内容に限定する趣旨ではない。 As described above, the hair treatment composition of the present embodiment contains an organic acid and / or phosphoric acid and an organic acid salt and / or phosphate in addition to thioglycolic acid as a reducing agent. . Therefore, most of the thioglycolic acid in the hair treatment composition is not dissociated or neutralized, is present in an acid state, and is considered to be easy to adjust to or maintain an acidic pH. It is done. However, it is not intended to limit the content described above.
ここで、本実施形態の毛髪処理剤組成物のｐＨは、酸性ｐＨの条件下で毛髪の傷みを十分に抑制しつつ良好なウエーブを発現させる観点から、２．５〜４．７であることが好ましく、より好ましくは３．５〜４．６である。特に、毛髪処理剤組成物をパーマネントウエーブ剤又は縮毛矯正剤として用いる場合、上述したｐＨに調整することが好ましい。上記ｐＨは、本実施形態の毛髪処理剤組成物中における各成分の含有量を適宜調整することで調整することができる。本実施形態の所望のｐＨに調整し、そのｐＨで安定させる観点から、毛髪処理剤組成物中における有機酸及び／又はリン酸の含有量は、０．４〜５０．０質量％が好ましく、より好ましくは２．０〜４０．０質量％である。特に、毛髪処理剤組成物をパーマネントウエーブ剤又は縮毛矯正剤として用いる場合、上述したに有機酸及び／又はリン酸の含有量に調整することが好ましい。また、同様の観点から、毛髪処理剤組成物中における有機酸塩及び／又はリン酸塩の含有量は、０．４〜３０．０質量％が好ましく、より好ましくは２．０〜２５．０質量％である。特に、毛髪処理剤組成物をパーマネントウエーブ剤又は縮毛矯正剤として用いる場合、上述したに有機酸塩及び／又はリン酸塩の含有量に調整することが好ましい。 Here, the pH of the hair treatment composition of the present embodiment is 2.5 to 4.7 from the viewpoint of expressing a good wave while sufficiently suppressing hair damage under acidic pH conditions. Is more preferable, and 3.5 to 4.6 is more preferable. In particular, when the hair treatment composition is used as a permanent wave agent or a hair straightener, it is preferably adjusted to the pH described above. The pH can be adjusted by appropriately adjusting the content of each component in the hair treatment composition of the present embodiment. From the viewpoint of adjusting to a desired pH of the present embodiment and stabilizing at the pH, the content of the organic acid and / or phosphoric acid in the hair treatment composition is preferably 0.4 to 50.0% by mass, More preferably, it is 2.0-40.0 mass%. In particular, when the hair treatment composition is used as a permanent wave agent or a hair straightener, it is preferably adjusted to the content of organic acid and / or phosphoric acid as described above. Further, from the same viewpoint, the content of the organic acid salt and / or phosphate in the hair treatment composition is preferably 0.4 to 30.0% by mass, more preferably 2.0 to 25.0. % By mass. In particular, when the hair treatment composition is used as a permanent wave agent or a hair straightener, it is preferably adjusted to the content of organic acid salt and / or phosphate as described above.
（その他の成分）
本実施形態の毛髪処理剤組成物が上述した各成分に加えて含み得るその他の成分としては、以下に限定されないが、例えば、金属封鎖剤及び感触改良剤が挙げられる。
(Other ingredients)
Other components that the hair treatment composition of this embodiment may contain in addition to the above-described components are not limited to the following, but include, for example, metal sequestering agents and feel improvers.
上記金属封鎖剤は、パーマ剤に微量に混入し得る金属成分に起因する還元剤の機能の阻害を防止するものであり、その具体例としては、以下に限定されないが、エデト酸及びその塩や、ジエチレントリアミン五酢酸及びその塩が挙げられる。 The metal sequestering agent is to prevent inhibition of the function of the reducing agent due to the metal component that can be mixed in the permanent agent in a trace amount. Specific examples thereof include, but are not limited to, edetic acid and its salts, , Diethylenetriaminepentaacetic acid and salts thereof.
上記感触改良剤は、毛髪の触感を向上させる機能を有するものであり、その具体例としては、以下に限定されないが、油剤、活性剤、多価アルコール及び高分子化合物が挙げられる。上記油剤は、他の感触改良剤（例えば活性剤）と併用して用いられることが好ましく、乳化物や可溶化したものが使用される。上記油剤の具体例としては、以下に限定されないが、セタノール、オリーブ油、イソプロピルミリステート等が挙げられる。上記活性剤は、特に櫛通り、手触りを改良するものであり、以下に限定されないが、例えば、塩化セチルトリメチルアンモニウム等が挙げられる。上記活性剤は、耐塩性を有するものであれば、単独で感触改良剤として用いることもできる。上記多価アルコールは、水溶性であって主に保湿効果を付与するものであり、以下に限定されないが、例えば、グリセリン、１，３−ブチレングリコール等が挙げられる。上記高分子化合物は、毛髪表面に皮膜をはらせて、毛の表面の傷みやザラツキを改善するものであり、以下に限定されないが、例えば、ポリオクタニウム１１（ＩＮＣＩ名）等が挙げられる。これらは１種を単独で又は２種以上を組み合わせて用いられるが、活性剤、多価アルコール及び高分子化合物を組み合わせて用いることが好ましく、それらに加えて油剤を組み合わせて用いることがより好ましい。 The feel improving agent has a function of improving the feel of hair, and specific examples thereof include, but are not limited to, oil agents, activators, polyhydric alcohols, and polymer compounds. The oil agent is preferably used in combination with other feel improving agents (for example, an activator), and an emulsion or a solubilized one is used. Specific examples of the oil include, but are not limited to, cetanol, olive oil, isopropyl myristate, and the like. The above-mentioned activator particularly improves the touch as a comb and is not limited to the following, and examples thereof include cetyltrimethylammonium chloride. If the said activator has salt tolerance, it can also be used independently as a touch improvement agent. Although the said polyhydric alcohol is water-soluble and mainly provides a moisturizing effect, it is not limited to the following, For example, glycerol, 1, 3- butylene glycol etc. are mentioned. The above-mentioned polymer compound applies a film to the hair surface to improve hair surface scratches and roughness, and is not limited to the following, but includes, for example, polyoctanium 11 (INCI name). These are used singly or in combination of two or more, but are preferably used in combination of an activator, a polyhydric alcohol and a polymer compound, and more preferably in combination with an oil agent.
［毛髪処理剤組成物の製造方法］
本実施形態に係る毛髪処理剤組成物の製造方法は、上述した本実施形態の毛髪処理剤組成物の構成が得られる方法である限り、特に限定されるものではない。例えば、チオグリコール酸と、有機酸及び／又はリン酸と、有機酸塩及び／又はリン酸塩と、を混合する等により、本実施形態の毛髪処理剤組成物を製造することができる。なお、毛髪の傷みを十分に抑制しつつより良好なウエーブを発現する毛髪処理剤組成物を得る観点から、本実施形態に係る毛髪処理剤組成物の製造方法としては、まず、有機酸塩及び／又はリン酸塩の水溶液を調製し、次いで当該水溶液に有機酸及び／又はリン酸を加え、十分に撹拌した後、チオグリコール酸を加えることが好ましい。
[Method for producing hair treatment composition]
The method for producing the hair treatment composition according to the present embodiment is not particularly limited as long as the method for producing the hair treatment composition of the present embodiment described above is obtained. For example, the hair treatment composition of the present embodiment can be produced by mixing thioglycolic acid, organic acid and / or phosphoric acid, and organic acid salt and / or phosphate. In addition, from the viewpoint of obtaining a hair treatment composition that expresses a better wave while sufficiently suppressing hair damage, the method for producing a hair treatment composition according to this embodiment includes an organic acid salt and It is preferable to prepare an aqueous solution of / or phosphate, add an organic acid and / or phosphoric acid to the aqueous solution, and after stirring well, add thioglycolic acid.
以下、実施例及び比較例により本実施形態を更に詳細に説明するが、本実施形態はこれらの実施例に限定されるものではない。 Hereinafter, although an embodiment and a comparative example explain this embodiment still in detail, this embodiment is not limited to these examples.
［実施例１〜２９、比較例１〜１２］
（パーマネントウエーブ剤第１剤の調製）
実施例及び比較例で用いる還元剤、有機酸、有機酸塩、リン酸塩、アルカリ剤としては、下記表１〜２に記載のものを用いた。また、上記の各材料の配合量については、表１〜２に記載のとおりとした。実施例では、有機酸塩又はリン酸塩の水溶液を調製し、次いで当該水溶液に有機酸又はリン酸を加え、十分に撹拌した後、チオグリコール酸を加え、より詳細には、まず、容器内で有機酸塩又はリン酸塩の水溶液を調製し、次いで当該水溶液に有機酸又はリン酸を加え、十分に撹拌した。撹拌後、チオグリコール酸を加え、さらに水を添加して全体量を１００ｍＬとした後、十分に撹拌混合することにより、実施例１〜２９に係るパーマネントウエーブ剤第１剤を調製した。また、容器内で水にチオグリコール酸又は５０％チオグリコール酸アンモニウム水溶液を添加して全体量を１００ｍＬとした後、十分に撹拌混合することにより、比較例１及び１０に係るパーマネントウエーブ剤第１剤を調製した。さらに、容器内で水に有機酸を加え、十分に撹拌した後、チオグリコール酸を加え、さらに水を添加して全体量を１００ｍＬとした後、十分に撹拌混合することにより、比較例２〜５に係るパーマネントウエーブ剤第１剤を調製した。また、容器内で有機酸塩又はリン酸塩の水溶液を調製した後、チオグリコール酸又は５０％チオグリコール酸アンモニウム水溶液を加え、さらに水を添加して全体量を１００ｍＬとした後、十分に撹拌混合することにより、比較例６〜８、１１及び１２係るパーマネントウエーブ剤第１剤を調製した。そして、容器内で水に５０％チオグリコール酸アンモニウム水溶液を添加し、さらに２８％アンモニア水を加え、さらに水を添加して全体量を１００ｍＬとした後、十分に撹拌混合することにより、比較例９に係るパーマネントウエーブ剤第１剤を調製した。なお、水には精製水を用いた。
[Examples 1 to 29, Comparative Examples 1 to 12]
(Preparation of the first permanent wave agent)
As the reducing agent, organic acid, organic acid salt, phosphate, and alkali agent used in Examples and Comparative Examples, those described in Tables 1 and 2 below were used. Moreover, about the compounding quantity of said each material, it was as having described in Tables 1-2. In Examples, an aqueous solution of an organic acid salt or phosphate is prepared, and then an organic acid or phosphoric acid is added to the aqueous solution. After sufficiently stirring, thioglycolic acid is added. Then, an aqueous solution of an organic acid salt or phosphate was prepared, and then an organic acid or phosphoric acid was added to the aqueous solution, followed by thorough stirring. After stirring, thioglycolic acid was added, water was further added to make the total amount 100 mL, and the mixture was thoroughly stirred and mixed to prepare the permanent wave agent first agent according to Examples 1 to 29. Moreover, after adding thioglycolic acid or 50% ammonium thioglycolate aqueous solution to water in a container to make the total amount 100 mL, the permanent wave agent No. 1 according to Comparative Examples 1 and 10 is sufficiently stirred and mixed. An agent was prepared. Furthermore, after adding an organic acid to water in a container and sufficiently stirring, after adding thioglycolic acid and further adding water to make the total amount 100 mL, by sufficiently stirring and mixing, Comparative Example 2 A permanent wave first agent according to No. 5 was prepared. Also, after preparing an aqueous solution of organic acid salt or phosphate in the container, add thioglycolic acid or 50% ammonium thioglycolate aqueous solution, and then add water to make the total volume 100 mL, and then stir well The permanent wave agent 1st agent which concerns on Comparative Examples 6-8, 11 and 12 was prepared by mixing. Then, a 50% ammonium thioglycolate aqueous solution was added to water in a container, 28% ammonia water was further added, and water was further added to bring the total amount to 100 mL. A permanent wave agent No. 1 according to No. 9 was prepared. Note that purified water was used as water.
また、臭素酸ナトリウムを８ｇ計りとり、これに水を加えて溶解した後、さらに水を加えて１００ｍＬのパーマネントウエーブ剤第２剤を調製した。 Further, 8 g of sodium bromate was weighed and dissolved by adding water, and then water was further added to prepare 100 mL of a permanent wave agent second agent.
次いで、３０ｃｍの健康毛１．５〜２．０ｇを用意した。この健康毛をラウリル硫酸ナトリウム３％水溶液に１０分間浸漬した後、流水で３０秒濯ぎ、室温（１８〜２２℃）で静置乾燥し、試料とした。この試料に対して、室温（１８〜２２℃）下、以下に示す処理を行った。 Next, 1.5 to 2.0 g of 30 cm healthy hair was prepared. The healthy hair was immersed in a 3% aqueous solution of sodium lauryl sulfate for 10 minutes, rinsed with running water for 30 seconds, and allowed to stand and dry at room temperature (18-22 ° C.) to prepare a sample. This sample was subjected to the following treatment at room temperature (18-22 ° C.).
上記試料に対して、１ｍＬのパーマネントウエーブ剤第１剤を均一に塗布した。次に、上記塗布後の試料をロッド（ロッド径１５ｍｍ、長さ９０ｍｍ）に巻き付け、再度１ｍＬのパーマネントウエーブ剤第１剤を均一に塗布した。次いで、実施例１〜２９及び比較例１０〜１２については、試料を１５分間放置した後、その健康毛に対して再度２ｍＬのパーマネントウエーブ剤第１剤を均一に塗布した。一方、比較例１〜９については、２回目のパーマネントウエーブ剤第１剤塗布から８分間経過後に再度、その試料に対して２ｍＬのパーマネントウエーブ剤第１剤を均一に塗布した。 1 mL of permanent wave agent 1st agent was uniformly apply | coated with respect to the said sample. Next, the sample after the application was wound around a rod (rod diameter 15 mm, length 90 mm), and 1 mL of the permanent wave agent first agent was uniformly applied again. Next, for Examples 1 to 29 and Comparative Examples 10 to 12, after leaving the sample for 15 minutes, 2 mL of the permanent wave agent 1st agent was uniformly applied to the healthy hair again. On the other hand, in Comparative Examples 1 to 9, 2 mL of the permanent wave agent first agent was uniformly applied to the sample again after 8 minutes from the second application of the first permanent wave agent first agent.
上記の要領でパーマネントウエーブ剤第１剤の塗布を完了した後、実施例１〜２９及び比較例１０〜１２については１５分間放置することとし、比較例１〜９については７分間放置することとした。 After completing the application of the first permanent wave agent as described above, Examples 1 to 29 and Comparative Examples 10 to 12 are allowed to stand for 15 minutes, and Comparative Examples 1 to 9 are allowed to stand for 7 minutes. did.
上記のとおり放置した後、試料にスプレイヤーで１０回水を吹き付け、パーマネントウエーブ剤第１剤を濯ぎ落とした。次いで、３ｍＬのパーマネントウエーブ剤第２剤を試料に均一に塗布し、１０分間放置した。この操作をさらに１回繰り返した。 After leaving as described above, the sample was sprayed with water 10 times with a sprayer to rinse away the first permanent wave agent. Subsequently, 3 mL of permanent wave agent 2nd agent was uniformly apply | coated to the sample, and it was left to stand for 10 minutes. This operation was repeated once more.
上記の要領でパーマネントウエーブ剤第２剤の塗布を完了した後、試料からロッドを外し、流水で１０秒間濯いだ。その後、自然乾燥した。このようにして得られた処理後の試料を、以下の評価に供した。 After completing the application of the second permanent wave agent as described above, the rod was removed from the sample and rinsed with running water for 10 seconds. Thereafter, it was naturally dried. The treated sample thus obtained was subjected to the following evaluation.
（ウエーブ力）
美容師３人が目視で試験後の毛髪のウエーブのリッチ感、強さを各自が判定し、以下の基準に基づき１〜５段階で総合的に評価した。「５」が最もウエーブ力が強く、数字が小さくなるにつれてウエーブ力が弱くなることを意味する。その結果を表１〜２に併せて示す。
１：未処理毛と同じ。
２：ウエーブが出るが弱い。
３：ウエーブが出るがやや弱い。
４：パーマネントウエーブ剤として最適なウエーブ力を有する。
５：ウエーブ力が強く、縮毛矯正剤には最適。
(Wave force)
Three hairdressers visually evaluated the richness and strength of the hair after the test, and evaluated it comprehensively in 1 to 5 steps based on the following criteria. “5” means that the wave force is the strongest and the wave force becomes weaker as the number decreases. The result is combined with Tables 1-2, and is shown.
1: Same as untreated hair.
2: Wave appears but is weak.
3: A wave appears but is slightly weak.
4: Has an optimum wave power as a permanent wave agent.
5: Strong wave power, ideal for hair straighteners.
（毛髪の傷み）
美容師３人が手で試験後の毛髪を触り、その手触りから、各自が毛髪の傷み具合を判定し、以下の基準に基づいて総合的に評価した。その結果を表１〜２に併せて示す。
○：未処理毛と同じ（傷んでいない）。
△：ほとんど傷んでいない。
×：傷んでいる。
(Hair damage)
Three hairdressers touched the hair after the test with their hands, and based on the touch, each one judged the degree of hair damage, and comprehensively evaluated based on the following criteria. The result is combined with Tables 1-2, and is shown.
○: Same as untreated hair (not damaged).
Δ: Almost not damaged
X: It is damaged.
Claims (8)
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2019167111A1 (en) * | 2018-02-27 | 2019-09-06 | アドバンス株式会社 | Hair treatment agent and hair treatment method |
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| WO2019167111A1 (en) * | 2018-02-27 | 2019-09-06 | アドバンス株式会社 | Hair treatment agent and hair treatment method |
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