JPH05294814A - Middle treating agent composition of permanent wave - Google Patents
Middle treating agent composition of permanent waveInfo
- Publication number
- JPH05294814A JPH05294814A JP4096488A JP9648892A JPH05294814A JP H05294814 A JPH05294814 A JP H05294814A JP 4096488 A JP4096488 A JP 4096488A JP 9648892 A JP9648892 A JP 9648892A JP H05294814 A JPH05294814 A JP H05294814A
- Authority
- JP
- Japan
- Prior art keywords
- agent
- permanent wave
- hair
- wave
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はパーマネントウェーブ中
間処理剤組成物、更に詳細には、酸性〜弱アルカリ性の
パーマネントウェーブ第１剤処理によって生成する毛髪
中の混合ジスルフィドを解裂することによりパーマネン
トウェーブ形成能を向上させ、かつ、パーマネントウェ
ーブ処理による毛髪の損傷を防ぐパーマネントウェーブ
中間処理剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a permanent wave intermediate treatment composition, and more particularly, to a permanent wave treatment by cleaving the mixed disulfide in the hair produced by the treatment of an acidic to weakly alkaline permanent wave first agent. The present invention relates to a composition for a permanent wave intermediate treatment agent, which improves the forming ability and prevents damage to hair due to a permanent wave treatment.
【０００２】[0002]
【従来の技術】髪に所望のウェーブを付与するためのパ
ーマネントウェーブ法は、チオグリコール酸、システイ
ン等の還元剤を主成分とするパーマネントウェーブ第１
剤（以下「第１剤」という）を用いて毛髪中のＳ−Ｓ結
合を還元開鎖し、次いで臭素酸塩、過ホウ酸塩、過酸化
水素水等の酸化剤を主成分とするパーマネントウェーブ
第２剤（以下「第２剤」という）で酸化閉鎖する方法で
ある。2. Description of the Related Art A permanent wave method for imparting a desired wave to hair is a permanent wave method which is mainly composed of a reducing agent such as thioglycolic acid and cysteine.
Agent (hereinafter referred to as the "first agent") to reduce and open the S-S bond in the hair, and then a permanent wave mainly composed of an oxidizing agent such as bromate, perborate, and hydrogen peroxide solution. It is a method of oxidatively closing with a second agent (hereinafter referred to as "second agent").
【０００３】しかし、この方法によると、酸化・還元と
いう悪条件にさらされるため、毛髪の強度の低下、感触
の劣化等の現象が生じ、この様な毛髪は、ヘアスタイル
を整えるために毛髪の手入をする際、ブラシあるいは櫛
通りが悪く、ひっかけ等が生じ、毛小皮の剥離、枝毛、
切毛となって損傷されるという問題があった。However, according to this method, since it is exposed to adverse conditions such as oxidation and reduction, phenomena such as a decrease in the strength of the hair, a deterioration in the feel, etc. occur, and such a hair undergoes a When carrying out maintenance, brushes or combs do not pass properly, causing trapping etc., peeling of hair follicles, split ends,
There was a problem that it would be cut and damaged.
【０００４】従って従来、パーマネントウェーブ処理に
よるかかる毛髪の損傷を抑え感触の向上をはかると共に
ウェーブ形成能を向上させる目的で様々なパーマネント
ウェーブ中間処理剤組成物が提供されている。例えば、
特開昭６２−２４６５０９号公報ではケラチン加水分解
物を添加することにより、またイギリス特許公開第２１
６０４１９号ではプロテイン加水分解物を添加すること
により、毛髪の損傷を防止している。更に、米国特許第
４４９４５５７号においては、硫酸マグネシウム及びタ
ンパク加水分解物と油剤と界面活性剤と無機塩等の混合
物を用いることでウェーブ形成能を向上させ、パーマも
ちを良くしている。Therefore, conventionally, various permanent wave intermediate treatment compositions have been provided for the purpose of suppressing the damage to the hair due to the permanent wave treatment, improving the touch and improving the wave forming ability. For example,
In JP-A-62-246509, by adding a keratin hydrolyzate, British Patent Publication No. 21
No. 60419 prevents damage to hair by adding a protein hydrolyzate. Further, in U.S. Pat. No. 4,494,557, a mixture of magnesium sulfate and protein hydrolyzate, an oil agent, a surfactant, an inorganic salt and the like is used to improve the wave forming ability and to improve the perm.
【０００５】しかしながら、従来のパーマネントウェー
ブ中間処理剤組成物は、パーマネントウェーブによる髪
の損傷感を抑え、感触の向上をはかるのみで、髪の損傷
を本質的に改善するものではなく、またウェーブ形成能
も満足のいくものではなかった。However, the conventional permanent wave intermediate treatment agent composition suppresses the feeling of damage to hair due to permanent wave and only improves the feeling, and does not essentially improve hair damage, and it does not cause wave formation. Noh was not satisfactory either.
【０００６】一方、毛髪の膨潤を抑え、蛋白質やアミノ
酸の流出を防ぐ目的でパーマネントウェーブ第１剤のpH
を酸性〜弱アルカリ性にした低損傷パーマネントウェー
ブ処理が行われている。しかし、かかるpHでは、チオグ
リコール酸、システイン等の還元剤によるＳ−Ｓ結合の
還元開鎖において、毛髪中のシステイン残基とメルカプ
ト化合物との結合体である混合ジスルフィドの生成が起
こり、続いて行われる第２剤による酸化が不完全なもの
となるため、パーマネントウェーブのウェーブ効率が低
くなると共に毛髪の損傷もさけられないという欠点を有
していた。On the other hand, the pH of the permanent wave first agent is controlled for the purpose of suppressing the swelling of hair and preventing the outflow of proteins and amino acids.
A low-damage permanent wave treatment that makes acid to weakly alkaline is performed. However, at such pH, in the reduction open chain of the S—S bond by a reducing agent such as thioglycolic acid or cysteine, mixed disulfide, which is a conjugate of the cysteine residue in the hair and the mercapto compound, is produced, and the subsequent treatment is performed. Since the oxidation with the second agent is incomplete, the wave efficiency of the permanent wave is low and the hair is unavoidably damaged.
【０００７】[0007]
【発明が解決しようとする課題】従って、pHが酸性〜弱
アルカリ性である第１剤を使用したパーマにおいてもウ
ェーブ形成能に優れ、かつ毛髪の損傷を防止するパーマ
ネントウェーブ中間処理剤組成物の開発が望まれてい
た。Accordingly, the development of a permanent wave intermediate treatment agent composition having excellent wave-forming ability even in the perm using the first agent having a pH of acidic to weakly alkaline and preventing hair damage. Was desired.
【０００８】[0008]
【課題を解決するための手段】かかる実状において、本
発明者らは鋭意研究を行った結果、炭酸塩及び炭酸水素
塩が混合ジスルフィドの解裂に有効であり、これらを配
合したパーマネントウェーブ中間処理剤組成物を用いれ
ば毛髪のウェーブ形成率が向上し、損傷も抑えられるこ
とを見出し本発明を完成した。Under such circumstances, as a result of intensive studies conducted by the present inventors, carbonate and hydrogen carbonate are effective in cleaving mixed disulfides, and a permanent wave intermediate treatment containing them is performed. The present invention has been completed by finding that the use of the agent composition improves the wave formation rate of hair and suppresses damage.
【０００９】すなわち、本発明は炭酸塩又は炭酸水素塩
を含有することを特徴とするパーマネントウェーブ中間
処理剤組成物を提供するものである。That is, the present invention provides a permanent wave intermediate treatment composition containing a carbonate or a hydrogen carbonate.
【００１０】本発明に使用される炭酸塩としては例えば
炭酸ナトリウム、炭酸カリウム、炭酸アンモニウム、炭
酸ナトリウムカリウム、炭酸リチウム、炭酸セシウム、
炭酸カルシウム、炭酸マグネシウム等が挙げられ、ま
た、炭酸水素塩としては炭酸水素ナトリウム、炭酸水素
カリウム、炭酸水素アンモニウム、炭酸水素マグネシウ
ムカリウム、炭酸水素リチウム、カルバミン酸炭酸水素
アンモニウム等が挙げられるが、これらのうち、炭酸ナ
トリウム、炭酸カリウム、炭酸アンモニウム、炭酸ナト
リウムカリウム、炭酸水素ナトリウム、炭酸水素カリウ
ム、炭酸水素アンモニウム、炭酸水素マグネシウムカリ
ウムが特に好ましい。等が挙げられる。Examples of the carbonate used in the present invention include sodium carbonate, potassium carbonate, ammonium carbonate, sodium potassium carbonate, lithium carbonate, cesium carbonate,
Examples thereof include calcium carbonate and magnesium carbonate, and examples of the hydrogen carbonate include sodium hydrogen carbonate, potassium hydrogen carbonate, ammonium hydrogen carbonate, potassium magnesium hydrogen carbonate, lithium hydrogen carbonate, ammonium hydrogen carbamate, and the like. Among these, sodium carbonate, potassium carbonate, ammonium carbonate, sodium potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate, ammonium hydrogen carbonate, and magnesium hydrogen carbonate are particularly preferable. Etc.
【００１１】これらの炭酸塩及び炭酸水素塩は一種を単
独で、又は二種以上を組み合わせて用いることができ、
本発明のパーマネントウェーブ中間処理剤組成物中に合
計で０．５〜１０重量％（以下、単に％で示す）、特に
１〜５％配合されるのが好ましい。These carbonates and hydrogen carbonates may be used alone or in combination of two or more,
It is preferable that the permanent wave intermediate treatment agent composition of the present invention is compounded in a total amount of 0.5 to 10% by weight (hereinafter referred to simply as%), particularly 1 to 5%.
【００１２】また、本発明のパーマネントウェーブ中間
処理剤組成物は、酸性〜弱アルカリ性において、有効的
に混合ジスルフィドを開裂するため、pHを６〜１０、特
に８〜１０に調整することが好ましい。pHが６未満では
効果が充分得られず、またpHが１０を超えると刺激性の
点であまり好ましくない。かかるpHに調整するために用
いられるpH調整剤としては、例えばクエン酸、コハク
酸、酢酸、乳酸、酒石酸、グリシン、アスパラギン酸等
の弱酸又はその塩、水酸化ナトリウム、水酸化カリウ
ム、アンモニア、モノエタノールアミン、ジエタノール
アミン、トリエタノールアミン等のアルカリ、リジン、
アルギニン等の塩基性アミノ酸などが挙げられる。Further, in the permanent wave intermediate treatment agent composition of the present invention, it is preferable to adjust the pH to 6 to 10, particularly 8 to 10 in order to effectively cleave mixed disulfides in acidic to weakly alkaline conditions. If the pH is less than 6, the effect is not sufficiently obtained, and if the pH exceeds 10, it is not preferable in terms of irritation. Examples of the pH adjuster used to adjust the pH include weak acids such as citric acid, succinic acid, acetic acid, lactic acid, tartaric acid, glycine, and aspartic acid, or salts thereof, sodium hydroxide, potassium hydroxide, ammonia, and mono. Alkaline such as ethanolamine, diethanolamine, triethanolamine, lysine,
Examples thereof include basic amino acids such as arginine.
【００１３】本発明のパーマネントウェーブ中間処理剤
組成物中には、上記必須成分の他に、必要に応じて通常
使用されている界面活性剤、溶剤、油剤、湿潤剤、着色
剤、乳化剤、香料等の任意成分を配合することができ
る。更にまた、特開昭５６−９２８１２号公報に記載の
カチオニックポリマー、両性ポリマー又はジメチルポリ
シロキサン、メチルフェニルポリシロキサン、環状シリ
コーン、ポリエーテル変性シリコーン、アミノ変性シリ
コーン等のシリコーン類を配合して、毛髪保護効果を高
めることもできる。In the permanent wave intermediate treatment agent composition of the present invention, in addition to the above-mentioned essential components, a surfactant, a solvent, an oil agent, a wetting agent, a coloring agent, an emulsifier and a fragrance which are usually used as required. It is possible to mix optional components such as. Furthermore, by blending a cationic polymer, an amphoteric polymer or silicones such as dimethylpolysiloxane, methylphenylpolysiloxane, cyclic silicone, polyether-modified silicone, amino-modified silicone described in JP-A-56-92812, It can also enhance the hair protection effect.
【００１４】本発明のパーマネントウェーブ中間処理剤
組成物は、上記必須成分及び任意成分を水又は水性溶媒
に溶解し、溶液、乳液、エアゾール等にすることにより
調製される。The permanent wave intermediate treatment agent composition of the present invention is prepared by dissolving the above essential components and optional components in water or an aqueous solvent to prepare a solution, emulsion or aerosol.
【００１５】かくして得られた本発明のパーマネントウ
ェーブ中間処理剤組成物は、通常のパーマネントウェー
ブ処理における第１剤処理と第２剤処理の中間に、毛髪
に塗布又は噴霧することによって使用される。特に酸性
〜弱アルカリ性の第１剤で処理し、次いで本発明組成物
で処理した後第２剤で処理することが好ましい。ここ
で、酸性〜弱アルカリ性のパーマネントウェーブ第１剤
としては、チオグリコール酸又はその塩類あるいはそれ
らのエステル等の誘導体、Ｌ−システイン、Ｎ−アセチ
ルシステイン、チオ乳酸などを含み、pH４〜８に調整さ
れた一般のものを用いることが好ましい。また、パーマ
ネントウェーブ第２剤としては臭素酸塩、過ホウ酸塩、
過酸化水素、ヨウ素等の酸化剤を主成分とするものを用
いるとよい。The thus-obtained permanent wave intermediate treatment agent composition of the present invention is used by applying or spraying to the hair between the first agent treatment and the second agent treatment in the usual permanent wave treatment. In particular, it is preferable that the treatment is performed with an acidic to weakly alkaline first agent, then with the composition of the present invention, and then with the second agent. Here, the acidic to weakly alkaline permanent wave first agent contains thioglycolic acid or its salts or derivatives thereof such as esters, L-cysteine, N-acetylcysteine, thiolactic acid, etc., and is adjusted to pH 4 to 8. It is preferable to use the general one described above. Also, as the permanent wave second agent, bromate, perborate,
It is preferable to use a material containing an oxidizing agent such as hydrogen peroxide or iodine as a main component.
【００１６】[0016]
【発明の効果】本発明のパーマネントウェーブ中間処理
剤組成物で、第１剤と第２剤の中間において毛髪を処理
すると、第１剤によって生成した毛髪内の混合ジスルフ
ィドを解裂することができるため、ウェーブ形成率が向
上し、また毛髪の損傷を抑えることができる。[Effects of the Invention] When the hair is treated with the permanent wave intermediate treatment composition of the present invention in the middle of the first part and the second part, the mixed disulfide in the hair produced by the first part can be cleaved. Therefore, the wave formation rate is improved, and damage to hair can be suppressed.
【００１７】[0017]
【実施例】次に実施例を挙げて本発明を更に説明する
が、本発明はこれらによって何ら限定されるものではな
い。The present invention will be further described with reference to examples, but the present invention is not limited thereto.
【００１８】実施例１〜３、比較例１〜２ 下記コールドウェーブ第１剤と第２剤を用いてパーマネ
ントウェーブ処理する方法において、第１剤と第２剤と
の中間において、表１に示すパーマネントウェーブ中間
処理剤組成物（実施例１〜３、比較例１）で毛髪を処理
したときのパーマネントのかかり具合をウェーブ度及び
カール径を測定することにより評価した。その結果を表
２に示す。 使用薬剤： （１）コールドウェーブ第１剤 チオグリコール酸アンモニウム塩 ７．０（％） 水，リン酸 （pHをリン酸で６．５に調整） ９３．０ （２）コールドウェーブ第２剤 臭素酸ナトリウム ５．０（％） 水 ９５．０Examples 1 to 3 and Comparative Examples 1 to 2 In the method of performing permanent wave treatment using the following cold wave first agent and second agent, shown in Table 1 between the first agent and the second agent. The degree to which the permanent was applied when the hair was treated with the permanent wave intermediate treatment agent composition (Examples 1 to 3 and Comparative Example 1) was evaluated by measuring the wave degree and the curl diameter. The results are shown in Table 2. Drugs used: (1) Cold wave first agent Ammonium thioglycolate 7.0 (%) Water, phosphoric acid (pH adjusted to 6.5 with phosphoric acid) 93.0 (2) Cold wave second agent Bromine Sodium acid 5.0 (%) Water 95.0
【００１９】また、下記の組成のコールドウェーブ第１
剤と上記組成の第２剤を用いて、パーマネントウェーブ
中間処理剤組成物を用いることなしに毛髪を処理したと
きのパーマネントのかかり具合をウェーブ度及びカール
径を測定することにより評価した。その結果を比較例２
として表２に示す。 使用薬剤： （１）コールドウェーブ第１剤 チオグリコール酸アンモニウム ７．０（％） 炭酸水素アンモニウム ４．０ 水，リン酸 （pHをリン酸で６．５に調整） ８９．０The cold wave of the following composition No. 1
Using the agent and the second agent having the above composition, the degree of permanent application when hair was treated without using a permanent wave intermediate treatment agent composition was evaluated by measuring the wave degree and curl diameter. The results are shown in Comparative Example 2
Are shown in Table 2. Drugs used: (1) Cold wave first agent Ammonium thioglycolate 7.0 (%) Ammonium hydrogen carbonate 4.0 Water, phosphoric acid (pH adjusted to 6.5 with phosphoric acid) 89.0
【００２０】[0020]
【表１】 [Table 1]
【００２１】評価方法： （１）ウェーブ度 常法に従ってブリーチ及びパーマ処理を各々１回行った
１５cmの日本人毛髪１０本を一束とし、ガラス管（直径
１０mm）に巻き、これを第１剤中に３０℃で２０分間浸
漬した。これを中間処理剤（実施例１〜３、比較例１）
に１０分間浸漬した後、第２剤中に１０分間浸漬し、水
で充分にすすいだ後、毛束をガラス管よりはずすと、毛
髪はコイル状となる。このときの毛髪のコイルの長さを
測定し、ウェーブ度を下式によって求めた。また、比較
例２のみは、第１剤中に３０℃で３０分間浸漬した後、
中間処理を行わず、直ちに第２剤中に１０分間浸漬し、
次いで同様にしてウェーブ度を求めた。Evaluation method: (1) Wave degree A bundle of 10 Japanese hair of 15 cm, each of which was bleached and permed once according to the usual method, was wrapped in a glass tube (diameter 10 mm), and this was used as the first agent. It was immersed therein at 30 ° C. for 20 minutes. This is an intermediate treatment agent (Examples 1 to 3, Comparative Example 1)
After immersing in the second agent for 10 minutes, immersing in the second agent for 10 minutes, thoroughly rinsing with water, and then removing the hair bundle from the glass tube, the hair becomes a coil. The length of the hair coil at this time was measured, and the wave degree was calculated by the following formula. Further, in Comparative Example 2 only, after being immersed in the first agent at 30 ° C. for 30 minutes,
Immediately soak in the second agent for 10 minutes without intermediate treatment,
Then, the wave degree was similarly determined.
【００２２】[0022]
【数１】 [Equation 1]
【００２３】（２）カール径 上述の（１）で得られた毛髪のコイルの内径を測定し、
カール径（mm）とした。(2) Curl diameter The inner diameter of the hair coil obtained in (1) above was measured,
The curl diameter (mm) was used.
【００２４】[0024]
【表２】 [Table 2]
【００２５】表２の結果より、本発明のパーマネントウ
ェーブ中間処理剤組成物を用いれば、パーマネントのか
かり具合が良好であることがわかる。From the results shown in Table 2, it can be seen that the permanent wave intermediate treatment agent composition of the present invention has a good degree of permanent application.
【００２６】実施例４ 実施例３のパーマネントウェーブ中間処理剤組成物を用
いて、実施例１〜３及び比較例１と同様にパーマ処理を
行った場合の、第１剤処理後、パーマネントウェーブ中
間処理剤組成物処理後及び第２剤処理後の毛髪弾性率の
変化を調べた。その結果を表３に示す。尚、表３中の数
値は処理前の弾性率を１００とした場合の数値である。Example 4 When the permanent wave intermediate treatment agent composition of Example 3 was used to carry out the perm treatment in the same manner as in Examples 1 to 3 and Comparative Example 1, after the first agent treatment, the permanent wave intermediate treatment was performed. The change in hair elastic modulus after the treatment with the treatment composition and the treatment with the second agent was examined. The results are shown in Table 3. The numerical values in Table 3 are numerical values when the elastic modulus before treatment is 100.
【００２７】[0027]
【表３】 [Table 3]
【００２８】表３の結果より、本発明のパーマネントウ
ェーブ中間処理剤組成物を用いれば、毛髪の弾性率の低
下が生じないことがわかる。From the results shown in Table 3, it can be seen that the use of the permanent wave intermediate treatment composition of the present invention does not cause a decrease in the elastic modulus of hair.
【００２９】実施例５ 実施例１で用いた第１剤と第２剤の中間において、下記
に示す組成のパーマネントウェーブ中間処理剤組成物で
処理を行ったところ、実施例１〜３と同様の結果が得ら
れた。 （組成） （％） 炭酸水素アンモニウム ４．０ プロピレングリコール ２．０ 塩化ステアリルトリメチルアンモニウム（２８％） １．０ ポリオキシエチレンラウリルエーテル（２３Ｅ．Ｏ．） ０．５ 香料 ０．０５ アミノ変性シリコーン* １．０ アンモニア水（２８％） 適量** イオン交換水 バランス * : トーレシリコーン ＳＭ８７０２０（東レ（株）） **: pH８．０となる量Example 5 In the middle of the first agent and the second agent used in Example 1, a treatment with a permanent wave intermediate treatment agent composition having the following composition was carried out. Results were obtained. (Composition) (%) Ammonium hydrogen carbonate 4.0 Propylene glycol 2.0 Stearyl trimethyl ammonium chloride (28%) 1.0 Polyoxyethylene lauryl ether (23 EO) 0.5 Perfume 0.05 Amino-modified silicone * 1.0 Ammonia water (28%) Appropriate amount ** Ion-exchanged water balance *: Toray Silicone SM87020 (Toray Industries, Ltd.) **: pH 8.0
Claims (2)
特徴とするパーマネントウェーブ中間処理剤組成物。1. A permanent wave intermediate treatment agent composition comprising a carbonate or a hydrogen carbonate.
理し、次いで炭酸塩又は炭酸水素塩を含有するパーマネ
ントウェーブ中間処理剤組成物で処理した後、パーマネ
ントウェーブ第２剤で処理することを特徴とするパーマ
ネントウェーブ処理方法。2. Hair is treated with a permanent wave first agent, and then treated with a permanent wave intermediate treatment agent composition containing a carbonate or hydrogen carbonate, and then treated with a permanent wave second agent. Permanent wave processing method.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4096488A JPH06102618B2 (en) | 1992-04-16 | 1992-04-16 | Permanent wave intermediate treatment composition |
| EP93921088A EP0673640B1 (en) | 1992-04-16 | 1993-09-29 | Intermediate permanent wave treatment |
| PCT/JP1993/001393 WO1995008977A1 (en) | 1992-04-16 | 1993-09-29 | Intermediate permanent wave treatment composition |
| US08/943,206 US5858337A (en) | 1992-04-16 | 1997-10-03 | Intermediate treatment composition for permanent wave |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4096488A JPH06102618B2 (en) | 1992-04-16 | 1992-04-16 | Permanent wave intermediate treatment composition |
| PCT/JP1993/001393 WO1995008977A1 (en) | 1992-04-16 | 1993-09-29 | Intermediate permanent wave treatment composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05294814A true JPH05294814A (en) | 1993-11-09 |
| JPH06102618B2 JPH06102618B2 (en) | 1994-12-14 |
Family
ID=26434440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4096488A Expired - Fee Related JPH06102618B2 (en) | 1992-04-16 | 1992-04-16 | Permanent wave intermediate treatment composition |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPH06102618B2 (en) |
| WO (1) | WO1995008977A1 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012532864A (en) * | 2009-07-10 | 2012-12-20 | ロレアル | Permanent deformation method of keratin fiber |
| JP2013028545A (en) * | 2011-07-27 | 2013-02-07 | Frasco:Kk | Ion water for permanent wave and operation method of permanent wave using the same |
| JP2013129608A (en) * | 2011-12-20 | 2013-07-04 | Takara Belmont Co Ltd | Deodorization treatment agent and deodorization treatment method for hair |
| JP2013245189A (en) * | 2012-05-25 | 2013-12-09 | Takara Belmont Co Ltd | Hair treating agent and method for treating hair |
| JP2015117186A (en) * | 2013-12-17 | 2015-06-25 | 株式会社ミルボン | Treatment agent for hair deformation |
| JP2017114838A (en) * | 2015-12-25 | 2017-06-29 | タカラベルモント株式会社 | Intermediate treatment agent for hair deformation treatment |
| JP2017218416A (en) * | 2016-06-08 | 2017-12-14 | 株式会社ミルボン | First agent for hair deformation, hair deforming agent and hair deforming method |
| JP2022031006A (en) * | 2020-08-07 | 2022-02-18 | 義幸 江口 | Permanent wave application method |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2470596A1 (en) | 1979-11-28 | 1981-06-12 | Oreal | COMPOSITION FOR THE TREATMENT OF KERATIN FIBERS BASED ON AMPHOTERIC POLYMERS AND CATIONIC POLYMERS |
| US4494557A (en) | 1982-09-20 | 1985-01-22 | Nagel Gerald D | Method of conditioning hair |
| GB2160419B (en) | 1984-06-08 | 1990-02-14 | Crestol Ltd | Treatment of hair, skin and nails |
| JPS62246509A (en) | 1986-04-11 | 1987-10-27 | Kao Corp | Permanent wave intermediate treatment agent composition |
| JPH078775B2 (en) * | 1989-11-10 | 1995-02-01 | タカラベルモント株式会社 | First agent for permanent wave |
-
1992
- 1992-04-16 JP JP4096488A patent/JPH06102618B2/en not_active Expired - Fee Related
-
1993
- 1993-09-29 WO PCT/JP1993/001393 patent/WO1995008977A1/en active IP Right Grant
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012532864A (en) * | 2009-07-10 | 2012-12-20 | ロレアル | Permanent deformation method of keratin fiber |
| JP2013028545A (en) * | 2011-07-27 | 2013-02-07 | Frasco:Kk | Ion water for permanent wave and operation method of permanent wave using the same |
| JP2013129608A (en) * | 2011-12-20 | 2013-07-04 | Takara Belmont Co Ltd | Deodorization treatment agent and deodorization treatment method for hair |
| JP2013245189A (en) * | 2012-05-25 | 2013-12-09 | Takara Belmont Co Ltd | Hair treating agent and method for treating hair |
| JP2015117186A (en) * | 2013-12-17 | 2015-06-25 | 株式会社ミルボン | Treatment agent for hair deformation |
| JP2017114838A (en) * | 2015-12-25 | 2017-06-29 | タカラベルモント株式会社 | Intermediate treatment agent for hair deformation treatment |
| JP2017218416A (en) * | 2016-06-08 | 2017-12-14 | 株式会社ミルボン | First agent for hair deformation, hair deforming agent and hair deforming method |
| JP2022031006A (en) * | 2020-08-07 | 2022-02-18 | 義幸 江口 | Permanent wave application method |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1995008977A1 (en) | 1995-04-06 |
| JPH06102618B2 (en) | 1994-12-14 |
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