JP2016172697A - Body detergent and production method thereof - Google Patents

Body detergent and production method thereof Download PDF

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JP2016172697A
JP2016172697A JP2015052852A JP2015052852A JP2016172697A JP 2016172697 A JP2016172697 A JP 2016172697A JP 2015052852 A JP2015052852 A JP 2015052852A JP 2015052852 A JP2015052852 A JP 2015052852A JP 2016172697 A JP2016172697 A JP 2016172697A
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JP6648975B2 (en
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剛 永松
Takeshi Nagamatsu
剛 永松
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MORIKAWA KENKODO KK
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Abstract

PROBLEM TO BE SOLVED: To provide body detergents effective in improving moisture retention and rough and dry skin, and to provide production methods of the detergents.SOLUTION: A body detergent containing wasp larvae-derived oils and fats and/or a saponified material thereof is obtained by adding wasp larvae-derived oils and fats and/or a saponified material thereof to a saponified material as main raw oils and fats, or saponifying by combining wasp larvae-derived oils and fats with main raw oils and fats. Preferably, the content of wasp larvae-derived oils and fats and/or a saponified material thereof is 1-8 parts by mass to 100 parts by mass of total amount of main raw oils and fats.SELECTED DRAWING: Figure 1

Description

本発明は、蜂の子由来の油脂及び/又はその鹸化物を含有し、保湿性と肌荒れ改善に効果がある、身体用浄剤及び該洗浄剤の製造方法に関する。   The present invention relates to a cleansing agent for body and a method for producing the cleaning agent, which contains oil and / or fat derived from bees and / or a saponified product thereof and is effective in improving moisture retention and rough skin.

化粧石鹸、ボディソープ、シャンプー等の身体用洗浄剤は、油脂、又は油脂を予め加水分解して得た脂肪酸を、アルカリ剤で鹸化させた石鹸素地を主成分とし、種々の添加剤が加えられて、泡立ち、泡切れ、香りのほか、すべすべ、つるつる、しっとりとした肌の感じ、保湿性の効果をもたらす工夫がなされている。   Body cleaners such as cosmetic soaps, body soaps, shampoos, etc. are mainly composed of soap bases obtained by saponifying fats or fatty acids obtained by pre-hydrolysis of fats and oils with an alkaline agent, and various additives are added. In addition to foaming, running out of bubbles, and fragrance, it has been devised to provide a smooth, smooth, moist skin feel and moisturizing effect.

例えば、下記特許文献1には、石鹸素地に蜂蜜を添加して保湿力を高めた、蜂蜜石鹸が開示されている。蜂蜜は糖類であるため、一般的には、石鹸素地に多く添加すると、固まり難くなって軟質化してしまうため、蜂蜜の添加量は1重量%程度の含有率が限界とされているが、特許文献1に開示された蜂蜜石鹸は、ラウリン酸及びオレイン酸を主成分とするパーム油を鹸化した主石鹸素地と、パルミチン酸、ミリスチン酸、ステアリン酸を成分とする飽和脂肪酸群を鹸化した副石鹸素地と、グリセリン、エタノール、スクロースを成分とする透明化添加剤とを特定の配合比で混練し、蜂蜜含有率を10〜15重量%まで引き上げている。   For example, Patent Document 1 below discloses a honey soap in which honey is added to a soap base to increase the moisturizing power. Since honey is a saccharide, generally it will harden and soften when added in large amounts to soap bases, so the amount of honey added is limited to about 1% by weight. The honey soap disclosed in Document 1 is an auxiliary soap obtained by saponifying a main soap base obtained by saponifying palm oil mainly composed of lauric acid and oleic acid, and a saturated fatty acid group comprising palmitic acid, myristic acid and stearic acid. The substrate and the clarification additive containing glycerin, ethanol and sucrose as components are kneaded at a specific blending ratio to raise the honey content to 10 to 15% by weight.

また、特許文献2には、蜂が集めた花粉をアルコール溶液に数週間浸漬してビーポリンエキスを抽出し、透明石鹸にビーポリンエキスを10%配合したポリン石鹸が開示されている。   Patent Document 2 discloses a porin soap in which pollen collected by bees is immersed in an alcohol solution for several weeks to extract a beeporin extract, and 10% of the beeporin extract is blended with a transparent soap.

特許第5425412号公報Japanese Patent No. 5425412 特開2003−73695号公報JP 2003-73695 A

しかしながら、蜂蜜も蜂花粉も蜂が集めてきた植物由来の素材であって、動物体としての蜂そのものを石鹸材料として利用しているわけではない。   However, honey and bee pollen are plant-derived materials collected by bees, and the bees themselves as animals are not used as soap materials.

蜂の子(蜂の幼虫及び蛹)は、栄養価の高い蜂蜜及び蜂花粉を餌として育ち、体内に8種類の必須アミノ酸をはじめ、全部で18種類ものアミノ酸と20種類のビタミンミネラルを豊富に含んでいる。   Bee pups (bee larvae and moths) are fed with nutritious honey and bee pollen and are rich in 18 essential amino acids and 20 vitamin minerals, including 8 essential amino acids. Contains.

このような蜂の子を身体用の洗浄剤として用いることは、これまでに試みられたことがなかった。また、蜂の子を洗浄剤に添加した場合に、どのような効果がもたらされるかについて検討されたこともなかった。   The use of such bees as a cleaning agent for the body has never been attempted. Moreover, it has not been examined what kind of effect is brought about when a bee is added to a cleaning agent.

したがって、本発明の目的は、蜂の子由来の油脂及び/又はその鹸化物を含有し、保湿性と肌荒れ改善に効果がある、身体用浄剤及びその製造方法を提供することにある。   Accordingly, an object of the present invention is to provide a body cleanser and a method for producing the same, which contain oil and / or fat derived from bees and / or a saponified product thereof and are effective in improving moisture retention and rough skin.

上記目的を達成するため、本発明の身体用洗浄剤は、蜂の子由来の油脂及び/又はその鹸化物を含有することを特徴とする。   In order to achieve the above object, the body cleaning agent of the present invention is characterized by containing a fat and oil derived from bees and / or a saponified product thereof.

本発明の身体用洗浄剤においては、前記蜂の子由来の油脂及び/又はその鹸化物の含有量が、前記主原料油脂の合計量100質量部に対して、1〜8質量部であることが好ましい。   In the body cleaning agent of the present invention, the content of the oil and / or saponified product thereof derived from the bees is 1 to 8 parts by mass with respect to 100 parts by mass of the total amount of the main raw material oil and fat. Is preferred.

また、本発明の身体用洗浄剤において、前記蜂の子は、女王蜂の幼虫及び/又は蛹であることが好ましい。   In the body cleaning agent of the present invention, the bee cub is preferably a queen bee larva and / or a moth.

また、本発明の身体用洗浄剤において、蜂の子由来の油脂及び/又はその鹸化物以外に、牛脂、豚脂、ヤシ油、パーム油、オリーブ油、大豆油、落花生油、綿実油、ヒマシ油、ゴマ油、ナタネ油、キリ油、シソ油、ヒマワリ油、ブドウ種子油、アボガド油、サザンカ油、茶実油、椿油、馬油から選ばれた少なくとも1種からなる主原料油脂の鹸化物を含有することが好ましい。   Further, in the body cleaning agent of the present invention, beef tallow, lard, coconut oil, palm oil, olive oil, soybean oil, peanut oil, cottonseed oil, castor oil, in addition to the oil and / or saponified product derived from bees Contains a saponified product of at least one main raw material fat selected from sesame oil, rapeseed oil, tung oil, perilla oil, sunflower oil, grape seed oil, avocado oil, sasanqua oil, tea seed oil, coconut oil and horse oil It is preferable.

本発明の身体用洗浄剤の製造方法は、蜂の子由来の油脂を、主原料油脂に配合して鹸化するか、あるいは主原料油脂の鹸化物に配合することを特徴とする。   The method for producing a body cleaning agent of the present invention is characterized in that oil derived from bees is blended in a main raw material fat and saponified, or is blended in a saponified product of the main raw material fat.

また、本発明の身体用洗浄剤の製造方法の1実施形態においては、蜂の子又はその加工物に有機溶媒を加えて油脂を抽出した後、有機溶媒を蒸発させて蜂の子由来の油脂を得ることができる。   In one embodiment of the method for producing a body cleaner of the present invention, an organic solvent is added to a bee or a processed product thereof to extract the oil and fat, and then the organic solvent is evaporated to obtain the oil and fat derived from the bee. Can be obtained.

上記実施形態において、前記有機溶媒は、メタノール、エタノール、プロパノール、ブタノール、アセトン及びヘキサンからなる群より選ばれた1種又はその混合物を用いることが好ましい。   In the above embodiment, the organic solvent is preferably one selected from the group consisting of methanol, ethanol, propanol, butanol, acetone, and hexane, or a mixture thereof.

また、本発明の身体用洗浄剤の製造方法の他の実施形態においては、蜂の子又はその加工物に水を加えて加熱することにより油脂を抽出し、得られた油脂を分離することにより蜂の子由来の油脂を得ることができる。   Moreover, in other embodiment of the manufacturing method of the body washing | cleaning agent of this invention, by adding water to a bee or its processed material and heating and extracting fats and oils, and separating the obtained fats and oils Oils and fats derived from bees can be obtained.

上記実施形態において、前記油脂抽出時の加熱温度は、75〜98℃であることが好ましい。   In the said embodiment, it is preferable that the heating temperature at the time of the said fat extraction is 75-98 degreeC.

また、本発明の身体用洗浄剤の製造方法の更に他の実施形態においては、蜂の子又はその加工物をプロテアーゼによって酵素分解し、遊離した油脂を乾燥させて蜂の子由来の油脂を得ることができる。   In still another embodiment of the method for producing a body cleaning agent of the present invention, a bee or a processed product thereof is enzymatically decomposed with a protease, and the released fat is dried to obtain fat derived from the bee. be able to.

また、本発明の身体用洗浄剤の製造方法においては、前記蜂の子由来の油脂の配合量を、前記主原料油脂の合計量100質量部に対して、1〜8質量部とすることが好ましい。   Moreover, in the manufacturing method of the body washing | cleaning agent of this invention, let the compounding quantity of the fats and oils derived from the said bee child be 1-8 mass parts with respect to 100 mass parts of total amounts of the said main raw material fats and oils. preferable.

また、本発明の身体用洗浄剤の製造方法において、前記蜂の子として、女王蜂の幼虫及び/又は蛹を用いることが好ましい。   Moreover, in the manufacturing method of the body washing | cleaning agent of this invention, it is preferable to use the larva and / or moth of a queen bee as said bee child.

また、本発明の身体用洗浄剤の製造方法において、前記主原料油脂として、牛脂、豚脂、ヤシ油、パーム油、オリーブ油、大豆油、落花生油、綿実油、ヒマシ油、ゴマ油、ナタネ油、キリ油、シソ油、ヒマワリ油、ブドウ種子油、アボガド油、サザンカ油、茶実油、椿油、馬油から選ばれた少なくとも1種の油脂を用いることが好ましい。   Further, in the method for producing a body cleaning agent of the present invention, the main raw material fats and oils include beef tallow, lard, palm oil, palm oil, olive oil, soybean oil, peanut oil, cottonseed oil, castor oil, sesame oil, rapeseed oil, drill It is preferable to use at least one oil selected from oil, perilla oil, sunflower oil, grape seed oil, avocado oil, sasanqua oil, tea seed oil, coconut oil, and horse oil.

本発明によれば、蜂の子由来の油脂及び/又はその鹸化物を含有させることにより、保湿性と肌荒れ改善に効果がある身体用浄剤及びその製造方法を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the cleansing agent for body which has an effect in a moisturizing property and rough skin improvement by containing the fats and oils derived from a bee and / or its saponified product, and its manufacturing method can be provided.

本発明の身体用洗浄剤において、蜂の子由来の油脂の配合率を変え、洗顔後の経過時間に対して肌の水分量を調べた関係図である。In the body cleaner of this invention, it is the related figure which changed the compounding rate of the fats and oils derived from a bee, and investigated the moisture content of the skin with respect to the elapsed time after face-washing. 本発明の身体用洗浄剤において、蜂の子由来の油脂を配合したものと配合しないものとで、洗顔後の経過時間に対して肌の水分量を調べた関係図である。It is the relationship figure which investigated the moisture content of the skin with respect to the elapsed time after face-washing with what does not mix | blend the fats and oils derived from a bee in the body cleaning agent of this invention. 本発明の身体用洗浄剤を用いて洗顔した後の、倍率50倍の光学顕微鏡写真である。It is an optical microscope photograph of 50-times magnification after wash | cleaning face using the body washing | cleaning agent of this invention. 本発明の身体用洗浄剤を用いて洗顔した後の、倍率200倍の光学顕微鏡写真である。It is an optical microscope photograph of 200 times magnification after washing the face using the body cleaner of the present invention.

まず、本発明の身体用洗浄剤の製造原料について説明する。   First, the manufacturing raw material of the body cleaning agent of this invention is demonstrated.

本発明で使用される蜂の子の種類は、蜂の幼虫又は蛹であれば特に限定されず、例えばミツバチ科、スズメバチ科、アシナガバチ科の蜂の幼虫又は蛹を使用することができ、好ましくはミツバチ科、スズメバチ科の蜂を挙げることができる。更に、ミツバチ科の蜂としてセイヨウミツバチ、スズメバチ科の蜂としてクロスズメバチを挙げることができる。ミツバチ科の蜂を用いた場合は入手しやすい点で好ましい。   The kind of bee kid used in the present invention is not particularly limited as long as it is a bee larva or a moth, and for example, a bee larva or moth of a honey bee family, a wasp family, a wasp family can be used, and preferably The bees of honeybees and hornets can be mentioned. Furthermore, honeybees can be cited as honeybees and honeybees can be cited as honeybees. The use of bees of the honey bee family is preferable in terms of easy availability.

本発明において、蜂の子としては、雄蜂、働き蜂、女王蜂のいずれの蜜蜂の子を用いてもよい。   In the present invention, as a bee child, any of bees, bees, queen bees and bees may be used.

雄蜂の子は、雌蜂の子にはない、特有のホルモン等を含んでいるため、特別な美容効果が期待できる。雄蜂が生まれてくる数はとても少ないが、雄蜂用の巣房を有する巣板を人工的に作って設置しておくことにより、雄蜂の子を効率よく生ませることができる。   A male bee child contains a special hormone, etc., which is not found in a female bee child, and therefore a special beauty effect can be expected. Although the number of male bees is born very few, it is possible to produce male bees efficiently by artificially creating and installing a nest board having a bunch of male bees.

一方、働き蜂と女王蜂は、雌であるが、ローヤルゼリーを食べると女王蜂となり、花粉と蜂蜜を食べると働き蜂になる。そこで、女王蜂用の巣房(小部屋、王台ともいう)を有する巣板を人工的に作り、その巣房に雌蜂の幼虫を入れておくと、働き蜂がローヤルゼリーを運んでくるため、女王蜂の幼虫を多く繁殖させることができる。   On the other hand, worker bees and queen bees are female, but if they eat royal jelly, they become queen bees, and if they eat pollen and honey, they become worker bees. Therefore, when a nest plate having a nest for a queen bee (also called a small room or a royal stand) is artificially created and a female bee larva is placed in the nest, the worker bee carries the royal jelly, so the queen bee Can breed many larvae.

本発明においては、生理活性効果が高い成分を豊富に含む雄蜂の子又は女王蜂の子を用いることが好ましく、特に女王蜂の子が好ましい。   In the present invention, it is preferable to use a male bee cub or a queen bee cub containing abundant components having a high physiological activity effect, and particularly preferably a queen bee cub.

蜂の子としては、特に産卵後20〜23日、より好ましくは産卵後21日の、蛹の状態の蜂の子を用いることが好ましい。蛹の状態の蜂の子、特に羽化直前の蛹の状態の蜂の子は、蛋白質、アミノ酸、羽化ホルモンなどの栄養源や生理活性物質を豊富に含み、身体用洗浄剤の原料として用いると、保湿効果を更に高めることができる。   As a bee child, it is preferable to use a bee child in a cocoon state 20 to 23 days after egg laying, more preferably 21 days after egg laying. Bee pupae in the cocoon state, especially those just before the emergence, are rich in nutrients and physiologically active substances such as proteins, amino acids, and emergence hormones. The moisturizing effect can be further enhanced.

蜂の子の種類又は性別、産地は、身体用洗浄剤に対する消費者の好みに合わせて、使い分けることができる。   The type or gender of the bee cub and the place of production can be selected according to the consumer's preference for the body cleaner.

本発明の身体用洗浄剤には、油脂にアルカリ剤を加えて鹸化した、石鹸素地を用いることができる。使用される主原料油脂は、特に限定されないが、例えば、牛脂、豚脂、ヤシ油、パーム油、オリーブ油、大豆油、落花生油、綿実油、ヒマシ油、ゴマ油、ナタネ油、キリ油、シソ油、ヒマワリ油、ブドウ種子油、アボガド油、サザンカ油、茶実油、椿油、馬油から選ばれた少なくとも1種の油脂を用いることができる。   As the body cleaning agent of the present invention, a soap base obtained by saponifying an oil and fat with an alkali agent can be used. The main raw material fat used is not particularly limited, for example, beef tallow, lard, coconut oil, palm oil, olive oil, soybean oil, peanut oil, cottonseed oil, castor oil, sesame oil, rapeseed oil, drill oil, perilla oil, At least one oil selected from sunflower oil, grape seed oil, avocado oil, sasanqua oil, tea seed oil, coconut oil, and horse oil can be used.

また、前記油脂に、パルミチン酸、ミリスチン酸、ステアリン酸、オレイン酸、ラウリン酸、イソステアリン酸、リノール酸、リノリン酸、ラノリンなどの脂肪酸を混合し、洗浄力、起泡性、冷水への溶け易さ、皮膚への刺激性などの石鹸特性を調製することができる。   In addition, fatty acids such as palmitic acid, myristic acid, stearic acid, oleic acid, lauric acid, isostearic acid, linoleic acid, linolenic acid, and lanolin are mixed with the fats and oils, and the detergency, foamability, and ease of dissolving in cold water are mixed. Soap properties such as skin irritation can be prepared.

また、前記アルカリ剤には、水酸化ナトリウム、水酸化カリウム、トリエタノールアミンなどを用いることができる。水酸化カリウムは水酸化ナトリウムより溶解性が高く、固形石鹸や粉石鹸にはナトリウム石鹸が適し、液体石鹸にはカリウム石鹸が適する。日本など軟水地域ではほぼナトリウム石鹸であるが、欧州など硬水地域ではカリウム石鹸が浴用石鹸として好まれる。   Moreover, sodium hydroxide, potassium hydroxide, triethanolamine, etc. can be used for the said alkali agent. Potassium hydroxide is more soluble than sodium hydroxide. Sodium soap is suitable for solid soap and powder soap, and potassium soap is suitable for liquid soap. Although it is almost sodium soap in soft water areas such as Japan, potassium soap is preferred as a bath soap in hard water areas such as Europe.

本発明の身体用洗浄剤には、上記成分の他に、必要に応じて、高級アルコール、糖、グリセリン等の透明化剤、トコフェノール、BHA、BHT等の抗酸化剤、EDTA塩等のキレート化剤、香料、色素、ビタミン類等を適宜配合することができる。   In addition to the above-mentioned components, the body cleaning agent of the present invention includes a clarifying agent such as higher alcohol, sugar and glycerin, an antioxidant such as tocophenol, BHA and BHT, and a chelate such as EDTA salt, if necessary. Agents, fragrances, pigments, vitamins and the like can be appropriately blended.

本発明の身体用洗浄剤は、蜂の子由来の油脂及び/又はその鹸化物を、主原料油脂(蜂の子由来の油脂以外の油脂)の合計量100質量部に対して1〜8質量部含有することが好ましく、2〜5質量部含有することがより好ましい。上記含有量が1質量部よりも少ないと、保湿性等の改善効果が充分に得られず、8質量部よりも多いと、蜂の子に由来する雑臭が感じられる傾向となるので、好ましくない。   The body cleaning agent of the present invention is 1 to 8 masses of bee-derived fats and / or saponified products thereof with respect to 100 parts by mass of the total amount of main raw material fats (oils and fats other than bee-derived fats and oils). It is preferable to contain part, and it is more preferable to contain 2-5 mass parts. When the content is less than 1 part by mass, a sufficient improvement effect such as moisture retention cannot be obtained, and when the content is more than 8 parts by mass, a miscellaneous odor derived from bees tends to be felt. Absent.

なお、本発明によれば、蜂の子から油脂を抽出又は分離する際に、例えば水を加えて加熱した場合などでは、水溶性の抽出成分が得られる場合がある。該水溶性の抽出成分は、他の用途に転用してもよいが、減圧濃縮して、本発明の身体用洗浄剤の製造工程における鹸化後に、添加してもよい。   In addition, according to this invention, when extracting or isolate | separating fats and oils from a bee, for example, when adding water and heating, a water-soluble extraction component may be obtained. The water-soluble extraction component may be diverted to other uses, but may be added after concentration under reduced pressure and saponification in the production process of the body washing agent of the present invention.

本発明の身体用洗浄剤は、固形石鹸などの固形状をなす製品としてもよく、ボディソープ、シャンプーなどの液状をなす製品としてもよい。なお、本発明において、身体用洗浄剤とは、人又は動物の身体を洗浄するために用いられる洗浄剤を意味する。例えば、化粧石鹸、洗顔石鹸、ボディソープ、シャンプー、浴用石鹸、ハンドソープ、手洗い用石鹸、デオドラント石鹸、薬用せっけん、殺菌石鹸などが含まれる。   The body cleaning agent of the present invention may be a solid product such as a soap, or a liquid product such as a body soap or shampoo. In the present invention, the body cleaning agent means a cleaning agent used for cleaning a human or animal body. For example, cosmetic soap, facial soap, body soap, shampoo, bath soap, hand soap, hand soap, deodorant soap, medicated soap, sterilizing soap and the like are included.

次に、本発明の身体用洗浄剤の製造方法について説明する。   Next, the manufacturing method of the body cleaning agent of this invention is demonstrated.

本発明の身体用洗浄剤の製造方法は、主原料油脂の鹸化物に、蜂の子由来の油脂及び/又はその鹸化物を添加するか、主原料油脂に蜂の子由来の油脂を配合して鹸化することを特徴とする。そこで、[1]蜂の子から油脂を得る工程と、[2]蜂の子由来の油脂及び/又はその鹸化物を用いて身体用洗浄剤を製造する工程について説明する。   In the method for producing a body cleaning agent of the present invention, a bee-derived oil and / or a saponified product thereof is added to a saponified product of a main raw material oil or fat, or a bee-derived oil and fat is added to a main raw material fat. It is characterized by saponifying. Therefore, [1] a process for obtaining fats and oils from bees and [2] a process for producing a body cleanser using fats and oils derived from bees and / or saponified products thereof will be described.

[1]蜂の子から油脂を得る工程
蜂の子から油脂を得る工程は、特に限定されないが、好ましくは下記の方法が採用できる。
[1] Step of obtaining fats and oils from beesaw The step of obtaining fats and oils from beeskins is not particularly limited, but preferably the following method can be employed.

(A)有機溶媒による抽出方法
蜂の子は生で使用することもできるが、ペースト状又は乾燥粉末に加工した方が、有機溶媒による抽出効率が高い。蜂の子を粉末化する方法は特に限定されないが、粉砕機でペースト状にした蜂の子を凍結乾燥して粉末化することが好ましい。凍結乾燥によれば、美容効果に優れる蛋白質、アミノ酸、ビタミン等の熱変性を抑制できるため、抽出した蜂の子油脂にこれらの美容成分を多く含有させることができる。
(A) Extraction method with organic solvent Although bees can be used raw, the extraction efficiency with an organic solvent is higher when processed into a paste or dry powder. The method for pulverizing the honeybee is not particularly limited, but it is preferable to freeze-dry the honeybee paste that has been made into a paste by a pulverizer. According to lyophilization, heat denaturation of proteins, amino acids, vitamins, and the like, which have excellent cosmetic effects, can be suppressed, so that many of these cosmetic ingredients can be contained in the extracted bee oleum fat.

蜂の子又は上記のような方法によって得られた加工物に、有機溶媒を加えて、混練し、蜂の子由来の油脂を有機溶媒に溶出させることができる。有機溶媒としては、メタノール、エタノール、プロパノール、ブタノール、アセトン及びヘキサンからなる群より選ばれた1種又はその混合物を好ましく用いることができる。蜂の子由来の油脂を含む有機溶媒は、遠心分離、ろ過、静置などの方法によって固形の残滓から分離し、液相として回収することができる。更に、前記回収物から有機溶媒を蒸発させると、目的とする蜂の子由来の油脂が得られる。   An organic solvent is added to a bee or a processed product obtained by the method as described above, followed by kneading, and the oil derived from the bee can be eluted in the organic solvent. As the organic solvent, one or a mixture selected from the group consisting of methanol, ethanol, propanol, butanol, acetone and hexane can be preferably used. The organic solvent containing the oil derived from the bees can be separated from the solid residue by a method such as centrifugation, filtration, or standing, and recovered as a liquid phase. Furthermore, when the organic solvent is evaporated from the recovered material, the desired bee-derived fats and oils are obtained.

(B)熱水による抽出法
蜂の子、もしくはそのペースト又は乾燥粉末等の加工物に水を加えて加熱すると、蜂の子由来の油脂が熱で融け出し、油脂と、水溶性の抽出液と、残滓とに分離する。これを静置すると、比重差によって油脂は上層に浮上し残滓は下層に沈むため、上層の油脂を分離して採取することができる。あるいは、油脂と、水溶性の抽出液と、残滓とが混合した抽出液を、遠心分離又はろ過することにより、油脂を採取することもできる。
(B) Extraction method with hot water When water is added to a bee or its processed product such as paste or dry powder and heated, the bee-derived oil and fat is melted by heat, and the oil and fat and water-soluble extract And the residue. When this is left standing, the fats and oils float to the upper layer and the residue sinks to the lower layer due to the difference in specific gravity, so that the upper layer of fats and oils can be separated and collected. Or fats and oils can also be extract | collected by centrifuging or filtering the extract which mixed fats and oils, a water-soluble extract, and the residue.

前記油脂抽出時の加熱温度は、75〜98℃とすることが好ましい。75℃よりも低いと油脂の抽出が不十分になり、98℃よりも高いとビタミン等の有効成分が変性しやすくなるので好ましくない。   It is preferable that the heating temperature at the time of oil extraction is 75 to 98 ° C. When the temperature is lower than 75 ° C., extraction of fats and oils is insufficient, and when the temperature is higher than 98 ° C., active ingredients such as vitamins are easily denatured.

(C)酵素による抽出法
蜂の子又はその加工物を構成するタンパク質をプロテアーゼによって酵素分解し、遊離した油脂を遠心分離、ろ過、静置分離によって回収した後、乾燥すれば、目的とする蜂の子由来の油脂が得られる。
(C) Extraction method by enzyme Enzymatic degradation of the protein that constitutes the bee or its processed product by protease, and the recovered oil is recovered by centrifugation, filtration, and stationary separation, and then dried to obtain the target bee. Oil derived from the pups is obtained.

蜂の子に作用させるプロテアーゼは、微生物由来、動物由来又は植物由来のいずれのものであってもよい。プロテアーゼは、粗酵素でも精製された酵素でもよく、またポリエチレングリコールなどで修飾されたものであってもよい。更に、2種類以上のプロテアーゼを組み合わせて用いても良い。   The protease that acts on the bees can be derived from microorganisms, animals, or plants. The protease may be a crude enzyme or a purified enzyme, or may be modified with polyethylene glycol or the like. Further, two or more kinds of proteases may be used in combination.

これら微生物、植物又は動物由来のプロテアーゼの内、特に微生物由来のプロテアーゼが好適に用いられる。また、微生物の中でもバチルス(Bacillus)属、パエニバチルス(Paenibacillus)属、アスペルギルス(Aspergillus)属、リゾプス(Rhizopus)属又はストレプトマイセス(Streptomyces)属の微生物を挙げることができ、更に好ましくはバチルス(Bacillus)属、パエニバチルス(Paenibacillus)属の微生物を挙げることができる。   Among these microorganism, plant or animal-derived proteases, particularly microorganism-derived proteases are preferably used. In addition, among microorganisms, microorganisms of the genus Bacillus, Paenibacillus, Aspergillus, Rhizopus or Streptomyces can be mentioned, and more preferably Bacillus. And microorganisms belonging to the genus Paenibacillus.

これら微生物の具体的な例として枯草菌(Bacillus subtilis)、バチルス ステアロサーモフィルス(Bacillus stearothermophilus)、バチルス リケニフォルミス(Bacillus licheniformis)、バチルス アルカロフィルス(Bacillus alcalophilus)、パエニバチルス ポリミキサ(Paenibacillus polymyxa)、アスペルギルス オリーゼ(Aspergillus oryzae)、アスペルギルス メレウス(Aspergillus melleus)、アスペルギルス ニガー(Aspergillus niger)、アスペルギルス ホエニシス(Aspergillus phoenicis)、アスペルギルス ソウヤ(Aspergillus sojae)、リゾプス ニベウス(Rhizopus niveus)、ストレプトマイセス グリセウス(Streptomyces griseus)を好適に挙げることができる。更に好適には、枯草菌、バチルス リケニフォルミス、アスペルギルス メレウスを挙げることができる。   Specific examples of these microorganisms include Bacillus subtilis, Bacillus stearothermophilus, Bacillus licheniformis, Bacillus alcalophilus, Paenibacillus polymyxa, Paenibacillus polymyxa, (Aspergillus oryzae), Aspergillus melleus, Aspergillus niger, Aspergillus phoenicis, Aspergillus sojae, Aspergillus rep Can be listed. More preferred examples include Bacillus subtilis, Bacillus licheniformis, and Aspergillus mereus.

これらのプロテアーゼを蜂の子に作用させる際のpHは、蜂の子の成分の安定性及びプロテアーゼの反応至適pH及び安定性を考慮して適宜決定することができる。更に、プロテアーゼを蜂の子に作用させる際の温度は、蜂の子の成分の安定性及びプロテアーゼの反応至適温度及び安定性を考慮して適宜決定することができる。また、金属塩、キレート剤、無機塩類など適宜加えても良い。   The pH at which these proteases act on bees can be appropriately determined in consideration of the stability of the components of the bees and the optimum pH and stability of the protease reaction. Furthermore, the temperature at which the protease is allowed to act on the bee can be appropriately determined in consideration of the stability of the components of the bee and the optimum reaction temperature and stability of the protease. Moreover, you may add suitably a metal salt, a chelating agent, inorganic salts, etc.

[2]蜂の子由来の油脂及び/又はその鹸化物を用いて身体用洗浄剤を製造する工程
この工程としては、例えば次の方法が挙げられる。
(a)主原料油脂の鹸化物に、蜂の子由来の油脂を添加する方法。
(b)蜂の子由来の油脂の鹸化物と、主原料油脂の鹸化物と混合する方法。
(c)蜂の子由来の油脂と主原料油脂を混合し、然る後に前記混合物を鹸化する方法。
(d)前記(b)又は(c)によって得られた鹸化物に、更に蜂の子由来の油脂を添加する方法。
[2] Process for producing body cleaning agent using oil and / or saponified product derived from bees and child This process includes, for example, the following method.
(A) A method of adding fats and oils derived from bees to saponified products of main raw material fats and oils.
(B) A method of mixing a saponified product of a bean-derived oil and a saponified product of a main raw material oil.
(C) A method in which fat and oil derived from bees and main raw material fat and oil are mixed, and then the mixture is saponified.
(D) A method of further adding bee-derived fats and oils to the saponified product obtained in (b) or (c).

本発明においては、前述したように、前記蜂の子由来の油脂及び/又はその鹸化物の添加量を、主原料油脂(蜂の子由来の油脂以外の油脂)の合計量を100質量部としたとき、1〜8質量部とすることが好ましく、2〜5質量部とすることが更に好ましい。   In the present invention, as described above, the addition amount of the fat and oil derived from the bees and / or the saponified product thereof is set to 100 parts by mass of the total amount of the main raw material fats and oils (oils and fats other than the fats and oils derived from the bees). When it does, it is preferable to set it as 1-8 mass parts, and it is still more preferable to set it as 2-5 mass parts.

本発明によれば、主原料油脂、又は主原料油脂に蜂の子由来の油脂を添加した油脂混合物をアルカリ剤と共に反応釜に投入し、撹拌しながら加熱して、鹸化することができる。   According to the present invention, the main raw material fat or oil, or a mixture of fats and oils obtained by adding bee-derived fats and oils to the main raw material fat can be put into the reaction kettle together with the alkali agent, and heated with stirring to saponify.

鹸化工程において不飽和脂肪酸が酸化されると、生成された過酸化物、酸、アルデヒド類が皮膚を刺激してスキントラブルを起こしたり、製品が変色したり、腐敗臭を放つなどの品質が低下するため、反応釜に窒素等の不活性ガスを導入し、不飽和脂肪酸の酸化を抑制することが好ましい。   When unsaturated fatty acids are oxidized in the saponification process, the generated peroxides, acids, and aldehydes will irritate the skin, causing skin troubles, discoloration of the product, and the odor of spoilage. Therefore, it is preferable to introduce an inert gas such as nitrogen into the reaction kettle to suppress the oxidation of the unsaturated fatty acid.

上記鹸化工程において、中和反応は50〜80℃で行うことが好ましく、55〜65℃で行うことが特に好ましい。中和温度が60℃よりも高いと脂肪酸の酸化が進行し易くなり、中和温度が40℃未満であると、原料油脂の融点によっても異なるが、中和不十分となって未反応の脂肪酸が多く残る。鹸化後に塩化ナトリウム水溶液を加えて塩析し、未反応の油脂を減らすことができるが、蜂の子由来の有効成分(美容成分)も減少するため、好ましくない。塩析する場合は、上記(a)のように、主原料油脂を鹸化した後に蜂の子由来の油脂を添加する方法、又は、上記(d)のように蜂の子由来の油脂を添加して失われた美容成分を補充する方法を採用することが好ましい。   In the saponification step, the neutralization reaction is preferably performed at 50 to 80 ° C, particularly preferably at 55 to 65 ° C. When the neutralization temperature is higher than 60 ° C., the oxidation of fatty acid is likely to proceed. When the neutralization temperature is lower than 40 ° C., the neutralization is insufficient and the unreacted fatty acid is different depending on the melting point of the raw oil and fat. Many remain. After saponification, an aqueous sodium chloride solution is added for salting out to reduce unreacted oils and fats, but this is not preferable because the active ingredients (beauty ingredients) derived from bees are also reduced. In the case of salting out, a method of adding oil derived from bees after saponifying main raw material fats and oils as in (a) above, or adding fats and oils derived from bees like in (d) above. It is preferable to employ a method of replenishing lost cosmetic ingredients.

以上は、原料を加熱して鹸化する釜炊き鹸化法について説明したが、鹸化方法は釜炊き鹸化法に限定されず、原料を加熱しない冷製法を用いてもよい。   The above has described the pot-saponified saponification method in which the raw material is heated to saponify, but the saponification method is not limited to the pot-cooked saponification method, and a cold production method in which the raw material is not heated may be used.

以下に実施例を挙げて本発明について更に具体的に説明する。   Hereinafter, the present invention will be described in more detail with reference to examples.

[実施例1]
以下の工程によって、蜂の子由来の油脂の配合量が3質量%の身体用洗浄剤(化粧石鹸)を製造した。
[Example 1]
The body cleaning agent (cosmetic soap) having a blending amount of oil and fat derived from bees was 3% by mass by the following steps.

(蜂の子由来の油脂の抽出工程)
台湾産のミツバチ科の女王蜂の幼虫を調理用ミキサー機でペースト状にした後、凍結乾燥して粉末化した。この乾燥粉末100質量部を浄水900質量部に懸濁し、2N NaOHでpH7に調整後、枯草菌由来のプロテアーゼ1質量部を添加し、40℃で16時間静置して酵素分解すると、上層の油相と下層の水相とに分離した。蜂の子由来の油脂は油相に含まれているため、油相を回収した。前記回収した油相は、90℃で10分間加熱処理して酵素を失活させた後、凍結乾燥して蜂の子由来の油脂を粉末化した。
(Extraction process of oil derived from bees)
A honeybee queen larva from Taiwan was made into a paste using a cooking mixer and then freeze-dried to a powder. 100 parts by mass of this dry powder was suspended in 900 parts by mass of purified water, adjusted to pH 7 with 2N NaOH, added with 1 part by mass of protease derived from Bacillus subtilis, and allowed to stand at 40 ° C. for 16 hours for enzymatic degradation. It separated into an oil phase and a lower aqueous phase. Since the fat and oil derived from bees was contained in the oil phase, the oil phase was recovered. The recovered oil phase was heat-treated at 90 ° C. for 10 minutes to inactivate the enzyme, and then freeze-dried to powder the oil derived from bees.

(身体用洗浄剤の製造工程)
牛脂80質量部、ヤシ油20質量部(主原料油脂の合計100質量部)に、エタノール20質量部を加え、窒素ガス雰囲気下の反応釜中で、55℃で加熱混合した。これに別途水酸化トリウム及び水を、10分間かけて少しずつ滴下し、温度を65℃に保ちながら、中和反応をさせて、中和物を得た。反応終了後、温度を65℃に保ったままで、前記中和物に、蜂の子由来の油脂を3質量部、砂糖を11質量部、グリセリンを9質量部添加して溶解させ、身体用洗浄剤を得た。この身体用洗浄剤を枠に流し込み、冷却固化した後、切断、乾燥し、包装した。
(Manufacturing process of body cleaner)
20 parts by mass of ethanol was added to 80 parts by mass of beef tallow and 20 parts by mass of coconut oil (a total of 100 parts by mass of the main raw material oil), and the mixture was heated and mixed at 55 ° C. in a reaction kettle under a nitrogen gas atmosphere. Separately, thorium hydroxide and water were added dropwise little by little over 10 minutes, and a neutralization reaction was carried out while maintaining the temperature at 65 ° C. to obtain a neutralized product. After completion of the reaction, with the temperature kept at 65 ° C., 3 parts by weight of bees-derived fats and oils, 11 parts by weight of sugar and 9 parts by weight of glycerin are added to and dissolved in the neutralized product to wash the body. An agent was obtained. The body cleaner was poured into a frame, cooled and solidified, then cut, dried and packaged.

[実施例2]
蜂の子由来の油脂の添加量を5質量部に変更し、他は実施例1と同様にして、身体用洗浄剤(化粧石鹸)を製造した。
[Example 2]
The addition amount of fat and oil derived from bees was changed to 5 parts by mass, and the rest was manufactured in the same manner as in Example 1 to produce a body detergent (cosmetic soap).

[比較例1]
蜂の子由来の油脂を含まない(配合量0質量%)身体用洗浄剤(化粧石鹸)を製造した。牛脂80質量部及びヤシ油20質量部に、エタノール20質量部を加え、実施例1と同様にして鹸化反応させて、身体用洗浄剤を製造した。
[Comparative Example 1]
A body-cleaning agent (cosmetic soap) that does not contain bee-derived fats and oils (formulation amount 0 mass%) was produced. 20 parts by mass of ethanol was added to 80 parts by mass of beef tallow and 20 parts by mass of coconut oil, and a saponification reaction was carried out in the same manner as in Example 1 to produce a body cleaner.

以下、身体用洗浄剤の評価結果について説明する。   Hereinafter, the evaluation results of the body cleaner will be described.

[肌の水分量の評価1]
実施例1及び2と、比較例1で製造した身体用洗浄剤による、洗顔後の肌水分量を、角層膜厚・水分計(ASAHIBIOMED社製、型式「ASA−M1」)を用いて評価した。
[Evaluation of skin moisture content 1]
The skin moisture content after washing with the body cleaners produced in Examples 1 and 2 and Comparative Example 1 was evaluated using a stratum corneum film thickness / moisture meter (model “ASA-M1” manufactured by ASAHIBIOMED). did.

対象者として、30代男性1名、40代男性1名、50代男性1名を選び、1日当たり1回の洗顔を3日間実施し、洗顔前、洗顔5分後、洗顔30分後について、対象者の頬中央部の水分量を測定した。   Select one male in their 30s, one male in their 40s, and one male in their 50s, and carry out a face wash once a day for 3 days, before face washing, 5 minutes after face washing, and 30 minutes after face washing. The amount of water in the center of the cheek of the subject was measured.

図1には、蜂の子由来の油脂の配合率を変え、洗顔後の経過時間に対して肌の水分量を調べた結果が3名の平均値として示されている。水分量は、洗顔前の値を100%とし、洗顔5分後及び洗顔30分後の水分量を、洗顔前の値に対する相対値で表されている。   In FIG. 1, the result of examining the moisture content of the skin with respect to the elapsed time after the face washing is shown as an average value of three persons by changing the blending ratio of the oil derived from bees. The amount of water is expressed as a value relative to the value before the face washing, with the value before the face washing being 100% and the water amount after 5 minutes after the face washing and 30 minutes after the face washing.

蜂の子由来の油脂の配合率が0質量%の場合(比較例1)は、30分後に肌の平均水分量は63%まで低下し、肌がつっぱった感じになった。蜂の子由来の油脂の配合率が3%(主原料油脂100質量部に対して3質量部)の場合(実施例1)は、30分後に肌の平均水分量は137%まで上昇し、保湿力に改善が見られた。蜂の子由来の油脂の配合率が5%(主原料油脂100質量部に対して5質量部)の場合(実施例2)は、30分後に肌の平均水分量は226%まで上昇しており、保湿力が大幅に上がって、肌がしっとりし、すべすべ感やつるつる感が生まれた。   When the blending ratio of the oil derived from bees was 0% by mass (Comparative Example 1), after 30 minutes, the average moisture content of the skin decreased to 63%, and the skin became tight. In the case where the blending ratio of the oil derived from beesko is 3% (3 parts by mass with respect to 100 parts by mass of the main raw material oil and fat) (Example 1), the average moisture content of the skin rises to 137% after 30 minutes, There was an improvement in moisture retention. When the blending ratio of the fat derived from beesko is 5% (5 parts by mass with respect to 100 parts by mass of the main raw material fat and oil) (Example 2), the average moisture content of the skin increases to 226% after 30 minutes. As a result, the moisturizing power was greatly improved, the skin was moist, and a smooth and smooth feeling was born.

[肌の水分量の評価2]
対象者を男性5名、女性5名の計10名とし、洗顔前、洗顔5分後、洗顔10分後について、前記評価1と同様にして、対象者の頬中央部の水分量を測定した。
[Evaluation of skin moisture content 2]
The subjects were 5 men and 5 women in total, and the amount of water in the center of the cheek of the subject was measured in the same manner as in Evaluation 1 before washing, 5 minutes after washing, and 10 minutes after washing. .

図2には、蜂の子由来の油脂の配合しない場合(0質量%)と3%(主原料油脂100質量部に対して3質量部)配合した場合について、洗顔後の経過時間に対して肌の水分量を調べた結果を、10名の平均値として示した。洗顔効果に個人差はあるものの、母数を増やし、平均した結果で比較すれば、蜂の子由来の油脂の配合した石鹸で洗顔した方が、肌の保湿性が向上する結果となった。   FIG. 2 shows the elapsed time after washing the face when no bee-derived fats and oils are blended (0% by mass) and 3% (3 parts by mass with respect to 100 parts by mass of the main raw material fats and oils). The result of examining the moisture content of the skin was shown as the average value of 10 people. Although there are individual differences in the facial cleansing effect, when the population was increased and the average results were compared, it was found that the skin moisturizing property was improved when the face was washed with soap containing oil derived from bees.

[顕微鏡観察による肌の状態分析]
肌の水分量の評価1と同時に実施した、肌の顕微鏡観察の結果について説明する。図3には顕微鏡によって肌を50倍に拡大した写真、図4には200倍に拡大した写真した写真が示されている。洗顔前の肌において、倍率50倍では分かり難いが、倍率200倍では角層が捲れて肌荒れした箇所(写真中では矢印で示される場所)が随所に見られる。蜂の子由来の油脂の配合しない場合(0質量%)は、洗顔した後でも角層の捲れがまだ残っている。一方、蜂の子由来の油脂を配合(3質量%と5質量%)した場合は、洗顔した後では捲れていた角層が洗い落とされ、肌荒れしていた箇所が分からなくなっている。このように、本発明の洗浄剤は、蜂の子由来の油脂を配合することにより、角層を整える効果が生まれている。
[Skin condition analysis by microscopic observation]
The result of the microscopic observation of the skin carried out simultaneously with the evaluation 1 of the skin moisture amount will be described. FIG. 3 shows a photograph of the skin magnified 50 times with a microscope, and FIG. 4 shows a photograph of the photograph magnified 200 times. On the skin before face washing, it is difficult to understand at a magnification of 50 times, but at a magnification of 200 times, the stratum corneum is drowned and rough skin (locations indicated by arrows in the photograph) can be seen everywhere. In the case where the fat and oil derived from bees was not blended (0% by mass), the stratum corneum still remains even after face washing. On the other hand, when oils and fats derived from bees were blended (3% by mass and 5% by mass), the stratum corneum that had been drowned after washing the face was washed away, and the parts that had become rough were not known. Thus, the cleaning agent of the present invention has the effect of adjusting the stratum corneum by blending the bees-derived oils and fats.

[使用感アンケート]
下記表1には、使用感アンケートの各質問に対する回答分布と、その分布に重みづけをして得られる5段階評価(++、+、0、−、−−)が示されている。
[Usage survey]
Table 1 below shows the answer distribution for each question in the usability questionnaire and the five-level evaluation (++, +, 0, −, −−) obtained by weighting the distribution.

表1の結果から、蜂の子由来の油脂を添加しても、泡の細かさは、石鹸素地の良い点をそのまま残し、特に悪影響は見られない。泡切れは、石鹸素地の良い点をそのまま残し、特に悪影響は見られない。保湿感は、いずれも好結果になっている。   From the results shown in Table 1, even when the bees-derived fats and oils are added, the fineness of the foam leaves the good point of the soap base as it is and no particular adverse effect is observed. Foam cutting leaves the good point of the soap base as it is, and no particular adverse effect is seen. Both moisturizing feelings have been successful.

肌の状態については、「しっとり」、「すべすべ」、「つるつる」、「ハリが出た」という回答は「良い」の範疇に含め、「つっぱる」等の回答は「悪い」の範疇に含めた。蜂の子由来の油脂を配合した洗浄剤は、同油脂を配合しないものより、良好な結果が得られている。   Regarding the condition of the skin, “moist”, “smooth”, “smooth”, “smooth” answers were included in the “good” category, and “smooth” responses were included in the “bad” category. . The cleaning agent containing the oil derived from the bees has better results than those not containing the oil.

Claims (13)

主原料油脂の鹸化物と、蜂の子由来の油脂及び/又はその鹸化物とを含有することを特徴とする身体用洗浄剤。   A body cleanser comprising a saponified product of a main raw material oil and fat, a fat and fat derived from bees and / or a saponified product thereof. 前記蜂の子由来の油脂及び/又はその鹸化物の含有量が、前記主原料油脂の合計量100質量部に対して、1〜8質量部である請求項1に記載の身体用洗浄剤。   2. The body cleanser according to claim 1, wherein the content of the fat and / or saponified product derived from the bees is 1 to 8 parts by mass with respect to 100 parts by mass of the total amount of the main raw material fat and oil. 前記蜂の子は、女王蜂の幼虫及び/又は蛹である請求項1又は2に記載の身体用洗浄剤。   The body cleaning agent according to claim 1 or 2, wherein the bee cub is a queen bee larva and / or a moth. 蜂の子由来の油脂及び/又はその鹸化物以外に、牛脂、豚脂、ヤシ油、パーム油、オリーブ油、大豆油、落花生油、綿実油、ヒマシ油、ゴマ油、ナタネ油、キリ油、シソ油、ヒマワリ油、ブドウ種子油、アボガド油、サザンカ油、茶実油、椿油、馬油から選ばれた少なくとも1種からなる主原料油脂の鹸化物を含有する請求項1〜3のいずれか1項に記載の身体用洗浄剤。   In addition to bees and fats and / or saponified products thereof, beef tallow, lard, palm oil, palm oil, olive oil, soybean oil, peanut oil, cottonseed oil, castor oil, sesame oil, rapeseed oil, drill oil, perilla oil, The saponified product of at least one main raw material fat selected from sunflower oil, grape seed oil, avocado oil, sasanqua oil, tea seed oil, coconut oil, and horse oil. The body cleaner as described. 主原料油脂の鹸化物に、蜂の子由来の油脂及び/又はその鹸化物を添加するか、主原料油脂に蜂の子由来の油脂を配合して鹸化することを特徴とする身体用洗浄剤の製造方法。   A saponification product for saponification of saponified products of main raw material fats and oils, wherein saponified oils and / or saponified products thereof are added, or saponified products of bee products are added to main raw material fats and oils. Manufacturing method. 蜂の子又はその加工物に有機溶媒を加えて油脂を抽出した後、有機溶媒を蒸発させて、前記蜂の子由来の油脂を得る請求項5記載の身体用洗浄剤の製造方法。   The manufacturing method of the body washing | cleaning agent of Claim 5 which obtains the fats and oils derived from the said bee child by evaporating an organic solvent after adding an organic solvent to a bee child or its processed material. 前記有機溶媒は、メタノール、エタノール、プロパノール、ブタノール、アセトン及びヘキサンからなる群より選ばれた1種又はその混合物である請求項6に記載の身体用洗浄剤の製造方法。   The method for producing a body washing agent according to claim 6, wherein the organic solvent is one selected from the group consisting of methanol, ethanol, propanol, butanol, acetone, and hexane, or a mixture thereof. 蜂の子又はその加工物に水を加えて加熱することにより油脂を抽出し、得られた油脂を分離することにより、前記蜂の子由来の油脂を得る請求項5記載の身体用洗浄剤の製造方法。   6. The body cleaning agent according to claim 5, wherein oil or fat is extracted by adding water to a bee or a processed product thereof and heating to obtain the oil and fat derived from the bee. Production method. 前記油脂抽出時の加熱温度は、75〜98℃とする請求項8に記載の身体用洗浄剤の製造方法。   The manufacturing method of the body washing | cleaning agent of Claim 8 which sets the heating temperature at the time of the said fats and oils to 75-98 degreeC. 蜂の子又はその加工物をプロテアーゼによって酵素分解し、遊離した油脂を乾燥させて蜂の子由来の油脂を得る請求項5記載の身体用洗浄剤の製造方法。   The method for producing a body cleaner according to claim 5, wherein the bee or the processed product thereof is enzymatically decomposed with a protease, and the released fats and oils are dried to obtain fats and oils derived from bees. 前記蜂の子由来の油脂の配合量を、前記主原料油脂の合計量100質量部に対して、1〜8質量部とする請求項5〜10のいずれか1項に記載の身体用洗浄剤の製造方法。   The amount of the fats and oils derived from the bees is 1 to 8 parts by mass with respect to 100 parts by mass of the total amount of the main raw material fats and oils. Manufacturing method. 前記蜂の子として、女王蜂の幼虫及び/又は蛹を用いる請求項5〜11のいずれか1項に記載の身体用洗浄剤の製造方法。   The method for producing a body cleaning agent according to any one of claims 5 to 11, wherein a queen bee larva and / or a moth is used as the bee cub. 前記主原料油脂として、牛脂、豚脂、ヤシ油、パーム油、オリーブ油、大豆油、落花生油、綿実油、ヒマシ油、ゴマ油、ナタネ油、キリ油、シソ油、ヒマワリ油、ブドウ種子油、アボガド油、サザンカ油、茶実油、椿油、馬油から選ばれた少なくとも1種を用いる請求項5〜12のいずれか1項に記載の身体用洗浄剤の製造方法。
The main raw material fats and oils include beef tallow, lard, palm oil, palm oil, olive oil, soybean oil, peanut oil, cottonseed oil, castor oil, sesame oil, rapeseed oil, tung oil, perilla oil, sunflower oil, grape seed oil, avocado oil The manufacturing method of the body washing | cleaning agent of any one of Claims 5-12 using at least 1 sort (s) chosen from sasanka oil, tea seed oil, coconut oil, and horse oil.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020196583A1 (en) * 2019-03-26 2020-10-01 株式会社山田養蜂場本社 Method for producing enzymolyzed honeybee larvae

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001204421A (en) * 1999-11-18 2001-07-31 Hisako Kasuga Powder of queen-bee larva, powder of worker bee pupa, and method for producing them
JP2013018940A (en) * 2011-07-14 2013-01-31 Asahi Kosan Kk Solid soap and method of manufacturing the same
JP2013082701A (en) * 2011-09-30 2013-05-09 Yamada Bee Farm Corp Gnetum gnemon composition including apiculture product

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001204421A (en) * 1999-11-18 2001-07-31 Hisako Kasuga Powder of queen-bee larva, powder of worker bee pupa, and method for producing them
JP2013018940A (en) * 2011-07-14 2013-01-31 Asahi Kosan Kk Solid soap and method of manufacturing the same
JP2013082701A (en) * 2011-09-30 2013-05-09 Yamada Bee Farm Corp Gnetum gnemon composition including apiculture product

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020196583A1 (en) * 2019-03-26 2020-10-01 株式会社山田養蜂場本社 Method for producing enzymolyzed honeybee larvae

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