JPH07179895A - Soap - Google Patents

Soap

Info

Publication number
JPH07179895A
JPH07179895A JP35482193A JP35482193A JPH07179895A JP H07179895 A JPH07179895 A JP H07179895A JP 35482193 A JP35482193 A JP 35482193A JP 35482193 A JP35482193 A JP 35482193A JP H07179895 A JPH07179895 A JP H07179895A
Authority
JP
Japan
Prior art keywords
soap
honey
germanium
organogermanium
organic germanium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP35482193A
Other languages
Japanese (ja)
Inventor
Yuko Hochido
雄幸 寳地戸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kojundo Kagaku Kenkyusho KK
Original Assignee
Kojundo Kagaku Kenkyusho KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kojundo Kagaku Kenkyusho KK filed Critical Kojundo Kagaku Kenkyusho KK
Priority to JP35482193A priority Critical patent/JPH07179895A/en
Publication of JPH07179895A publication Critical patent/JPH07179895A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/38Products in which the composition is not well defined

Abstract

PURPOSE:To prepare a soap which is less irritant to the skin and gives no feel of roughness to the skin during use and offers feel of refreshment after use. CONSTITUTION:A soap comprising an organogermanium. The soap may be a honey soap comprising honey collected after giving a feed containing an organogermanium to honeybees. The organogermanium is preferably a water-soluble one, such as L-arginine germanium or L-lysine germanium, with carboxyethyl germanium sesquioxide being particularly preferred.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、洗浄用石鹸に関し、さ
らに詳細には低刺激性で、使用中はきしみ感がなく、使
用後はさっぱり感に優れ、皮膚の洗浄に好適な石鹸に関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a soap for washing, and more particularly to a soap which is hypoallergenic, has no squeaky feeling during use, and has a refreshing feeling after use and is suitable for cleaning skin. Is.

【0002】[0002]

【従来の技術】従来、低刺激性石鹸としては、ラウリル
硫酸ナトリウムなどの中性に近い陰イオン性界面活性
剤、N−アシルグルタミン酸ナトリウムなどの弱酸性界
面活性剤等を含有した石鹸が知られている。
2. Description of the Related Art Conventionally, as a mild soap, a soap containing a near neutral anionic surfactant such as sodium lauryl sulfate and a weakly acidic surfactant such as sodium N-acylglutamate is known. ing.

【0003】また、石鹸中に含まれる遊離アルカリの影
響を低減する目的で、脂肪酸トリエタノールアミン塩を
基剤として使用した洗浄剤も知られている。さらに、石
鹸基剤にスルホコハク酸アルキルエステルまたはそのエ
チレンオキシド付加物の塩を加えた石鹸も知られてい
る。
Further, a detergent using a fatty acid triethanolamine salt as a base is also known for the purpose of reducing the influence of free alkali contained in soap. Furthermore, soaps in which a salt of sulfosuccinic acid alkyl ester or its ethylene oxide adduct is added to a soap base are also known.

【0004】[0004]

【発明が解決しようとする課題】これら従来の低刺激性
石鹸は、洗浄力が強すぎる、pHが8〜9でアルカリ性
が強い等、刺激性という点で未だ満足できるものではな
く、さらに使用中にべたつき感やぬめり感があったり、
乾燥後につっぱり感やかさつき感がするなど、使用感の
面でも問題があった。したがって、低刺激性で、かつ使
用感に優れた石鹸が望まれていた。
These conventional hypoallergenic soaps are still unsatisfactory in terms of irritation, such as excessively detergency, pH 8 to 9 and strong alkalinity, and they are still in use. There is a sticky feeling and slimy feeling,
There was also a problem in terms of usability such as a feeling of tightness and bulkiness after drying. Therefore, a soap that is low in irritation and excellent in feeling of use has been desired.

【0005】[0005]

【課題を解決するための手段】本発明者は、かかる実情
に鑑み鋭意研究を行った結果、有機ゲルマニウムを石鹸
に配合すれば、従来の石鹸に比較し低刺激であり、しか
も使用中のきしみ感がなく、使用後はさっぱりとした感
触が得られることを見出し、本発明を完成するに至っ
た。
Means for Solving the Problems As a result of intensive studies in view of such circumstances, the present inventor has found that when organic germanium is blended with soap, it is less irritating than conventional soaps and squeaks during use. It was found that there was no feeling and a refreshing feel was obtained after use, and the present invention was completed.

【0006】本発明において用いられる有機ゲルマニウ
ムは水溶性であることが好ましい。水溶性有機ゲルマニ
ウムとしてはL−アルギニンゲルマニウム、L−リジン
ゲルマニウム等があるが、特にカルボキシエチルゲルマ
ニウム三二酸化物で化学式(GeCHCHCOO
H)が好ましい。
The organic germanium used in the present invention is preferably water-soluble. The water-soluble organic germanium is L- arginine germanium, L- lysine germanium, etc., but especially formula carboxyethyl germanium sesquioxide (GeCH 2 CH 2 COO
H) 2 O 3 is preferred.

【0007】元来、このカルボキシエチルゲルマニウム
三二酸化物は癌の治験薬として開発されたものであり、
また、人体の皮膚から非常によく吸収されることが証明
されている。したがって、この有機ゲルマニウムを溶か
したお湯に手、足をひたす温浴治療法では、疲労、不眠
症、夜間多尿症、冷症、肥満、神経痛、腰痛、肩こり、
便秘、痔、しもやけ、水虫等に効果があることが知られ
ている。
Originally, this carboxyethyl germanium sesquioxide was developed as an investigational drug for cancer,
It has also been shown to be very well absorbed through the skin of the human body. Therefore, in the hot bath treatment method in which the hands and feet are immersed in hot water containing this organic germanium, fatigue, insomnia, nocturia, coldness, obesity, neuralgia, low back pain, stiff shoulders,
It is known to be effective against constipation, hemorrhoids, sprouting and athlete's foot.

【0008】本発明は、石鹸中に有機ゲルマニウムを配
合したものおよび有機ゲルマニウムを添加配合した餌料
を蜜蜂に給餌し、その後採蜜したハチミツを含有させた
ハチミツ石鹸である。ハチミツ石鹸に対する有機ゲルマ
ニウムの配合量は0.01〜5重量%が好ましい。
The present invention is a honey soap containing honey which is obtained by feeding a bee containing a mixture of organic germanium and a mixture of organic germanium added to soap, and then containing the honey collected. The amount of the organic germanium compounded with respect to the honey soap is preferably 0.01 to 5% by weight.

【0009】有機ゲルマニウムを含有するハチミツの採
取法は、特許1685637号、特願平3−23860
1号、特願平3−302826号、特願平3−3338
54号、特願平3−338855号、特願平3−354
116号等に詳述されている方法と同様に、カルボキシ
エチルゲルマニウム三二酸化物とショ糖を水に溶解して
蜜蜂用餌料とし、この餌料を蜜蜂に給餌した後、蜜蜂が
貯蔵した貯蜜を採取することによって得られる。
A method for collecting honey containing organic germanium is disclosed in Japanese Patent No. 1685637 and Japanese Patent Application No. 23860/1990.
No. 1, Japanese Patent Application No. 3-302826, Japanese Patent Application No. 3-3338
54, Japanese Patent Application No. 3-338855, Japanese Patent Application No. 3-354
Similar to the method described in detail in No. 116, etc., carboxyethylgermanium sesquioxide and sucrose are dissolved in water to form a feed for honeybees. After feeding this feed to honeybees, the honey stored by the honeybees is stored. Obtained by collecting.

【0010】この場合、蜜蜂が持つ酵素で活性化された
有機ゲルマニウムが得られるが、採蜜したハチミツ中に
含まれる有機ゲルマニウムの量は給餌した有機ゲルマニ
ウムの量の80〜100%である。
In this case, the organic germanium activated by the enzyme possessed by the bee is obtained, and the amount of the organic germanium contained in the honey that has been harvested is 80 to 100% of the amount of the fed organic germanium.

【0011】本発明において、石鹸の基剤としては、例
えばラウリン酸、ミリスチン酸、パルミチン酸、ステア
リン酸等の高級脂肪酸、また、牛脂、豚脂等の動物性油
脂及びヤシ油、パーム油、大豆油等の植物性油脂を分解
して得られる脂肪酸等一般的な基剤が用いられる。
In the present invention, examples of the soap base include higher fatty acids such as lauric acid, myristic acid, palmitic acid and stearic acid, and animal oils and fats such as beef tallow and lard and coconut oil, palm oil and large oils. Common bases such as fatty acids obtained by decomposing vegetable oils such as soybean oil are used.

【0012】また、プロピレングリコール、グリセリン
等の保湿剤、高級アルコール、他のエステル、シリコン
等の油剤、アルキルアミンオキサイド、脂肪酸アルカノ
ールアマイド、イミダゾリン系両性界面活性剤等の界面
活性剤、シリコーン誘導体、スクワラン、ラノリン等の
感触向上剤、その他希釈剤、消炎剤、粘度調整剤、可溶
化剤、香料、色素、紫外線吸収剤、酸化防止剤、殺菌
剤、防腐剤等を配合することができる。
Further, moisturizing agents such as propylene glycol and glycerin, higher alcohols, other esters, oil agents such as silicon, alkylamine oxides, fatty acid alkanol amides, surfactants such as imidazoline-based amphoteric surfactants, silicone derivatives, squalane. , Lanolin and other texture-improving agents, as well as other diluents, anti-inflammatory agents, viscosity modifiers, solubilizing agents, fragrances, dyes, ultraviolet absorbers, antioxidants, bactericides, preservatives and the like.

【0013】[0013]

【実施例1】 以上を混合し加熱撹拌の後、枠に注入し、冷却固化、切
断の後、乾燥させて型打ちして固形石鹸を製造した。
[Example 1] The above was mixed, heated and stirred, poured into a frame, cooled and solidified, cut, dried, and stamped to produce solid soap.

【0014】[0014]

【実施例2】 を含有するハチミツ以上を混合し実施例1と同様にして
固形ハチミツ石鹸を製造した。
Example 2 The solid honey soap was manufactured in the same manner as in Example 1 by mixing the above ingredients containing honey.

【0015】[0015]

【比較例】[Comparative example]

以上を混合し実施例1と同様にして固形石鹸を製造し
た。
The above was mixed and the solid soap was manufactured in the same manner as in Example 1.

【0016】(評価方法)上記実施例1、実施例2、比
較例の石鹸について、パネラー10名により、水道水で
手洗い試験を行い、きしみ感のなさ及びさっぱり感につ
いて、以下の基準で判定した。 ◎非常に良好 ○良好 △普通 ×不良 その結果を次の表で示す。
(Evaluation method) The soaps of Examples 1 and 2 and Comparative Example were subjected to a hand-washing test with tap water by 10 panelists, and the squeaky feeling and the refreshing feeling were judged according to the following criteria. . ◎ Very good ○ Good △ Normal × Poor The results are shown in the following table.

【0017】[0017]

【表1】 [Table 1]

【0018】表1から明かなように、本発明になる石鹸
は、使用中にきしみ感がなく、使用後はさっぱりとした
使用感を有する優れたものであった。また、実施例1と
実施例2の本発明品を4名づつ計8名のパネラーに一週
間、体洗いに使用してもらったが、いずれも肌荒れ等の
刺激は全く認められなかった。
As can be seen from Table 1, the soap according to the present invention was excellent in that it had no squeaky feeling during use and a refreshing feeling after use. Further, the present invention products of Example 1 and Example 2 were used by 4 panelists of 4 persons for a week for body washing, but no irritation such as rough skin was observed at all.

【0019】[0019]

【発明の効果】本発明の石鹸は、低刺激性であり、使用
中はきしみ感がなく、滑らかな感触を有し、使用後はさ
っぱりした感触が得られるため、皮膚の洗浄に好適なも
のである。また、本発明の石鹸は、低刺激性であるた
め、特に刺激に対して敏感な皮膚を有する人には好適で
ある。さらに、本発明になる石鹸に含有されている有機
ゲルマニウムは皮膚から非常によく吸収される特徴があ
る。
INDUSTRIAL APPLICABILITY The soap of the present invention is hypoallergenic, has no squeaky feeling during use, has a smooth feel, and provides a refreshing feel after use, and is therefore suitable for cleaning the skin. Is. Further, the soap of the present invention is hypoallergenic, and is therefore suitable for a person having a skin particularly sensitive to irritation. Furthermore, the organic germanium contained in the soap according to the present invention is characterized by being very well absorbed through the skin.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 有機ゲルマニウムを含有することを特徴
とする石鹸。
1. A soap containing organic germanium.
【請求項2】 有機ゲルマニウムを添加配合した餌料を
蜜蜂に給餌し、その後採蜜したハチミツを含有すること
を特徴とするハチミツ石鹸。
2. A honey soap characterized in that it comprises a honey that is fed with a feed containing organic germanium added thereto and then honey is collected.
JP35482193A 1993-12-22 1993-12-22 Soap Pending JPH07179895A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP35482193A JPH07179895A (en) 1993-12-22 1993-12-22 Soap

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP35482193A JPH07179895A (en) 1993-12-22 1993-12-22 Soap

Publications (1)

Publication Number Publication Date
JPH07179895A true JPH07179895A (en) 1995-07-18

Family

ID=18440132

Family Applications (1)

Application Number Title Priority Date Filing Date
JP35482193A Pending JPH07179895A (en) 1993-12-22 1993-12-22 Soap

Country Status (1)

Country Link
JP (1) JPH07179895A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100507901B1 (en) * 2002-06-28 2005-08-11 황만선 Manufacture method of aminoacid germanium soap
JP2009275200A (en) * 2008-05-19 2009-11-26 B Bee:Kk Method for producing honey soap
JP2011057765A (en) * 2009-09-07 2011-03-24 Yamada Bee Farm Corp Framed transparent bar soap

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100507901B1 (en) * 2002-06-28 2005-08-11 황만선 Manufacture method of aminoacid germanium soap
JP2009275200A (en) * 2008-05-19 2009-11-26 B Bee:Kk Method for producing honey soap
JP2011057765A (en) * 2009-09-07 2011-03-24 Yamada Bee Farm Corp Framed transparent bar soap

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