JP2016041681A - フッ素化有機化合物の製造方法、及びフッ素化試薬 - Google Patents

フッ素化有機化合物の製造方法、及びフッ素化試薬 Download PDF

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Publication number
JP2016041681A
JP2016041681A JP2015075179A JP2015075179A JP2016041681A JP 2016041681 A JP2016041681 A JP 2016041681A JP 2015075179 A JP2015075179 A JP 2015075179A JP 2015075179 A JP2015075179 A JP 2015075179A JP 2016041681 A JP2016041681 A JP 2016041681A
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Prior art keywords
group
substituents
pyridine
organic compound
examples
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JP2015075179A
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English (en)
Japanese (ja)
Inventor
昌弘 東
Masahiro Azuma
東　　昌弘
洋介 岸川
Yosuke Kishikawa
洋介 岸川
淳 白井
Atsushi Shirai
淳 白井
敬 並川
Takashi Namikawa
敬 並川
寿美 石原
Sumi Ishihara
寿美 石原
原　正治
Masaharu Hara
正治 原
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Daikin Industries Ltd
Hokkaido University NUC
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Daikin Industries Ltd
Hokkaido University NUC
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Priority to JP2015075179A priority Critical patent/JP2016041681A/ja
Publication of JP2016041681A publication Critical patent/JP2016041681A/ja
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C19/00—Acyclic saturated compounds containing halogen atoms
    • C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
    • C07C19/16—Acyclic saturated compounds containing halogen atoms containing fluorine and iodine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B39/00—Halogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
    • C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C23/00—Compounds containing at least one halogen atom bound to a ring other than a six-membered aromatic ring
    • C07C23/02—Monocyclic halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/22—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of halogens; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/287—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/307—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
    • C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
JP2015075179A 2014-04-02 2015-04-01 フッ素化有機化合物の製造方法、及びフッ素化試薬 Pending JP2016041681A (ja)

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JP2014076210 2014-04-02
JP2014169917 2014-08-22
JP2014169917 2014-08-22
JP2015075179A JP2016041681A (ja) 2014-04-02 2015-04-01 フッ素化有機化合物の製造方法、及びフッ素化試薬

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JP2017154640A Active JP6740192B2 (ja) 2014-04-02 2017-08-09 フッ素化有機化合物の製造方法、及びフッ素化試薬
JP2019087905A Pending JP2019137693A (ja) 2014-04-02 2019-05-07 フッ素化有機化合物の製造方法、及びフッ素化試薬
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018104408A (ja) * 2016-12-26 2018-07-05 ダイキン工業株式会社 ジフルオロメチレン化合物の製造方法
WO2022131378A1 (ja) * 2020-12-18 2022-06-23 ダイキン工業株式会社 フッ素化有機化合物の製造方法
JPWO2022163746A1 (enExample) * 2021-01-29 2022-08-04

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6974734B2 (ja) * 2018-04-25 2021-12-01 ダイキン工業株式会社 ジフルオロメチレン化合物の製造方法
CN112125773A (zh) * 2020-10-02 2020-12-25 中国船舶重工集团公司第七一八研究所 一种1,2,3,4-四氯六氟丁烷的制备方法
CN112321398B (zh) * 2020-11-06 2021-11-23 中山大学 一种通过腙化脂肪链单酮合成α-氟化酮的方法
JP7464867B2 (ja) 2022-07-05 2024-04-10 ダイキン工業株式会社 フッ素化有機化合物の製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001096263A1 (en) * 2000-06-13 2001-12-20 Daikin Industries, Ltd. Processes for the production of fluorinated organic compounds and fluorinating agents
JP2002363111A (ja) * 2001-05-31 2002-12-18 Daikin Ind Ltd フッ素化有機化合物の製造方法及びフッ素化試薬
JP2002363110A (ja) * 2001-05-31 2002-12-18 Daikin Ind Ltd フッ素化有機化合物の製造方法及びフッ素化試薬

Family Cites Families (4)

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Publication number Priority date Publication date Assignee Title
JP3931957B2 (ja) 2001-11-09 2007-06-20 ダイキン工業株式会社 五フッ化ヨウ素によるフッ素化スルフィド類の製造法
JP4940544B2 (ja) 2004-11-30 2012-05-30 ダイキン工業株式会社 五フッ化ヨウ素による含フッ素有機化合物の製造方法
JP2015075179A (ja) * 2013-10-09 2015-04-20 株式会社北川鉄工所 回転装置
JP6380429B2 (ja) * 2016-03-02 2018-08-29 トヨタ自動車株式会社 自動車

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001096263A1 (en) * 2000-06-13 2001-12-20 Daikin Industries, Ltd. Processes for the production of fluorinated organic compounds and fluorinating agents
JP2002363111A (ja) * 2001-05-31 2002-12-18 Daikin Ind Ltd フッ素化有機化合物の製造方法及びフッ素化試薬
JP2002363110A (ja) * 2001-05-31 2002-12-18 Daikin Ind Ltd フッ素化有機化合物の製造方法及びフッ素化試薬

Non-Patent Citations (7)

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Title
AYUBA, SHINICHI ET AL.: "Fluorination of sulfides using IF5-Et3N-3HF", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, vol. 75, no. 7, JPN6016026900, 2002, pages 1597 - 1603, XP093126682, ISSN: 0003358775 *
CHAMBERS, RICHARD D. ET AL.: "New fluorocarbon iodides", CHEMICAL COMMUNICATIONS, JPN6016026895, 2001, pages 2428 - 2429, ISSN: 0003358778 *
HARA, SHOJI ET AL.: "IF5-pyridine-HF: air- and moisture-stable fluorination reagent", TETRAHEDRON, vol. 68, no. 49, JPN6016026885, 2012, pages 10145 - 10150, XP055612631, ISSN: 0003358774, DOI: 10.1016/j.tet.2012.09.104 *
RE, SALVATORE ET AL.: "Fluorination for modern industry - A holistic approach", SPECIALITY CHEMICALS MAGAZINE, vol. 24, no. 2, JPN6016026887, 2004, pages 28 - 31, ISSN: 0003358776 *
ROZEN, SHLOMO ET AL.: "A new method for introducing iodo and bromo fluorides into organic molecules using elemental fluorin", JOURNAL OF ORGANIC CHEMISTRY, vol. 50巻, No.18, JPN6016026898, 1985, pages 3342 - 3348, ISSN: 0003358779 *
ROZEN, SHLOMO ET AL.: "A novel method for preparation of vicinal fluoroiodo compounds using elemental fluorine", TETRAHEDRON LETTERS, vol. 21, no. 47, JPN6016026901, 1980, pages 4543 - 4546, ISSN: 0003358780 *
YONEDA, NORIHIKO ET AL.: "Novel fluorination reagent: IF5/Et3N-3HF", CHEMISTRY LETTERS, JPN6016026890, 2001, pages 222 - 223, ISSN: 0003358777 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018104408A (ja) * 2016-12-26 2018-07-05 ダイキン工業株式会社 ジフルオロメチレン化合物の製造方法
JP7057489B2 (ja) 2016-12-26 2022-04-20 ダイキン工業株式会社 ジフルオロメチレン化合物の製造方法
WO2022131378A1 (ja) * 2020-12-18 2022-06-23 ダイキン工業株式会社 フッ素化有機化合物の製造方法
JPWO2022131378A1 (enExample) * 2020-12-18 2022-06-23
JP7704380B2 (ja) 2020-12-18 2025-07-08 ダイキン工業株式会社 フッ素化有機化合物の製造方法
JPWO2022163746A1 (enExample) * 2021-01-29 2022-08-04
JP7779271B2 (ja) 2021-01-29 2025-12-03 Ａｇｃ株式会社 水素還元反応によるハイドロフルオロカーボンの製造方法

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JP7076724B2 (ja) 2022-05-30
JP2019137693A (ja) 2019-08-22
JP2021121640A (ja) 2021-08-26
JP6740192B2 (ja) 2020-08-12
JP2017203041A (ja) 2017-11-16
US20150315136A1 (en) 2015-11-05

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