JP2016005583A - アルキレングリコールを含むエアゾール臭気除去組成物 - Google Patents
アルキレングリコールを含むエアゾール臭気除去組成物 Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims abstract description 134
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- -1 alkylene glycol Chemical compound 0.000 title claims abstract description 46
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title claims abstract description 24
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000004094 surface-active agent Substances 0.000 claims abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
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- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 61
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- 239000007789 gas Substances 0.000 claims description 20
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 9
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- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 7
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 7
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- 229910052783 alkali metal Inorganic materials 0.000 claims description 6
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 4
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- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
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- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000003570 air Substances 0.000 claims description 2
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- 150000003333 secondary alcohols Chemical class 0.000 claims 2
- 239000001509 sodium citrate Substances 0.000 claims 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 1
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- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
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- PUSPAPGHKSLKKH-UHFFFAOYSA-N 2-methyl-1,2-thiazolidin-3-one Chemical compound CN1SCCC1=O PUSPAPGHKSLKKH-UHFFFAOYSA-N 0.000 description 1
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- AJBZENLMTKDAEK-UHFFFAOYSA-N 3a,5a,5b,8,8,11a-hexamethyl-1-prop-1-en-2-yl-1,2,3,4,5,6,7,7a,9,10,11,11b,12,13,13a,13b-hexadecahydrocyclopenta[a]chrysene-4,9-diol Chemical compound CC12CCC(O)C(C)(C)C1CCC(C1(C)CC3O)(C)C2CCC1C1C3(C)CCC1C(=C)C AJBZENLMTKDAEK-UHFFFAOYSA-N 0.000 description 1
- 241001133760 Acoelorraphe Species 0.000 description 1
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- 244000144725 Amygdalus communis Species 0.000 description 1
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- 240000003538 Chamaemelum nobile Species 0.000 description 1
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
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- 239000002386 air freshener Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
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- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
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- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
- Medicinal Preparation (AREA)
- Catching Or Destruction (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
ここでは、Kはヘンリーの法則の定数として知られている平衡定数、pは溶液上の臭気の分圧、cは溶液中の臭気の濃度である。
構成成分 重量%
逆浸透水 95.93
トリエチレングリコール(98%) 1.0
窒素ガス 0.68
プロピレングリコール 0.5
芳香剤 0.5
水素添加ひまし油60エトキシレート 0.47
リン酸水素二カリウム 0.32
第二級C6−C17アルコールエトキシレート(3−6EO) 0.28
リン酸二水素カリウム 0.17
防腐剤* 0.15
100%
*2−メチル−4−イソチアゾリン−3−オン
Claims (23)
- (a)約0.1から約10重量%の少なくとも1つのアルキレングリコールと、
(b)約0.1から約4重量%の少なくとも1つの界面活性剤であって、前記少なくとも1つの界面活性剤の1つ以上が約7から約20の親水親油バランス(HLB)を持つものと、
(c)室温で最大でおよそ180psigとなる約0.1から約5重量%の圧縮ガス噴射剤と、
(d)約0.01から約5重量%の緩衝系と、
(e)約0.01から約10重量%の少なくとも1つの芳香剤と、
(f)差引残の水と、
を含む、エアゾール臭気処理水性組成物であって、
前記組成物が揮発性有機化合物成分を組成物100重量%中5.0%未満含み、低分子量の1価アルコールを含まず、前記少なくとも1つの芳香剤が(i)前記少なくとも1つの界面活性剤、(ii)前記少なくとも1つのアルキレングリコール、又は(iii)前記少なくとも1つの界面活性剤と前記少なくとも1つのアルキレングリコールによって可溶化され、前記組成物のpHが約4から約8である組成物。 - 前記少なくとも1つのアルキレングリコールが約0.1から5重量%の量で存在する請求項1の組成物。
- 前記少なくとも1つのアルキレンが約0.5から1.5重量%の量で存在する請求項1に記載の組成物。
- 前記少なくとも1つのアルキレングリコールがプロピレングリコール、トリエチレングリコール、又はプロピレングリコールとトリエチレングリコールである請求項1の組成物。
- 前記圧縮ガス噴射剤が約0.1から約3.5重量%で存在する請求項1の組成物。
- 前記緩衝系がクエン酸、クエン酸化合物、又はクエン酸とクエン酸化合物の組み合わせである請求項1の組成物。
- 前記緩衝系がクエン酸と、アルカリ金属のクエン酸塩、リン酸水素二カリウム、リン酸二水素カリウム、重炭酸ナトリウム及びアルカリ金属の水酸化物の少なくとも1つとである請求項1の組成物。
- 前記緩衝系がクエン酸とクエン酸ナトリウムである請求項1の組成物。
- 前記緩衝系がクエン酸とリン酸水素二カリウムである請求項1の組成物。
- 前記緩衝系がリン酸水素二カリウムとリン酸二水素カリウムである請求項1の組成物。
- 前記HLBが約9から約18である請求項1の組成物。
- 前記HLBが約12から約16である請求項1の組成物。
- 前記少なくとも1つの非イオン性界面活性剤が、水素添加ひまし油エトキシレートと第二級アルコールエトキシレートである請求項1の組成物。
- 前記圧縮ガス噴射剤が、窒素、空気、亜酸化窒素、二酸化炭素、不活性ガス、又はそれら混合物である請求項1の組成物。
- 前記少なくとも1つのアルキレングリコールが約0.1から約3.0重量%のトリエチレングリコールと約0.1から約3.0重量%のプロピレングリコールを含む請求項1の組成物。
- 1つの防腐剤を更に含む請求項1の組成物。
- (a)約0.1から約10重量%のプロピレングリコール及び任意で少なくとも1つの追加のアルキレングリコールと、
(b)約0.1から約4重量%の少なくとも1つの界面活性剤であって、前記少なくとも1つの界面活性剤が水素添加ひまし油エトキシレートと第二級アルコールエトキシレートを含む2つの非イオン性界面活性剤を含むものと、
(c)室温で最大でおよそ180psigとなる少なくとも窒素を含む約0.1から約5重量%の圧縮ガス噴射剤と、
(d)約0.01から約10重量%の少なくとも1つの芳香剤と、
(e)約0.01から約5重量%の緩衝系と、
(f)差引残の水と、
を含む、エアゾール臭気処理水性組成物であって、
前記組成物が揮発性有機化合物成分を組成物100重量%中5.0%未満含み、低分子量の1価アルコールを含まず、前記少なくとも1つの芳香剤が前記2つの非イオン性界面活性剤と前記プロピレングリコールによって可溶化され、前記組成物のpHが約4から約8となる組成物。 - 前記少なくとも1つの追加アルキレングリコールとして、約0.1から約5重量%のトリエチレングリコールを更に含む請求項17の組成物。
- 前記緩衝系がクエン酸と、アルカリ金属のクエン酸塩、リン酸水素二カリウム、リン酸二水素カリウム、重炭酸ナトリウムとアルカリ金属の水酸化物の内の少なくとも1つとである請求項17の組成物。
- 前記緩衝系がクエン酸とクエン酸ナトリウムである請求項17の組成物。
- 前記緩衝系がクエン酸とリン酸水素二カリウムである請求項17の組成物。
- 前記緩衝系がリン酸水素二カリウムとリン酸二水素カリウムである請求項17の組成物。
- 防腐剤を更に含む請求項17の組成物。
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US12/801,640 US8287841B2 (en) | 2010-06-18 | 2010-06-18 | Aerosol odor eliminating compositions containing alkylene glycol(s) |
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AU2011265714B9 (en) | 2014-07-24 |
US20110311460A1 (en) | 2011-12-22 |
CN104606698A (zh) | 2015-05-13 |
BR112012032420B1 (pt) | 2018-05-08 |
CA2803097A1 (en) | 2011-12-22 |
US9987387B2 (en) | 2018-06-05 |
JP6085343B2 (ja) | 2017-02-22 |
CN103079601A (zh) | 2013-05-01 |
EP2582403B1 (en) | 2017-04-26 |
AU2014202918A1 (en) | 2014-06-19 |
ES2625075T3 (es) | 2017-07-18 |
JP2013529971A (ja) | 2013-07-25 |
EP2582403A1 (en) | 2013-04-24 |
CN104606698B (zh) | 2017-12-08 |
MX2012014886A (es) | 2013-05-09 |
MX346687B (es) | 2017-03-29 |
US20130001260A1 (en) | 2013-01-03 |
US8568703B2 (en) | 2013-10-29 |
AU2014202918B2 (en) | 2014-09-11 |
AU2011265714B2 (en) | 2014-03-20 |
BR112012032420A2 (pt) | 2015-10-06 |
US8287841B2 (en) | 2012-10-16 |
JP5795367B2 (ja) | 2015-10-14 |
US20140021226A1 (en) | 2014-01-23 |
WO2011159350A1 (en) | 2011-12-22 |
CN103079601B (zh) | 2015-03-11 |
AU2011265714A1 (en) | 2013-01-10 |
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