JP2015524008A - 一体型ホットメルト接着剤包装フィルムおよびその使用 - Google Patents
一体型ホットメルト接着剤包装フィルムおよびその使用 Download PDFInfo
- Publication number
- JP2015524008A JP2015524008A JP2015512674A JP2015512674A JP2015524008A JP 2015524008 A JP2015524008 A JP 2015524008A JP 2015512674 A JP2015512674 A JP 2015512674A JP 2015512674 A JP2015512674 A JP 2015512674A JP 2015524008 A JP2015524008 A JP 2015524008A
- Authority
- JP
- Japan
- Prior art keywords
- hot melt
- melt adhesive
- packaging film
- package
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004831 Hot glue Substances 0.000 title claims abstract description 90
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- 238000002844 melting Methods 0.000 claims abstract description 26
- 230000008018 melting Effects 0.000 claims abstract description 26
- 229920001155 polypropylene Polymers 0.000 claims abstract description 4
- 239000000853 adhesive Substances 0.000 claims description 31
- 229920002959 polymer blend Polymers 0.000 claims description 20
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 10
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 9
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims description 8
- 239000012943 hotmelt Substances 0.000 claims description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 7
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- -1 polypropylene Polymers 0.000 claims description 6
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- 239000005060 rubber Substances 0.000 claims description 5
- 229920006132 styrene block copolymer Polymers 0.000 claims description 5
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims description 4
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
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- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- WXCZUWHSJWOTRV-UHFFFAOYSA-N but-1-ene;ethene Chemical compound C=C.CCC=C WXCZUWHSJWOTRV-UHFFFAOYSA-N 0.000 description 1
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- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
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- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
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- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
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Classifications
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Mechanical Engineering (AREA)
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- Wrappers (AREA)
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Abstract
Description
包装フィルムとして試料1〜7を形成した。プロピレン(PP)およびブタン/エチレンコモノマー含量を表1に示す。粘度はレオメータを用い、せん断をほぼゼロとして200℃で測定した。フィルムは二軸押出機でポリマー成分を溶融させ、次いでそれを冷ロールで厚み1.5ミル(mil)に流延することにより形成した。フィルムの混和性は約10,000グラムの非晶質ポリα−オレフィン接着剤(Henkel社のDISPOMELT(登録商標)LITE 300)を(接着剤に対し)約0.5wt%のフィルム試料と溶融タンク中で160℃で溶融することによって評価した。撹拌せずにフィルム試料を接着剤中に溶融するために必要な時間を記録した。試料8では、さらに、VA含量3%EVAフィルムのブローフィルムを本検討のために用いた。
試料フィルムの溶融強度を評価するため、試料フィルムの溶融温度および溶融弾性率の特性を評価した。その結果を表2に示す。融点は2920DSC(示差走査熱量測定法)TA装置によって測定した。約5〜10mgの試料をクリンプしたアルミナパン内にシールし、−40℃に冷却し、2920 DSC TA装置によって10℃/分の速度で180℃まで再加熱した。第2の加熱サイクルを用いて、ピーク融点およびTmオフセット値を評価した。
試料4〜8について、その噴霧性を分析した。約10,000gのDISPOMELT LITE(登録商標)Lite 300接着剤の試料を厚み約1.5ミルの試料フィルムでカプセル化した。160℃に設定した熱溶融タンクに、試料4〜6については3時間(試料7については10時間、試料8については24時間)、パッケージを装填した。次いで溶融した接着剤を4ポートのITWスプレーヘッド(Nordson)から噴霧し、1分あたりの迷走(stray)滴数を表3に記録した。それぞれの試料フィルムのTmオフセットも表3に記録する。
種々のホットメルト接着剤(1,000g)および包装フィルム(ホットメルト接着剤に対して0.5wt%)を用いたホットメルト接着剤パッケージを形成した。これらを、表4に列挙する。それぞれのパッケージを熱溶融タンクに装填し、撹拌せずに、表示した温度に加熱した。ホットメルト接着剤中のフィルムの混和性を目視により観察した。また、フィルム試料が完全に溶解し、接着剤中に混和するために必要な時間を記録した。
包装フィルムとして試料1〜7を形成した。プロピレン(PP)およびブテン/エチレンコモノマー含量を表1に示す。粘度はレオメータを用い、せん断をほぼゼロとして200℃で測定した。フィルムは二軸押出機でポリマー成分を溶融させ、次いでそれを冷ロールで厚み1.5ミル(mil)に流延することにより形成した。フィルムの混和性は約10,000グラムの非晶質ポリα−オレフィン接着剤(Henkel社のDISPOMELT(登録商標)LITE 300)を(接着剤に対し)約0.5wt%のフィルム試料と溶融タンク中で160℃で溶融することによって評価した。撹拌せずにフィルム試料を接着剤中に溶融するために必要な時間を記録した。試料8では、さらに、酢酸ビニル含量3%EVAフィルムのブローフィルムを本検討のために用いた。
Claims (20)
- ポリマーブレンドを含むホットメルト包装フィルムであって、
ポリマーブレンドは、少なくとも70wt%のプロピレン含量を有し、
包装フィルムは、(a)200℃における粘度範囲が約200,000〜3,000,000cpsであり、(b)ピーク溶融温度範囲が約90〜140℃であり、(c)Tmオフセット温度が149℃未満であり、(d)100℃における貯蔵弾性率(G’)の範囲が約1×106〜約1×108パスカルである、ホットメルト包装フィルム。 - 抗ブロッキング剤、抗酸化剤、流れ調整剤、充填剤、染料およびそれらの混合物からなる群から選択される添加剤をさらに含む、請求項1に記載の包装フィルム。
- ポリマーブレンド中の少なくとも1種のポリマーが、メタロセン触媒によるポリプロピレンポリマーである、請求項1に記載の包装フィルム。
- ポリマーブレンドがエチレンおよび/またはブテンコモノマーを含む、請求項1に記載の包装フィルム。
- ポリマーブレンドが、
a.約70〜約99wt%のプロピレン含量、
b.約1〜約30wt%のエチレンおよび/またはブテン含量
を有する、請求項4に記載の包装フィルム。 - 請求項1に記載の包装フィルムを含む物品。
- ホットメルト接着剤パッケージである、請求項6に記載の物品。
- 枕、円筒、パウチ、ブロック、カートリッジまたはチャブである、請求項7に記載の物品。
- 一体型ホットメルト接着剤パッケージであって、
(a)ポリ−α−オレフィン、ゴム、スチレン系ブロック−コポリマー、エチレン−酢酸ビニル、エチレン−酢酸ブチル、およびそれらの混合物からなる群から選択されるホットメルト接着剤と、
(b)少なくとも70wt%のプロピレンを含むポリマーブレンドを含み、(a)200℃における粘度範囲が約200,000〜3,000,000cpsであり、(b)ピーク溶融温度範囲が約90〜140℃であり、(c)Tmオフセット温度が149℃未満であり、(d)100℃における貯蔵弾性率(G’)の範囲が約1×106〜約1×108パスカルである、包装フィルムと、
を含み、
包装フィルムが、ホットメルト接着剤パッケージ中に、ホットメルト接着剤パッケージの全重量に対して約0.2〜約2%存在し、
包装フィルムが、149℃以上の温度で、全く撹拌せずに、ホットメルト接着剤と100%混和性である、一体型ホットメルト接着剤パッケージ。 - 包装フィルムが抗ブロッキング剤、抗酸化剤、流れ調整剤、充填剤、染料およびそれらの混合物からなる群から選択される添加剤をさらに含む、請求項9に記載の一体型ホットメルト接着剤パッケージ。
- ポリマーブレンド中の少なくとも1種のポリマーが、メタロセン触媒によるポリプロピレンポリマーである、請求項9に記載の一体型ホットメルト接着剤パッケージ。
- ポリマーブレンドがエチレンおよび/またはブテンコモノマーを含む、請求項11に記載の一体型ホットメルト接着剤パッケージ。
- ポリマーブレンドが、
a.約70〜約99wt%のプロピレン含量、
b.約1〜約30wt%のエチレンおよび/またはブテン含量
を有する、請求項11に記載の一体型ホットメルト接着剤パッケージ。 - ホットメルト接着剤が、ポリ−α−オレフィン、オレフィンブロックコポリマーまたはスチレン系ブロック−コポリマーをベースとする接着剤である、請求項9に記載の一体型ホットメルト接着剤パッケージ。
- 約0.5ミルから約5ミルの厚みを有する単層の包装フィルムを含む、請求項9に記載の一体型ホットメルト接着剤パッケージ。
- 多層の包装フィルムを含み、それぞれの層の厚みが約0.5ミル〜約5ミルである、請求項9に記載の一体型ホットメルト接着剤パッケージ。
- 枕、円筒、パウチ、ブロック、カートリッジまたはチャブとして形成される、請求項9に記載の一体型ホットメルト接着剤パッケージ。
- 一体型ホットメルト接着剤パッケージを形成する方法であって、
1.包装フィルムをカプセル化容器として用意するステップと、
2.溶融状態のホットメルト接着剤を包装フィルムにポンプ注入し、または注ぐステップであって、包装フィルムがヒートシンクと直接接触するステップと、
3.包装フィルムをシールするステップと、
4.シールパッケージを冷却するステップと、
を含み、
包装フィルムは、少なくとも70wt%のプロピレンを含むポリマーブレンドを含み、包装フィルムは、(a)200℃における粘度範囲が約200,000〜3,000,000cpsであり、(b)ピーク溶融温度範囲が約90〜140℃であり、(c)Tmオフセット温度が149℃未満であり、(d)100℃における貯蔵弾性率(G’)の範囲が約1×106から約1×108パスカルであり、
ホットメルト接着剤がポリ−α−オレフィン、ゴム、スチレン系ブロックコ−ポリマー、エチレン−酢酸ビニル、エチレン−酢酸ブチル、およびそれらの混合物からなる群から選択され、
冷却されたシールパッケージが非粘着性である、
方法。 - 溶融状態のホットメルト接着剤をポンプ注入するまたは注ぐステップが、約150℃以下の温度で実施される、請求項18に記載の一体型ホットメルト接着剤パッケージを形成する方法。
- ヒートシンクが水である、請求項18に記載の一体型ホットメルト接着剤パッケージを形成する方法。
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US201261648290P | 2012-05-17 | 2012-05-17 | |
US61/648,290 | 2012-05-17 | ||
US13/800,445 US9272795B2 (en) | 2012-05-17 | 2013-03-13 | Integral hot melt adhesive packaging films and use thereof |
US13/800,445 | 2013-03-13 | ||
PCT/US2013/039232 WO2013173072A1 (en) | 2012-05-17 | 2013-05-02 | Integral hot melt adhesive packaging films and use thereof |
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JP2015524008A true JP2015524008A (ja) | 2015-08-20 |
JP5773402B2 JP5773402B2 (ja) | 2015-09-02 |
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US (2) | US9272795B2 (ja) |
EP (1) | EP2872549B1 (ja) |
JP (1) | JP5773402B2 (ja) |
KR (1) | KR101569358B1 (ja) |
CN (1) | CN104334618B (ja) |
AR (1) | AR091074A1 (ja) |
BR (1) | BR112014028390B1 (ja) |
CA (1) | CA2871977A1 (ja) |
ES (1) | ES2701438T3 (ja) |
MX (1) | MX360424B (ja) |
PT (1) | PT2872549T (ja) |
RU (1) | RU2014151003A (ja) |
TW (1) | TWI563047B (ja) |
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2013
- 2013-03-13 US US13/800,445 patent/US9272795B2/en active Active
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- 2013-05-02 CA CA2871977A patent/CA2871977A1/en not_active Abandoned
- 2013-05-02 RU RU2014151003A patent/RU2014151003A/ru unknown
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- 2013-05-02 ES ES13790214T patent/ES2701438T3/es active Active
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- 2013-05-16 TW TW102117432A patent/TWI563047B/zh not_active IP Right Cessation
- 2013-05-17 AR ARP130101711 patent/AR091074A1/es unknown
-
2016
- 2016-01-22 US US15/004,187 patent/US10364079B2/en active Active
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2018502018A (ja) * | 2014-11-14 | 2018-01-25 | ガラ・インダストリーズ・インコーポレイテッドGala Industries, Inc. | 粘着性物質包装用フィルム |
US11383496B2 (en) | 2014-11-14 | 2022-07-12 | Maag Gala, Inc. | Film for bagging tacky materials |
JP2017105171A (ja) * | 2015-11-26 | 2017-06-15 | 日本ポリプロ株式会社 | 積層発泡シート及び熱成形体 |
WO2019124088A1 (en) | 2017-12-18 | 2019-06-27 | Henkel Ag & Co. Kgaa | Film-wrapped type hot melt adhesive |
KR20200098652A (ko) | 2017-12-18 | 2020-08-20 | 헨켈 아게 운트 코. 카게아아 | 필름-래핑된 유형 핫 멜트 접착제 |
Also Published As
Publication number | Publication date |
---|---|
TWI563047B (en) | 2016-12-21 |
CN104334618A (zh) | 2015-02-04 |
US10364079B2 (en) | 2019-07-30 |
BR112014028390A2 (pt) | 2018-05-29 |
WO2013173072A1 (en) | 2013-11-21 |
KR20140144743A (ko) | 2014-12-19 |
EP2872549A4 (en) | 2016-04-27 |
AR091074A1 (es) | 2014-12-30 |
EP2872549A1 (en) | 2015-05-20 |
TW201400569A (zh) | 2014-01-01 |
US20160137371A1 (en) | 2016-05-19 |
MX360424B (es) | 2018-11-01 |
BR112014028390B1 (pt) | 2020-12-29 |
MX2014013876A (es) | 2015-02-12 |
KR101569358B1 (ko) | 2015-11-24 |
PT2872549T (pt) | 2018-11-09 |
CA2871977A1 (en) | 2013-11-21 |
JP5773402B2 (ja) | 2015-09-02 |
RU2014151003A (ru) | 2016-07-10 |
US9272795B2 (en) | 2016-03-01 |
CN104334618B (zh) | 2016-08-17 |
EP2872549B1 (en) | 2018-10-03 |
ES2701438T3 (es) | 2019-02-22 |
US20130309427A1 (en) | 2013-11-21 |
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