JP2015522678A5 - - Google Patents
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- JP2015522678A5 JP2015522678A5 JP2015519004A JP2015519004A JP2015522678A5 JP 2015522678 A5 JP2015522678 A5 JP 2015522678A5 JP 2015519004 A JP2015519004 A JP 2015519004A JP 2015519004 A JP2015519004 A JP 2015519004A JP 2015522678 A5 JP2015522678 A5 JP 2015522678A5
- Authority
- JP
- Japan
- Prior art keywords
- aqueous
- alkyd
- composite binder
- emulsion
- coating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000839 emulsion Substances 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003973 paint Substances 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 3
- 239000011256 inorganic filler Substances 0.000 claims description 3
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 3
- 239000001023 inorganic pigment Substances 0.000 claims description 3
- 229920000180 alkyd Polymers 0.000 claims 24
- 239000011230 binding agent Substances 0.000 claims 17
- 239000002131 composite material Substances 0.000 claims 16
- 239000004815 dispersion polymer Substances 0.000 claims 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 8
- 239000000178 monomer Substances 0.000 claims 7
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 6
- 238000004332 deodorization Methods 0.000 claims 6
- 239000000126 substance Substances 0.000 claims 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 5
- 229920002635 polyurethane Polymers 0.000 claims 5
- 239000004814 polyurethane Substances 0.000 claims 5
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims 4
- 239000012965 benzophenone Substances 0.000 claims 4
- 229920000642 polymer Polymers 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 4
- 238000003756 stirring Methods 0.000 claims 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 3
- 150000008062 acetophenones Chemical class 0.000 claims 3
- 150000008366 benzophenones Chemical class 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims 2
- 238000007720 emulsion polymerization reaction Methods 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- WXPWZZHELZEVPO-UHFFFAOYSA-N (4-methylphenyl)-phenylmethanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 WXPWZZHELZEVPO-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 230000009477 glass transition Effects 0.000 claims 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- HPAFOABSQZMTHE-UHFFFAOYSA-N phenyl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)C1=CC=CC=C1 HPAFOABSQZMTHE-UHFFFAOYSA-N 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000000049 pigment Substances 0.000 description 9
- 239000000945 filler Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 239000006224 matting agent Substances 0.000 description 3
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 229940097275 indigo Drugs 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 1
- 241000238370 Sepia Species 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- 241000219995 Wisteria Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- FAWGZAFXDJGWBB-UHFFFAOYSA-N antimony(3+) Chemical compound [Sb+3] FAWGZAFXDJGWBB-UHFFFAOYSA-N 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- UHHXUPJJDHEMGX-UHFFFAOYSA-K azanium;manganese(3+);phosphonato phosphate Chemical compound [NH4+].[Mn+3].[O-]P([O-])(=O)OP([O-])([O-])=O UHHXUPJJDHEMGX-UHFFFAOYSA-K 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- -1 calcium carbonate Chemical class 0.000 description 1
- 229940093876 calcium carbonate / kaolin Drugs 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 description 1
- 150000004696 coordination complex Chemical class 0.000 description 1
- 150000005125 dioxazines Chemical class 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- PXZQEOJJUGGUIB-UHFFFAOYSA-N isoindolin-1-one Chemical compound C1=CC=C2C(=O)NCC2=C1 PXZQEOJJUGGUIB-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- RYZCLUQMCYZBJQ-UHFFFAOYSA-H lead(2+);dicarbonate;dihydroxide Chemical compound [OH-].[OH-].[Pb+2].[Pb+2].[Pb+2].[O-]C([O-])=O.[O-]C([O-])=O RYZCLUQMCYZBJQ-UHFFFAOYSA-H 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- WOTPFVNWMLFMFW-ISLYRVAYSA-N para red Chemical compound OC1=CC=C2C=CC=CC2=C1\N=N\C1=CC=C(N(=O)=O)C=C1 WOTPFVNWMLFMFW-ISLYRVAYSA-N 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12175345 | 2012-07-06 | ||
| EP12175345.3 | 2012-07-06 | ||
| PCT/EP2013/063035 WO2014005862A1 (de) | 2012-07-06 | 2013-06-21 | Verwendung wässriger hybridbindemittel und alkydsysteme für beschichtungsmittel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2015522678A JP2015522678A (ja) | 2015-08-06 |
| JP2015522678A5 true JP2015522678A5 (enExample) | 2018-04-05 |
Family
ID=48741079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015519004A Pending JP2015522678A (ja) | 2012-07-06 | 2013-06-21 | 水性複合結合剤およびアルキド系の、コーティング剤のための使用 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9567484B2 (enExample) |
| EP (1) | EP2870208A1 (enExample) |
| JP (1) | JP2015522678A (enExample) |
| CN (1) | CN104428378A (enExample) |
| AU (1) | AU2013286181B2 (enExample) |
| BR (1) | BR112015000169A2 (enExample) |
| RU (1) | RU2015103810A (enExample) |
| WO (1) | WO2014005862A1 (enExample) |
| ZA (1) | ZA201500804B (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2641752T3 (es) * | 2014-11-04 | 2017-11-13 | Basf Se | Procedimiento para la preparación de una dispersión acuosa de polímero |
| CN104893622B (zh) * | 2015-06-23 | 2016-08-24 | 周美琴 | 一种抗氧化粘结剂组合物 |
| CN104877577B (zh) * | 2015-06-23 | 2017-03-08 | 周美琴 | 一种具有紫外线吸收功能的抗氧化粘结剂组合物 |
| CN105131192B (zh) * | 2015-08-06 | 2017-12-29 | 惠州市安品新材料有限公司 | 改性阻燃醇酸树脂及包含该树脂的组合物 |
| CN108430953B (zh) * | 2015-10-20 | 2021-01-26 | 巴斯夫欧洲公司 | 用于涂覆纤维水泥板的涂料组合物 |
| US10829579B2 (en) * | 2017-01-25 | 2020-11-10 | Dic Corporation | Active-energy-ray-curable aqueous resin composition and undercoat agent for inorganic-material thin film |
| CN121873663A (zh) * | 2017-11-10 | 2026-04-17 | 宣伟公司 | 包含氨基甲酸酯醇酸和丙烯酸类胶乳树脂的涂料组合物 |
| ES2931335T3 (es) * | 2018-04-20 | 2022-12-28 | Basf Se | Composición adhesiva con contenido de gel a base de reticulación mediante grupos ceto o aldehído |
| WO2020098919A1 (de) * | 2018-11-13 | 2020-05-22 | Wacker Chemie Ag | Beschichtungsmittel für schmutzabweisende sowie abriebsbeständige beschichtungen |
| CN109957313A (zh) * | 2019-03-11 | 2019-07-02 | 长兴特殊材料（苏州）有限公司 | 一种光固化型涂料配方及其应用 |
| MX2022004160A (es) * | 2019-10-29 | 2022-05-02 | Dow Global Technologies Llc | Composicion de poliuretano de dos componentes. |
| AU2020402084B2 (en) * | 2019-12-10 | 2026-01-22 | Akzo Nobel Coatings International B.V. | Two-component solvent-based coating composition |
| CN113336923A (zh) * | 2020-08-27 | 2021-09-03 | 广东珠江化工涂料有限公司 | 一种含羰基基团的水性醇酸树脂的制备方法及其涂料 |
| WO2025245332A1 (en) * | 2024-05-23 | 2025-11-27 | Benjamin Moore & Co. | Architectural compositions with improved gloss retention |
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| JPS5033767B1 (enExample) | 1971-03-11 | 1975-11-04 | ||
| DE2722097C3 (de) | 1977-05-16 | 1981-09-17 | Basf Ag, 6700 Ludwigshafen | (Meth)acryloxy-alkylpropanale, Verfahren zu dessen Herstellung und Verwendung derselben |
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| US4733005A (en) | 1986-04-21 | 1988-03-22 | The Dow Chemical Company | Phosphinyl-containing ethylenically unsaturated compounds |
| DE3930585A1 (de) | 1989-09-13 | 1991-03-21 | Basf Ag | Waessrige kunstharzzubereitungen |
| DE4219384A1 (de) | 1992-06-13 | 1993-12-23 | Basf Ag | Bei Raumtemperatur mit Hydroxylaminen oder Oximethern vernetzbare Dispersion oder Lösung |
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| US6369135B1 (en) * | 1995-08-15 | 2002-04-09 | Georgia Tech Research Corporation | Water-borne alkyd coatings by miniemulsion polymerization |
| SE508224C2 (sv) | 1996-01-18 | 1998-09-14 | Akzo Nobel Ind Coatings Ab | Vattenburen hybridbindemedelskomposition samt användning därav |
| PL334920A1 (en) | 1997-01-30 | 2000-03-27 | Dsm Nv | Composition crossclinkable by irradiation |
| DE19750618A1 (de) | 1997-11-14 | 1999-05-20 | Basf Ag | Pigmenthaltige Zubereitungen auf der Basis wässriger Polymerisatdispersionen |
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| ES2476415T3 (es) * | 2005-05-02 | 2014-07-14 | Basf Se | Procedimiento para el tratamiento de superficies de madera |
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| US9315660B2 (en) * | 2007-06-15 | 2016-04-19 | Basf Se | Low-VOC aqueous hybrid binders |
| US20090004394A1 (en) | 2007-06-29 | 2009-01-01 | Anne Denise Koller | Aqueous polymeric composition |
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| NO2225337T3 (enExample) * | 2007-11-19 | 2018-01-20 | ||
| EP2342245B1 (en) | 2008-10-09 | 2019-03-06 | Allnex Netherlands B.V. | Aqueous hybrid dispersions |
| DE102009001966A1 (de) | 2009-03-30 | 2010-10-07 | Evonik Röhm Gmbh | Beschichtungszusammensetzung,(Meth)acryl-Polymer und Monomermischung zur Herstellung des(Meth)acryl-Polymers |
| CN102666593B (zh) | 2009-12-16 | 2015-03-04 | 巴斯夫欧洲公司 | 水性混合基料用于光泽涂料中 |
| US8785557B2 (en) * | 2009-12-16 | 2014-07-22 | Basf Se | Use of aqueous hybrid binders for gloss paints |
| JP6076252B2 (ja) * | 2010-09-01 | 2017-02-08 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 水性のエマルションポリマー、その製造及び使用 |
-
2013
- 2013-06-21 JP JP2015519004A patent/JP2015522678A/ja active Pending
- 2013-06-21 EP EP13732874.6A patent/EP2870208A1/de not_active Withdrawn
- 2013-06-21 US US14/407,290 patent/US9567484B2/en not_active Expired - Fee Related
- 2013-06-21 WO PCT/EP2013/063035 patent/WO2014005862A1/de not_active Ceased
- 2013-06-21 CN CN201380036178.5A patent/CN104428378A/zh active Pending
- 2013-06-21 BR BR112015000169A patent/BR112015000169A2/pt not_active IP Right Cessation
- 2013-06-21 AU AU2013286181A patent/AU2013286181B2/en not_active Ceased
- 2013-06-21 RU RU2015103810A patent/RU2015103810A/ru unknown
-
2015
- 2015-02-04 ZA ZA2015/00804A patent/ZA201500804B/en unknown
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