JP2015145696A - Vacuum heat-insulating material, heat-insulating box using vacuum heat-insulating material, and method for manufacturing vacuum heat-insulating material - Google Patents

Vacuum heat-insulating material, heat-insulating box using vacuum heat-insulating material, and method for manufacturing vacuum heat-insulating material Download PDF

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JP2015145696A
JP2015145696A JP2014018160A JP2014018160A JP2015145696A JP 2015145696 A JP2015145696 A JP 2015145696A JP 2014018160 A JP2014018160 A JP 2014018160A JP 2014018160 A JP2014018160 A JP 2014018160A JP 2015145696 A JP2015145696 A JP 2015145696A
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heat insulating
vacuum heat
insulating material
less
fiber
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JP6192554B2 (en
JP2015145696A5 (en
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貴祥 向山
Takayoshi Mukoyama
貴祥 向山
一正 藤村
Kazumasa Fujimura
一正 藤村
犬塚 隆之
Takayuki Inuzuka
隆之 犬塚
洋輔 藤森
Yosuke Fujimori
洋輔 藤森
尚平 安孫子
Shohei Abiko
尚平 安孫子
浩明 高井
Hiroaki Takai
浩明 高井
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Mitsubishi Electric Corp
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Mitsubishi Electric Corp
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Priority to JP2014018160A priority Critical patent/JP6192554B2/en
Priority to PCT/JP2015/050403 priority patent/WO2015115149A1/en
Priority to CN201580006850.5A priority patent/CN105992902B/en
Priority to RU2016135626A priority patent/RU2658725C1/en
Priority to SG11201605643YA priority patent/SG11201605643YA/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/06Arrangements using an air layer or vacuum
    • F16L59/065Arrangements using an air layer or vacuum using vacuum
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/06Walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2201/00Insulation
    • F25D2201/10Insulation with respect to heat
    • F25D2201/14Insulation with respect to heat using subatmospheric pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2500/00Problems to be solved
    • F25D2500/02Geometry problems

Abstract

PROBLEM TO BE SOLVED: To provide a vacuum heat-insulating material that can control a weight ratio of short fibers, an average fiber angle and its standard deviation and has excellent heat-insulating performance, also provide a heat-insulating box using the vacuum heat-insulating material, and a method for manufacturing the vacuum heat-insulating material.SOLUTION: This invention provides a vacuum heat-insulating material (1) equipped with a core material (2) formed of a fiber aggregate, and an outer cover material (3) covering the core material (2), with the interior of the outer cover material (3) being sealed under reduced pressure. The core material (2) is formed such that the weight ratio of fibers having fiber length of 1.85 mm or less is 11 wt% or less of the core material (2).

Description

本発明は、真空断熱材及びこの真空断熱材を用いた断熱箱、特に冷熱機器への使用に好適な真空断熱材及び断熱箱、及び製造方法に関する。   The present invention relates to a vacuum heat insulating material and a heat insulating box using the vacuum heat insulating material, in particular, a vacuum heat insulating material and a heat insulating box suitable for use in a refrigeration apparatus, and a manufacturing method.

冷蔵庫などの断熱箱の断熱材として用いられている従来の真空断熱材としては、ガラス繊維の集合体で形成される芯材を、ガスバリア性を有する外包材で被覆し、外包材の内部が減圧されて密閉されたものがある(例えば、特許文献1参照)。   As a conventional vacuum heat insulating material used as a heat insulating material for a heat insulating box such as a refrigerator, a core material formed of an aggregate of glass fibers is covered with an outer packaging material having a gas barrier property, and the inside of the outer packaging material is decompressed. And sealed (see, for example, Patent Document 1).

このように外包材の内部を減圧した真空断熱材は、嵩張るガラス繊維の集合体を外包材で被覆し減圧密閉することによって厚さが薄くなるとともに、外包材内部の気体の対流と熱伝導の影響を小さくして断熱性能の向上を図るものである。一般に、断熱材の伝熱機構は、固体および気体成分の熱伝導、輻射、対流により引き起こされる。一方、外包材内部を減圧密閉された真空断熱材は、気体成分の熱伝導と対流に関してはその影響は小さい。また、常温以下の温度領域での使用においては、輻射の影響も殆どない。よって、常温以下の温度領域で使用される冷蔵庫等に適用する真空断熱材においては、固体成分の熱伝導を抑制することが重要となる。そこで、断熱性能に優れる真空断熱用芯材として、種々の形態をした繊維が報告されている。近年では激しい省エネルギー競争によって、薄くても断熱性能のより優れた真空断熱材、とりわけ芯材となる高い断熱性を有する繊維集合体が強く求められている。   In this way, the vacuum heat insulating material in which the inside of the outer packaging material is depressurized is thinned by covering the bulky glass fiber aggregate with the outer packaging material and sealing under reduced pressure, and the convection and heat conduction of the gas inside the outer packaging material are reduced. The effect is reduced to improve the heat insulation performance. In general, the heat transfer mechanism of a heat insulating material is caused by heat conduction, radiation, and convection of solid and gas components. On the other hand, the vacuum heat insulating material whose inside of the outer packaging material is sealed under reduced pressure has little effect on the heat conduction and convection of the gas component. Further, there is almost no influence of radiation when used in a temperature range below room temperature. Therefore, in a vacuum heat insulating material applied to a refrigerator or the like used in a temperature range below room temperature, it is important to suppress the heat conduction of the solid component. Therefore, various forms of fibers have been reported as vacuum insulation core materials having excellent heat insulation performance. In recent years, due to fierce energy-saving competition, there is a strong demand for a vacuum heat insulating material with excellent heat insulating performance even when it is thin, in particular, a fiber assembly having high heat insulating properties as a core material.

真空断熱材の熱伝導率を低減する方法として、真空断熱材を構成するガラス繊維を断熱方向に対して垂直方向に配向することによって、ガラス繊維による伝熱を抑制したものがある(例えば、特許文献2参照)。   As a method of reducing the thermal conductivity of the vacuum heat insulating material, there is one in which heat transfer by the glass fiber is suppressed by orienting the glass fiber constituting the vacuum heat insulating material in a direction perpendicular to the heat insulating direction (for example, patents) Reference 2).

また、バインダーを使用してガラス繊維を乾式法により加熱加圧成形し、ガラス繊維を伝熱方向に対して垂直に配向するだけでなく、長さが100μm以下の短い繊維を40〜70%含有させることにより、繊維を伝わる熱を途切れさせ、固体熱伝導率を低減したものがある(例えば、特許文献3参照)。   In addition, glass fibers are heated and pressed by a dry method using a binder, and the glass fibers are not only oriented perpendicular to the heat transfer direction, but also contain 40 to 70% of short fibers with a length of 100 μm or less. As a result, the heat transmitted through the fibers is interrupted to reduce the solid thermal conductivity (for example, see Patent Document 3).

また、バインダーを使用しない乾式法において、平均繊維径が2〜5μmのガラス繊維でなり、ショット(ダマ)の混入率が0.5質量%以下で、かつショットの平均粒径が150μm以下であって、500μm以上の繊維長を有するガラス繊維の割合が80%以上であるガラス繊維積層体を芯材とする断熱性に優れた真空断熱材がある(例えば、特許文献4参照)。   Further, in a dry method that does not use a binder, the glass fiber has an average fiber diameter of 2 to 5 μm, the shot (dama) mixing rate is 0.5 mass% or less, and the average particle diameter of the shot is 150 μm or less. In addition, there is a vacuum heat insulating material excellent in heat insulating properties using a glass fiber laminate in which the ratio of glass fibers having a fiber length of 500 μm or more is 80% or more (see, for example, Patent Document 4).

特許第3580315号公報(要約、図1)Japanese Patent No. 3580315 (Summary, FIG. 1) 特開平9−4785号公報(要約)Japanese Patent Laid-Open No. 9-4785 (Summary) 特許第3513143号公報(段落[0006])Japanese Patent No. 3513143 (paragraph [0006]) 特開2009−155172号公報(要約)JP 2009-155172 A (summary)

真空断熱材の熱伝導率を低減する方法として、真空断熱材を構成するガラス繊維を断熱方向に対して垂直方向に配向して積層するものがあるが、ガラス繊維を断熱方向に対して垂直方向に配向して積層しただけでは、ガラス繊維を伝わる熱が存在してしまうために固体熱伝導率が大きくなり、真空断熱材において初期熱伝導率の低減に限界があった。   As a method for reducing the thermal conductivity of the vacuum heat insulating material, there is a method in which the glass fibers constituting the vacuum heat insulating material are oriented and laminated in a direction perpendicular to the heat insulating direction, but the glass fibers are perpendicular to the heat insulating direction. If the layers are simply oriented and laminated, the heat transmitted through the glass fiber is present, so that the solid thermal conductivity is increased, and there is a limit to the reduction of the initial thermal conductivity in the vacuum heat insulating material.

また、バインダーを用いて加熱加圧成形によりガラス繊維を結着させる方法では、加熱するための動力費やバインダーの材料費が増加し、真空断熱材を安価に得られないだけでなく、経時的な熱伝導率悪化が大きいという課題があった。これは、真空断熱材にした際に、真空中でバインダーから低分子のガス成分が放出され、真空度が低下するためである。   In addition, the method of binding glass fibers by heat and pressure molding using a binder increases not only the power cost for heating and the material cost of the binder, but also the vacuum heat insulating material cannot be obtained at a low cost. There was a problem that the thermal conductivity was greatly deteriorated. This is because when a vacuum heat insulating material is used, a low molecular gas component is released from the binder in vacuum, and the degree of vacuum is lowered.

また、バインダーを使用しない乾式法では、ガラス繊維の長さ及び短繊維の重量割合をコントロールできても、真空断熱材にした状態での繊維角度のコントロールはできないという課題があった。   Moreover, in the dry method which does not use a binder, even if the length of the glass fiber and the weight ratio of the short fiber can be controlled, there is a problem that the fiber angle in a state where the vacuum heat insulating material is used cannot be controlled.

本発明は、前記課題を解決するためになされたもので、短繊維の重量割合、平均繊維角度及びその標準偏差をコントロールできて、断熱性能に優れる真空断熱材、真空断熱材を用いた断熱箱、及び真空断熱材の製造方法を提供することを目的とする。   The present invention has been made to solve the above-mentioned problems, and can control the weight ratio of short fibers, the average fiber angle, and the standard deviation thereof, and is excellent in heat insulation performance. Heat insulation box using a vacuum heat insulation material And it aims at providing the manufacturing method of a vacuum heat insulating material.

本発明に係る真空断熱材は、繊維集合体で構成される芯材と、芯材を被覆する外包材とを備え、外包材の内部が減圧密封された真空断熱材であって、芯材は繊維長1.85mm以下の繊維の重量割合がこの芯材の11wt%以下であるものである。   A vacuum heat insulating material according to the present invention is a vacuum heat insulating material that includes a core material composed of a fiber assembly and an outer packaging material that covers the core material, and the inside of the outer packaging material is hermetically sealed under reduced pressure. The weight ratio of fibers having a fiber length of 1.85 mm or less is 11 wt% or less of the core material.

本発明に係る真空断熱材において、芯材は繊維長1.85mm以下の繊維の重量割合がこの芯材の11wt%以下であるので、芯材の断熱方向への熱パス経路を短くし断熱性能を悪化させる因子である繊維長1.85mm以下の繊維の影響を最小限に抑えることができる。このため、高い断熱性能を得ることができる。
また、繊維長1.85mm以下の繊維の重量割合を芯材の11wt%以下にすることによって、繊維長1.85mm以上の繊維が芯材の断熱方向に対して垂直に配向しやすくなり、芯材の断熱方向に配向し断熱性能を悪化させる因子である繊維長1.85mm以下の繊維の影響を最小限に抑えることができる。このため、断熱性能に優れる真空断熱材を得ることができる。
そして、本発明の真空断熱材を冷蔵庫等の断熱箱に適用することによって、製品の断熱効果が上がり、製品の壁の厚みを薄くすることができ、製品の限られたスペースで内容積を大きくすることができる。
In the vacuum heat insulating material according to the present invention, since the weight ratio of the fiber having a fiber length of 1.85 mm or less is 11 wt% or less of the core material, the heat path path in the heat insulating direction of the core material is shortened and the heat insulating performance. The influence of a fiber having a fiber length of 1.85 mm or less, which is a factor that deteriorates the resistance, can be minimized. For this reason, high heat insulation performance can be obtained.
In addition, by setting the weight ratio of the fibers having a fiber length of 1.85 mm or less to 11 wt% or less of the core material, the fibers having a fiber length of 1.85 mm or more can be easily oriented perpendicular to the heat insulating direction of the core material. The influence of fibers having a fiber length of 1.85 mm or less, which is a factor that is oriented in the heat insulating direction of the material and deteriorates the heat insulating performance, can be minimized. For this reason, the vacuum heat insulating material excellent in heat insulation performance can be obtained.
And by applying the vacuum heat insulating material of the present invention to a heat insulation box such as a refrigerator, the heat insulation effect of the product is improved, the thickness of the product wall can be reduced, and the internal volume is increased in a limited space of the product. can do.

本発明の実施形態1に係る真空断熱材の芯材の繊維長1.85mm以下の繊維の重量割合と熱伝導率との関係を示すグラフである。It is a graph which shows the relationship between the weight ratio of the fiber with a fiber length of 1.85 mm or less of the core material of the vacuum heat insulating material which concerns on Embodiment 1 of this invention, and thermal conductivity. 本発明の実施形態1に係る真空断熱材の芯材の平均繊維長の測定における光学顕微鏡写真である。It is an optical microscope photograph in the measurement of the average fiber length of the core material of the vacuum heat insulating material which concerns on Embodiment 1 of this invention. 本発明の実施形態1に係る真空断熱材の芯材の平均繊維角度の測定における光学顕微鏡写真である。It is an optical microscope photograph in the measurement of the average fiber angle of the core material of the vacuum heat insulating material which concerns on Embodiment 1 of this invention. 本発明の実施形態1に係る真空断熱材の芯材の平均繊維角度と熱伝導率との関係を示すグラフである。It is a graph which shows the relationship between the average fiber angle of the core material of the vacuum heat insulating material which concerns on Embodiment 1 of this invention, and thermal conductivity. 本発明の実施形態1に係る真空断熱材の芯材の繊維角度標準偏差と熱伝導率との関係を示すグラフである。It is a graph which shows the relationship between the fiber angle standard deviation of the core material of the vacuum heat insulating material which concerns on Embodiment 1 of this invention, and thermal conductivity. 本発明の実施形態1に係る真空断熱材を示す断面図である。It is sectional drawing which shows the vacuum heat insulating material which concerns on Embodiment 1 of this invention. 本発明の実施形態1に係る真空断熱材の製造方法を示す模式図である。It is a schematic diagram which shows the manufacturing method of the vacuum heat insulating material which concerns on Embodiment 1 of this invention. 本発明の実施形態2に係る断熱箱を示す模式図である。It is a schematic diagram which shows the heat insulation box which concerns on Embodiment 2 of this invention.

実施形態1.
本発明の実施形態1に係る真空断熱材は、芯材となる繊維集合体において、繊維長1.85mm以下の繊維(以下、これを「短繊維」という場合もある)の重量割合が、芯材の11wt%以下であり、好ましくは芯材の8wt%以下である。ここで、繊維長1.85mm以下の繊維(短繊維)の重量割合は、次の方法で測定された測定値を意味する。
Embodiment 1. FIG.
The vacuum heat insulating material according to Embodiment 1 of the present invention is such that the weight ratio of fibers having a fiber length of 1.85 mm or less (hereinafter sometimes referred to as “short fibers”) in the fiber assembly serving as the core is the core. It is 11 wt% or less of the material, and preferably 8 wt% or less of the core material. Here, the weight ratio of fibers (short fibers) having a fiber length of 1.85 mm or less means a measured value measured by the following method.

(短繊維の重量割合測定方法)
秤量した繊維100mLをビーカーに入れ、蒸留水50mLを加え超音波洗浄機で5分間拡散させた。その後、繊維が2本以上接触している塊状の繊維を精密ピンセットで1分以内に取り除ける量を全て取り除き、精密ピンセットで摘み取ることのできない残った繊維(短繊維)を濾過して乾燥させた。ろ紙に残った短繊維を秤量し、初期繊維量で割ることで、その重量割合を求めた。
(Short fiber weight ratio measurement method)
100 mL of the weighed fiber was put in a beaker, 50 mL of distilled water was added, and the mixture was diffused with an ultrasonic cleaner for 5 minutes. Thereafter, all of the aggregated fibers in contact with two or more fibers were removed with precision tweezers within 1 minute, and the remaining fibers (short fibers) that could not be picked with precision tweezers were filtered and dried. The short fibers remaining on the filter paper were weighed and divided by the initial fiber amount to obtain the weight ratio.

図1は本発明の実施形態1に係る真空断熱材の芯材の繊維長1.85mm以下の繊維の重量割合と熱伝導率との関係を示すグラフであり、縦軸に熱伝導率[mW/m・K]をとり、横軸に繊維長1.85mm以下の繊維の重量割合[wt%]をとったものである。
この結果から明らかなように、繊維長1.85mm以下の繊維の重量割合が芯材の11wt%以下の範囲において、熱伝導率は2.0mW/m・K以下でほぼ一定であった。これに対し、繊維長1.85mm以下の繊維の重量割合が芯材の11wt%を超えると、熱伝導率は2.0mW/m・K以上に増加する。
以上の結果より、熱伝導率2.0mW/m・K以下の真空断熱材を構成する繊維長1.85mm以下の繊維の重量割合は、芯材の11wt%以下である。
前記測定方法における短繊維の平均繊維長は、次の方法で求めた。
FIG. 1 is a graph showing the relationship between the weight ratio of fibers having a fiber length of 1.85 mm or less and the thermal conductivity of the core material of the vacuum heat insulating material according to Embodiment 1 of the present invention, and the vertical axis represents the thermal conductivity [mW / M · K], and the horizontal axis represents the weight ratio [wt%] of fibers having a fiber length of 1.85 mm or less.
As is clear from this result, the thermal conductivity was almost constant at 2.0 mW / m · K or less in the range where the weight ratio of the fiber having a fiber length of 1.85 mm or less was 11 wt% or less of the core material. On the other hand, when the weight ratio of fibers having a fiber length of 1.85 mm or less exceeds 11 wt% of the core material, the thermal conductivity increases to 2.0 mW / m · K or more.
From the above results, the weight ratio of the fibers having a fiber length of 1.85 mm or less constituting the vacuum heat insulating material having a thermal conductivity of 2.0 mW / m · K or less is 11 wt% or less of the core material.
The average fiber length of the short fibers in the measurement method was determined by the following method.

(平均繊維長の測定方法)
水中に分散させた数mg程度の短繊維をシャーレ上に数滴滴下し、110℃の高温槽内で水分を蒸発させた。乾燥した繊維を光学顕微鏡(20〜100倍)で観察し、任意の1箇所の繊維20本についてその長さを0.01mm単位まで測定し、この測定を5箇所について行い、合計100本の繊維の長さの平均値をもって平均繊維長とした。
(Measurement method of average fiber length)
Several drops of several mg of short fibers dispersed in water were dropped on the petri dish, and the water was evaporated in a high-temperature bath at 110 ° C. The dried fiber was observed with an optical microscope (20 to 100 times), the length of 20 fibers at any one place was measured to the nearest 0.01 mm, this measurement was performed at 5 places, and a total of 100 fibers. The average value of the lengths was taken as the average fiber length.

図2は本発明の実施形態1に係る真空断熱材の芯材の平均繊維長の測定における光学顕微鏡写真である。
本測定法によって重量割合測定における短繊維の平均繊維長を測定した結果、平均繊維長は0.50mmであり、標準偏差σは0.45mmであることが分った。すなわち、熱伝導率が2.0mW/m・K以下の真空断熱材を構成する芯材は、平均短繊維長+3σである繊維長1.85mm以下の繊維の重量割合が芯材の11wt%以下である。標準偏差σは、データの分布の広がり幅(ばらつき)をみる一つの尺度である。平均短繊維長+3σで求められる繊維長1.85mmを最長とする繊維長の範囲内に、採取した短繊維の長さの全データの99.73%が分布する。
FIG. 2 is an optical micrograph in the measurement of the average fiber length of the core material of the vacuum heat insulating material according to Embodiment 1 of the present invention.
As a result of measuring the average fiber length of the short fibers in the weight ratio measurement by this measurement method, it was found that the average fiber length was 0.50 mm and the standard deviation σ was 0.45 mm. That is, the core material constituting the vacuum heat insulating material having a thermal conductivity of 2.0 mW / m · K or less has an average short fiber length + 3σ of fiber length of 1.85 mm or less, and the weight ratio of the core material is 11 wt% or less. It is. The standard deviation σ is one measure for looking at the spread width (variation) of the data distribution. 99.73% of the total length data of the collected short fibers is distributed within the range of the fiber length that is 1.85 mm long as the average short fiber length + 3σ.

本発明の実施形態1に係る真空断熱材の芯材となる繊維集合体において、芯材の断熱方向に対して垂直な面に対する繊維角度φの平均値は14°以下である。ここで、芯材の断熱方向に対して垂直な面に対する繊維角度φの平均値(平均繊維角度)は、次の方法で測定された測定値を意味する。   In the fiber assembly serving as the core material of the vacuum heat insulating material according to Embodiment 1 of the present invention, the average value of the fiber angle φ with respect to the plane perpendicular to the heat insulating direction of the core material is 14 ° or less. Here, the average value (average fiber angle) of the fiber angle φ with respect to the plane perpendicular to the heat insulating direction of the core means a measured value measured by the following method.

(平均繊維角度の測定方法)
図3は本発明の実施形態1に係る真空断熱材の芯材の平均繊維角度の測定における光学顕微鏡写真であり、図中に測定例を示している。
すなわち、真空断熱材の状態での厚みを保持するため、真空断熱材の外側をエポキシ樹脂で固めた後、真空下で芯材内部にエポキシ樹脂を流し込み、硬化させた。硬化後、真空断熱材の中央部を断熱方向に沿う水平な面で切断し、切断面を研磨し、芯材の断熱方向に対して垂直な面を角度の基準となる水平面(0°)として光学顕微鏡で観察した。繊維断面を全て楕円であると仮定し、切断した断面の周囲幅1mm範囲を除いた任意の1箇所について、画面上の繊維全ての長軸の長さa[μm]、短軸の長さb[μm]、及び長軸と角度の基準となる水平面とのなす角度θ[°]を、それぞれ0.01μm、0.01μmおよび0.01°単位までそれぞれ測定し、測定結果を下式(1)に代入して繊維角度φ[°]を算出し、この測定を2箇所について行い、合計200本の繊維角度φの平均値をもって平均繊維角度とした。ここで、角度θは楕円の長軸と水平面とのなす角度であるのに対して、繊維角度φは楕円の長軸と水平面とのなす角度に、切断面とのなす角度を含めた角度である。
(Measurement method of average fiber angle)
FIG. 3 is an optical micrograph in the measurement of the average fiber angle of the core material of the vacuum heat insulating material according to Embodiment 1 of the present invention, and a measurement example is shown in the figure.
That is, in order to maintain the thickness of the vacuum heat insulating material, the outside of the vacuum heat insulating material was hardened with an epoxy resin, and then the epoxy resin was poured into the core material under vacuum to be cured. After curing, the central part of the vacuum heat insulating material is cut by a horizontal surface along the heat insulating direction, the cut surface is polished, and the surface perpendicular to the heat insulating direction of the core material is used as a horizontal plane (0 °) as a reference for the angle. Observed with an optical microscope. Assuming that the cross section of the fiber is all elliptical, the long axis length a [μm] and the short axis length b of all the fibers on the screen at any one location except the range of the peripheral width of 1 mm of the cut cross section. [μm] and the angle θ [°] between the major axis and the horizontal plane that is the reference of the angle are measured to 0.01 μm, 0.01 μm, and 0.01 ° units, respectively, and the measurement result is expressed by The fiber angle φ [°] was calculated by substituting in (), and this measurement was performed at two locations. The average value of a total of 200 fiber angles φ was taken as the average fiber angle. Here, the angle θ is an angle between the major axis of the ellipse and the horizontal plane, whereas the fiber angle φ is an angle including the angle between the major axis of the ellipse and the horizontal plane and the angle formed with the cut surface. is there.

Figure 2015145696
Figure 2015145696

図4は本発明の実施形態1に係る真空断熱材の芯材の平均繊維角度と熱伝導率との関係を示すグラフであり、縦軸に熱伝導率[mW/m・K]をとり、横軸に平均繊維角度[°]をとったものである。
この結果から明らかなように、平均繊維角度が14°以下の範囲において、熱伝導率は2.0mW/m・K以下でほぼ一定であった。これに対し、平均繊維角度が14°を超えると、熱伝導率は2.0mW/m・K以上に増加することが分った。
以上の結果より、熱伝導率2.0mW/m・K以下の真空断熱材を構成する芯材の平均繊維角度は14°以下である。
FIG. 4 is a graph showing the relationship between the average fiber angle of the core material of the vacuum heat insulating material according to Embodiment 1 of the present invention and the thermal conductivity, and the vertical axis represents the thermal conductivity [mW / m · K], The horizontal axis shows the average fiber angle [°].
As is apparent from the results, the thermal conductivity was almost constant at 2.0 mW / m · K or less in the range where the average fiber angle was 14 ° or less. In contrast, it has been found that when the average fiber angle exceeds 14 °, the thermal conductivity increases to 2.0 mW / m · K or more.
From the above results, the average fiber angle of the core material constituting the vacuum heat insulating material having a thermal conductivity of 2.0 mW / m · K or less is 14 ° or less.

図5は本発明の実施形態1に係る真空断熱材の芯材の繊維角度標準偏差と熱伝導率との関係を示すグラフであり、縦軸に熱伝導率[mW/m・K]をとり、横軸に繊維角度標準偏差[°]をとったものである。
この結果から明らかなように、繊維角度の標準偏差が12°以下の範囲において、熱伝導率は2.0mW/m・K以下でほぼ一定であった。これに対し、12°を超えると、2.0mW/m・K以上に増加することが分った。
以上の結果より、2.0mW/m・K以下の真空断熱材を構成する芯材の繊維角度の標準偏差は12°以下である。
FIG. 5 is a graph showing the relationship between the fiber angle standard deviation of the core material of the vacuum heat insulating material according to Embodiment 1 of the present invention and the thermal conductivity, and the vertical axis represents the thermal conductivity [mW / m · K]. The horizontal axis is the fiber angle standard deviation [°].
As is apparent from the results, the thermal conductivity was substantially constant at 2.0 mW / m · K or less in the range where the standard deviation of the fiber angle was 12 ° or less. On the other hand, when it exceeded 12 degrees, it turned out that it increases to 2.0 mW / m * K or more.
From the above results, the standard deviation of the fiber angle of the core material constituting the vacuum heat insulating material of 2.0 mW / m · K or less is 12 ° or less.

繊維長1.85mm以下の繊維の重量割合、平均繊維角度および繊維角度標準偏差と、熱伝導率との関係において、それぞれ変曲点を有することに関しては、パーコレーション理論によって説明できる。例えば、繊維長1.85mm以下の繊維の重量割合について考える。VIP(真空断熱材:Vacuum Insulation Panel)の断熱性能を悪化させる要因の一つとして、VIPの断熱方向に配向される繊維がある。繊維が短くなればなるほどVIPの断熱方向に配向される確率が高くなるため、短い繊維が少ないほうが断熱性能は高いと考えられる。しかしながら、断熱方向に配向した繊維が複数重なり、断熱方向への熱パス経路が繋がらなければ断熱性能への影響は少ない。   The relationship between the weight ratio of fibers having a fiber length of 1.85 mm or less, the average fiber angle and fiber angle standard deviation, and the thermal conductivity can be explained by percolation theory. For example, consider the weight ratio of fibers with a fiber length of 1.85 mm or less. One of the factors that deteriorate the heat insulation performance of VIP (Vacuum Insulation Panel) is a fiber oriented in the heat insulation direction of VIP. The shorter the fibers, the higher the probability that they will be oriented in the heat insulating direction of VIP. Therefore, it is considered that the heat insulating performance is higher when there are fewer short fibers. However, if a plurality of fibers oriented in the heat insulation direction overlap and the heat path path in the heat insulation direction is not connected, the influence on the heat insulation performance is small.

本発明では、繊維長1.85mm以下の繊維を短繊維と定義しており、この短繊維が少ないほうが断熱性は高いと考えられる。実験の結果、短繊維の重量割合が芯材の11wt%以下においては、熱伝導率は一定であり、短繊維の重量割合が芯材の11wt%を超えると、熱伝導率が急増したことが判明した。このことは、繊維長1.85mm以下の繊維の重量割合が芯材の11wt%である点が、断熱方向に配向された繊維が複数重なり、断熱方向への熱パス経路の繋がりが急増する変曲点である(パーコレーションの臨界点である)ことを示唆している。
以上の理由から、繊維長1.85mm以下の繊維の重量割合と熱伝導率との関係において、変曲点を有すると考えられる。さらに、平均繊維角度および繊維角度標準偏差と、熱伝導率との関係において、それぞれ変曲点を有することに関しても、同様に考えることができる。
In the present invention, fibers having a fiber length of 1.85 mm or less are defined as short fibers, and it is considered that the heat insulation is higher when the number of short fibers is smaller. As a result of the experiment, when the weight ratio of the short fibers is 11 wt% or less of the core material, the thermal conductivity is constant, and when the weight ratio of the short fibers exceeds 11 wt% of the core material, the thermal conductivity increases rapidly. found. This is because the weight ratio of the fiber having a fiber length of 1.85 mm or less is 11 wt% of the core material, and a plurality of fibers oriented in the heat insulation direction overlap, and the connection of the heat path path in the heat insulation direction increases rapidly. This suggests that the point is a critical point (percolation critical point).
For the above reasons, it is considered that there is an inflection point in the relationship between the weight ratio of fibers having a fiber length of 1.85 mm or less and the thermal conductivity. Furthermore, regarding the relationship between the average fiber angle, the fiber angle standard deviation, and the thermal conductivity, it can be similarly considered that each has an inflection point.

図6は本発明の実施形態1に係る真空断熱材を示す断面図である。
図6において、真空断熱材1は、繊維集合体で構成される芯材2と、芯材2を被覆するガスバリア性の外包材3と、外包材3の内部の水分を吸着して経時劣化を抑制する水分吸着剤4とを備えている。外包材3の内部は、1〜3Pa(パスカル)の真空度に減圧された状態で、開口部が例えばヒートシールの溶着シール部5によって密封されている。
FIG. 6 is a cross-sectional view showing a vacuum heat insulating material according to Embodiment 1 of the present invention.
In FIG. 6, the vacuum heat insulating material 1 is deteriorated with time by adsorbing a core material 2 composed of a fiber assembly, a gas barrier outer packaging material 3 covering the core material 2, and moisture inside the outer packaging material 3. And a moisture adsorbent 4 to be suppressed. The inside of the outer packaging material 3 is sealed by, for example, a heat-sealing welding seal portion 5 in a state where the pressure is reduced to a vacuum degree of 1 to 3 Pa (Pascal).

芯材2は、ガラス繊維、アルミナ繊維、シリカアルミナ繊維、シリカ繊維、ロックウール、炭化ケイ素繊維、又は不織布を使用でき、特に指定するものではない。   As the core material 2, glass fiber, alumina fiber, silica alumina fiber, silica fiber, rock wool, silicon carbide fiber, or nonwoven fabric can be used, and is not particularly specified.

外包材3は、少なくともガスバリア層および熱溶着層を有するものであり、必要に応じて表面保護層を設けてもよい。ガスバリア層としては、金属または金属酸化物、あるいはダイヤモンドライクカーボンを蒸着したプラスチックフィルムや金属箔を用いることができ、ガス透過を低減する目的で使用できるものであればよく、特に指定するものではない。
また、プラスチックフィルム上への金属酸化物蒸着の材料は、シリカ、アルミナを用いることができ、特に指定するものではない。
The outer packaging material 3 has at least a gas barrier layer and a heat welding layer, and may be provided with a surface protective layer as necessary. As the gas barrier layer, a metal film, a metal oxide, or a plastic film or metal foil on which diamond-like carbon is deposited can be used as long as it can be used for the purpose of reducing gas permeation, and is not particularly specified. .
Further, silica or alumina can be used as a material for metal oxide vapor deposition on the plastic film, and is not particularly specified.

外包材3の熱溶着層は、外包材3を構成するフィルムの中で最もガス透過度が大きい部分であり、熱溶着層の性質は真空断熱材の経時断熱性能に大きく影響する。熱溶着層の厚さは、減圧封止工程における封止品質の安定性や、熱溶着部端面からのガス侵入の抑制や、ガスバリア層として金属箔を使用した場合における熱伝導による表面からのヒートリークを考慮すると、25μm〜60μmが適している。   The heat welding layer of the outer packaging material 3 is a portion having the highest gas permeability in the film constituting the outer packaging material 3, and the property of the heat welding layer greatly affects the heat insulation performance of the vacuum heat insulating material over time. The thickness of the heat-welded layer is the stability of the sealing quality in the reduced-pressure sealing process, the suppression of gas intrusion from the end face of the heat-welded part, and the heat from the surface due to heat conduction when a metal foil is used as the gas barrier layer. In consideration of the leak, 25 μm to 60 μm is suitable.

熱溶着層の材料としては、無延伸ポリプロピレンフィルム、高密度ポリエチレンフィルム、直鎖状低密度ポリエチレンフィルムを用いることができ、特に指定するものではない。   As the material for the heat-welded layer, an unstretched polypropylene film, a high-density polyethylene film, or a linear low-density polyethylene film can be used, and is not particularly specified.

また、ガスバリア層の外側にさらに表面保護層を設けることも可能である。表面保護層としては、ポリエチレンテレフタレートフィルム、ポリプロピレンフィルム、ナイロンフィルムの延伸加工品が利用でき、さらに外側にナイロンフィルムを用いると、耐折り曲げ性、耐突き刺し性が向上する。   It is also possible to further provide a surface protective layer outside the gas barrier layer. As the surface protective layer, a stretched product of a polyethylene terephthalate film, a polypropylene film, or a nylon film can be used. Further, when a nylon film is used on the outer side, the bending resistance and the puncture resistance are improved.

また、外包材3の袋形状は、四方シール袋、ガゼット袋、三方シール袋、ピロー袋、センターテープシール袋があるが、特に指定するものではない。   The bag shape of the outer packaging material 3 includes a four-side seal bag, a gusset bag, a three-side seal bag, a pillow bag, and a center tape seal bag, but is not particularly specified.

水分吸着剤4は、例えば通気性の良い袋に挿入された酸化カルシウム(CaO)である。水分吸着剤4は、CaOのみに限定されず、例えばゼオライトのように、水分吸着性を有するものであればよく、特に限定されるものではない。   The moisture adsorbent 4 is, for example, calcium oxide (CaO) inserted into a bag having good air permeability. The moisture adsorbent 4 is not limited to CaO, and is not particularly limited as long as it has moisture adsorption properties such as zeolite.

次に、本発明の実施形態1に係る真空断熱材1の製造方法について説明する。
本実施形態の真空断熱材1に使用する芯材2は、例えばバインダーを使用しない乾式法によって製造したガラス繊維集合体で構成される。このガラス繊維集合体で構成される芯材2は、嵩密度が小さく真空断熱材1を製造する際のハンドリング性及び外包材3への挿入性が悪い。そのため、芯材2として取扱うためには加工により嵩密度を大きくする必要がある。
Next, the manufacturing method of the vacuum heat insulating material 1 which concerns on Embodiment 1 of this invention is demonstrated.
The core material 2 used for the vacuum heat insulating material 1 of this embodiment is comprised with the glass fiber aggregate manufactured by the dry method which does not use a binder, for example. The core material 2 composed of this glass fiber aggregate has a low bulk density and poor handling properties when inserting the vacuum heat insulating material 1 and insertability into the outer packaging material 3. Therefore, in order to handle as the core material 2, it is necessary to increase the bulk density by processing.

図7は本発明の実施形態1に係る真空断熱材の製造方法を示す模式図である。
加工装置6は、芯材2を圧縮する圧縮機構7を有する。芯材2は、真空断熱材1として必要な幅と長さにそろえられた上で、加工装置6に設置される。このとき、芯材2の厚みは、真空断熱材1の厚みと比較し10倍以上の厚みを有している。
FIG. 7 is a schematic view showing a method for manufacturing a vacuum heat insulating material according to Embodiment 1 of the present invention.
The processing device 6 includes a compression mechanism 7 that compresses the core material 2. The core material 2 is installed in the processing device 6 after being aligned with the width and length necessary for the vacuum heat insulating material 1. At this time, the thickness of the core material 2 is 10 times or more that of the vacuum heat insulating material 1.

次に、圧縮機構7により芯材2を繰り返し圧縮する。圧縮するときの圧力は、0.02〜0.07MPaが好ましく、0.02〜0.04MPaであればより好ましい。圧縮回数は50〜1000回が好ましい。前記条件で圧縮することで、繊維長1.85mm以下の繊維の重量割合は圧縮前の状態を維持したまま、繊維が徐々にずれて再配置を繰り返し、芯材2の断熱方向に対して垂直な面に対する繊維角度φの平均値が14°以下であり、標準偏差は12°以下である芯材2が得られる。   Next, the core material 2 is repeatedly compressed by the compression mechanism 7. The pressure when compressing is preferably 0.02 to 0.07 MPa, and more preferably 0.02 to 0.04 MPa. The number of compressions is preferably 50 to 1000 times. By compressing under the above conditions, the weight ratio of fibers with a fiber length of 1.85 mm or less keeps the state before compression, and the fibers gradually shift and repeat rearrangement, and perpendicular to the heat insulation direction of the core material 2. A core material 2 having an average value of the fiber angle φ with respect to a smooth surface of 14 ° or less and a standard deviation of 12 ° or less is obtained.

50〜1000回圧縮するときの圧力が0.07MPaを超えると、繊維が破断し、繊維長1.85mm以下の繊維の重量割合が芯材2の11wt%以上となり、断熱性能に優れた真空断熱材が得られない。その原因として、短繊維が、主体となる繊維の間を充填したり、主体となる繊維の間に絡みついたりして、繊維間に熱伝導が発生し、芯材の厚み方向に沿って熱伝導を引き起こすことによって、断熱性能を低下させているものと考えられる。   When the pressure when compressed 50 to 1000 times exceeds 0.07 MPa, the fiber breaks, the weight ratio of the fiber having a fiber length of 1.85 mm or less becomes 11 wt% or more of the core material 2, and vacuum insulation with excellent heat insulation performance The material is not obtained. The cause is that short fibers are filled between the main fibers or entangled between the main fibers, causing heat conduction between the fibers, and heat conduction along the thickness direction of the core material. It is considered that the heat insulation performance is lowered by causing

一方、50〜1000回圧縮するときの圧力が0.02MPaを下回ると、繊維がずれることによる再配置が起こりにくくなり、芯材2の断熱方向に対して垂直な面に対する繊維角度φの平均値を14°以下に制御することができず、断熱性能に優れた真空断熱材が得られない。また、嵩密度が増加せずハンドリング性及び外包材3への挿入性が改善されず、効率的に真空断熱材を製造できない。   On the other hand, when the pressure when compressed 50 to 1000 times is less than 0.02 MPa, rearrangement due to fiber displacement is less likely to occur, and the average value of the fiber angle φ with respect to the plane perpendicular to the heat insulating direction of the core material 2 Cannot be controlled to 14 ° or less, and a vacuum heat insulating material excellent in heat insulating performance cannot be obtained. Further, the bulk density does not increase, the handling property and the insertion property into the outer packaging material 3 are not improved, and the vacuum heat insulating material cannot be produced efficiently.

次に、嵩密度が高く加工された芯材2を外包材3へ挿入し、水分除去のための乾燥工程を経た後、水分吸着剤4が挿入され、外包材3の内部が1〜3Pa(パスカル)の真空度に減圧された状態で開口部がヒートシールにより密封されることによって、真空断熱材1が得られる。なお、乾燥工程は、芯材2とこの芯材2を被覆する外包材3の水分を除去できる条件である、例えば100℃で2時間の加熱を行えばよいが、加熱条件はこれに限定されず、芯材2とこの芯材2を被覆する外包材3の水分を除去できる条件であればよい。
また、水分吸着剤4は、乾燥工程を経た後に挿入されることに限定されず、乾燥工程の前や、加工装置6で、芯材2とこの芯材2を被覆する外包材3を圧縮する前に挿入されていてもよい。
Next, the core material 2 processed with a high bulk density is inserted into the outer packaging material 3, and after passing through a drying process for removing moisture, the moisture adsorbent 4 is inserted, and the interior of the outer packaging material 3 is 1 to 3 Pa ( The vacuum heat insulating material 1 is obtained by sealing the opening by heat sealing in a state where the pressure is reduced to Pascal). In the drying process, for example, heating may be performed at 100 ° C. for 2 hours, which is a condition capable of removing moisture from the core material 2 and the outer packaging material 3 covering the core material 2, but the heating condition is limited to this. The core material 2 and the outer packaging material 3 covering the core material 2 may be removed under any conditions.
Further, the moisture adsorbent 4 is not limited to being inserted after the drying process, but compresses the core material 2 and the outer packaging material 3 covering the core material 2 before the drying process or by the processing device 6. It may be inserted before.

本発明の実施形態1に係る真空断熱材1について、熱伝導率、繊維長1.85mm以下の繊維の重量割合、芯材2の断熱方向に対して垂直な面に対する繊維角度φの平均値及びその標準偏差について評価した。熱伝導率は、定常法により熱伝導率計で測定した。測定条件は、高温側37.7℃、低温側10℃、平均温度23.85℃で実施した。繊維長1.85mm以下の繊維の重量割合が芯材2の11wt%以下、芯材2の断熱方向に対して垂直な面に対する繊維角度φの平均値が14°以下、及び標準偏差が12°以下であれば、熱伝導率は2.0mW/m・K以下であった。以上の結果より、本実施形態の方法で加工した前記条件を満たす真空断熱材は、断熱性能に優れたものであることが分かった。   About the vacuum heat insulating material 1 which concerns on Embodiment 1 of this invention, thermal conductivity, the weight ratio of the fiber of 1.85 mm or less of fiber length, the average value of fiber angle (phi) with respect to a surface perpendicular | vertical with respect to the heat insulation direction of the core material 2, and The standard deviation was evaluated. The thermal conductivity was measured with a thermal conductivity meter by a steady method. The measurement conditions were a high temperature side of 37.7 ° C., a low temperature side of 10 ° C., and an average temperature of 23.85 ° C. The weight ratio of the fibers having a fiber length of 1.85 mm or less is 11 wt% or less of the core material 2, the average value of the fiber angle φ with respect to the plane perpendicular to the heat insulation direction of the core material 2 is 14 ° or less, and the standard deviation is 12 °. Below, the thermal conductivity was 2.0 mW / m · K or less. From the above results, it was found that the vacuum heat insulating material satisfying the above conditions processed by the method of the present embodiment was excellent in heat insulating performance.

実施形態2.
前記実施形態では、真空断熱材1及びその製造方法について説明してきたが、この真空断熱材1を使用することで、消費電力の小さな冷蔵庫の断熱箱を提供することができる。
図8は本発明の実施形態2に係る断熱箱(本実施形態では冷蔵庫の断熱箱を示す)を示す模式図であり、図中、前述の実施形態1のものに相当する部分には同一符号を付してある。
図8において、断熱箱8は、ABS樹脂で構成される内箱9と、鋼板で構成される外箱10と、内箱9と外箱10との間の空間の片面(内箱9側)に配設された真空断熱材1と、内箱9と外箱10との間の真空断熱材1以外の空間に発泡充填された発泡ウレタン断熱材11とを有している。なお、内箱9及び外箱10は、共通する面にそれぞれ開口部(図示せず)が形成されており、この開口部に開閉扉(図示せず)が設けられている。それ以外の部分は、一般的な冷蔵庫に用いられている断熱箱と違いがないため、図示及び説明を省略する。
Embodiment 2. FIG.
Although the said vacuum insulation material 1 and its manufacturing method were demonstrated in the said embodiment, the heat insulation box of a refrigerator with small power consumption can be provided by using this vacuum heat insulation material 1. FIG.
FIG. 8 is a schematic view showing a heat insulation box according to the second embodiment of the present invention (in this embodiment, a heat insulation box of a refrigerator). In the figure, parts corresponding to those of the first embodiment are denoted by the same reference numerals. Is attached.
In FIG. 8, the heat insulating box 8 includes an inner box 9 made of ABS resin, an outer box 10 made of a steel plate, and one side of the space between the inner box 9 and the outer box 10 (inner box 9 side). And a urethane foam heat insulating material 11 filled in a space other than the vacuum heat insulating material 1 between the inner box 9 and the outer box 10. The inner box 9 and the outer box 10 each have an opening (not shown) formed on a common surface, and an opening / closing door (not shown) is provided in the opening. Other parts are the same as the heat insulation box used in a general refrigerator, and thus illustration and description thereof are omitted.

前記の冷蔵庫の断熱箱8において、真空断熱材1が配置される範囲は限定するものではなく、内箱9と外箱10との間に形成される空間の全範囲であっても、あるいは一部であってもよく、また前記開閉扉の内部に配置されてもよい。   In the heat insulating box 8 of the refrigerator, the range in which the vacuum heat insulating material 1 is disposed is not limited, and may be the entire space formed between the inner box 9 and the outer box 10, or It may be a part, and may be arranged inside the opening / closing door.

前記のように構成した冷蔵庫の断熱箱8は、本発明の真空断熱材1を発泡ウレタン断熱材11中に埋設して併用しているので、さらに断熱効果が上がり、消費電力の低減等による省エネ効果が得られる。   The refrigerator heat insulating box 8 configured as described above uses the vacuum heat insulating material 1 of the present invention embedded in the urethane foam heat insulating material 11 and uses it in combination. An effect is obtained.

1 真空断熱材、2 芯材、3 外包材、4 水分吸着剤、5 溶着シール部、6 加工装置、7 圧縮機構、8 断熱箱、9 内箱、10 外箱、11 発泡ウレタン断熱材。   DESCRIPTION OF SYMBOLS 1 Vacuum heat insulating material, 2 core material, 3 outer packaging material, 4 moisture adsorption agent, 5 welding seal part, 6 processing apparatus, 7 compression mechanism, 8 heat insulation box, 9 inner box, 10 outer box, 11 urethane foam heat insulating material.

Claims (6)

繊維集合体で構成される芯材と、前記芯材を被覆する外包材とを備え、前記外包材の内部が減圧密封された真空断熱材であって、
前記芯材は繊維長1.85mm以下の繊維の重量割合が前記芯材の11wt%以下であることを特徴とする真空断熱材。
A vacuum heat insulating material comprising a core material composed of a fiber assembly and an outer packaging material covering the core material, the inside of the outer packaging material being sealed under reduced pressure,
The vacuum heat insulating material according to claim 1, wherein a weight ratio of fibers having a fiber length of 1.85 mm or less is 11 wt% or less of the core material.
前記芯材の断熱方向に対して垂直な面に対する前記繊維長1.85mm以下の繊維の繊維角度の平均値が14°以下であることを特徴とする請求項1に記載の真空断熱材。   2. The vacuum heat insulating material according to claim 1, wherein an average value of fiber angles of fibers having a fiber length of 1.85 mm or less with respect to a plane perpendicular to a heat insulating direction of the core material is 14 ° or less. 前記芯材の断熱方向に対して垂直な面に対する前記繊維長1.85mm以下の繊維の繊維角度の標準偏差が12°以下であることを特徴とする請求項2に記載の真空断熱材。   The vacuum heat insulating material according to claim 2, wherein a standard deviation of a fiber angle of the fiber having a fiber length of 1.85 mm or less with respect to a plane perpendicular to the heat insulating direction of the core material is 12 ° or less. 外箱と、前記外箱の内部に配置された内箱とを備え、前記外箱と内箱との間に請求項1〜3のいずれか一項に記載の真空断熱材を配置したことを特徴とする真空断熱材を用いた断熱箱。   It comprises an outer box and an inner box arranged inside the outer box, and the vacuum heat insulating material according to any one of claims 1 to 3 is arranged between the outer box and the inner box. Insulated box using a special vacuum insulation material. ガラス繊維の集合体を、荷重制御できる圧縮機構によって予め設定された圧力で厚み方向に予め設定された回数繰り返し圧縮することで、繊維長1.85mm以下の繊維の重量割合が11wt%以下である芯材を作成する工程と、
前記芯材を外包材へ挿入し、前記外包材の内部を予め設定された真空度に減圧する工程と、
前記外包材を減圧された状態で、開口部を密封する工程と、
を有することを特徴とする真空断熱材の製造方法。
The weight ratio of fibers having a fiber length of 1.85 mm or less is 11 wt% or less by repeatedly compressing an aggregate of glass fibers by a preset number of times in the thickness direction with a preset pressure by a load controllable compression mechanism. Creating a core material;
Inserting the core material into an outer packaging material, and depressurizing the interior of the outer packaging material to a preset vacuum degree;
Sealing the opening in a state where the outer packaging material is decompressed;
The manufacturing method of the vacuum heat insulating material characterized by having.
前記ガラス繊維の集合体を、前記圧縮機構によって0.02〜0.07MPaの圧力で50〜1000回圧縮することを特徴とする請求項5に記載の真空断熱材の製造方法。   The method for producing a vacuum heat insulating material according to claim 5, wherein the aggregate of glass fibers is compressed 50 to 1000 times at a pressure of 0.02 to 0.07 MPa by the compression mechanism.
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