JP2015134888A - 熱媒体油 - Google Patents
熱媒体油 Download PDFInfo
- Publication number
- JP2015134888A JP2015134888A JP2014007403A JP2014007403A JP2015134888A JP 2015134888 A JP2015134888 A JP 2015134888A JP 2014007403 A JP2014007403 A JP 2014007403A JP 2014007403 A JP2014007403 A JP 2014007403A JP 2015134888 A JP2015134888 A JP 2015134888A
- Authority
- JP
- Japan
- Prior art keywords
- heat medium
- rosin
- rosins
- medium oil
- butanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 44
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 44
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000003921 oil Substances 0.000 claims abstract description 36
- 150000002148 esters Chemical class 0.000 claims abstract description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000001298 alcohols Chemical class 0.000 claims abstract description 9
- 238000009835 boiling Methods 0.000 claims abstract description 9
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims abstract description 6
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003784 tall oil Substances 0.000 claims abstract description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims abstract 4
- 235000013305 food Nutrition 0.000 abstract description 7
- 229930014626 natural product Natural products 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 150000003138 primary alcohols Chemical class 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 28
- 241000196324 Embryophyta Species 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 150000004702 methyl esters Chemical class 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 description 3
- 239000008158 vegetable oil Substances 0.000 description 3
- PKQYSCBUFZOAPE-UHFFFAOYSA-N 1,2-dibenzyl-3-methylbenzene Chemical compound C=1C=CC=CC=1CC=1C(C)=CC=CC=1CC1=CC=CC=C1 PKQYSCBUFZOAPE-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- UMSGIWAAMHRVQI-UHFFFAOYSA-N 1-ethyl-4-(4-ethylphenyl)benzene Chemical group C1=CC(CC)=CC=C1C1=CC=C(CC)C=C1 UMSGIWAAMHRVQI-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000002551 biofuel Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- -1 demulsifiers Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 235000018927 edible plant Nutrition 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010735 electrical insulating oil Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000010773 plant oil Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
Description
酸価:JIS K0070に準じて測定した。
粘度:B型粘度計(製品名「VISCO BLOCK VTB−250」、(株)トキメック製、ローターNo.HM−3)を用い、40℃で測定した。
沸点:試料100mlと沸騰石をト字管が設置された内容量200mlのフラスコに入れ、温度計の水銀球の上端がト字管の留出口の中央部にくるように設置した。ついで、マントルヒーターで加熱しながら、1分間に3〜4mlの留出速度で蒸留し始めた時の温度を沸点として読み取った。
ロジン類の含有率:ロジン類の分子量を302、アルコール類の分子量をXとし、下記の式により算出した。
ロジン類の含有率(%)=〔302/(X+302)〕×100
引火点:JIS K2265に準じ、クリーブランド開放式引火点測定装置にて測定した。
熱伝導率:熱線法(JIS R2251−1を参照)に準じ、熱伝導率測定装置(商品名「ARC−TC−1000型」、アグネ社製)を用いて、150℃で測定した。
中国ガムロジンのメチルエステル(荒川化学工業(株)製、試作品)の測定値(酸価、粘度、沸点、引火点、熱伝導率)、植物由来成分率の計算値を表1に示す。
中国不均化ロジンのメチルエステル(荒川化学工業(株)製、試作品)の各測定値などを表1に示す。
中国水素化ロジンのメチルエステル(荒川化学工業(株)製、試作品)の各測定値などを表1に示す。
中国不均化ロジンのエチルエステル(荒川化学工業(株)製、試作品)の各測定値などを表1に示す。
中国不均化ロジンのブチルエステル(荒川化学工業(株)製、試作品)の各測定値などを表1に示す。
Claims (5)
- ロジン類と炭素数1〜10の一価アルコール類からなる液状ロジンエステル類のうちの少なくとも1種を含有することを特徴とする熱媒体油。
- 前記ロジン類が、精製ロジン、不均化ロジンおよび水素化ロジンからなる群より選ばれる少なくとも1種である請求項1記載の熱媒体油。
- 前記アルコール類が、メタノール、エタノール、n−プロパノール、イソプロパノール、n−ブタノール、イソブタノール、sec−ブタノールおよびtert−ブタノールからなる群より選ばれる少なくとも1種である請求項1または2に記載の熱媒体油。
- 前記ロジンエステル類が、酸価が2.0mgKOH/g以下、40℃における粘度が2000mPa・s以下、沸点が300℃以上、引火点が150℃以上、および150℃における熱伝導率が0.11W/m・K以上のものである請求項1〜3のいずれかに記載の熱媒体油。
- 前記ロジンエステル類におけるロジン類の含有率が50〜90重量%である請求項1〜4のいずれかに記載の熱媒体油。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP2014007403A JP6168412B2 (ja) | 2014-01-20 | 2014-01-20 | 熱媒体油 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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JP2014007403A JP6168412B2 (ja) | 2014-01-20 | 2014-01-20 | 熱媒体油 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015134888A true JP2015134888A (ja) | 2015-07-27 |
JP6168412B2 JP6168412B2 (ja) | 2017-07-26 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2014007403A Expired - Fee Related JP6168412B2 (ja) | 2014-01-20 | 2014-01-20 | 熱媒体油 |
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JP (1) | JP6168412B2 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102354474B1 (ko) * | 2021-02-17 | 2022-01-20 | 김동관 | 폐기물 유화장치 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5636569A (en) * | 1979-09-03 | 1981-04-09 | Agency Of Ind Science & Technol | Flon-resistant heat medium oil |
JPH03109493A (ja) * | 1989-09-22 | 1991-05-09 | Nippon Steel Corp | レールおよび車輪用潤滑剤 |
JPH059481A (ja) * | 1991-06-28 | 1993-01-19 | Tonen Corp | トラクシヨンドライブ流体 |
US5932030A (en) * | 1995-06-19 | 1999-08-03 | Sony Corporation | Flux for soldering using solder preforms |
JP2000072715A (ja) * | 1998-08-31 | 2000-03-07 | Idemitsu Kosan Co Ltd | 多価アルコールエステル化合物及び該化合物を含む潤滑油組成物 |
JP2012201833A (ja) * | 2011-03-28 | 2012-10-22 | Lion Corp | エステル合成油 |
WO2013065653A1 (ja) * | 2011-10-31 | 2013-05-10 | ぺんてる株式会社 | インキ組成物 |
-
2014
- 2014-01-20 JP JP2014007403A patent/JP6168412B2/ja not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5636569A (en) * | 1979-09-03 | 1981-04-09 | Agency Of Ind Science & Technol | Flon-resistant heat medium oil |
JPH03109493A (ja) * | 1989-09-22 | 1991-05-09 | Nippon Steel Corp | レールおよび車輪用潤滑剤 |
JPH059481A (ja) * | 1991-06-28 | 1993-01-19 | Tonen Corp | トラクシヨンドライブ流体 |
US5932030A (en) * | 1995-06-19 | 1999-08-03 | Sony Corporation | Flux for soldering using solder preforms |
JP2000072715A (ja) * | 1998-08-31 | 2000-03-07 | Idemitsu Kosan Co Ltd | 多価アルコールエステル化合物及び該化合物を含む潤滑油組成物 |
JP2012201833A (ja) * | 2011-03-28 | 2012-10-22 | Lion Corp | エステル合成油 |
WO2013065653A1 (ja) * | 2011-10-31 | 2013-05-10 | ぺんてる株式会社 | インキ組成物 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102354474B1 (ko) * | 2021-02-17 | 2022-01-20 | 김동관 | 폐기물 유화장치 |
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Publication number | Publication date |
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JP6168412B2 (ja) | 2017-07-26 |
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