JP2014521128A5 - - Google Patents
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- JP2014521128A5 JP2014521128A5 JP2014521820A JP2014521820A JP2014521128A5 JP 2014521128 A5 JP2014521128 A5 JP 2014521128A5 JP 2014521820 A JP2014521820 A JP 2014521820A JP 2014521820 A JP2014521820 A JP 2014521820A JP 2014521128 A5 JP2014521128 A5 JP 2014521128A5
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- Prior art keywords
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- electrochromic device
- mixed oxide
- metal
- layer
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- 239000002184 metal Substances 0.000 claims 6
- 229910052751 metal Inorganic materials 0.000 claims 6
- 230000003287 optical Effects 0.000 claims 3
- 239000010416 ion conductor Substances 0.000 claims 2
- 238000004061 bleaching Methods 0.000 claims 1
- 150000002500 ions Chemical class 0.000 claims 1
- 230000031700 light absorption Effects 0.000 claims 1
- 229910044991 metal oxide Inorganic materials 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 claims 1
Claims (15)
- (a)エレクトロクロミック層または対電極層の一方を含む第1の電極と、
(b)前記エレクトロクロミック層または対電極層の他方を含む第2の電極と、
(c)前記第1および第2の電極間でイオンを伝導させるためのイオン伝導体層と、
(d)第1の導電層と、
(e)第2の導電層と
を含み、
前記第1および第2の電極ならびに前記イオン伝導体層が、前記第1の導電層と第2の導電層との間に挟まれており、
前記対電極層が、式LixNi(II)1−yNi(III)yMzOa(式中、Mは金属であり、xは約0から約10であり、yは約0から約1であり、zは約0から約10であり、aは約(0.5x+1+0.5y+z)から約(0.5x+1+0.5y+3.5z)である。)を有する少なくとも1種の混合酸化物を含む、
エレクトロクロミックデバイス。 - 前記混合酸化物が、式LixNi(II)(1−y)Ni(III)(y)M(A)zO(1+0.5x+0.5y+1.5z)を有し、式中、Aは、前記金属Mの酸化状態である請求項1に記載のエレクトロクロミックデバイス。
- M(A)が、Al(III)、Sc(III)、Cr(III)、Co(III)、Y(III)、Rh(III)、In(III)、La(III)、Ce(III)、Nd(III)、およびSm(III)からなる群から選択される、請求項2に記載のエレクトロクロミックデバイス。
- 前記混合酸化物が、式LixNi(II)(1−y)Ni(III)(y)M(A)zO(1+0.5x+0.5y+2z)を有し、式中、Aは、前記金属Mの酸化状態である請求項1に記載のエレクトロクロミックデバイス。
- M(A)が、Si(IV)、Ti(IV)、Mn(IV)、Zr(IV)、Sn(IV)、Ce(IV)、Hf(IV)、Re(IV)、およびIr(IV)からなる群から選択される、請求項4に記載のエレクトロクロミックデバイス。
- 前記混合酸化物が、式LixNi(II)(1−y)Ni(III)(y)M(A)zO(1+0.5x+0.5y+2.5z)を有し、式中、Aは、前記金属Mの酸化状態である請求項1に記載のエレクトロクロミックデバイス。
- M(A)が、V(V)、Nb(V)、Sb(V)、Ta(V)、およびPa(V)からなる群から選択される、請求項6に記載のエレクトロクロミックデバイス。
- 前記混合酸化物が、式LixNi(II)(1−y)Ni(III)(y)M(A)zO(1+0.5x+0.5y+3z)を有し、式中、Aは、前記金属Mの酸化状態である請求項1に記載のエレクトロクロミックデバイス。
- M(A)が、Cr(VI)、Se(VI)、Mo(VI)、Te(VI)、およびW(VI)からなる群から選択される、請求項8に記載のエレクトロクロミックデバイス。
- 前記混合酸化物が、Li2.3Ni(II)(0.5)Ni(III)(0.5)Y(III)0.3O3.1、Li 2.3 Ni(II) (0.5) Ni(III) (0.5) Zr(IV) 0.3 O 3.25 、Li 2.3 Ni(II) (0.5) Ni(III) (0.5) Hf(IV) 0.3 O 3.25 、Li 2.3 Ni(II) (0.5) Ni(III) (0.5) Zr(IV) 0.294 Hf(IV) 0.006 O 3.25 、Li 2.3 Ni(II) (0.5) Ni(III) (0.5) Ta(V) 0.3 O 3.4 のいずれかである、請求項1に記載のエレクトロクロミックデバイス。
- 前記混合酸化物は、追加の金属または金属酸化物がさらにドープされている、請求項1に記載のエレクトロクロミックデバイス。
- 前記混合酸化物が、約450nmの光学波長で、少なくとも約10μm−1の暗状態での光学密度を有するか、又は約450nmの光学波長で、約0.5μm −1 未満の漂白状態光吸収を有する請求項1に記載のエレクトロクロミックデバイス。
- 前記混合酸化物が、少なくとも約2.0の屈折率を有する、請求項1に記載のエレクトロクロミックデバイス。
- 前記対電極層の厚さが、約80nmから約500nmの範囲にある、請求項1に記載のエレクトロクロミックデバイス。
- 前記混合酸化物が、実質的に非晶質である、請求項1に記載のエレクトロクロミックデバイス。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161510381P | 2011-07-21 | 2011-07-21 | |
US61/510,381 | 2011-07-21 | ||
PCT/US2012/047569 WO2013013135A1 (en) | 2011-07-21 | 2012-07-20 | Electrochromic nickel oxide simultaneously doped with lithium and a metal dopant |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2014521128A JP2014521128A (ja) | 2014-08-25 |
JP2014521128A5 true JP2014521128A5 (ja) | 2015-10-01 |
JP6067010B2 JP6067010B2 (ja) | 2017-01-25 |
Family
ID=46639675
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014521820A Active JP6067010B2 (ja) | 2011-07-21 | 2012-07-20 | リチウムおよび金属ドーパントが同時にドープされたエレクトロクロミック酸化ニッケル |
Country Status (6)
Country | Link |
---|---|
US (5) | US8687261B2 (ja) |
EP (1) | EP2734601B1 (ja) |
JP (1) | JP6067010B2 (ja) |
KR (1) | KR101933370B1 (ja) |
CN (2) | CN107300819B (ja) |
WO (1) | WO2013013135A1 (ja) |
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-
2012
- 2012-07-20 EP EP12744150.9A patent/EP2734601B1/en active Active
- 2012-07-20 KR KR1020147004337A patent/KR101933370B1/ko active IP Right Grant
- 2012-07-20 CN CN201710580279.9A patent/CN107300819B/zh active Active
- 2012-07-20 CN CN201280046248.0A patent/CN103814107B/zh active Active
- 2012-07-20 WO PCT/US2012/047569 patent/WO2013013135A1/en active Application Filing
- 2012-07-20 JP JP2014521820A patent/JP6067010B2/ja active Active
- 2012-07-20 US US13/554,144 patent/US8687261B2/en active Active
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2013
- 2013-09-19 US US14/031,573 patent/US9651845B2/en active Active
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2017
- 2017-04-05 US US15/479,942 patent/US10514581B2/en active Active
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2019
- 2019-11-20 US US16/689,799 patent/US11520204B2/en active Active
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2022
- 2022-10-31 US US18/051,309 patent/US20230168557A1/en active Pending
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