JP2014521128A5 - - Google Patents

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JP2014521128A5
JP2014521128A5 JP2014521820A JP2014521820A JP2014521128A5 JP 2014521128 A5 JP2014521128 A5 JP 2014521128A5 JP 2014521820 A JP2014521820 A JP 2014521820A JP 2014521820 A JP2014521820 A JP 2014521820A JP 2014521128 A5 JP2014521128 A5 JP 2014521128A5
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electrochromic device
mixed oxide
metal
layer
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JP2014521820A
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JP2014521128A (ja
JP6067010B2 (ja
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Priority claimed from PCT/US2012/047569 external-priority patent/WO2013013135A1/en
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Claims (15)

  1. (a)エレクトロクロミック層または対電極層の一方を含む第1の電極と、
    (b)前記エレクトロクロミック層または対電極層の他方を含む第2の電極と、
    (c)前記第1および第2の電極間でイオンを伝導させるためのイオン伝導体層と、
    (d)第1の導電層と、
    (e)第2の導電層と
    を含み、
    前記第1および第2の電極ならびに前記イオン伝導体層が、前記第1の導電層と第2の導電層との間に挟まれており、
    前記対電極層が、式LiNi(II)1−yNi(III)(式中、Mは金属であり、xは約0から約10であり、yは約0から約1であり、zは約0から約10であり、aは約(0.5x+1+0.5y+z)から約(0.5x+1+0.5y+3.5z)である。)を有する少なくとも1種の混合酸化物を含む、
    エレクトロクロミックデバイス。
  2. 前記混合酸化物が、式LiNi(II)(1−y)Ni(III)(y)M(A)(1+0.5x+0.5y+1.5z)を有し、式中、Aは、前記金属Mの酸化状態である請求項1に記載のエレクトロクロミックデバイス。
  3. M(A)が、Al(III)、Sc(III)、Cr(III)、Co(III)、Y(III)、Rh(III)、In(III)、La(III)、Ce(III)、Nd(III)、およびSm(III)からなる群から選択される、請求項2に記載のエレクトロクロミックデバイス。
  4. 前記混合酸化物が、式LiNi(II)(1−y)Ni(III)(y)M(A)(1+0.5x+0.5y+2z)を有し、式中、Aは、前記金属Mの酸化状態である請求項1に記載のエレクトロクロミックデバイス。
  5. M(A)が、Si(IV)、Ti(IV)、Mn(IV)、Zr(IV)、Sn(IV)、Ce(IV)、Hf(IV)、Re(IV)、およびIr(IV)からなる群から選択される、請求項4に記載のエレクトロクロミックデバイス。
  6. 前記混合酸化物が、式LiNi(II)(1−y)Ni(III)(y)M(A)(1+0.5x+0.5y+2.5z)を有し、式中、Aは、前記金属Mの酸化状態である請求項1に記載のエレクトロクロミックデバイス。
  7. M(A)が、V(V)、Nb(V)、Sb(V)、Ta(V)、およびPa(V)からなる群から選択される、請求項6に記載のエレクトロクロミックデバイス。
  8. 前記混合酸化物が、式LiNi(II)(1−y)Ni(III)(y)M(A)(1+0.5x+0.5y+3z)を有し、式中、Aは、前記金属Mの酸化状態である請求項1に記載のエレクトロクロミックデバイス。
  9. M(A)が、Cr(VI)、Se(VI)、Mo(VI)、Te(VI)、およびW(VI)からなる群から選択される、請求項8に記載のエレクトロクロミックデバイス。
  10. 前記混合酸化物が、Li2.3Ni(II)(0.5)Ni(III)(0.5)Y(III)0.33.1Li 2.3 Ni(II) (0.5) Ni(III) (0.5) Zr(IV) 0.3 3.25 、Li 2.3 Ni(II) (0.5) Ni(III) (0.5) Hf(IV) 0.3 3.25 、Li 2.3 Ni(II) (0.5) Ni(III) (0.5) Zr(IV) 0.294 Hf(IV) 0.006 3.25 、Li 2.3 Ni(II) (0.5) Ni(III) (0.5) Ta(V) 0.3 3.4 のいずれかである、請求項1に記載のエレクトロクロミックデバイス。
  11. 前記混合酸化物は、追加の金属または金属酸化物がさらにドープされている、請求項1に記載のエレクトロクロミックデバイス。
  12. 前記混合酸化物が、約450nmの光学波長で、少なくとも約10μm−1の暗状態での光学密度を有するか、又は約450nmの光学波長で、約0.5μm −1 未満の漂白状態光吸収を有する請求項1に記載のエレクトロクロミックデバイス。
  13. 前記混合酸化物が、少なくとも約2.0の屈折率を有する、請求項1に記載のエレクトロクロミックデバイス。
  14. 前記対電極層の厚さが、約80nmから約500nmの範囲にある、請求項1に記載のエレクトロクロミックデバイス。
  15. 前記混合酸化物が、実質的に非晶質である、請求項1に記載のエレクトロクロミックデバイス。
JP2014521820A 2011-07-21 2012-07-20 リチウムおよび金属ドーパントが同時にドープされたエレクトロクロミック酸化ニッケル Active JP6067010B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161510381P 2011-07-21 2011-07-21
US61/510,381 2011-07-21
PCT/US2012/047569 WO2013013135A1 (en) 2011-07-21 2012-07-20 Electrochromic nickel oxide simultaneously doped with lithium and a metal dopant

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JP2014521128A JP2014521128A (ja) 2014-08-25
JP2014521128A5 true JP2014521128A5 (ja) 2015-10-01
JP6067010B2 JP6067010B2 (ja) 2017-01-25

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JP2014521820A Active JP6067010B2 (ja) 2011-07-21 2012-07-20 リチウムおよび金属ドーパントが同時にドープされたエレクトロクロミック酸化ニッケル

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US (5) US8687261B2 (ja)
EP (1) EP2734601B1 (ja)
JP (1) JP6067010B2 (ja)
KR (1) KR101933370B1 (ja)
CN (2) CN107300819B (ja)
WO (1) WO2013013135A1 (ja)

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