JP2014225013A - ハロー防止層を有するホログラフィック記録媒体およびその製造 - Google Patents
ハロー防止層を有するホログラフィック記録媒体およびその製造 Download PDFInfo
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- B32B2307/40—Properties of the layers or laminate having particular optical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
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-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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Abstract
【解決手段】基材層104ならびにキャリア箔102およびその上に配置された記録層101を組み合わせた少なくとも1つの複合材料を有する層状構成体300であって、層状構成体300は、キャリア箔102および記録層101を組み合わせた複合材料から脱離可能な黒色層103を含み、記録層101は、ポリイソシアネート成分、イソシアネート反応性成分、少なくとも1つの書込みモノマーおよび少なくとも1つの光開始剤を含む感光性ポリマー組成物から形成される感光性ポリマーであることを特徴とする。
【選択図】図3
Description
・高い光学性、低散乱性、理想的にはホログラフィック露光中の自己現像性、理想的には湿式化学的または熱的処理のない単純な再処理、良好な長期安定性、良好な環境安定性、生成物統合工程との親和性。
・次は、ホログラフィックパラメーターの更なる要件、例えばスペクトル感度、光化学的または光物理的処理における線形性、屈折率変調の大きさ、ホログラムのスペクトル幅、方位分解能、過露光の低傾向、および規定された角度およびスペクトル色を再生成し得る可能性である。
・機械的安定性、すなわちホログラフィック露光中における非振動性。よくある問題は、様々な視野角から見ることができるマスターホログラムにおける暗点である。これは、露光期間中の層状系の一部における不十分な安定性(「フラッピング」)の結果としてホログラム平面からの媒体振動によって透過ホログラムで引き起こされることが知られている。
・波面を保つ光学的に透明なベース材料。複屈折であるか、または厚み変動を有する物質が有するよくある問題は、トランファーホログラム平面における目に見える暗点である。複屈折は、レーザービームの規定された偏光(いわゆるs-s偏光)を局所的に変え得、そのために偏光変調およびホログラムを生成する輝度変調が作られる。従って、光強度がホログラフィック格子を構成するには足りず、そのコントラストは弱い。
・再帰反射の回避。一部のホログラフィックフィルムは、いわゆるハロー防止(anti-halo)仕上げを有し、例えばハレーション防止層の形状である。これは、光吸収材または反射防止層として機能し、記録層と逆側の背面層との間に組み込まれるか、または逆側に直接適用される更なる箔または層である。逆側とは、透過ホログラムが露光される時におけるレーザー遠隔側である。これらの位置におけるその機能は、散乱および反射光反射がベース材料(箔またはプレート)によって反射されて記録層に戻り、ゴーストホログラムとして知られる望ましくない更なるホログラムを生成することを防ぐことである。逆側の反射はまた、明るいホログラフィック領域の周りにハロー(halo)を生成し得る。当業者は、記録層とハロー防止層との間、逆側の基材とハロー防止層との間におけるあらゆる種類の境界層異質物または空気含有物がホログラムにおいてニュートンリングまたはストライプをもたらすであろうことも知っている。従って、ハロー防止層は、その隣接する前面層とぴったり重ねて処理を終わらせなければならない。ホログラムが使用可能であるためにハロー防止層が完全に満たさなければならない更なる要件は、ハロー防止層がホログラフィック露光および任意の次の現像/固定工程後に完全に分離できるという実現性である。
・基材層を付与する工程、
・キャリア箔上に記録層を適用することによって複合材料を製造する工程
を含む、本発明による層状構成体の製造方法であって、
黒色層は、複合材料から離れた面を向く基材層の表面上に配置され、記録層は、基材層を向くキャリア箔の表面上に配置され、ここで、これらの層は、黒色層、基材層、記録層およびキャリア箔の順で互いに特に直接重なり、または
黒色層は、基材層から離れた面を向くキャリア箔の表面上に配置され、記録層は、基材層を向くキャリア箔の表面上に配置され、ここでこれらの層は、基材層、記録層、キャリア箔および黒色層の順で互いに特に直接重なり、または
黒色層は、基材層から離れた面を向く記録層の表面上にあり、キャリア箔は、基材層を向く記録層の表面上にあり、ここでこれらの層は、基材層、キャリア箔、記録層および黒色層の順で互いに特に直接重なる
ことを特徴とする方法を提供する。
ポリイソシアネートが二量化またはオリゴマー化脂肪族および/または脂環族ジ-またはトリイソシアネートを含むことが特に好ましい。非常に特に好ましいポリイソシアネートは、HDI、TMDI、1,8-ジイソシアナト-4-(イソシアナトメチル)オクタンまたはその混合物に基づく、イソシアヌレート、ウレトジオンおよび/またはイミノオキサジアジンジオンである。
-CH2-CH(R)-O- (I)
〔式中、Rは、ヘテロ原子によって割り込まれてもよく(例えばエーテル酸素)もしくは置換されてもよいアルキルまたはアリール基、または水素である〕
のオキシアルキレン単位から構成され、Yは内在するスターターである〕
のヒドロキシル官能性マルチブロックコポリマーを含むイソシアネート反応性成分からなる。
図1は、本発明の層状構成体の第1の実施態様を示し、
図2は、本発明の層状構成体の第2の実施態様を示し、
図3は、本発明の層状構成体の第3の実施態様を示し、
図4は、感光性ポリマーフィルムの製造のための箔コーティング機器の概略的配置を示し、
図5は、λ=633nm(ヘリウムネオンレーザー)におけるホログラフィック媒体テスター(HMT)の配置を示す:M=鏡、S=シール、SF=空間フィルター、CL=コリメータレンズ、λ/2=λ/2プレート、PBS=偏光ビームスプリッター、D=検出器、I=絞り、α0=-16.8°、β0=36.8°は試料外(媒体の外)で測定されたコヒーレントビームの入射角である。RD=回転ステージの基準方向、
図6は、回転角Ωに対して丸としてプロットされた測定回折効率η、および実線としてKogelnik理論に合わせたもの、ならびに右側のy軸において黒色層のない送信電力を示し、
図7は、黒色層を用いた際の図6の測定曲線を示し、ならびに
図8は、試料の構成および用いた試料の位置を示す。
成分A:
Bayer MaterialScience AG(Leverkusen、独国)製の製品、その調製は以下に記載される。
成分B1(ホスホロチオイルトリス(オキシ-4,1-フェニレンイミノカルボニルオキシエタン-2,1-ジイル)トリアクリレート):
Bayer MaterialScience AG(Leverkusen、独国)製の製品、その調製は以下に記載される。
成分B2(2-({[3-(メチルスルファニル)フェニル]カルバモイル}オキシ)エチルプロプ-2-エノアート):
Bayer MaterialScience AG(Leverkusen、独国)の製品、その調製は以下に記載される。
成分C(ビス(2,2,3,3,4,4,5,5,6,6,7,7-ドデカフルオロヘプチル)(2,2,4-トリメチルヘキサン-1,6-ジイル)ビスカルバメート):
Bayer MaterialScience AG(Leverkusen、独国)の製品、その調製は以下に記載される。
成分D:
Fascat 4102 0.07%、ウレタン化触媒、ブチル錫トリス(2-エチルヘキサノエート)、Arkema GmbH(Duesseldorf、独国)製の製品。
BYK(登録商標)310:
BYK-Chemie GmbH(Wesel、独国)製のシリコーン系表面添加剤、キシレン中25%溶液
成分E:
0.26%ビス(2-エチルヘキシル)スルホスクシナートとしてC. I. Basic Blue 3、0.13%ビス(2-エチルヘキシル)スルホスクシナートとしてSafranine O、およびCGI 909 (BASF SE(Basle、スイス)製の実験生成物)1.5%を有する0.13%ビス(2-エチルヘキシル)スルホスクシナートとしてAstrazon Orange G、溶液として、5.8%の酢酸エチルに溶解。百分率は媒体の全組成物に基づく。色素の調製はPCT/EP 2011/069389から知られる。
成分F:
酢酸エチル(CAS番号141-78-6)。
成分G:
Desmodur(登録商標)N 3900、Bayer MaterialScience AG(Leverkusen、独国)の市販製品、ヘキサンジイソシアネート系ポリイソシアネート、イミノオキサジアジンジオンの比率30%以上、NCO含有量:23.5%。
キャリア基材:
キャリア箔1は、Hostaphan(登録商標)RNK 36μm、Mitsubishi Polyester Film GmbH(Wiesbaden、独国)の製品である。
キャリア箔2は、Transphan(登録商標)OG 622 SL(60μm)、LOFO High Tech Film GmbH(Weil am Rhein、独国)製の製品である。
キャリア箔3は、Tacphan(登録商標)915 GL(50μm)、LOFO High Tech Film GmbH(Weil am Rhein、独国)製の製品である。
成分Aの調製:
1Lフラスコ中に、0.18gの錫オクトアート、374.8gのε-カプロラクトンおよび374.8gの2官能性ポリテトラヒドロフランポリエーテルポリオール(OHの当量500g/モル)をまず充填し、120℃に加熱し、固体含有量(非揮発製成分に起因する比率)が99.5重量%以上まで、この温度に維持した。この後、冷却して、ワックス状の固体として生成物を得た。
500mL丸底フラスコ中に、0.1gの2,6-ジ-tert-ブチル-4-メチルフェノール、0.05gのジブチル錫ジラウレート(Desmorapid(登録商標)Z、Bayer MaterialScience AG、Leverkusen、独国)および213.07gの27%濃度溶液の酢酸エチル中トリス(p-イソシアナトフェニル)チオホスフェート(Desmodur(登録商標)RFE、Bayer MaterialScience AG(Leverkusen、独国)製の製品)をまず充填し、60℃に加熱した。その後、42.37gの2-ヒドロキシエチルアクリレートを滴下し、イソシアネート含有量が0.1%未満に低下するまで、混合物を60℃でさらに維持した。この後、冷却および減圧下での酢酸エチルの完全除去を行い、部分的に結晶性の固体として生成物を得た。
100mL丸底フラスコ中に、0.02gの2,6-ジ-tert-ブチル-4-メチルフェノール、0.01gのDesmorapid(登録商標)Z、および11.7gの3-(メチルチオ)フェニルイソシアネートをまず充填し、60℃まで加熱した。その後、8.2gの2-ヒドロキシエチルアクリレートを滴下し、イソシアネート含有量が0.1%未満に低下するまで、混合物を60℃でさらに維持した。この後、冷却して、淡黄色の液体として生成物を得た。
2000mL丸底フラスコ中に、0.02gのDesmorapid(登録商標)Zおよび3.60gの2,4,4-トリメチルヘキサン1,6-ジイソシアネート(TMDI)をまず充填し、70℃に加熱した。この後、11.39gの2,2,3,3,4,4,5,5,6,6,7,7-ドデカフルオロヘプタン-1-オールを滴下し、イソシアネート含有量が0.1%未満に低下するまで、混合物を70℃でさらに維持した。この後、冷却して無色のオイルとして生成物を得た。
本発明のおよび本発明でない感光性ポリマー組成物からの、フィルム形状のホログラフィック媒体について、連続的製造をここで説明する。
1 ストック貯蔵容器
2 計量添加手段
3 減圧脱気手段
4 フィルター
5 静的ミキサー
6 コーティング手段
7 循環空気乾燥機
8 キャリア箔
9 カバー層
黒色層1は、SK 5545 AD 68 S2、Bischof + Klein GmbH & Co. KG(Lengerich、独国)製の製品、黒色ポリプロピレン箔上のアクリレート接着剤の接着剤箔である。吸収係数Q=0.519。
黒色層2は、Dupli-Colorプラチナ、MOTIP DUPLI GmbH(Hassmersheim、独国)製の製品、アクリル酸系スプレーラッカーであり、80μmの層厚みで適用。吸収係数Q=0.503。ラッカー層の層厚み45μm。
黒色層3は、Dupli-Color Quality Paintジェット黒色マット、MOTIP DUPLI GmbH(Hassmersheim、独国)製の製品、耐候性合成樹脂スプレーラッカーであり、80μm層厚みで適用。吸収係数Q=0.510。ラッカー層の層厚み35μm。
黒色層4は、Marabu Buntlack Colorspray Professional、シルクマット、Marabu GmbH & Co. KG(Tamm、独国)製の製品、合成樹脂スプレーラッカーであり、80μm層厚みで適用。吸収係数Q=0.497。ラッカー層の層厚み50μm。
黒色層5は、Bayer MaterialScience AG(Leverkusen、独国)の製品であり、その調製は以下に記載される。吸収係数Q=0.501。ラッカー層の層厚み30μm。
黒色層6は、Bayer MaterialScience AG(Leverkusen、独国)の製品であり、その調製は以下に記載される。吸収係数Q=0.507。ラッカー層の層厚み40μm。
黒色層7は、3M Deutschland GmbH(Neuss、独国)製の製品コードScotch、Vinyl Electrical Tape 22を有する粘着テープである。吸収係数Q=0.507。
黒色層8は、nolax AG(Sempach-Station、スイス)製の製品コードn-10-129を有する粘着テープである(タイプ:黒色ポリカーボネートキャリア箔を有するゴム系感圧粘着テープ)。吸収係数Q=0.549。
黒色層9は、3M Deutschland GmbH(Neuss、独国)製の製品コードScotchcal 70を有する粘着テープである(タイプ:黒色キャリア箔を有するアクリレート系感圧粘着テープ)。吸収係数Q=0.508。
黒色層10は、AF Adhaesive Formteile GmbH(Pfinztal、独国)製の製品コードAF 24.449を有する粘着テープである(タイプ:黒色キャリア箔を有するシリコーン系感圧粘着テープ)。吸収係数Q=0.650。
黒色層11は、AF Adhaesive Formteile GmbH(Pfinztal、独国)製の製品コードAF 01.9473を有する粘着テープである(タイプ:黒色キャリア箔を有するアクリレート系感圧粘着テープ)。吸収係数Q=0.510。
黒色層12は、Huntsman Advanced Materials(欧州)BVBA(Everberg、ベルギー)製のAraldite 2026 A製品(ポリウレタンに基づく2成分液体接着剤)およびBayer MaterialScience AG(Leverkusen、独国)製の製品Makrofol DE 1-4、黒色を用い、その調製は以下に記載される。吸収係数Q=0.514。硬化接着剤層の層厚み40μm。
まず冷却器を備えたグラインド容器に室温で29.06gのDesmophen A160(Nuplex Resins GmbH(Bitterfeld-Wolfen、独国)製の製品、ソルベントナフサ中60%溶液)を充填し、次に0.20gのBYK(登録商標)141(BYK-Chemie GmbH(Wesel、独国)製の製品)および12.0gのSolvesso 100(Azelis Deutschland GmbH(Sankt Augustin、独国)製の製品)を充填する。この後、26.32gのBayferrox 318 M(LANXESS Deutschland GmbH(Leverkusen、独国)製の製品、CAS番号1317-61-9)および18gのMicro-Talc(Mondo Minerals BV(Amsterdam、オランダ)製の製品、CAS番号14807-96-6)を少しずつ添加する前に、1.0gのCAB-O-SIL(登録商標)TS-720シリカ(Cabot Rheinfelden GmbH & Co. KG(Rheinfelden、独国)製の製品)を手動で攪拌する。次にラッカー混合物を約17.3gの2.6〜3mmガラスビーズ(Sigmund Lindner GmbH(Warmensteinach、独国)製の製品)と混合し、溶解機においてプラスチックディスクを用いて2400rpmで30分間錬磨(grind)する。温度を最大+40℃とするために水冷を施し、次にふるい除去および室温で1日間温置試験を行う。
まずグラインド容器に室温で305.50gのBayhydrol UH 2593/1(Bayer MaterialScience AG(Leverkusen、独国)の製品、脂肪族、脂肪酸修飾アニオン性ポリウレタン分散体)および105.50gのBayhydrol UH 240(Bayer MaterialScience AG(Leverkusen、独国)の製品、脂肪族、アニオン性ポリエステル-ポリウレタン分散体)を充填する。800〜1000rpmで攪拌する溶解機ディスクを用いた攪拌下において(発泡を避けなければならない)、均質になるまでバインダーを1分間混合し、次に1.00gのBYK(登録商標)022(BYK-Chemie GmbH(Wesel、独国)製の製品)、1.00gのBYK(登録商標)028(BYK-Chemie GmbH(Wesel、独国)製の製品)、3.00gのBYK(登録商標)346(BYK-Chemie GmbH(Wesel、独国)製の製品)および3.75gのW 250大豆レシチン(Lubrizol Deutschland GmbH(Ritterhude、独国)製の製品)と連続して混合し、ここでは、各添加後に5分間攪拌する。その後、1.50gのBorchi Gel 0625(OMG Borchers GmbH(Langenfeld、独国)製の製品)を添加し、10分間攪拌する。最後に、この後に75.00gのブチルグリコール(Brenntag GmbH(Muelheim/Ruhr、独国)製の製品、完全脱イオン水中50%溶解)、および53.65gの水性顔料ペーストブラック(10.4重量%のSetaqua B E 270、Nuplex Resins GmbH(Bitterfeld-Wolfen、独国)製の製品および41.6重量%の完全脱イオン水からなり、32.0重量%のBorchi Gel 0851、OMG Borchers GmbH(Langenfeld、独国)製の製品および16.0重量%のColour Black FW 200、Degussa AG(Frankfurt/Main、独国)製の製品と混合した)の添加を行う。この2つを素早く連続して添加し、次にバッチ全体をさらに10分間攪拌する。
1.ガラスプレートの予洗浄:
サイズに関して可能であれば、実験室器具洗浄機において標準サイクル+乾燥サイクルでガラスプレートを予洗浄する。そうでなければ、スポンジ、洗浄液および水を用いてガラスを手で洗浄し、完全脱イオン水を用いてきれいにすすぎ、圧縮空気を用いて吹き飛ばし乾燥し、また清浄な薄紙を用いて再度乾燥する。大きなガラスプレートは、ラック上に置いた後に洗浄する場合に、より扱い易い。
a)黒色層1の適用
200mm×100mm以下のガラスプレートは、GSH 380ローラーラミネーターにおいて、ローラーの間に粘着テープを挿入し次に個々のガラスプレートにおいて押し付けることによって、ローラーからそこに適用した粘着テープを有する。次にテープを有するガラスプレートを、カッター刃を用いて切断する。領域全体が粘着テープと接触するのを達成するために、プラスチックスパチュラまたはドクターブレードを用いて、手で箔を個々の試料のガラス上に押しつけ、必要であれば閉じ込められた空気を絞り出す。
ラッカー処理するガラスプレートのガラス表面を、アセトンを用いて脱脂後、黒色スプレーラッカーを、予め降ったスプレー缶から6回十字に通して直接適用し、室温で1日間乾燥する。ラッカー処理されていない逆側を、クレープ粘着テープを用いて全体を覆う。
上記のラッカー組成物を、ポリマービーカーに置き、9.07gのDesmodur(登録商標)N 75 MPA/キシレン(Bayer MaterialScience AG(Leverkusen、独国)の製品)と混合し、次に、均一になるまで木製スパチュラを用いて約1分間攪拌し、240μmの高速フィルターを通してスプレーガンに導入する。
既に他方の側上に黒色層を有するガラスプレートを、ラミネートする表面を上に向けて置く。ラミネーション前に、その表面を、フィルター処理したEtOH、PAグレードを用いてスプレー処理し、抜けのない布を円状に動かして拭く。その直後に、ガラスプレートのリムを超えて約1〜2cm突き出るようなサイズの予め生成した感光性ポリマー片を剥がし、ラミネーション手動ローラーを用いて穏やかな圧力および流れるような動きでガラスプレート上にラミネートする。突出した端部を除去するため、カッター刃およびガラスプレートよりも各端部において約6mm小さい調製テンプレートの中心配置を用いて、ガラスを横切り、過剰分を切り取る。予め作成した試料を遮光する方法でアルミニウムバッグに充填し、シールする。
黒色層における反射率の測定
ガラスキャリアおよび黒色層の層状パッケージの透過率および反射スペクトルを、ETA-Optik分光計およびETA-RT CD測定システム(STEAG製)を用いて測定した。測定中、黒色層は、光源から離れた面を向くガラスキャリア側上であった。リファレンスとして、黒色ガラスキャリアも測定した。試料の反射率およびリファレンスの反射率をそれぞれ、532nmにおけるスペクトルから取り出した。評価のため、試料の反射率およびリファレンスの反射率の間に係数(割合)を作成した。この値は吸収係数Qという。
黒色層の厚みを、Mitutoyo Corporation(Kanagawa、Japan)製のマイクロメーター測定機器を用いて測定した。まず未塗工の基材を、複数点で厚み測定し、次に、塗工後に、黒色層と共に基材を厚み測定した。2つの値の間の差異を用いて黒色層の厚みを決定する。
物理的層厚みを、市販の白色光干渉計、例えばIngenieursbuero Fuchs製のFTM-Lite NIR層厚み測定器を用いて測定した。
約1gの試料を、仕上げ未処理の缶蓋において適用し、ペーパークリップを用いて完全に分布させた。缶蓋およびペーパークリップは事前に秤量した。ペーパークリップを加えた試料および缶蓋を、125℃で1時間オーブン乾燥した。固体含有量は:
(最終の重量−風袋)*100/(元の重量−風袋)
で与えられる。
報告された粘度は、DIN EN ISO 2431および/またはDIN 53211によるDIN 4mmによる流出カップ(DIN4カップ)を用いて測定した。
報告されたNCO価(イソシアネート含有量)は、DIN EN ISO 11909によって測定した。
測定は、全透過率を決定するために、Hunter Lab, FMS Jansen GmbH & Co. KG(Murnau am Staffelsee、独国)製のHunter Ultrascan Pro積分球分光計において標準規格ASTM E 1348/ISO 13468に従って行った。全透過率は360nm〜840nmの間の平均透過率を指し、ここではそれぞれ1シングル測定を5nm毎に行う。測定は、D65光源および10°の観測角を使用する。測定範囲は、測定を比色定量のために850nmに対して行う場合だけは除いて、350nm〜1100nmである。校正のために空気中の測定を用い、この測定の透過率を100%に設定する。
次に、「ホログラフィック媒体の製造」部分において記載されたように得られた媒体を、そのホログラフィック特性について、図5のような測定構成を用いて次にようにテストした:
ヘリウムネオンレーザー(Melles Griot 25-LHP-928-249、放射波長633nm)のビームを、空間フィルター(SF)およびコリメータレンズ(CL)を用いて、平行な均一のビームに変換した。シグナルおよびリファレンスビームの最終断面を、虹彩絞り(I)によって確立する。虹彩絞りの開きの直径は0.4cmである。偏光依存性ビームスプリッター(PBS)は、レーザービームを2つのコヒーレント同偏光ビームに分ける。λ/2プレートを通して、リファレンスビームの出力を0.5mWに調整し、シグナルビームの出力を0.5mWに調整した。出力は、試料を分離した半導体検出器(D)を用いて測定した。リファレンスビームの入射角(α0)は−26.8°であり、シグナルビームの入射角(β0)は26.8°である。角度は、ビーム方向に垂直な試料から始めて測定する。従って、図5によれば、α0は負号を有し、β0は正号を有する。試料(媒体)の場所において、2つの重なり合うビームの干渉場は、試料において2つのビーム入射の角ディセレクタに平行である明および暗ストライプの格子を生成した(透過ホログラム)。格子周期とも言われるストライプ間隔Λは、媒体において〜702nmである(媒体の屈折率は〜1.504と想定される)。
・両シャッター(S)を露光時間tの間、開ける。
・その後、シャッター(S)を閉じ、媒体は、まだ重合していない書込みモノマーの拡散を5分間可能とされる。
Kogelnikによれば、次が、透過ホログラムのブラッグ曲線η(Ω)に当てはまる:
2−計量添加手段
3−減圧脱気手段
4−フィルター
5−静的ミキサー
6−コーティング手段
7−循環空気乾燥機
8−キャリア箔
9−カバー層
Claims (13)
- 基材層(104)ならびにキャリア箔(102)およびその上に配置された記録層(101)を組み合わせた少なくとも1つの複合材料を有する層状構成体(100、200、300)であって、
層状構成体(100、200、300)は、キャリア箔(102)および記録層(101)を組み合わせた複合材料から脱離可能な黒色層(103)を含み、記録層(101)は、ポリイソシアネート成分、イソシアネート反応性成分、少なくとも1つの書込みモノマーおよび少なくとも1つの光開始剤を含む感光性ポリマー組成物から形成される感光性ポリマーであることを特徴とする、層状構成体。 - 記録層(101)はそこにホログラムを形成するのに適当であり、および/または少なくとも1つのホログラムが記録層(101)に形成され、ここでホログラムは、特に体積ホログラム、非常に好ましくは透過ホログラムであることを特徴とする、請求項1に記載の層状構成体。
- 黒色層(103)は、基材層(104)の一方の側上にあり、キャリア箔(102)および記録層(101)を組み合わせた複合材料は、基材層(104)の他方の側上にあり、記録層(101)は基材層(104)に面し、ここでこれらの層は特に、黒色層(103)、基材層(104)、記録層(101)およびキャリア箔(102)の順で互いに直接重なることを特徴とする、請求項1または2に記載の層状構成体。
- 黒色層(103)は、基材層(104)から離れた面を向くキャリア箔(102)の面上にあり、記録層(101)は、基材層(104)を向くキャリア箔(102)の面上にあり、ここでこれらの層は特に、基材層(104)、記録層(101)、キャリア箔(102)および黒色層(103)の順で互いに直接重なることを特徴とする、請求項1または2に記載の層状構成体。
- 黒色層(103)は、基材層(104)から離れた面を向く記録層(101)の面上にあり、キャリア箔(102)は、基材層(104)を向く記録層(101)の面上にあり、ここでこれらの層は特に、基材層(104)、キャリア箔(102)、記録層(101)および黒色層(103)の順で互いに直接重なることを特徴とする、請求項1または2に記載の層状構成体。
- 基材層(104)は、透明であり、>80%、好ましくは>89%のASTM E 1348 D65/10°半球透過率および<0.5%、好ましくは<0.1%のASTM D 1003ヘイズを有するガラスおよび熱可塑性プラスチックから特に選択されることを特徴とする、請求項1〜5のいずれかに記載の層状構成体。
- 黒色層(103)は、黒色粘着テープ、黒色ラミネート箔、黒色顔料含有ホットメルト接着剤、黒色顔料含有ホットメルト接着剤箔および黒色ラッカーから選択されることを特徴とする、請求項1〜6のいずれかに記載の層状構成体。
- 黒色層(103)は光散乱粒子を含まないことを特徴とする、請求項1〜7のいずれかに記載の層状構成体。
- 黒色層(103)は、Q≦0.70、好ましくはQ≦0.55、より好ましくはQ≦0.52の反射測定吸収係数を有し、ここで、吸収係数Qは、532nmの波長における透明なガラス側からの照射において、黒色層(103)を有さない同じガラスプレートと比較した、黒色層(103)を有するガラスプレートの反射比率を表すことを特徴とする、請求項1〜8のいずれかに記載の層状構成体。
- キャリア箔(102)は透明な箔から選択されることを特徴とする、請求項1〜9のいずれかに記載の層状構成体。
- キャリア箔(102)およびそれと独立して黒色粘着テープの箔は、ポリカーボネート、ポリエチレンテレフタラート、ポリブチレンテレフタラート、ポリエチレン、ポリプロピレン、酢酸セルロース、水和セルロース、硝酸セルロース、シクロオレフィンポリマー、ポリスチレン、ポリエポキシド、ポリスルホン、三酢酸セルロース、ポリアミド、ポリメチルメタクリレート、ポリ塩化ビニル、ポリビニルブチラール、ポリジシクロペンタジエン、およびその混合物および/またはラミネートに基づく箔、特にポリカーボネート、ポリエチレンテレフタラート、ポリアミド、三酢酸セルロースおよびその混合物および/またはラミネートに基づく箔から選択されることを特徴とする、請求項1〜10のいずれかに記載の層状構成体。
- ・基材層(104)を付与する工程、
・キャリア箔(102)上に記録層(101)を適用することによって複合材料を製造する工程
を含む、請求項1〜11のいずれかに記載の層状構成体(100、200、300)の製造方法であって、
黒色層(103)は、複合材料から離れた面を向く基材層(104)の表面上に配置され、記録層(101)は、基材層(104)を向くキャリア箔(102)の表面上に配置され、ここで、これらの層は特に、黒色層(103)、基材層(104)、記録層(101)およびキャリア箔(102)の順で互いに直接重なり、または
黒色層(103)は、基材層(104)から離れた面を向くキャリア箔(102)の表面上に配置され、記録層(101)は、基材層(104)を向くキャリア箔(102)の表面上に配置され、ここで、これらの層は特に、基材層(104)、記録層(101)、キャリア箔(102)および黒色層(103)の順で互いに直接重なり、または
黒色層(103)は、基材層(104)から離れた面を向く記録層(101)の表面上にあり、キャリア箔(102)は、基材層(104)を向く記録層(101)の表面上にあり、ここで、これらの層は特に、基材層(104)、キャリア箔(102)、記録層(101)および黒色層(103)の順で互いに直接重なることを特徴とする方法。 - 記録層(101)は、少なくともホログラム、特に体積ホログラムを製造するために露光され、ここで好ましくはホログラムが製造された後に、記録層(101)およびキャリア箔(102)を組み合わせた複合材料を基材層(104)から分離し、黒色層(103)を分離することを特徴とする、請求項12に記載の方法。
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