JP2014190423A - 一酸化窒素の品質維持方法 - Google Patents
一酸化窒素の品質維持方法 Download PDFInfo
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- JP2014190423A JP2014190423A JP2013066132A JP2013066132A JP2014190423A JP 2014190423 A JP2014190423 A JP 2014190423A JP 2013066132 A JP2013066132 A JP 2013066132A JP 2013066132 A JP2013066132 A JP 2013066132A JP 2014190423 A JP2014190423 A JP 2014190423A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/06—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with compressed gases
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
- C01B21/24—Nitric oxide (NO)
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0104—Shape cylindrical
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0107—Single phase
- F17C2223/0123—Single phase gaseous, e.g. CNG, GNC
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/01—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the phase
- F17C2225/0107—Single phase
- F17C2225/0123—Single phase gaseous, e.g. CNG, GNC
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/03—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the pressure level
- F17C2225/035—High pressure, i.e. between 10 and 80 bars
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0337—Heat exchange with the fluid by cooling
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
【解決手段】一酸化窒素を高圧ガス容器に保存した状態で運搬する際に、前記高圧ガス容器に一酸化窒素を1.96MPa〜3.5MPaのゲージ圧で充填することで保存し、前記高圧ガス容器の外表面温度を−15℃〜5℃の範囲に保持した状態で運搬する。
【選択図】図1
Description
3NO→NO2 +N2 O…(1)
-d[NO]/dt =k′[NO]3 = d[N2 O]/dt = d[NO2 ]/dt …(2)
ここで、k′は反応速度定数、 d/dt は時間微分、[NO]、[N2 O]、[N2 O]はそれぞれ一酸化窒素、二酸化窒素、亜酸化窒素のモル濃度である。
V=AP3 e(-B/(RT)) …(3)
式(3)を用いることで、充填圧力Pと高圧ガス容器の表面温度Tとから、不均化反応による亜酸化窒素または二酸化窒素の濃度の一日当たりの増加分Vすなわち生成速度を演算できる。その一日当たりの増加分Vに高圧ガス容器内での一酸化窒素の保存期間を乗じた濃度増加分が許容値以下となるように、充填圧力Pと高圧ガス容器の表面温度Tとを設定すればよい。
Claims (4)
- 一酸化窒素を高圧ガス容器に保存した状態で運搬する際に、前記高圧ガス容器に一酸化窒素を1.96MPa〜3.5MPaのゲージ圧で充填することにより保存し、前記高圧ガス容器の外表面温度を−15℃〜5℃の範囲に保持した状態で運搬することを特徴とする一酸化窒素の品質維持方法。
- 一酸化窒素を高圧ガス容器に保存した状態で運搬する際に、前記高圧ガス容器内における一酸化窒素の不均化反応による亜酸化窒素または二酸化窒素の生成速度と、前記高圧ガス容器への一酸化窒素の充填圧力と、前記高圧ガス容器の外表面温度との間の関係を表す実験式を求め、
求めた前記実験式と、前記高圧ガス容器内での一酸化窒素の保存期間と、その保存期間の経過時における亜酸化窒素または二酸化窒素の濃度増加分の許容値とから、前記高圧ガス容器への一酸化窒素の充填圧力と、前記高圧ガス容器の外表面温度とを設定することを特徴とする一酸化窒素の品質維持方法。 - 前記高圧ガス容器内における一酸化窒素の不均化反応による亜酸化窒素または二酸化窒素の濃度(体積比)の一日当たりの増加分をV(ppm/day)、前記高圧ガス容器への一酸化窒素の充填圧力をゲージ圧でP(MPa)、前記高圧ガス容器の外表面温度を絶対温度でT(K)、気体定数をR、実験により求められる定数をA、実験により求められる活性化エネルギーをBとして、前記実験式をV=AP3 e(-B/(RT)) とする請求項2に記載の一酸化窒素の品質維持方法。
- 前記高圧ガス容器を、収納室の温度調節機能を有するコンテナに収納して運搬する請求項1〜3の中の何れか1項に記載の一酸化窒素の品質維持方法。
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013066132A JP6041387B2 (ja) | 2013-03-27 | 2013-03-27 | 一酸化窒素の品質維持方法 |
SG11201507550SA SG11201507550SA (en) | 2013-03-27 | 2013-09-04 | Method for preserving quality of nitric oxide |
CN201380074487.1A CN105074318B (zh) | 2013-03-27 | 2013-09-04 | 一氧化氮的品质维持方法 |
KR1020157024721A KR101740842B1 (ko) | 2013-03-27 | 2013-09-04 | 일산화질소의 품질 유지 방법 |
PCT/JP2013/073787 WO2014155770A1 (ja) | 2013-03-27 | 2013-09-04 | 一酸化窒素の品質維持方法 |
US14/769,934 US9945516B2 (en) | 2013-03-27 | 2013-09-04 | Method for preserving quality of nitric oxide |
TW102132828A TWI598533B (zh) | 2013-03-27 | 2013-09-11 | 一氧化氮之品質維持方法 |
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JP2013066132A JP6041387B2 (ja) | 2013-03-27 | 2013-03-27 | 一酸化窒素の品質維持方法 |
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JP2014190423A true JP2014190423A (ja) | 2014-10-06 |
JP6041387B2 JP6041387B2 (ja) | 2016-12-07 |
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US (1) | US9945516B2 (ja) |
JP (1) | JP6041387B2 (ja) |
KR (1) | KR101740842B1 (ja) |
CN (1) | CN105074318B (ja) |
SG (1) | SG11201507550SA (ja) |
TW (1) | TWI598533B (ja) |
WO (1) | WO2014155770A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2019174181A (ja) * | 2018-03-27 | 2019-10-10 | 国立研究開発法人農業・食品産業技術総合研究機構 | 3成分同時分析装置および3成分同時分析方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111720728B (zh) * | 2020-05-15 | 2021-11-02 | 厚普清洁能源股份有限公司 | 一种限压式气体充装系统及充装方法 |
Family Cites Families (8)
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JP3880103B2 (ja) * | 1996-07-18 | 2007-02-14 | 住友精化株式会社 | 医療用一酸化窒素混合ガスおよびその製造方法 |
US6109260A (en) * | 1998-02-18 | 2000-08-29 | Datex-Ohmeda, Inc. | Nitric oxide administration device with timed pulse |
US8518457B2 (en) * | 2004-05-11 | 2013-08-27 | Pulmonox Technologies Corporation | Use of inhaled gaseous nitric oxide as a mucolytic agent or expectorant |
US7618594B2 (en) * | 2004-08-18 | 2009-11-17 | Geno Llc | Conversion of nitrogen dioxide (NO2) to nitric oxide (NO) |
US8518933B2 (en) * | 2009-04-23 | 2013-08-27 | Abbvie Inc. | Modulators of 5-HT receptors and methods of use thereof |
WO2011137124A1 (en) * | 2010-04-26 | 2011-11-03 | Geno Llc | Delivery of ultra pure nitric oxide (no) |
JP2014520113A (ja) * | 2011-06-10 | 2014-08-21 | ゲノ エルエルシー | 一酸化窒素(no)の加圧容器 |
FR2991026B1 (fr) * | 2012-05-24 | 2014-07-04 | Air Liquide Sante Int | Conditionnement a haute pression d'un melange gazeux no/azote |
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- 2013-03-27 JP JP2013066132A patent/JP6041387B2/ja active Active
- 2013-09-04 US US14/769,934 patent/US9945516B2/en active Active
- 2013-09-04 CN CN201380074487.1A patent/CN105074318B/zh active Active
- 2013-09-04 SG SG11201507550SA patent/SG11201507550SA/en unknown
- 2013-09-04 KR KR1020157024721A patent/KR101740842B1/ko active IP Right Grant
- 2013-09-04 WO PCT/JP2013/073787 patent/WO2014155770A1/ja active Application Filing
- 2013-09-11 TW TW102132828A patent/TWI598533B/zh active
Non-Patent Citations (1)
Title |
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JPN6013057758; Hirokazu TSUKAHARA, Takanobu ISHIDA, Mitsufumi MAYUMI: 'Gas-phase oxidation and disproportionation of nitric oxide' Methods in Enzymology Vol. 359, 2002, pages 168-179 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2019174181A (ja) * | 2018-03-27 | 2019-10-10 | 国立研究開発法人農業・食品産業技術総合研究機構 | 3成分同時分析装置および3成分同時分析方法 |
JP7048087B2 (ja) | 2018-03-27 | 2022-04-05 | 国立研究開発法人農業・食品産業技術総合研究機構 | 3成分同時分析装置および3成分同時分析方法 |
Also Published As
Publication number | Publication date |
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TW201437537A (zh) | 2014-10-01 |
KR101740842B1 (ko) | 2017-05-26 |
TWI598533B (zh) | 2017-09-11 |
SG11201507550SA (en) | 2015-10-29 |
KR20150137056A (ko) | 2015-12-08 |
CN105074318A (zh) | 2015-11-18 |
JP6041387B2 (ja) | 2016-12-07 |
US20160003414A1 (en) | 2016-01-07 |
US9945516B2 (en) | 2018-04-17 |
WO2014155770A1 (ja) | 2014-10-02 |
CN105074318B (zh) | 2017-05-03 |
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