JP2014169227A - Hair cosmetic composition - Google Patents
Hair cosmetic composition Download PDFInfo
- Publication number
- JP2014169227A JP2014169227A JP2013040212A JP2013040212A JP2014169227A JP 2014169227 A JP2014169227 A JP 2014169227A JP 2013040212 A JP2013040212 A JP 2013040212A JP 2013040212 A JP2013040212 A JP 2013040212A JP 2014169227 A JP2014169227 A JP 2014169227A
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic composition
- hair cosmetic
- agent
- oil
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 61
- 239000002537 cosmetic Substances 0.000 title claims abstract description 48
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 47
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 15
- 241000220317 Rosa Species 0.000 claims abstract description 11
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 5
- 239000003205 fragrance Substances 0.000 claims description 19
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims description 8
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 claims description 8
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 claims description 6
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 claims description 4
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 claims description 4
- 235000000484 citronellol Nutrition 0.000 claims description 4
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- 125000003118 aryl group Chemical group 0.000 claims description 3
- 229930007790 rose oxide Natural products 0.000 claims description 3
- 239000000796 flavoring agent Substances 0.000 abstract description 6
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- -1 drinia Chemical compound 0.000 description 25
- 230000000873 masking effect Effects 0.000 description 18
- 238000002156 mixing Methods 0.000 description 15
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- 229930195729 fatty acid Natural products 0.000 description 13
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- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
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- SFEOKXHPFMOVRM-BQYQJAHWSA-N γ-ionone Chemical compound CC(=O)\C=C\C1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-BQYQJAHWSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、アンモニアなどの不快臭をマスキングすることを特徴とする毛髪化粧料組成物に関する。 The present invention relates to a hair cosmetic composition characterized by masking an unpleasant odor such as ammonia.
毛髪化粧料組成物としては、染毛剤、脱染剤、脱色剤、脱染脱色剤などが知られている。上記の毛髪化粧料組成物は、一般的に、アルカリ剤及び酸化染料を含む第1剤、酸化剤を含む第2剤など、2種類以上の剤から調合される。これらの第1剤にはアルカリ剤としてアンモニアなどが配合されるが、これらの成分は施術者にとって不快臭であり大きな問題である。この不快臭をマスキングする手段としてさまざまな方法がある。(例えば、特許文献1〜3を参照)。 Known hair cosmetic compositions include hair dyes, decolorants, decolorizers, decolorizers and the like. The above-described hair cosmetic composition is generally prepared from two or more kinds of agents such as a first agent containing an alkaline agent and an oxidation dye, and a second agent containing an oxidizing agent. Although ammonia etc. are mix | blended with these 1st agents as an alkaline agent, these components are an unpleasant odor for a practitioner and are a big problem. There are various methods for masking this unpleasant odor. (For example, refer to Patent Documents 1 to 3).
特許文献1には、グアニジウム塩、アルカノールアミン、アンモニアおよび高級アルコールを含有し、刺激臭、頭皮への刺激が少なく、迅速に染色できる毛髪化粧料組成物が記載されている。 Patent Document 1 describes a hair cosmetic composition that contains a guanidinium salt, an alkanolamine, ammonia, and a higher alcohol, has little irritating odor and irritation to the scalp, and can be dyed quickly.
特許文献2には、ジアルキルシクロヘキサンを含有することにより、刺激臭や毛髪に対するダメージを与えるアルカリ剤の配合量を減らし、且つ優れた脱色力、染毛効果が得られる毛髪化粧料組成物を得ることが記載されている。 Patent Document 2 provides a hair cosmetic composition that contains dialkylcyclohexane to reduce the blending amount of an alkaline agent that gives an irritating odor or damage to the hair, and that has excellent decoloring power and hair dyeing effect. Is described.
特許文献3には、三剤型の脱色剤組成物又は染毛剤組成物の第3剤に水飴を配合し、使用直前に混合することにより、仕上がり後の毛髪の感触を良好にする毛髪化粧料組成物が記載されている。 In Patent Document 3, hair makeup that improves the feel of the hair after finishing by blending chickenpox into the third agent of the three-part type depigmenting composition or hair dye composition and mixing immediately before use. A material composition is described.
引用文献1は、グアニジウム塩を、引用文献2は、ジアルキルシクロヘキサンをそれぞれ配合し、いずれの文献も、刺激臭であるアンモニアの配合量を減らすことにより、不快臭を抑えることを目的としているが、脱色力を低下させるという問題があった。また、第1剤中に香料を賦香するため、経時的に香料が劣化して、マスキング力の低下や香料の変臭といった問題があった。 Although Cited Document 1 contains a guanidinium salt and Cited Document 2 contains a dialkylcyclohexane, and each document aims to suppress an unpleasant odor by reducing the amount of ammonia, which is an irritating odor, There was a problem of reducing the decoloring power. Moreover, since the fragrance | flavor was scented in the 1st agent, the fragrance | flavor deteriorated with time, and there existed a problem of a masking power fall or a fragrance | flavor change smell.
引用文献3では、第3剤に水飴を配合し、使用直前に混合することにより、水飴を使用時まで安定な状態で保存でき、仕上がり後の毛髪の感触を良好にする旨は記載されているが、アンモニアなどの刺激臭の低減は、配合量を減らすことにより、不快臭を抑えているに過ぎない。 In the cited document 3, it is described that the varicella is blended into the third agent and mixed immediately before use, so that the varicella can be stored in a stable state until use, and the finished hair feel is improved. However, the reduction of irritating odors such as ammonia merely suppresses unpleasant odors by reducing the blending amount.
また、いずれの引用文献においても、第3剤中に配合されている成分は、過硫酸塩のような脱色促進剤や、引用文献3のような仕上がりを目的とした成分の配合は記載されているが、アンモニアやアンモニウム塩が配合されている剤と、別の剤には香料は賦香されていない。 Also, in any cited document, the ingredients blended in the third agent include a decolorization accelerator such as persulfate and a blend of ingredients for the purpose of finishing such as cited document 3. However, no fragrance is added to the agent containing ammonia or ammonium salt and the other agent.
そのため、アンモニア臭をマスキングし、施術者が快適に施術できる毛髪化粧料組成物が望まれていた。 Therefore, a hair cosmetic composition that masks the ammonia odor and allows the practitioner to perform comfortably has been desired.
本発明者らは、上記の課題を解決するために鋭意検討を行った結果、アンモニアまたはアンモニウム塩を配合する剤と、それとは別の剤にバラの香気成分を配合することで、アンモニア臭をマスキングし、施術者が快適に施術できる毛髪化粧料を見出し、本願発明を完成するに至った。すなわち、本願発明は、アンモニアまたはアンモニウム塩を配合する剤と、それとは別の剤にバラの香気成分を配合することを特徴とする毛髪化粧料組成物を提供するものである。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that an ammonia odor can be obtained by blending a rose fragrance component in an agent that contains ammonia or an ammonium salt and another agent. The present inventors have completed the present invention by masking and finding a hair cosmetic that can be comfortably performed by the practitioner. That is, this invention provides the hair cosmetic composition characterized by mix | blending a rose fragrance | flavor component with the agent which mix | blends an ammonia or ammonium salt, and another agent.
本願発明の毛髪化粧料組成物は、アンモニア臭をマスキングし、施術者が快適に施術することができる。 The hair cosmetic composition of the present invention masks the ammonia odor and allows the practitioner to perform comfortably.
以下、本願発明の好適な実施形態について説明する。
本願発明の毛髪化粧料組成物は、毛髪の染色、脱色、脱染などの目的で使用されるものであれば良く、2剤式の酸化染毛剤、3剤式の酸化染毛剤、2剤式の脱色剤、3剤式の脱色剤などが挙げられる。
Hereinafter, preferred embodiments of the present invention will be described.
The hair cosmetic composition of the present invention may be any hair dyeing, decoloring, decoloring and the like, as long as it is a two-part oxidative hair dye, a three-part oxidative hair dye, Examples of the agent-type decolorizing agent include a three-agent type decolorizing agent.
本願発明の毛髪化粧料組成物は、2剤式の酸化染毛剤、3剤式の酸化染毛剤、2剤式の脱色剤、3剤式の脱色剤など、その混合比は通常実施される混合比であれば特に限定されない。 The hair cosmetic composition of the present invention has a two-component oxidative hair dye, a three-component oxidative hair dye, a two-component decolorant, a three-component decolorant, and the like, and the mixing ratio is usually implemented. The mixing ratio is not particularly limited.
本願発明に用いられる香気成分としては、香調は特に限定されないが、好ましくはダマセノン、ダマスコン、フェニルエチルアルコール、シトロネロール、ゲラニオール、ネロール、ローズオキシド、シトロネリルアセテート、フェニルエチルアセテート、ドリニア、ゲラニルアセテート、フェニルアセトアルデヒドジメチルアセタール、ジメチルベンジルカルボニルアセテートなどのバラの香気成分が挙げられる。 As the fragrance component used in the present invention, the fragrance is not particularly limited, but preferably damasenone, damascon, phenylethyl alcohol, citronellol, geraniol, nerol, rose oxide, citronellyl acetate, phenylethyl acetate, drinia, geranyl acetate, Examples include aromatic components of rose such as phenylacetaldehyde dimethyl acetal and dimethylbenzyl carbonyl acetate.
上記香気成分は、1種または2種以上を含有しても良い。また、配合量は、特に限定されないが、0.1〜1.0質量%が好ましく、さらに0.15〜0.40質量%が好ましい。 The fragrance component may contain one kind or two or more kinds. Moreover, although a compounding quantity is not specifically limited, 0.1-1.0 mass% is preferable, and also 0.15-0.40 mass% is preferable.
本願発明には、上記の成分のほか、次の成分の1種または2種以上を適宜含有しても良い。 In addition to the above components, the present invention may appropriately include one or more of the following components.
本願発明における毛髪化粧料組成物は、その他の香気成分として、炭化水素類、アルコール類、フェノール類、アルデヒド類、ケトン類、エステル類などの単独あるいは組み合わせによって得られる合成香料、花精油類、種子・果実の精油類、根・根茎の精油類、ハーブの精油類、枝葉・幹材の精油類などに分類される天然香料、加水分解法、酵素分解法、凍結融解法、溶媒抽出法、水蒸気蒸留法などによって得られる香気成分を含む抽出物などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention comprises, as other aroma components, synthetic fragrances, flower essential oils, seeds obtained by a single or combination of hydrocarbons, alcohols, phenols, aldehydes, ketones, esters, etc.・ Natural fragrances classified into fruit essential oils, root / rhizome essential oils, herb essential oils, branch leaves / stem essential oils, etc., hydrolysis method, enzymatic decomposition method, freeze-thaw method, solvent extraction method, water vapor You may contain at least 1 among the extract containing the aromatic component obtained by a distillation method etc.
本発明における毛髪化粧料組成物は、合成香料として、リナロール、リナリルアセテート、ターピネオール、シトロネロール、フェニルエチルアルコール、ベンジルアセテート、アニスアルデヒド、イソ・イー・スーパー、エチルアセテート、シトラール、ヘリオトロピン、ベンジルアルコール、エチルブチレート、シンナミックアルデヒド、オイゲノール、エチルイソバレレート、メントール、オクタナール、デカナール、アネトール、シトロネリルイソブチレート、シトロネリルニトリル、シトロネリルプロピオネート、ジヒドロミルセノール、シトロネラール、リリアール、トリプラール、γ−ノナラクトン、ゲラニルホーメート、ゲラニルイソブチレート、ゲラニルニトリル、ジメチルベンジルカルビノール、シス−3−ヘキセノール、シネオール、アリルヘプタノエート、シンナミルアセテート、ジメチルベンジルカルビニルアセテート、α−イオノン、β−イオノン、γ−イオノン、リモネン、アリルヘプタノエート、アリルオクタノエート、α−ピネン、ベンズアルデヒド、リナロールオキサイド、スチラリルアセテート、テトラヒドロゲラニオール、テトラヒドロリナロール、メチルアンスラニレート、ネロリドール、リラール、ヘリオナール、イソアミルサリシレート、ヘキシルアセテート、エチル−2−メチルブチレート、などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention includes linalool, linalyl acetate, terpineol, citronellol, phenylethyl alcohol, benzyl acetate, anisaldehyde, iso-e super, ethyl acetate, citral, heliotropin, benzyl alcohol, as a synthetic fragrance. Ethyl butyrate, cinnamic aldehyde, eugenol, ethyl isovalerate, menthol, octanal, decanal, anethole, citronellyl isobutyrate, citronellyl nitrile, citronellyl propionate, dihydromyrsenol, citronellal, lyial, tripral, γ-nonalactone, geranyl formate, geranyl isobutyrate, geranyl nitrile, dimethylbenzyl carbinol, cis-3-hexeno , Cineol, allyl heptanoate, cinnamyl acetate, dimethylbenzyl carvinyl acetate, α-ionone, β-ionone, γ-ionone, limonene, allyl heptanoate, allyl octanoate, α-pinene, benzaldehyde, linalool oxide , Styrylyl acetate, tetrahydrogeraniol, tetrahydrolinalool, methylanthranilate, nerolidol, rilal, helional, isoamyl salicylate, hexyl acetate, ethyl-2-methylbutyrate, etc. .
本発明における毛髪化粧料組成物は、精油として、イランイラン油、ローズ油、ネロリ油、クローブ油、スターアニス油、レモン油、ベルガモット油、ライム油、フェンネル油、イリス油、レモングラス油、ラベンダー油、ペパーミント油、クラリセージ油、タイム油、アビエス油、ヒノキ油、サンダルウッド油、ローズウッド油、ユーカリ油などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention comprises, as essential oils, ylang ylang oil, rose oil, neroli oil, clove oil, star anise oil, lemon oil, bergamot oil, lime oil, fennel oil, iris oil, lemongrass oil, lavender You may contain at least 1 among oil, peppermint oil, clary sage oil, thyme oil, abies oil, cypress oil, sandalwood oil, rosewood oil, eucalyptus oil, etc.
本発明における毛髪化粧料組成物は、植物性抽出物として、オレンジ果実エキス、コーヒーエキス、カロットエキス、グレープフルーツエキス、バラエキス、セイヨウハッカエキス、ラベンダーエキス、レモンエキス、ヒノキ水、ユーカリ水、ヨモギ水、ローズマリー水、ラベンダー水、ローズ水、カモミラ水、アンズ果汁、オレンジ果汁、カロット果汁、ストロベリー果汁、モモ果汁などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition in the present invention is a plant extract, orange fruit extract, coffee extract, carrot extract, grapefruit extract, rose extract, mint extract, lavender extract, lemon extract, cypress water, eucalyptus water, mugwort water, At least one of rosemary water, lavender water, rose water, chamomile water, apricot juice, orange juice, carrot juice, strawberry juice, peach juice and the like may be contained.
本発明における毛髪化粧料組成物は、酸化染料として、パラフェニレンジアミン、5−アミノオルトクレゾール、トルエン−2,5−ジアミン、2−クロロ−パラフェニレンジアミン、N−メトキシエチル−パラフェニレンジアミン、N,N−ビス(2−ヒドロキシエチル)−パラフェニレンジアミン、2−(2−ヒドロキシエチル)−パラフェニレンジアミン、2,6−ジメチルパラフェニレンジアミン、4,4’−ジアミノジフェニルアミン、1,3−ビス(N−(2−ヒドロキシエチル)−N−(4−アミノフェニル)アミノ)−2−プロパノール、PEG−3,3,2’−パラフェニレンジアミン、パラアミノフェノール、パラメチルアミノフェノール、3−メチル−4−アミノフェノール、2−アミノメチル−4−アミノフェノール、2−(2−ヒドロキシエチルアミノメチル)−4−アミノフェノール、オルトアミノフェノール、2−アミノ−5−メチルフェノール、2−アミノ−6−メチルフェノール、2−アミノ−5−アセタミドフェノール、3,4−ジアミノ安息香酸、5−アミノサリチル酸、2,4,5,6−テトラアミノピリミジン、2,5,6−トリアミノ−4−ヒドロキシピリミジン、4,5−ジアミノ−1−(4’−クロロベンジル)ピラゾール、4,5−ジアミノ−1−ヒドロキシエチルピラゾール、メタフェニレンジアミン、2,4−ジアミノフェノキシエタノール、2−アミノ−4−(2−ヒドロキシエチルアミノ)アニソール、2,4−ジアミノ−5−メチルフェネトール、2,4−ジアミノ−5−(2−ヒドロキシエトキシ)トルエン、2,4−ジメトキシ−1,3−ジアミノベンゼン、2,6−ビス(2−ヒドロキシエチルアミノ)トルエン、2,4−ジアミノ−5−フルオロトルエン、1,3−ビス(2,4−ジアミノフェノキシ)プロパン、メタアミノフェノール、2−メチル−5−アミノフェノール、2−メチル−5−(2−ヒドロキシエチルアミノ)フェノール、2,4−ジクロロ−3−アミノフェノール、2−クロロ−3−アミノ−6−メチルフェノール、2−メチル−4−クロロ−5−アミノフェノール、N−シクロペンチル−メタアミノフェノール、2−メチル−4−メトキシ−5−(2−ヒドロキシエチルアミノ)フェノール、2−メチル−4−フルオロ−5−アミノフェノール、レゾルシン、2−メチルレゾルシン、4−クロロレゾルシン、1−ナフトール、1,5−ジヒドロキシナフタレン、1,7−ジヒドロキシナフタレン、2,7−ジヒドロキシナフタレン、2−イソプロピル−5−メチルフェノール、4−ヒドロキシインドール、5−ヒドロキシインドール、6−ヒドロキシインドール、7−ヒドロキシインドール、6−ヒドロキシベンゾモルホリン、3,4−メチレンジオキシフェノール、2−ブロモ−4,5−メチレンジオキシフェノール、3,4−メチレンジオキシアニリン、1−(2−ヒドロキシエチル)アミノ−3,4−メチレンジオキシベンゼン、2,6−ジヒドロキシ−3,4−ジメチルピリジン、2,6−ジメトキシ−3,5−ジアミノピリジン、2,3−ジアミノ−6−メトキシピリジン、2−メチルアミノ−3−アミノ−6−メトキシピリジン、2−アミノ−3−ヒドロキシピリジン、2,6−ジアミノピリジン、および、それらの塩類、ならびに、「医薬部外品原料規格」(薬事日報社、1991年6月発行)に収載された酸化染料などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition in the present invention includes, as oxidation dyes, paraphenylenediamine, 5-aminoorthocresol, toluene-2,5-diamine, 2-chloro-paraphenylenediamine, N-methoxyethyl-paraphenylenediamine, N , N-bis (2-hydroxyethyl) -paraphenylenediamine, 2- (2-hydroxyethyl) -paraphenylenediamine, 2,6-dimethylparaphenylenediamine, 4,4′-diaminodiphenylamine, 1,3-bis (N- (2-hydroxyethyl) -N- (4-aminophenyl) amino) -2-propanol, PEG-3,3,2′-paraphenylenediamine, paraaminophenol, paramethylaminophenol, 3-methyl- 4-aminophenol, 2-aminomethyl-4-aminopheno 2- (2-hydroxyethylaminomethyl) -4-aminophenol, orthoaminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol, 2-amino-5-acetamidophenol, 3,4-diaminobenzoic acid, 5-aminosalicylic acid, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-hydroxypyrimidine, 4,5-diamino-1- (4′- Chlorobenzyl) pyrazole, 4,5-diamino-1-hydroxyethylpyrazole, metaphenylenediamine, 2,4-diaminophenoxyethanol, 2-amino-4- (2-hydroxyethylamino) anisole, 2,4-diamino-5 -Methylphenetole, 2,4-diamino-5- (2-hydroxyethoxy) toluene, 2 4-dimethoxy-1,3-diaminobenzene, 2,6-bis (2-hydroxyethylamino) toluene, 2,4-diamino-5-fluorotoluene, 1,3-bis (2,4-diaminophenoxy) propane , Metaaminophenol, 2-methyl-5-aminophenol, 2-methyl-5- (2-hydroxyethylamino) phenol, 2,4-dichloro-3-aminophenol, 2-chloro-3-amino-6- Methylphenol, 2-methyl-4-chloro-5-aminophenol, N-cyclopentyl-metaaminophenol, 2-methyl-4-methoxy-5- (2-hydroxyethylamino) phenol, 2-methyl-4-fluoro -5-aminophenol, resorcin, 2-methylresorcin, 4-chlororesorcin, 1-naphthol, 1,5-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 2-isopropyl-5-methylphenol, 4-hydroxyindole, 5-hydroxyindole, 6-hydroxyindole, 7-hydroxyindole, 6-hydroxybenzomorpholine, 3,4-methylenedioxyphenol, 2-bromo-4,5-methylenedioxyphenol, 3,4-methylenedioxyaniline, 1- (2-hydroxyethyl) amino-3,4 -Methylenedioxybenzene, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-dimethoxy-3,5-diaminopyridine, 2,3-diamino-6-methoxypyridine, 2-methylamino-3- Amino-6-methoxypyridine, 2-amino-3-hydride At least one of xylidine, 2,6-diaminopyridine, and salts thereof, as well as oxidation dyes listed in “Quasi-drug Raw Material Standards” (Pharmaceutical Daily, June 1991), etc. You may contain.
本発明における毛髪化粧料組成物は、直接染料として、4−ニトロ−m−フェニレンジアミン、4−ニトロ−o−フェニレンジアミン、2−ニトロ−p−フェニレンジアミン、ピクラミン酸、1−アミノ−4−メチルアントラキノン、1,4−ジアミノアントラキノン、2−アミノ−4−ニトロフェノール、2−アミノ−5−ニトロフェノール、および、それらの塩類、ならびに、「医薬品等に使用することができるタール色素を定める省令」(昭和41年厚生省告示)により定められた酸性染料および塩基性染料などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention comprises, as a direct dye, 4-nitro-m-phenylenediamine, 4-nitro-o-phenylenediamine, 2-nitro-p-phenylenediamine, picramic acid, 1-amino-4- Methylanthraquinone, 1,4-diaminoanthraquinone, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, and their salts, and “Ministerial ordinance for determining tar dyes that can be used in pharmaceuticals, etc. ] (At least one of acid dyes and basic dyes defined by the Ministry of Health, Labor and Welfare in 1966) may be contained.
本発明における毛髪化粧料組成物は、酸性染料として、赤色2号、赤色3号、赤色102号、赤色104号の(1)、赤色105号の(1)、赤色106号、赤色201号、赤色227号、赤色230号の(1)、赤色230号の(2)、赤色231号、赤色232号、赤色401号、赤色502号、赤色503号、赤色504号、赤色506号、黄色4号、黄色5号、黄色202号(1)、黄色202号(2)、黄色203号、黄色402号、黄色403号の(1)、黄色406号、黄色407号、だいだい色402号、だいだい色205号、緑色3号、緑色204号、緑色205号、緑色401号、緑色402号、紫色401号、青色1号、青色2号、青色202号、青色203号、青色205号、かっ色201号、黒色401号などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention has, as acid dyes, red No. 2, red No. 3, red No. 102, red No. 104 (1), red No. 105 (1), red No. 106, red No. 201, Red 227, Red 230 (1), Red 230 (2), Red 231, Red 232, Red 401, Red 502, Red 503, Red 504, Red 506, Yellow 4 No. 5, Yellow No. 5, Yellow No. 202 (1), Yellow No. 202 (2), Yellow No. 203, Yellow No. 402, Yellow No. 403 (1), Yellow No. 406, Yellow No. 407, Orange No. 402, No. Color No. 205, Green No. 3, Green No. 204, Green No. 205, Green No. 401, Green No. 402, Purple No. 401, Blue No. 1, Blue No. 2, Blue No. 202, Blue No. 203, Blue No. 205, Brown 201, black 401 etc. Chi, may contain at least one.
本発明における毛髪化粧料組成物は、塩基性染料として、アンモニウム基およびカルベニウム基などを有する染料、具体的には、9−(ジメチルアミノ)−ベンゾ[a]フェノキサジ−7−イウム−クロライド(CI51175;ベーシック・ブルーNo.6)、ジ[4−(ジエチルアミノ)フェニル][4−(エチルアミノ)ナフチル]カルベニウム−クロライド(CI42595;ベーシック・ブルーNo.7)、3,7−ジ(ジメチルアミノ)フェノチアジン−5−イウム−クロライド(CI52015;ベーシック・ブルーNo.9)、ジ[4−(ジメチルアミノ)フェニル][4−(フェニルアミノ)ナフチル]カルベニウム−クロライド(CI44045;ベーシック・ブルーNo.26)、2−[(4−(エチル(2−ヒドロキシエチル)アミノ)フェニル)アゾ]−6−メトキシ−3−メチル−ベンゾチアゾリウム−硫酸メチル(CI11154;ベーシック・ブルーNo.41)、8−アミノ−2−ブロム−5−ヒドロキシ−4−イミノ−6−[(3−(トリメチルアンモニオ)フェニル)アミノ]−1(4H)−ナフタリノン−クロライド(CI56059;ベーシック・ブルーNo.99)、ビス[4−(ジメチルアミノ)−フェニル][4−(メチルアミノ)フェニル]カルベニウム−クロライド(CI42535;ベーシック・バイオレットNo.1)、トリス(4−アミノ−3−メチルフェニル)−カルベニウム−クロライド(CI42520;ベーシック・バイオレットNo.2)、トリス[4−(ジメチルアミノ)フェニル]カルベニウム−クロライド(CI42555;ベーシック・バイオレットNo.3)、2−[3,6−(ジエチルアミノ)ジベンゾピラニウム−9−イル]−安息香酸−クロライド(CI45170;ベーシック・バイオレットNo.10)、ジ(4−アミノフェニル)(4−アミノ−3−メチルフェニル)カルベニウム−クロライド(CI42510;ベーシック・バイオレットNo.14)、1,3−ビス[(2,4−ジアミノ−5−メチルフェニル)アゾ]−3−メチルベンゼン(CI21010;ベーシック・ブラウンNo.4)、1−[(4−アミノフェニル)アゾ]−7−(トリメチルアンモニオ)−2−ナフトール−クロライド(CI12250;ベーシック・ブラウンNo.16)、1−[(4−アミノ−3−ニトロフェニル)アゾ]−7−(トリメチルアンモニオ)−2−ナフトール−クロライド(CI12251;ベーシック・ブラウンNo.17)、3,7−ジアミノ−2,8−ジメチル−5−フェニル−フェナジニウム−クロライド(CI50240;ベーシック・レッドNo.2)、1,4−ジメチル−5−[(4−(ジメチルアミノ)フェニル)アゾ]−1,2,4−トリアゾリウム−クロライド(CI11055;ベーシック・レッドNo.22)、2−ヒドロキシ−1−[(2−メトキシフェニル)アゾ]−7−(トリメチルアンモニオ)−ナフタリン−クロライド(CI12245;ベーシック・レッドNo.76)、2−[2((2,4−ジメトキシフェニル)アミノ)エテニル]−1,3,3−トリメチル−3H−インドール−1−イウム−クロライド(CI48055;ベーシック・イエローNo.11)、3−メチル−1−フェニル−4−[(3−(トリメチルアンモニオ)フェニル)アゾ]−ピラゾール−5−オン−クロライド(CI12719;ベーシック・イエローNo.57)、ビス[4−(ジエチルアミノ)フェニル]フェニルカルベニウム−硫酸水素塩(1:1)(CI42040;ベーシック・グリーンNo.1)などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition in the present invention is a basic dye, such as a dye having an ammonium group and a carbenium group, specifically 9- (dimethylamino) -benzo [a] phenoxadi-7-ium chloride (CI 51175). Basic blue No. 6), di [4- (diethylamino) phenyl] [4- (ethylamino) naphthyl] carbenium chloride (CI42595; basic blue No. 7), 3,7-di (dimethylamino); Phenothiazine-5-ium chloride (CI 52015; Basic Blue No. 9), Di [4- (dimethylamino) phenyl] [4- (phenylamino) naphthyl] carbenium chloride (CI 44045; Basic Blue No. 26) , 2-[(4- (ethyl (2-hydro Cyethyl) amino) phenyl) azo] -6-methoxy-3-methyl-benzothiazolium-methyl sulfate (CI11154; basic blue No. 41), 8-amino-2-bromo-5-hydroxy-4-imino -6-[(3- (trimethylammonio) phenyl) amino] -1 (4H) -naphthalinone-chloride (CI 56059; Basic Blue No. 99), bis [4- (dimethylamino) -phenyl] [4- (Methylamino) phenyl] carbenium chloride (CI42535; basic violet No. 1), tris (4-amino-3-methylphenyl) -carbenium chloride (CI42520; basic violet No.2), tris [4- (Dimethylamino) phenyl] carbenium-chrome Id (CI42555; Basic Violet No. 3), 2- [3,6- (Diethylamino) dibenzopyranium-9-yl] -benzoic acid-chloride (CI45170; Basic Violet No. 10), Di (4- Aminophenyl) (4-amino-3-methylphenyl) carbenium chloride (CI42510; basic violet No. 14), 1,3-bis [(2,4-diamino-5-methylphenyl) azo] -3- Methylbenzene (CI21010; Basic Brown No. 4), 1-[(4-aminophenyl) azo] -7- (trimethylammonio) -2-naphthol-chloride (CI12250; Basic Brown No. 16), 1 -[(4-Amino-3-nitrophenyl) azo] -7- (to Limethylammonio) -2-naphthol chloride (CI12251; basic brown no. 17), 3,7-diamino-2,8-dimethyl-5-phenyl-phenazinium chloride (CI 50240; Basic Red No. 2), 1,4-dimethyl-5-[(4- (dimethylamino) phenyl ) Azo] -1,2,4-triazolium chloride (CI11055; Basic Red No. 22), 2-hydroxy-1-[(2-methoxyphenyl) azo] -7- (trimethylammonio) -naphthalene- Chloride (CI12245; Basic Red No. 76), 2- [2 ((2,4-dimethoxyphenyl) amino) ethenyl] -1,3,3-trimethyl-3H-indole-1-ium-chloride (CI48055; Basic Yellow No. 11), 3-methyl-1-phenyl-4-[(3- (trimethyl) Ammonio) phenyl) azo] -pyrazol-5-one-chloride (CI12719; basic yellow No. 57), bis [4- (diethylamino) phenyl] phenylcarbenium-hydrogen sulfate (1: 1) (CI41040; basic -You may contain at least 1 among green No.1).
本発明における毛髪化粧料組成物の第1剤は、アルカリ剤として、アンモニア、アルカノールアミン類(モノエタノールアミン、ジエタノールアミン、トリエタノールアミン、モノイソプロパノールアミン、ジイソプロパノールアミン、2−アミノ−2−メチル−1−プロパノール、2−アミノ−2−メチル−1,3−プロパンジオール等)、有機アミン類(モルホリン、グアニジン等)、無機アルカリ(水酸化ナトリウム、水酸化カリウム、炭酸ナトリウム、炭酸カリウム、炭酸水素ナトリウム、炭酸水素アンモニウム等)、塩基性アミノ酸(アルギニン、リジン等)、および、それらの塩類などのうち、少なくとも1つを含有してもよい。 The first agent of the hair cosmetic composition in the present invention includes, as an alkaline agent, ammonia, alkanolamines (monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, 2-amino-2-methyl- 1-propanol, 2-amino-2-methyl-1,3-propanediol, etc.), organic amines (morpholine, guanidine, etc.), inorganic alkalis (sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, hydrogen carbonate) Sodium, ammonium hydrogen carbonate, etc.), basic amino acids (arginine, lysine, etc.), and salts thereof may be contained.
本発明における毛髪化粧料組成物の第2剤は、酸化剤として、過酸化水素、過酸化尿素、過酸化メラミン、過炭酸ナトリウム、過炭酸カリウム、過ホウ酸ナトリウム、過ホウ酸カリウム、過硫酸アンモニウム、過酸化ナトリウム、過酸化カリウム、過酸化マグネシウム、過酸化バリウム、過酸化カルシウム、過酸化ストロンチウム、過酸化塩の過酸化水素付加物、リン酸塩の過酸化水素付加物、ピロリン酸塩の過酸化水素付加物、臭素酸ナトリウムなどのうち、少なくとも1つを含有してもよい。 The second agent of the hair cosmetic composition according to the present invention includes, as an oxidizing agent, hydrogen peroxide, urea peroxide, melamine peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, potassium perborate, ammonium persulfate. , Sodium peroxide, potassium peroxide, magnesium peroxide, barium peroxide, calcium peroxide, strontium peroxide, peroxide hydrogen peroxide adduct, phosphate hydrogen peroxide adduct, pyrophosphate peroxide You may contain at least 1 among a hydrogen oxide adduct, sodium bromate, etc.
本発明における毛髪化粧料組成物は、アニオン性界面活性剤として、ラウリル硫酸ナトリウム、ポリオキシエチレン(以下、POEという)ラウリルエーテル硫酸ナトリウム、ステアロイルメチルタウリンナトリウム、ドデシルベンゼンスルホン酸トリエタノールアミン、テトラデセンスルホン酸ナトリウム、POEラウリルエーテルリン酸、および、それらの塩類などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention includes, as an anionic surfactant, sodium lauryl sulfate, polyoxyethylene (hereinafter referred to as POE) sodium lauryl ether sulfate, sodium stearoylmethyl taurate, triethanolamine dodecylbenzenesulfonate, tetradecene, You may contain at least 1 among sodium sulfonate, POE lauryl ether phosphoric acid, and those salts.
本発明における毛髪化粧料組成物は、カチオン性界面活性剤として、塩化ラウリルトリメチルアンモニウム、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化アルキルトリメチルアンモニウム、塩化ジステアリルジメチルアンモニウム、臭化ラウリルトリメチルアンモニウム、臭化セチルトリメチルアンモニウム、臭化ステアリルトリメチルアンモニウム、塩化ジセチルジメチルアンモニウム、塩化ジココイルジメチルアンモニウム、塩化ドデシルジメチルエチルアンモニウム、塩化ポリオキシプロピレンメチルジエチルアンモニウム、塩化ベンザルコニウム、エチル硫酸ラノリン脂肪酸アミノプロピルエチルジメチルアンモニウム、セチルトリメチルアンモニウムサッカリン、ステアリルトリメチルアンモニウムサッカリンなどのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention comprises, as a cationic surfactant, lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, alkyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, lauryl trimethyl ammonium bromide, odor Cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, dicetyldimethylammonium chloride, dicocoyldimethylammonium chloride, dodecyldimethylethylammonium chloride, polyoxypropylenemethyldiethylammonium chloride, benzalkonium chloride, lanolin fatty acid ethylpropylethyldimethylsulfate Ammonium, cetyltrimethylammonium saccharin, stearyltrimethylan Among such onium saccharin may contain at least one.
本発明における毛髪化粧料組成物は、非イオン性界面活性剤として、POEアルキルエーテル類、POEアルキルフェニルエーテル類、POE・ポリオキシプロピレン(以下、POPという)アルキルエーテル類、POE脂肪酸類、POEソルビタン脂肪酸エステル類、POEヒマシ油、POE硬化ヒマシ油、POEソルビトールテトラ脂肪酸エステル、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステル、アルキルポリグルコシド、N−アルキルジメチルアミンオキシド、POEプロピレングリコール脂肪酸エステルなどのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention includes POE alkyl ethers, POE alkylphenyl ethers, POE polyoxypropylene (hereinafter referred to as POP) alkyl ethers, POE fatty acids, POE sorbitan as nonionic surfactants. Fatty acid esters, POE castor oil, POE hydrogenated castor oil, POE sorbitol tetra fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, sucrose fatty acid ester, alkylpolyglucoside, N-alkyldimethylamine oxide, POE propylene You may contain at least 1 among glycol fatty acid ester.
本発明における毛髪化粧料組成物は、両性界面活性剤として、2−ウンデシル−N,N,N−(ヒドロキシエチルカルボキシメチル)−2−イミダゾリンナトリウム、2−ココイル−2−イミダゾリニウムヒドロキサイト−1−カルボキシエチロキシ二ナトリウム塩、2−ヘプタデシル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾリニウムベタイン、ココアミドプロピルベタイン、ラウリルジメチルアミノ酢酸ベタイン、ラウラミドプロピルベタインなどのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention comprises 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide as an amphoteric surfactant. 1-carboxyethyloxy disodium salt, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, cocoamidopropyl betaine, lauryldimethylaminoacetic acid betaine, lauramidopropyl betaine, etc. You may contain.
本発明における毛髪化粧料組成物は、油性成分として、炭化水素、油脂、ロウ類、高級アルコール、高級脂肪酸、エステル類、シリコーン類などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition in the present invention may contain at least one of hydrocarbons, fats and oils, waxes, higher alcohols, higher fatty acids, esters, silicones and the like as oil components.
本発明における毛髪化粧料組成物は、炭化水素として、α−オレフィンオリゴマー、流動パラフィン、軽質イソパラフィン、軽質流動イソパラフィン、流動イソパラフィン、ワセリン、ポリエチレン末、オゾケライト、ポリブテン、セレシンなどのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition in the present invention contains at least one of α-olefin oligomer, liquid paraffin, light isoparaffin, light liquid isoparaffin, liquid isoparaffin, petroleum jelly, polyethylene powder, ozokerite, polybutene, ceresin and the like as hydrocarbons. You may contain.
本発明における毛髪化粧料組成物は、油脂として、植物油脂類(例えば、ヤシ油、パーム油、オリーブ油、アボカド油、ヒマシ油、ゴマ油、ローズヒップ油、メドウフォーム油、月見草油、マカデミアナッツ油、ハッカ油、トウモロコシ油、ナタネ油、コメヌカ油、シア脂など)、動物性油脂類(例えば、牛脂、乳脂、馬脂、ミンク油、ラノリンなど)などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention contains vegetable oils (for example, palm oil, palm oil, olive oil, avocado oil, castor oil, sesame oil, rosehip oil, meadow foam oil, evening primrose oil, macadamia nut oil, mint) Oil, corn oil, rapeseed oil, rice bran oil, shea fat, etc.) and animal fats (eg, beef tallow, milk fat, horse fat, mink oil, lanolin, etc.).
本発明における毛髪化粧料組成物は、ロウ類として、ミツロウ、キャンデリラロウ、コメヌカロウ、セラック、カルナウバロウ、ホホバ油などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition in the present invention may contain at least one of beeswax, candelilla wax, rice bran wax, shellac, carnauba wax, jojoba oil and the like as waxes.
本発明における毛髪化粧料組成物は、高級アルコールとして、ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコール、2−ヘキシルデカノール、イソステアリルアルコール、2−オクチルドデカノール、デシルテトラデカノール、オレイルアルコール、リノレイルアルコール、リノレニルアルコール、ラノリンアルコールなどのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention includes higher alcohols such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, 2-hexyldecanol, isostearyl alcohol, 2-octyldodecanol, decyltetradecanol. , Oleyl alcohol, linoleyl alcohol, linolenyl alcohol, lanolin alcohol and the like may be contained.
本発明における毛髪化粧料組成物は、高級脂肪酸として、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘニン酸、イソステアリン酸、ヒドロキシステアリン酸、オレイン酸、ウンデシレン酸、リノール酸、リシノール酸、ラノリン脂肪酸などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention includes higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, isostearic acid, hydroxystearic acid, oleic acid, undecylenic acid, linoleic acid, ricinoleic acid, and lanolin fatty acid. Etc., at least one of them may be contained.
本発明における毛髪化粧料組成物は、エステル類として、アジピン酸ジイソプロピル、アジピン酸ジイソブチル、アジピン酸ジオクチル、アジピン酸−2−ヘキシルデシル、アジピン酸ジイソステアリル、ミリスチン酸イソプロピル、オクタン酸セチル、イソオクタン酸セチル、イソノナン酸イソノニル、イソノナン酸イソデシル、イソノナン酸イソトリデシル、セバシン酸ジイソプロピル、ミリスチン酸オクチルドデシル、パルミチン酸イソプロピル、ステアリン酸ステアリル、ラウリン酸ヘキシル、ミリスチン酸ミリスチル、オレイン酸デシル、ジメチルオクタン酸ヘキシルデシル、ミリスチン酸トリイソデシル、ミリスチン酸イソステアリル、パルミチン酸2−エチルヘキシル、乳酸ラウリル、乳酸ミリスチル、乳酸セチル、乳酸オクチルドデシル、酢酸ラノリン、ステアリン酸イソセチル、イソステアリン酸イソセチル、12−ヒドロキシステアリン酸コレステリル、ジ−2−エチルヘキシル酸エチレングリコール、ジペンタエリスリット脂肪酸エステル、カプリン酸セチル、トリカプリル酸グリセリル、ジカプリン酸ネオペンチルグリコール、リンゴ酸ジイソステアリルなどのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention comprises, as esters, diisopropyl adipate, diisobutyl adipate, dioctyl adipate, 2-hexyldecyl adipate, diisostearyl adipate, isopropyl myristate, cetyl octanoate, isooctanoic acid Cetyl, isononyl isononanoate, isodecyl isononanoate, isotridecyl isononanoate, diisopropyl sebacate, octyldodecyl myristate, isopropyl palmitate, stearyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, myristic Triisodecyl acid, isostearyl myristate, 2-ethylhexyl palmitate, lauryl lactate, myristyl lactate, cetyl lactate, octyl lactate Ludodecyl, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, cetyl caprate, glyceryl tricaprylate, neopentyl glycol dicaprate, At least one of diisostearyl malate and the like may be contained.
本発明における毛髪化粧料組成物は、シリコーン類として、メチルポリシロキサン、高重合メチルポリシロキサン、メチルフェニルポリシロキサン、デカメチルシクロペンタシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーン、ベタイン変性シリコーン、アルキル変性シリコーン、アルコキシ変性シリコーンなどのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention includes, as silicones, methylpolysiloxane, highly polymerized methylpolysiloxane, methylphenylpolysiloxane, decamethylcyclopentasiloxane, polyether-modified silicone, amino-modified silicone, betaine-modified silicone, and alkyl-modified. You may contain at least 1 among silicone, an alkoxy modified silicone, etc.
本発明における毛髪化粧料組成物は、溶剤として、水、エタノール、イソプロパノール、n―プロパノール、n―ブタノール、イソブタノール、ベンジルアルコール、エチレングリコール、プロピレングリコール、グリセリン、1,3−ブチレングリコール、ジプロピレングリコール、3−メチル−1,3−ブタンジオール、ヘキシレングリコール、ジグリセリン、メチルカルビトール、エチルカルビトール、プロピルカルビトール、ブチルカルビトール、トリエチレングリコールモノエチルエーテル、トリエチレングリコールモノブチルエーテル、N−メチルピロリドン、N−オクチルピロリドン、N−ラウリルピロリドン、炭酸プロピレン、炭酸エチレン、ポリエチレングリコール、ポリプロピレングリコールなどのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition according to the present invention contains, as a solvent, water, ethanol, isopropanol, n-propanol, n-butanol, isobutanol, benzyl alcohol, ethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, dipropylene. Glycol, 3-methyl-1,3-butanediol, hexylene glycol, diglycerin, methyl carbitol, ethyl carbitol, propyl carbitol, butyl carbitol, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, N -At least one of methylpyrrolidone, N-octylpyrrolidone, N-laurylpyrrolidone, propylene carbonate, ethylene carbonate, polyethylene glycol, polypropylene glycol and the like It may contain.
本発明における毛髪化粧料組成物は、高分子化合物として、カルボキシメチルセルロース、カルボキシビニルポリマー、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース、メチルセルロース、キサンタンガム、カラギーナン、アルギン酸塩、ペクチン、フェラーセン、アラビアガム、ガッチガム、カラヤガム、トラガカントガム、カンテン末、ベントナイト、ポリ塩化ジメチルメチレンピペリジニウム液、塩化ジメチルジアリルアンモニウム・アクリル酸共重合体液、塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体液、アクリルアミド・アクリル酸・塩化ジメチルジアリルアンモニウム共重合体液、架橋性ポリアルキル酸塩などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition in the present invention includes, as a polymer compound, carboxymethylcellulose, carboxyvinyl polymer, hydroxyethylcellulose, hydroxypropylcellulose, methylcellulose, xanthan gum, carrageenan, alginate, pectin, ferrasene, gum arabic, gatch gum, karaya gum, Gum tragacanth, agar powder, bentonite, polydimethylmethylenepiperidinium chloride liquid, dimethyldiallylammonium chloride / acrylic acid copolymer liquid, dimethyldiallylammonium chloride / acrylamide copolymer liquid, acrylamide / acrylic acid / dimethyldiallylammonium chloride copolymer liquid, You may contain at least 1 among crosslinkable polyalkyl acid salt.
本発明における毛髪化粧料組成物は、その他の添加成分として、コラーゲン、ケラチン、エラスチン、フィブロイン、コンキオリン、大豆タンパク、カゼイン、ゼラチンなどの蛋白質を酸、アルカリ、酵素などにより加水分解した加水分解物、および、それらを4級化したカチオン変性蛋白質等のポリペプタイドと;ピロリドンカルボン酸ナトリウム、ヒアルロン酸などの保湿剤と;パラベンなどの防腐剤と;リン酸、クエン酸、硫酸、酢酸、乳酸、酒石酸、グリコール酸などのpH調整剤と;チオグリコール酸、亜硫酸塩、アスコルビン酸、ジブチルヒドロキシトルエンなどの酸化防止剤と;その他、アミノ酸、植物抽出液、生薬抽出物、ビタミン類、色素、香料、顔料、樹脂、紫外線吸収剤などのうち、少なくとも1つを含有してもよい。 The hair cosmetic composition of the present invention is a hydrolyzate obtained by hydrolyzing proteins such as collagen, keratin, elastin, fibroin, conchiolin, soy protein, casein, and gelatin with acids, alkalis, enzymes, etc. And quaternized polypeptides such as cation-denatured proteins; moisturizers such as sodium pyrrolidonecarboxylate and hyaluronic acid; preservatives such as parabens; phosphoric acid, citric acid, sulfuric acid, acetic acid, lactic acid, tartaric acid PH adjusters such as glycolic acid; antioxidants such as thioglycolic acid, sulfite, ascorbic acid and dibutylhydroxytoluene; amino acids, plant extracts, herbal extracts, vitamins, dyes, fragrances, pigments , Resin, ultraviolet absorber, etc.
次に、実施例を挙げて、本願発明をより詳細に説明する。本願発明はこれにより制限されるものではない。 Next, an Example is given and this invention is demonstrated in detail. The present invention is not limited thereby.
目次
A.実施形態
A−1.毛髪化粧料組成物の構成
A−2.評価試験
A−3.効果
Table of Contents A. Embodiment A-1. Composition of hair cosmetic composition A-2. Evaluation test A-3. effect
A−1.毛髪化粧料組成物の構成
表1は、染毛剤の第1剤の成分とその配合量を、表2は、第2剤の成分とその配合量を、表3は、第3剤の成分とその配合量をそれぞれ示す。各成分の配合量を示す数値の単位は、質量%である。また、毛髪化粧料組成物は、1剤、2剤及び3剤の混合物で、その混合比は任意に変更できる。
A-1. Composition of hair cosmetic composition Table 1 shows the components of the first agent of the hair dye and the amount thereof, Table 2 shows the components of the second agent and the amount thereof, and Table 3 shows the components of the third agent. And their blending amounts are shown respectively. The unit of the numerical value indicating the blending amount of each component is mass%. The hair cosmetic composition is a mixture of one agent, two agents, and three agents, and the mixing ratio can be arbitrarily changed.
A−2.評価試験:
専門の試験者1名が、ウィッグ(株式会社ビューラックス社製、カットマネキンNo.775S)に毛髪化粧料組成物(第1剤:第2剤:第3剤=5:10:1の割合で混合した混合物)120gを均一に塗布した。塗布直後に毛髪化粧料組成物をウィッグ上でしっかり揉み込んで泡立てた。その際の香りについて操作を行っていない専門の試験者5名が、操作後の「毛髪化粧料組成物のマスキング力」を評価基準にしたがって評価し、5名の平均点(少数点第1位を四捨五入)を評価点とした。
A-2. Evaluation test:
One expert tester has a hair cosmetic composition (first agent: second agent: third agent = 5: 10: 1) on wig (Bulux Co., Ltd., cut mannequin No. 775S). 120 g of the mixed mixture was applied uniformly. Immediately after application, the hair cosmetic composition was rubbed on the wig and foamed. Five expert testers who have not operated on the scent at that time evaluated the “masking power of the hair cosmetic composition” after the operation according to the evaluation criteria, and the average score of the five (first place in the decimal point) Was rounded off).
「マスキング力」の評価基準
5:マスキング力が非常に優れるもの
4:マスキング力が優れるもの
3:マスキング力が良好なもの
2:マスキング力がやや悪いもの
1:マスキング力が悪いもの
Evaluation criteria 5 for “masking power” 5: Very good masking power 4: Excellent masking power 3: Good masking power 2: Somewhat bad masking power 1: Low masking power
バラの香気成分であるダマスコンを第1剤及び第3剤に表4で示した量を配合した場合のマスキング力について、検討した。その結果、表4に示した様に、試料1及び2共に、評価点が5であった。
この結果より、毛髪化粧料組成物中の配合量が0.33質量%であれば、第1剤と第3剤の配合量を変化させても、マスキング力は変わらないことが分かった。
The masking power when Damascon, which is a fragrance component of roses, was blended with the first agent and the third agent in the amounts shown in Table 4 was examined. As a result, as shown in Table 4, the evaluation score was 5 for both samples 1 and 2.
From this result, it was found that if the blending amount in the hair cosmetic composition is 0.33% by mass, the masking power does not change even if the blending amounts of the first agent and the third agent are changed.
ダマスコン(試料1)及びバラ以外の香気成分である酢酸セドリル(ウッディ系香気成分:試料3)、ヘディオン(フローラル系香気成分:試料4)及びヒドロキシシトロネラール(スパイス系香気成分:試料5)のマスキング力について比較検討した。その結果、表5に示した様に、ダマスコンのみが評価点が5と、非常に優れたマスキング力を有していることが分かった。 Damascon (Sample 1) and Cedryl Acetate (Woody-type aroma component: Sample 3), Hedion (Floral-type aroma component: Sample 4) and Hydroxycitronellal (Spice-type aroma component: Sample 5) We compared the masking power. As a result, as shown in Table 5, it was found that only Damascon had an excellent masking power with an evaluation score of 5.
ダマスコン及びダマスコン以外のバラの香気成分であるシトロネロール、フェニルエチルアルコール及びローズオキシドのマスキング力について、第1剤と第3剤の配合量を変化させて比較検討した。その結果、いずれのバラの香気成分においても評価点が4以上と優れていることが分かった。 The masking power of citronellol, phenylethyl alcohol and rose oxide, which are rose aroma components other than damascon and damascon, was compared and examined by changing the blending amounts of the first and third agents. As a result, it was found that the evaluation score of 4 or more is excellent in any rose fragrance component.
A−3.効果
以上の試験結果から、バラの香気成分は、他の香気成分よりもマスキング力に優れていることが分かった。
A-3. Effect From the above test results, it was found that the rose fragrance component was superior in masking power to other fragrance components.
処方例1:脱色剤
表7の第1剤、表2の第2剤及び表8の第3剤を5:10:1の割合で混合し、処方例1の脱色剤を得た。各成分の配合量を示す数値の単位は、質量%である。 The 1st agent of Table 7, the 2nd agent of Table 2, and the 3rd agent of Table 8 were mixed in the ratio of 5: 10: 1, and the decoloring agent of the formulation example 1 was obtained. The unit of the numerical value indicating the blending amount of each component is mass%.
上記の脱色剤を用いて、染毛剤の評価試験と同様の試験を行った結果、脱色剤においても、バラの香気成分は、マスキング力に優れていることが分かった。 As a result of performing the same test as the hair dye evaluation test using the above-mentioned decoloring agent, it was found that also in the decoloring agent, the rose fragrance component was excellent in masking power.
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