JP2013533906A - ライナーレスラベル - Google Patents
ライナーレスラベル Download PDFInfo
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- JP2013533906A JP2013533906A JP2013513636A JP2013513636A JP2013533906A JP 2013533906 A JP2013533906 A JP 2013533906A JP 2013513636 A JP2013513636 A JP 2013513636A JP 2013513636 A JP2013513636 A JP 2013513636A JP 2013533906 A JP2013533906 A JP 2013533906A
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- polyurethane
- planar structure
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- acrylate
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- C08G18/72—Polyisocyanates or polyisothiocyanates
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- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
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Abstract
Description
(A)少なくとも1つのジオールおよび/またはポリオール成分、
(B)少なくとも1つのジ−および/またはポリイソシアネート成分、
(C)スルホネートおよび/またはカルボキシレート基を有する少なくとも1つの成分、
(D)必要に応じて、モノ−、ジ−および/またはトリ−アミノ−官能性および/またはヒドロキシアミノ官能性化合物、
(E)必要に応じて、他のイソシアネート反応性化合物。
成分A)、必要に応じて成分C)および必要に応じて成分E)および必要に応じて溶媒をまず充填し、20〜100℃にまで加熱する。撹拌しながら、成分B)を可能な限り迅速に添加する。発熱を利用して、反応混合物を、理論イソシアネート含有量に達するかまたは僅かに下になるまで40〜150℃で撹拌する。その間、触媒を必要に応じて添加し得る。次いで、該混合物を、溶媒を添加することにより、25〜95重量%、好ましくは35〜80重量%の固形分含有量へ希釈し、次いで鎖延長を、水および/または溶媒で希釈した成分E)を、必要に応じて成分C)と共に30〜120℃にて添加することにより行う。2〜60分の反応時間後に、まず、蒸留水を添加することにより、または充填した蒸留水中へ移すことにより、用いた溶媒を、部分的にまたは完全に分散工程中または分散工程後に留去する。
a)40〜70重量%のスチレンおよび/または他のビニル芳香族化合物、
b)4〜40重量%のアクリル酸エステル、
c)2〜5重量%の酸官能性オレフィン性不飽和モノマー、および
d)10〜40重量%のメタクリル酸エステル。
ガラス転移温度の決定
ガラス転移温度Tgは、DIN65467に従ってDSC(示差走査熱量測定)により決定する。この測定原理では、試験物質および不活性参考物質を、2つの計測セル中で加熱し、いずれも同じ温度を常に有する。試験物質における物理または化学変化は、参考からの温度差に典型的に関連する試料形態を変化させる。この温度差は、測定され、および熱流のための基準である更なる電力により補われる。測定全体の間、試験物質および参考を同じ温度/時間プログラムに付す。
分散体の混合物をテフロン製トレイ中へ注ぎ、約2mmの厚みを有する接着剤フィルムをもたらす(前提:分散体の密度=1g/cm3)。注いだ分散体は、23℃/50%相対湿気にて1週間乾燥させる。次いで接着剤フィルムを用いて貯蔵および損失弾性率データを決定する。
貯蔵および損失弾性率は、振動流動度測定によりASTM D 4440−08に従ってRheometrics ARES回転式レオメーターを用いて決定する。この測定原理では、上部および下部測定板を、測定板の位置をゼロに相当するギャップ間隔にて校正するために予め合わせる。測定板径と同じ直径を有する円形試料を、乾燥分散体から打ち抜く。試料を、測定板間に適用し、測定板を、試料高さにまで合わせ、10分間調節する。次いで板距離を、10N最大および2N最小の垂直力が生じるように減少させる。測定板を超えて突き出る可能性のある物質をブレードで除去する。振動測定は、100rad/秒にて開始する。次いで測定周波数は、3測定の工程において10日毎に0.01rad/秒まで減らす。振動の変形は、0.6%〜2%の端部振幅を有する。一定測定温度での計測のために、デバイスソフトウェアは、貯蔵および損失弾性率を各測定周波数についてトルク、引張および変形間の相差およびプレート形状から計算する。
平均粒径(APS)を、レーザー相関分光法(装置:Malvern Zetasizer 1000、Malvern Instruments LTD)により決定し、Z平均を与える。
固形物含有量は、DIN−EN ISO 3251に従って決定した。
重量平均分子量Mwは、GPCにより決定した(ゲルパーミエーションクロマトグラフィ):
装置:屈折率検出器を有するHewlett Packard 1100 seriesII
カラム加熱装置:VDS−Optilab Jetstream 2 Plus
条件:流速0.6mL/分、圧力110バール、温度30℃
標準:PSSポリマー(標準)Service GmbH、Mainz、ドイツ
化学薬品:
アクリル酸(ACS)、CAS 79−10−7、Aldrich、ドイツ
メチルメタクリレート(MMA)、CAS 80−62−6、Aldrich、ドイツ
スチレン(S)、CAS 100−42−5、Aldrich、ドイツ
N−ブチルアクリレート(BA)、CAS 141−32−2、Aldrich、ドイツ
ブチルメタクリレート(BMA)、CAS 97−88−1、Aldrich、ドイツ
過硫酸アンモニウム(APS)、CAS 7727−54−0、Aldrich、ドイツ
Emulsifier Tannemul(登録商標) 951 (E951)、CAS 68610−22−0、Tanatex、ドイツ
N−ドデシルメルカプタン、CAS 112−55−0、Aldrich、ドイツ
制御加熱および冷却および撹拌モーターを有する3リットルガラス反応器において、窒素雰囲気中で、まず、水を、対応する乳化剤量E1と共に充填する。次いで、溶液を所定温度へ加熱する。重合温度に達した後、内部シードの製造のためにモノマー混合物M1および開始剤混合物W1を、計量ポンプを用いて30分内に添加する。その後、モノマー混合物M2および水溶液W2を対応温度にて240分内に添加する。M2およびW2添加が完了した直後、水溶液W3を、後活性化のために60分内に添加し、分散体を、60分間撹拌し、次いで冷却する。pHを7へ設定するために、アンモニア溶液(W4)の対応量をゆっくり滴下し、完成分散体を125mmフィルターより取り出した。
ポリエステルジオール:Baycoll(登録商標) AD 2047、Bayer MaterialScience AG、ドイツ
実施例6:
486.25gのBaycoll(登録商標)AD 2047ポリエステルを、1時間100℃および15ミリバールにて脱水した。60℃にて80.52gのDesmodur(登録商標)I(1−イソシアナト−3,3,5−トリメチル−5−イソシアナトメチル−シクロヘキサン)を添加した。混合物を90℃にて1.80のイソシアネート含有量に達するまで撹拌した。反応混合物を、850gアセトン中で溶解し、50℃へ冷却した。9.62gN−(2−アミノエチル)−2−アミノエタンスルホン酸のナトリウム塩および8.20gジエタノールアミン の1.70gの水における溶液を添加して均質溶液へ強撹拌により添加した。30分の撹拌後、該混合物を50℃にて20分内に715gの水を添加することにより分散した。蒸留によるアセトンの分離後、40.1重量%の固形分含有量、250nmの分散相の平均粒径および6.7のpHを有する溶媒不含水性ポリウレタンポリウレア分散体を得た。ガラス転移温度Tgは+2℃であり、重量平均分子量Mwは35500g/モルであった。
Claims (21)
- 少なくとも1つの50℃〜90℃の範囲のTgアクリレートポリマーおよび少なくとも1つの−50℃〜10℃の範囲のガラス転移温度を有する非晶質ポリウレタンまたはポリウレタン−ポリウレアポリマーを含有し、該ガラス転移温度は、DSC計測によりDIN65467に従って20K/分の加熱速度にて決定される、水性接着剤組成物。
- アクリレートポリマーは、50℃〜80℃の範囲のガラス転移温度を有することを特徴とする、請求項1に記載の水性接着剤組成物。
- 非晶質ポリウレタンまたはポリウレタン−ポリウレアポリマーは、−50℃〜+5℃の範囲のガラス転移温度を有することを特徴とする、請求項1に記載の水性接着剤組成物。
- ポリウレタンまたはポリウレタン−ポリウレアポリマーは、15000〜150000g/モルの範囲の重量平均分子量Mwを有することを特徴とする、請求項1に記載の水性接着剤組成物。
- 分散体におけるポリウレタンまたはポリウレタン−ポリウレアポリマーは、30〜400nmの範囲の平均粒径を有することを特徴とする、請求項1に記載の水性接着剤組成物。
- アクリレートポリマーは、103〜106g/モルの範囲の重量平均分子量Mwを有することを特徴とする、請求項1に記載の水性接着剤組成物。
- アクリレートポリマーは、40〜200nmの範囲の平均粒径を有することを特徴とする、請求項1に記載の水性接着剤組成物。
- 基材上での熱活性化接着剤層の製造のための、請求項1〜7のいずれかに記載の水性接着剤組成物の使用。
- 熱活性化接着剤層は、50℃において1×105Paおよび1×108Paの間の1rad/秒における貯蔵弾性率G’を有することを特徴とする、請求項8に記載の使用。
- 熱活性化接着剤層は、70℃において1×104Paおよび1×107Paの間の1rad/秒における貯蔵弾性率G’を有することを特徴とする、請求項8に記載の使用。
- 熱活性化接着剤層は、90℃において1×103Paおよび1×106Paの間の1rad/秒における貯蔵弾性率G’を有することを特徴とする、請求項8に記載の使用。
- 基材は、紙、ボール紙、木材、繊維、金属、皮革、鉱物物質、天然または合成ゴムまたは合成物質から選択されることを特徴とする、請求項8に記載の使用。
- 熱活性化接着剤層は、請求項1〜7のいずれかに記載の水性接着剤組成物を含有することを特徴とする、熱活性化接着剤層を基材と共に含む平均構造物。
- 基材は、必要に応じて片面または両面に印刷し得る紙またはプラスチックシートであることを特徴とする、請求項13に記載の平面構造物。
- ラベルであることを特徴とする、請求項13に記載の平面構造物。
- 剥離紙または剥離フィルムを有さないラベル(「ライナーレスラベル」)であることを特徴とする、請求項15に記載の平面構造物。
- 接着剤層を、10〜50μmの層厚みを有する基材へ適用することを特徴とする、請求項13に記載の平面構造物の製造方法。
- 平面構造物を、まず50℃以上の温度へ加熱し、次いで物体へ適用することを特徴とする、請求項13〜17のいずれかに記載の平面構造物の物体への適用方法。
- 物体をまず50℃以上の温度へ加熱し、次いで平面構造物を適用することを特徴とする、請求項19に記載の方法。
- 平面構造物および物体を互いに別に50℃以上の温度へ加熱し、次いで平面構造物を物体上へ適用することを特徴とする、請求項19に記載の方法。
- 物体は、段ボール箱、缶、瓶またはプラスチック袋から選択されることを特徴とする、請求項19に記載の方法。
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WO2011154317A1 (en) | 2011-12-15 |
CN103097482B (zh) | 2016-08-03 |
BR112012031283A2 (pt) | 2016-11-01 |
JP5816276B2 (ja) | 2015-11-18 |
EP2580297A1 (en) | 2013-04-17 |
AU2011263874A1 (en) | 2013-01-17 |
US8980407B2 (en) | 2015-03-17 |
ES2466915T3 (es) | 2014-06-11 |
MX2012014435A (es) | 2013-02-07 |
EP2580297B1 (en) | 2014-05-14 |
TW201217474A (en) | 2012-05-01 |
US20130143010A1 (en) | 2013-06-06 |
KR20130119901A (ko) | 2013-11-01 |
EP2395064A1 (en) | 2011-12-14 |
TWI510583B (zh) | 2015-12-01 |
KR101826378B1 (ko) | 2018-02-06 |
CN103097482A (zh) | 2013-05-08 |
AU2011263874B2 (en) | 2015-11-26 |
CA2801618A1 (en) | 2011-12-15 |
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