JP2013532306A - 低いソーラファクターを有する太陽光制御板ガラス - Google Patents
低いソーラファクターを有する太陽光制御板ガラス Download PDFInfo
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- JP2013532306A JP2013532306A JP2013511668A JP2013511668A JP2013532306A JP 2013532306 A JP2013532306 A JP 2013532306A JP 2013511668 A JP2013511668 A JP 2013511668A JP 2013511668 A JP2013511668 A JP 2013511668A JP 2013532306 A JP2013532306 A JP 2013532306A
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- 239000010410 layer Substances 0.000 claims abstract description 262
- 238000000576 coating method Methods 0.000 claims abstract description 148
- 239000000758 substrate Substances 0.000 claims abstract description 137
- 239000011248 coating agent Substances 0.000 claims abstract description 128
- 239000002346 layers by function Substances 0.000 claims abstract description 126
- 239000011521 glass Substances 0.000 claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 37
- 230000005855 radiation Effects 0.000 claims abstract description 23
- 238000001228 spectrum Methods 0.000 claims abstract description 4
- 230000003287 optical effect Effects 0.000 claims description 122
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 37
- 229910052709 silver Inorganic materials 0.000 claims description 37
- 239000004332 silver Substances 0.000 claims description 37
- 238000010521 absorption reaction Methods 0.000 claims description 35
- 239000005357 flat glass Substances 0.000 claims description 10
- 230000031700 light absorption Effects 0.000 claims description 8
- 239000005329 float glass Substances 0.000 claims description 7
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 claims description 7
- 239000005340 laminated glass Substances 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 239000005361 soda-lime glass Substances 0.000 claims description 3
- 229910001316 Ag alloy Inorganic materials 0.000 claims description 2
- 230000008859 change Effects 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 74
- 239000010936 titanium Substances 0.000 description 45
- 239000011787 zinc oxide Substances 0.000 description 37
- GZCWPZJOEIAXRU-UHFFFAOYSA-N tin zinc Chemical compound [Zn].[Sn] GZCWPZJOEIAXRU-UHFFFAOYSA-N 0.000 description 29
- 238000010438 heat treatment Methods 0.000 description 27
- 229910052751 metal Inorganic materials 0.000 description 25
- 239000002184 metal Substances 0.000 description 25
- 229910010413 TiO 2 Inorganic materials 0.000 description 23
- 239000011701 zinc Substances 0.000 description 23
- 230000005540 biological transmission Effects 0.000 description 22
- 239000000047 product Substances 0.000 description 21
- 238000004519 manufacturing process Methods 0.000 description 19
- 230000007935 neutral effect Effects 0.000 description 19
- 230000002745 absorbent Effects 0.000 description 18
- 239000002250 absorbent Substances 0.000 description 18
- 238000000151 deposition Methods 0.000 description 18
- 229910052719 titanium Inorganic materials 0.000 description 17
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 16
- 230000008021 deposition Effects 0.000 description 15
- 229910052725 zinc Inorganic materials 0.000 description 15
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 14
- 230000003647 oxidation Effects 0.000 description 14
- 238000007254 oxidation reaction Methods 0.000 description 14
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 13
- XKRFYHLGVUSROY-UHFFFAOYSA-N argon Substances [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 13
- 230000001590 oxidative effect Effects 0.000 description 13
- 229910052782 aluminium Inorganic materials 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 230000001681 protective effect Effects 0.000 description 11
- 239000011241 protective layer Substances 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 10
- 230000004888 barrier function Effects 0.000 description 10
- 229910001128 Sn alloy Inorganic materials 0.000 description 9
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000919 ceramic Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 238000005728 strengthening Methods 0.000 description 9
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 238000004544 sputter deposition Methods 0.000 description 8
- 229910006404 SnO 2 Inorganic materials 0.000 description 7
- 229910052786 argon Inorganic materials 0.000 description 7
- 238000005452 bending Methods 0.000 description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 7
- 230000014509 gene expression Effects 0.000 description 6
- 238000005496 tempering Methods 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 5
- 238000004364 calculation method Methods 0.000 description 5
- 239000003989 dielectric material Substances 0.000 description 5
- 229910052758 niobium Inorganic materials 0.000 description 5
- 239000010955 niobium Substances 0.000 description 5
- 229910052763 palladium Inorganic materials 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- 229910007717 ZnSnO Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 229910001120 nichrome Inorganic materials 0.000 description 4
- 238000001579 optical reflectometry Methods 0.000 description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 4
- -1 polyethylene terephthalate Polymers 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- BNEMLSQAJOPTGK-UHFFFAOYSA-N zinc;dioxido(oxo)tin Chemical compound [Zn+2].[O-][Sn]([O-])=O BNEMLSQAJOPTGK-UHFFFAOYSA-N 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000005137 deposition process Methods 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 239000011224 oxide ceramic Substances 0.000 description 3
- 229910052574 oxide ceramic Inorganic materials 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000001429 visible spectrum Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- 230000003667 anti-reflective effect Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- KYKLWYKWCAYAJY-UHFFFAOYSA-N oxotin;zinc Chemical compound [Zn].[Sn]=O KYKLWYKWCAYAJY-UHFFFAOYSA-N 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- 238000000844 transformation Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
- 229910000684 Cobalt-chrome Inorganic materials 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- FGKRRBWIHMRUCR-UHFFFAOYSA-N [Sn].[Ti].[Zr] Chemical compound [Sn].[Ti].[Zr] FGKRRBWIHMRUCR-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000002998 adhesive polymer Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229910002065 alloy metal Inorganic materials 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000010952 cobalt-chrome Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000013003 hot bending Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 230000008450 motivation Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- RJSRQTFBFAJJIL-UHFFFAOYSA-N niobium titanium Chemical compound [Ti].[Nb] RJSRQTFBFAJJIL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000005546 reactive sputtering Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- PMTRSEDNJGMXLN-UHFFFAOYSA-N titanium zirconium Chemical compound [Ti].[Zr] PMTRSEDNJGMXLN-UHFFFAOYSA-N 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/20—Filters
- G02B5/208—Filters for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3613—Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3644—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the metal being silver
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3647—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer in combination with other metals, silver being more than 50%
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
- C03C17/366—Low-emissivity or solar control coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/0816—Multilayer mirrors, i.e. having two or more reflecting layers
- G02B5/085—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal
- G02B5/0858—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal the reflecting layers comprising a single metallic layer with one or more dielectric layers
Abstract
【選択図】なし
Description
光学的厚さ=d×nν
式中、dは、問題の層の幾何学的(物理的)厚さであり、nνは、以下の式を使用して得られる実質的な屈折率である:
式中、n(550)は550nmの波長の材料の屈折率である。
式中、Δa*及びΔb*は、スタックの各銀層及び各透明誘電体コーティングの厚さが±2.5%で個々に変動するときに見い出されるa*及びb*のそれぞれの最高値と最低値の間の差である。値a*及びb*は、光源D65/10°の下で測定されたCIELAB 1976L*a*b*値である。
6mmの厚さを有する標準ソーダライム透明フロートガラスの2m×1mのシートが、マグネトロンタイプの減圧(約0.3〜0.8Pa)で磁界によって増強されたスパッタリング装置に置かれる。このガラスシート上に、以下に説明される方法で多層太陽光制御スタックが付着される。
実施例2〜29は、実施例1と同じ材料で同じ構造に従って同じ方法で実施された。しかしながら、これらの実施例では、様々なコーティングの光学的厚さ及び様々な機能層の幾何学的厚さは、表1の表示に従って変更された。透明誘電体コーティングに関して、実施例1と同じ原理が使用された。即ち、それらは二つの層から形成され、それらの層の一方は、固定された厚さを有し、他方の層は、表に示された光学的厚さを得るために相補的な厚さを有する。様々な吸収層に関して、値Abs1,Abs2又はAbs3がゼロであるとき、これは、完成製品においてスタックのこの位置に吸収層が全くないこと、及び使用された犠牲層Tiが続く層を付着するための工程時に酸化物TiOXに変換されたことを意味する。欄Abs1,Abs2,Abs3に示されたゼロでない値は、完成製品において吸収層の幾何学的厚さに対応する。表でわかるように、全ての吸収層はスタックの内側上に位置される。
表1及び2に記載される比較例1(C1)は、本発明の外側のスタックを示し、その構造は、Germanらによる特許出願US2009/0047466A1によって記載される。
実施例30は、銀の四つの機能層を含む本発明による例示的実施形態である。従って、五つの透明誘電体コーティングが存在し、第五の透明誘電体コーティングはD5として言及される。
実施例31〜36は、実施例1〜27と同様の構造に従って同じ方法で実施された。差は以下に特定される。
実施例37及び38はまた、実施例1〜27と同様の構造に従って同じ方法で製造される。差は以下に特定される。
Claims (25)
- 赤外線を反射する材料に基づく少なくともn個の機能層、及び(n+1)個の透明誘電体コーティングを、各機能層が透明誘電体コーティングによって包囲されるように含み、nが3に等しいか又はそれより大きい、太陽光制御多層スタックを担持する透明基板において、スタックが、可視放射線スペクトルにおいて吸収性でありかつスタックの内側に位置される金属性の少なくとも一個の吸収層を含むこと、及び最後の機能層を越えて位置された最後の透明誘電体コーティングの光学的厚さに対する、透明基板から出発して、第二及び第三の機能層の間に位置された透明誘電体コーティングの光学的厚さの比が、1.25〜3.0であることを特徴とする透明基板。
- 最後の機能層を越えて位置された最後の透明誘電体コーティングの光学的厚さに対する、透明基板から出発して、第二及び第三の機能層の間に位置された透明誘電体コーティングの光学的厚さの比が、1.3〜2.6であることを特徴とする請求項1に記載の透明基板。
- 第一及び第二の機能層の間に位置された透明誘電体コーティングの光学的厚さに対する、透明基板から出発して、第二及び第三の機能層の間に位置された透明誘電体コーティングの光学的厚さの比が、0.3〜1.7であることを特徴とする請求項1又は2に記載の透明基板。
- 透明基板と第一の機能層の間に位置された透明誘電体コーティングの光学的厚さに対する、透明基板から出発して、第一及び第二の機能層の間に位置された透明誘導体コーティングの光学的厚さの比が、1.15〜3.4、好ましくは1.2〜3であることを特徴とする請求項1〜3のいずれかに記載の透明基板。
- 最後の機能層を越えて位置された透明誘電体コーティングの光学的厚さに対する、透明基板から出発して、透明基板と第一の機能層の間に位置された透明誘電体コーティングの光学的厚さの比が、0.3〜3.3であることを特徴とする請求項1〜4のいずれかに記載の透明基板。
- 第三の機能層の幾何学的厚さに対する、透明基板から出発して、第二及び第三の機能層の間に位置された透明誘電体コーティングの光学的厚さの比が、6.3〜13、好ましくは6.4〜11であることを特徴とする請求項1〜5のいずれかに記載の透明基板。
- 第二の機能層の幾何学的厚さに対する、透明基板から出発して、第三の機能層の幾何学的厚さの比が、0.45〜2.8、好ましくは0.5〜1.7であることを特徴とする請求項1〜6のいずれかに記載の透明基板。
- 吸収層が、機能層に直接近接して位置されることを特徴とする請求項1〜7のいずれかに記載の透明基板。
- 吸収層が、それと共通の界面を有する機能層上に直接位置されることを特徴とする請求項8に記載の透明基板。
- スタックが単一の吸収層のみを含むことを特徴とする請求項1〜9のいずれかに記載の透明基板。
- スタックが複数の吸収層を含み、それらの各々が機能層に直接近接して位置されることを特徴とする請求項1〜9のいずれかに記載の透明基板。
- 機能層の全てが銀又は銀合金に基づくことを特徴とする請求項1〜11のいずれかに記載の透明基板。
- 吸収層が最大7nm、好ましくは最大4.5nmの厚さを有することを特徴とする請求項1〜12のいずれかに記載の透明基板。
- 多層太陽光制御スタックが、6mmの厚さを有する標準ソーダライム透明フロートガラスのシートの上に付着され、コーティングされたモノリシック板ガラスの全光吸収率ALが少なくとも25%であることを特徴とする請求項1〜13のいずれかに記載の透明基板。
- 0〜55°の観察の角度の変化時の、透明基板側上の反射におけるa*及びb*の変化が、絶対値として最大3.7であることを特徴とする請求項1〜14のいずれかに記載の透明基板。
- スタックを担持する透明基板が、1.9より大きい、好ましくは1.94より大きい、有利には1.98より大きい選択性を有することを特徴とする請求項1〜15のいずれかに記載の透明基板。
- 透明基板が、標準ソーダライムシリカガラスのシートであることを特徴とする請求項1〜16のいずれかに記載の透明基板。
- 透明基板から出発して、第一、第二及び第三の機能層(それぞれIR1,IR2及びIR3)の幾何学的厚さが増加していること、D1の光学的厚さに対するD2の光学的厚さの比が1.25〜3.1であること、及びIR3の幾何学的厚さに対するD3の光学的厚さの比が6.3〜13であることを特徴とする請求項1〜17のいずれかに記載の透明基板。
- 透明基板から出発して、第一、第二及び第三の機能層の幾何学的厚さが減少していること、第三の機能層IR3の幾何学的厚さに対する第三の透明誘電体コーティングD3の光学的厚さの比が7〜11であること、及び最後の機能層を越えて位置された透明誘電体コーティングの光学的厚さに対する第一の透明誘電体コーティングD1の光学的厚さの比が1〜2.5であることを特徴とする請求項1〜18のいずれかに記載の透明基板。
- 第二の機能層IR2の幾何学的厚さが第一及び第三の機能層の幾何学的厚さより少なくとも5%、好ましくは少なくとも10%大きいこと、IR3の幾何学的厚さに対するD3の光学的厚さの比が7.2〜13であること、及び最後の透明誘電体コーティングの光学的厚さに対するD1の光学的厚さの比が1.3〜3.3であることを特徴とする請求項1〜17のいずれかに記載の透明基板。
- 透明基板から出発して三つの機能層の幾何学的厚さが10%の差の範囲内で等しいこと、最後のコーティングの光学的厚さに対するD1の光学的厚さの比が1.2〜2.1であること、及びD2の光学的厚さに対するD3の光学的厚さの比が0.5〜0.8であることを特徴とする請求項1〜17のいずれかに記載の透明基板。
- 透明基板から出発して第二の機能層の幾何学的厚さが第一及び第三の機能層の少なくとも一つの幾何学的厚さより少なくとも10%小さく、これらの二つの機能層の他方の厚さに等しいか又はそれより小さいこと、及び透明基板から出発して最後の機能層を越えて位置された最後の透明誘電体コーティングの光学的厚さに対する透明誘電体コーティングD3の光学的厚さの比が、2.6未満、好ましくは2.2未満、有利には2未満であることを特徴とする請求項1〜17のいずれかに記載の透明基板。
- IR3の幾何学的厚さに対するD3の光学的厚さの比が6.6〜10であること、及び層IR2に対するIR3の幾何学的厚さの比が1〜2.6であることを特徴とする請求項22に記載の透明基板。
- 請求項1〜23のいずれかに記載の透明基板を少なくとも一枚含む複層板ガラス。
- 接着性プラスチックによってガラス状材料のシートに接合された請求項1〜23のいずれかに記載の透明基板の少なくとも一枚を含む積層板ガラス。
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JPWO2014199872A1 (ja) * | 2013-06-14 | 2017-02-23 | コニカミノルタ株式会社 | 赤外遮蔽フィルムおよびこれを用いた赤外遮蔽体および熱線反射合わせガラス |
JPWO2015056752A1 (ja) * | 2013-10-17 | 2017-03-09 | コニカミノルタ株式会社 | 赤外遮蔽フィルムおよびこれを用いた赤外遮蔽体および熱線反射合わせガラス |
WO2015056752A1 (ja) * | 2013-10-17 | 2015-04-23 | コニカミノルタ株式会社 | 赤外遮蔽フィルムおよびこれを用いた赤外遮蔽体および熱線反射合わせガラス |
JP2021191723A (ja) * | 2015-09-01 | 2021-12-16 | ビトロ、エセ.ア.ベ. デ セ.ウベ. | 強化された太陽光制御性能を備えた太陽光制御コーティング |
KR20180048917A (ko) * | 2015-09-01 | 2018-05-10 | 비트로, 에스.에이.비. 데 씨.브이. | 강화된 태양광 제어 성능을 갖는 태양광 제어 코팅 |
JP2018528892A (ja) * | 2015-09-01 | 2018-10-04 | ビトロ、エセ.ア.ベ. デ セ.ウベ. | 強化された太陽光制御性能を備えた太陽光制御コーティング |
JP2020126267A (ja) * | 2015-09-01 | 2020-08-20 | ビトロ、エセ.ア.ベ. デ セ.ウベ. | 強化された太陽光制御性能を備えた太陽光制御コーティング |
KR102170018B1 (ko) * | 2015-09-01 | 2020-10-26 | 비트로 플랫 글래스 엘엘씨 | 강화된 태양광 제어 성능을 갖는 태양광 제어 코팅 |
JP7291750B2 (ja) | 2015-09-01 | 2023-06-15 | ビトロ、エセ.ア.ベ. デ セ.ウベ. | 強化された太陽光制御性能を備えた太陽光制御コーティング |
JP2018022042A (ja) * | 2016-08-03 | 2018-02-08 | 三菱マテリアル株式会社 | 赤外線フィルター、Zn−Sn含有酸化物膜およびZn−Sn含有酸化物スパッタリングターゲット |
WO2020022156A1 (ja) * | 2018-07-23 | 2020-01-30 | 大阪瓦斯株式会社 | 放射冷却装置 |
US11427500B2 (en) | 2018-07-23 | 2022-08-30 | Osaka Gas Co., Ltd. | Radiative cooling device |
JPWO2020022156A1 (ja) * | 2018-07-23 | 2020-12-17 | 大阪瓦斯株式会社 | 放射冷却装置 |
JP7462656B2 (ja) | 2019-01-30 | 2024-04-05 | サン-ゴバン グラス フランス | 熱特性を有する積層体及び吸収体層を備えた基材 |
Also Published As
Publication number | Publication date |
---|---|
EA201291341A1 (ru) | 2013-06-28 |
WO2011147864A1 (fr) | 2011-12-01 |
EP2577368B1 (fr) | 2023-07-26 |
JP5864555B2 (ja) | 2016-02-17 |
BE1019345A3 (fr) | 2012-06-05 |
CA2800252A1 (fr) | 2011-12-01 |
US20130057951A1 (en) | 2013-03-07 |
AU2011257245B2 (en) | 2015-02-05 |
BR112012030033A2 (pt) | 2016-08-02 |
AU2011257245A1 (en) | 2012-12-20 |
MX2012013662A (es) | 2013-05-01 |
PL2577368T3 (pl) | 2024-01-08 |
CA2800252C (fr) | 2020-12-29 |
EP2577368A1 (fr) | 2013-04-10 |
CN102918433A (zh) | 2013-02-06 |
US10025010B2 (en) | 2018-07-17 |
CN102918433B (zh) | 2017-10-27 |
EA025674B1 (ru) | 2017-01-30 |
SG185710A1 (en) | 2012-12-28 |
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