JP2013514257A - 選択触媒還元のための高シリカチャバザイト、その製造方法および使用方法 - Google Patents

選択触媒還元のための高シリカチャバザイト、その製造方法および使用方法 Download PDF

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JP2013514257A
JP2013514257A JP2012544509A JP2012544509A JP2013514257A JP 2013514257 A JP2013514257 A JP 2013514257A JP 2012544509 A JP2012544509 A JP 2012544509A JP 2012544509 A JP2012544509 A JP 2012544509A JP 2013514257 A JP2013514257 A JP 2013514257A
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metal
chabazite
weight
copper
pore
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JP2013514257A5 (enExample
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ホン−シン・リ
ウィリアム・イー・コーミアー
ビョルン・モデン
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ピーキュー コーポレイション
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/763—CHA-type, e.g. Chabazite, LZ-218
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/055—Peroxyhydrates; Peroxyacids or salts thereof
    • C01B15/16—Peroxyhydrates; Peroxyacids or salts thereof containing phosphorus
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
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    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Exhaust Gas After Treatment (AREA)
JP2012544509A 2009-12-17 2010-11-02 選択触媒還元のための高シリカチャバザイト、その製造方法および使用方法 Pending JP2013514257A (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/641,201 2009-12-17
US12/641,201 US10384162B2 (en) 2007-03-26 2009-12-17 High silica chabazite for selective catalytic reduction, methods of making and using same
PCT/US2010/055138 WO2011084218A2 (en) 2009-12-17 2010-11-02 High silica chabazite for selective catalytic reduction, methods of making using same

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JP2013514257A true JP2013514257A (ja) 2013-04-25
JP2013514257A5 JP2013514257A5 (enExample) 2013-08-01

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JP2012544509A Pending JP2013514257A (ja) 2009-12-17 2010-11-02 選択触媒還元のための高シリカチャバザイト、その製造方法および使用方法

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US (1) US10384162B2 (enExample)
EP (1) EP2512988A2 (enExample)
JP (1) JP2013514257A (enExample)
KR (1) KR20130019372A (enExample)
CN (1) CN102844096A (enExample)
BR (1) BR112012014744A2 (enExample)
CA (1) CA2784736A1 (enExample)
IN (1) IN2012DN05895A (enExample)
MX (1) MX363706B (enExample)
WO (1) WO2011084218A2 (enExample)

Cited By (9)

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WO2015146482A1 (ja) * 2014-03-26 2015-10-01 三菱樹脂株式会社 遷移金属含有ゼオライトの製造方法、及び該方法により得られる遷移金属ゼオライト、並びに該ゼオライトを用いた排ガス浄化処理用触媒
WO2016186040A1 (ja) * 2015-05-15 2016-11-24 イビデン株式会社 ゼオライト、該ゼオライトの製造方法、該ゼオライトを使用したハニカム触媒及び排ガス浄化装置
WO2016190237A1 (ja) * 2015-05-22 2016-12-01 イビデン株式会社 ゼオライトの製造方法並びにハニカム触媒の製造方法
WO2017002745A1 (ja) * 2015-07-02 2017-01-05 三菱樹脂株式会社 銅担持ゼオライト及び該ゼオライトを含む排ガス浄化処理用触媒
JP2017519627A (ja) * 2014-06-18 2017-07-20 ビーエーエスエフ コーポレーション モレキュラーシーブ触媒組成物、触媒複合体、システム、及び方法
JP2018016520A (ja) * 2016-07-28 2018-02-01 三菱ケミカル株式会社 Ａｅｉ型シリコアルミノ燐酸塩及びその製造方法
JP2019010642A (ja) * 2011-11-02 2019-01-24 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ 排気ガスを処理するための触媒化フィルター
JP2019511354A (ja) * 2016-02-03 2019-04-25 ビーエーエスエフ コーポレーション 銅および鉄共交換チャバザイト触媒
JP2023174787A (ja) * 2017-02-22 2023-12-08 東ソー株式会社 チャバザイト型ゼオライト及びその製造方法

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US7601662B2 (en) * 2007-02-27 2009-10-13 Basf Catalysts Llc Copper CHA zeolite catalysts
US7998423B2 (en) 2007-02-27 2011-08-16 Basf Corporation SCR on low thermal mass filter substrates
MX2009010369A (es) * 2007-03-26 2010-02-17 Pq Corp Material cristalino, microporoso, novedoso, que comprende un tamiz molecular o zeolita que tiene una estructura de abertura de poro de 8 anillos y metodos para hacer y utilizar los mismos.
DK2150328T5 (da) 2007-04-26 2015-06-29 Johnson Matthey Plc SCR-fremgangsmåde og system med Cu/SAPO-34 zeolitkatalysator
US20090196812A1 (en) * 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
GB2464478A (en) * 2008-10-15 2010-04-21 Johnson Matthey Plc Aluminosilicate zeolite catalyst and use thereof in exhaust gas after-treatment
US10583424B2 (en) * 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios
JP5482179B2 (ja) * 2008-12-22 2014-04-23 東ソー株式会社 チャバザイト型ゼオライト及びその製造方法
US8293198B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process of direct copper exchange into Na+-form of chabazite molecular sieve, and catalysts, systems and methods
US8293199B2 (en) * 2009-12-18 2012-10-23 Basf Corporation Process for preparation of copper containing molecular sieves with the CHA structure, catalysts, systems and methods
US9289756B2 (en) 2010-07-15 2016-03-22 Basf Se Copper containing ZSM-34, OFF and/or ERI zeolitic material for selective reduction of NOx
KR20130127427A (ko) 2010-07-15 2013-11-22 바스프 에스이 질소 산화물의 선택적인 환원을 위한 구리 함유 zsm-34, 오프레타이트 및/또는 에리오나이트 제올라이트 물질
DE112011103996T8 (de) * 2010-12-02 2013-12-19 Johnson Matthey Public Limited Company Metall-enthaltender Zeolithkatalysator
CN106279485B (zh) 2011-03-30 2018-10-02 日本聚乙烯株式会社 乙烯类聚合物、烯烃聚合用催化剂成分、包含所述成分的烯烃聚合用催化剂以及使用所述催化剂生产乙烯类聚合物的方法
EP2699345A4 (en) * 2011-04-18 2015-05-06 Pq Corp GROSS CIRCULAR INORGANIC CHABAZITE AND METHOD FOR ITS PREPARATION AND USE
RU2634702C2 (ru) * 2011-07-27 2017-11-03 Джонсон Мэтти Паблик Лимитед Компани Низкофосфористые хабазиты
EP2746225A4 (en) * 2011-08-18 2015-05-27 Ibiden Co Ltd COMPOSITE PART, WAVE STRUCTURE, MANUFACTURING METHOD AND EMISSION CONTROL DEVICE
US9999877B2 (en) * 2011-10-05 2018-06-19 Basf Se Cu-CHA/Fe-BEA mixed zeolite catalyst and process for the treatment of NOx in gas streams
US8956992B2 (en) * 2011-10-27 2015-02-17 GM Global Technology Operations LLC SCR catalysts preparation methods
JP5873562B2 (ja) * 2012-10-03 2016-03-01 イビデン株式会社 ハニカム構造体
JP6664961B2 (ja) * 2012-10-19 2020-03-13 ビーエーエスエフ コーポレーション 高温ｓｃｒ触媒としての８員環小孔分子ふるい
JP6278561B2 (ja) 2013-07-10 2018-02-14 国立大学法人広島大学 結晶性アルミノシリケート及びその製造方法
JP6245895B2 (ja) * 2013-08-27 2017-12-13 イビデン株式会社 ハニカム触媒及び排ガス浄化装置
JP6204751B2 (ja) * 2013-08-27 2017-09-27 イビデン株式会社 ハニカム触媒及び排ガス浄化装置
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