JP2013224426A - 活性化レゾール硬化ゴム組成物 - Google Patents
活性化レゾール硬化ゴム組成物 Download PDFInfo
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- JP2013224426A JP2013224426A JP2013082750A JP2013082750A JP2013224426A JP 2013224426 A JP2013224426 A JP 2013224426A JP 2013082750 A JP2013082750 A JP 2013082750A JP 2013082750 A JP2013082750 A JP 2013082750A JP 2013224426 A JP2013224426 A JP 2013224426A
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- Prior art keywords
- rubber composition
- rubber
- formaldehyde resin
- phenol formaldehyde
- zeolite
- Prior art date
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- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 154
- 229920001971 elastomer Polymers 0.000 title claims abstract description 138
- 239000005060 rubber Substances 0.000 title claims abstract description 137
- 229920003987 resole Polymers 0.000 title description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 95
- 238000000034 method Methods 0.000 claims abstract description 85
- 229920000642 polymer Polymers 0.000 claims abstract description 65
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 61
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000004971 Cross linker Substances 0.000 claims abstract description 48
- 239000012190 activator Substances 0.000 claims abstract description 33
- 230000008569 process Effects 0.000 claims description 37
- 238000002156 mixing Methods 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 27
- 238000004073 vulcanization Methods 0.000 claims description 27
- 229910003439 heavy metal oxide Inorganic materials 0.000 claims description 15
- 239000000945 filler Substances 0.000 claims description 13
- 229910001507 metal halide Inorganic materials 0.000 claims description 12
- 150000005309 metal halides Chemical class 0.000 claims description 12
- 239000004088 foaming agent Substances 0.000 claims description 11
- 238000000465 moulding Methods 0.000 claims description 11
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 10
- 229920005549 butyl rubber Polymers 0.000 claims description 10
- 238000004898 kneading Methods 0.000 claims description 10
- 239000003381 stabilizer Substances 0.000 claims description 10
- 229920000459 Nitrile rubber Polymers 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 150000002894 organic compounds Chemical class 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 244000043261 Hevea brasiliensis Species 0.000 claims description 7
- 229920003052 natural elastomer Polymers 0.000 claims description 7
- 229920001194 natural rubber Polymers 0.000 claims description 7
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical class CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 6
- 229920005683 SIBR Polymers 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 4
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 4
- 229920002857 polybutadiene Polymers 0.000 claims description 4
- 229920001195 polyisoprene Polymers 0.000 claims description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 3
- 239000004902 Softening Agent Substances 0.000 claims description 3
- 239000012080 ambient air Substances 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052794 bromium Inorganic materials 0.000 claims description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- 238000001721 transfer moulding Methods 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 3
- 239000010457 zeolite Substances 0.000 description 49
- 229910021536 Zeolite Inorganic materials 0.000 description 40
- 238000001723 curing Methods 0.000 description 33
- 230000000052 comparative effect Effects 0.000 description 28
- 239000003431 cross linking reagent Substances 0.000 description 19
- 239000003570 air Substances 0.000 description 17
- -1 polyethylene Polymers 0.000 description 15
- 239000000047 product Substances 0.000 description 14
- 239000004604 Blowing Agent Substances 0.000 description 11
- 230000009849 deactivation Effects 0.000 description 11
- 239000000178 monomer Substances 0.000 description 11
- 239000004711 α-olefin Substances 0.000 description 11
- 230000008901 benefit Effects 0.000 description 10
- 150000001993 dienes Chemical class 0.000 description 10
- 150000004291 polyenes Chemical class 0.000 description 10
- 239000011148 porous material Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- 239000005011 phenolic resin Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 8
- 239000002274 desiccant Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 150000002978 peroxides Chemical class 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000000292 calcium oxide Substances 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 150000004820 halides Chemical class 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000002896 organic halogen compounds Chemical class 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000004636 vulcanized rubber Substances 0.000 description 5
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000002174 Styrene-butadiene Substances 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000010734 process oil Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical class OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 150000005671 trienes Chemical class 0.000 description 4
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 3
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229940126062 Compound A Drugs 0.000 description 3
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 238000001994 activation Methods 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 2
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 2
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 2
- 239000004156 Azodicarbonamide Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
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- 150000007513 acids Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 2
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- 239000002585 base Substances 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
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- 230000015556 catabolic process Effects 0.000 description 2
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- 238000006243 chemical reaction Methods 0.000 description 2
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- 125000000524 functional group Chemical group 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229910001510 metal chloride Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
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- 238000001179 sorption measurement Methods 0.000 description 2
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- HLBZWYXLQJQBKU-UHFFFAOYSA-N 4-(morpholin-4-yldisulfanyl)morpholine Chemical compound C1COCCN1SSN1CCOCC1 HLBZWYXLQJQBKU-UHFFFAOYSA-N 0.000 description 1
- RMTZWXLMKQEBRG-UHFFFAOYSA-N 4-ethylidene-6,7-dimethylocta-1,6-diene Chemical compound C=CCC(=CC)CC(C)=C(C)C RMTZWXLMKQEBRG-UHFFFAOYSA-N 0.000 description 1
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
- DFVOXRAAHOJJBN-UHFFFAOYSA-N 6-methylhept-1-ene Chemical compound CC(C)CCCC=C DFVOXRAAHOJJBN-UHFFFAOYSA-N 0.000 description 1
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- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- MWRWFPQBGSZWNV-UHFFFAOYSA-N Dinitrosopentamethylenetetramine Chemical compound C1N2CN(N=O)CN1CN(N=O)C2 MWRWFPQBGSZWNV-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005063 High cis polybutadiene Substances 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
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Abstract
【解決手段】少なくとも1つのエラストマー性ポリマー、少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、活性化剤パッケージ、および少なくとも1つの活性化ゼオライトを含む加硫可能なゴム組成物を調製するに際し、活性化ゼオライトを、フェノールホルムアルデヒド樹脂架橋剤の添加の前、好ましくはさらにその活性化剤パッケージの添加の前に添加する、ゴム組成物の調製方法。
【選択図】なし
Description
少なくとも1つのエラストマー性ポリマー、
少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、
活性化剤パッケージ、および
少なくとも1つの活性化ゼオライト、
を含む加硫可能なゴム組成物によって達成されるが、その組成物は、以下の成分:
少なくとも1つのエラストマー性ポリマー、
少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、
活性化剤パッケージ、および
少なくとも1つの活性化ゼオライト、
の混合物を、それらの成分を混合し混練することによって調製する工程を含む方法によって調製され、
その特徴とするところは、その活性化ゼオライトを、そのフェノールホルムアルデヒド樹脂架橋剤の添加の前、好ましくはさらにその活性化剤パッケージの添加の前に添加することにある。
少なくとも1つのエラストマー性ポリマー、
少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、
活性化剤パッケージ、および
少なくとも1つの活性化ゼオライト、
を含む加硫可能なゴム組成物を調製するための方法であって、以下の成分:
少なくとも1つのエラストマー性ポリマー、
少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、
活性化剤パッケージ、および
少なくとも1つの活性化ゼオライト、
の混合物を、それらの成分を混合し混練することにより調製する工程を含む方法において、
その活性化ゼオライトを、そのフェノールホルムアルデヒド樹脂架橋剤の添加の前、好ましくはさらにその活性化剤パッケージの添加の前に添加することを特徴とする方法に関し、
ならびに、前記方法によって調製される、少なくとも1つのエラストマー性ポリマー、少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、活性化剤パッケージ、および少なくとも1つの活性化ゼオライトを含む加硫可能なゴム組成物にも関する。
本発明によるエラストマー性ポリマーは、DIN/ISO 1629においてRゴムと称される、二重結合含有ゴムを含有するのが好ましい。それらのゴムは、主鎖の中に二重結合を有し、不飽和の主鎖に加えて、側鎖の中にも二重結合を含有していてもよい。
「フェノールホルムアルデヒド樹脂架橋剤」、「フェノール樹脂」、「樹脂架橋剤」または「レゾール」という用語は、本明細書においては同一の意味を有していて、硬化剤として使用される、フェノールとホルムアルデヒドとをベースとする縮合反応生成物を表している。
いくつかの用途においては、フェノール樹脂そのままの固有の硬化速度で十分であるかもしれないが、市販されている実用的な加硫可能なゴム組成物には、好ましくは、フェノール樹脂と組み合わさって作用する1つまたは複数の加硫促進剤または触媒を含む活性化剤パッケージをさらに含んでいるであろう。加硫可能なゴム組成物中における加硫促進剤の基本的な機能は、硬化速度を高めることである。そのような反応剤は、加硫ゴム組成物の架橋密度、それに対応する物理的性質にも影響する可能性があるので、どのような加硫促進添加剤であっても、そのような物性を改良する傾向を有している筈である。
本出願の文脈においては、「活性化ゼオライト」という用語は、そのゼオライトが、予め吸着されている分子がその細孔に実質的に存在しないということを特徴としている。「実質的に存在しない」という用語は、そのゼオライトが、ゼオライトの量を基準にして、好ましくは0〜1重量%、より好ましくは0〜0.5重量%、最も好ましくは0〜0.1重量%の吸着された分子しか含まないということを意味している。そのような予め吸着されている分子の典型例としては、低分子量の極性化合物または炭化水素がある。しかしながら、ゼオライトが、湿分の形態の水分子を含んでいてもよく、これについては以下において説明する。そのような分子の吸着は、ゼオライトの失活をもたらすことになるであろう。
本発明の好ましい実施態様においては、本発明に従って調製される加硫可能なゴム組成物には、加工助剤、発泡剤、充填剤、軟化剤、および安定剤、またはそれらの組合せからなる群から選択される少なくとも1つの化合物が含まれている。
本発明の一つの実施態様は、加硫された物品を生産するための方法に関し、それには、本発明による方法において加硫可能なゴム組成物を調製する工程、または本発明に従って加硫可能なゴム組成物を調製し、その加硫可能なゴム組成物を成形および加硫する工程が含まれる。
本発明の方法においては、
少なくとも1つのエラストマー性ポリマー、
少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、
活性化剤パッケージ、および
少なくとも1つの活性化ゼオライト、
を含む加硫可能なゴム組成物を調製するが、その方法には、以下の成分
少なくとも1つのエラストマー性ポリマー、
少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、
活性化剤パッケージ、および
少なくとも1つの活性化ゼオライト
の混合物を、それらの成分を混合し混練することによって調製する工程が含まれ、
その特徴とするところは、フェノールホルムアルデヒド樹脂架橋剤の添加の前、好ましくはさらに活性化剤パッケージの添加の前に、活性化ゼオライトを添加することにある。
一般的手順
実施例および比較例の組成物は、かみ合いローターブレードを有する容量3リットルのインターナルミキサー(Shaw K1 Mark IV Intermix)を使用し、開始温度25℃で調製した。最初にエラストマー性ポリマーをミキサーに導入し、30秒間かけて粉砕してから、カーボンブラック、鉱油、およびゼオライトを添加した。混合温度が70℃に達するまで混合を続け、そこで、残りの成分を添加した。混合温度が95℃に達するまで混合を続け、そこでそのバッチを冷却のための2本ロールミル(Troester WNU 2)に移し、成分が高レベルの分散に達するまでブレンドした。
Claims (16)
- 少なくとも1つのエラストマー性ポリマー、
少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、
活性化剤パッケージ、および
少なくとも1つの活性化ゼオライト、
を含む加硫可能なゴム組成物を調製するための方法であって、以下の成分:
前記少なくとも1つのエラストマー性ポリマー、前記少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、前記活性化剤パッケージ、および前記少なくとも1つの活性化ゼオライト、
の混合物を、前記成分を混合し混練することにより調製する工程を含む方法において、
前記活性化ゼオライトが、前記フェノールホルムアルデヒド樹脂架橋剤の添加の前に添加されることを特徴とする、方法。 - 前記混合が、インターナルミキサー中、エクストルーダー中、またはミル上で実施されることを特徴とする、請求項1に記載の方法。
- 前記混合物が、85℃〜110℃の温度で混練されることを特徴とする、請求項1または2に記載の方法。
- 前記エラストマー性ポリマーが、天然ゴム、ポリブタジエンゴム、ニトリルゴム、水素化もしくは部分水素化ニトリルゴム、スチレン−ブタジエンゴム、スチレン−イソプレン−ブタジエンゴム、ブチルゴム、ポリクロロプレン、エチレンプロピレンゴム、塩素化ポリエチレン、クロロスルホン化ゴム、0.1〜10重量%の塩素含量を有する塩素化イソブチレン−イソプレンコポリマー、0.1〜10重量%の臭素含量を有する臭素化イソブチレン−イソプレンコポリマー、ポリイソプレンゴム、またはそれらの混合物であることを特徴とする、請求項1〜3のいずれか一項に記載の方法。
- 前記エラストマー性ポリマーが、1,1−二置換または1,1,2−三置換された炭素−炭素二重結合を含むことを特徴とする、請求項1〜3のいずれか一項に記載の方法。
- 前記活性化剤パッケージが、少なくとも1つの金属ハロゲン化物を含むことを特徴とする、請求項1〜5のいずれか一項に記載の方法。
- 前記活性化剤パッケージが、少なくとも1つのハロゲン化有機化合物を含むことを特徴とする、請求項1〜5のいずれか一項に記載の方法。
- 前記フェノールホルムアルデヒド樹脂が、ハロゲン化されていることを特徴とする、請求項1〜5のいずれか一項に記載の方法。
- 前記活性化剤パッケージが、少なくとも1つの重金属酸化物を含むことを特徴とする、請求項1〜8のいずれか一項に記載の方法。
- さらなる成分として、加工助剤、発泡剤、充填剤、軟化剤、および安定剤、またはそれらの組合せからなる群から選択される少なくとも1つの化合物を混合し混練することを特徴とする、請求項1〜9のいずれか一項に記載の方法。
- 加硫可能なゴム組成物であって、請求項1〜10のいずれか一項に記載の方法によって調製される、
少なくとも1つのエラストマー性ポリマー、
少なくとも1つのフェノールホルムアルデヒド樹脂架橋剤、
活性化剤パッケージ、および
少なくとも1つの活性化ゼオライト、
を含む、加硫可能なゴム組成物。 - 加硫された物品を生産するための方法であって、請求項1〜10のいずれか一項に記載の方法において加硫可能なゴム組成物を調製する工程または請求項11に記載の加硫可能なゴム組成物を調製する工程、前記加硫可能なゴム組成物を成形する工程、および加硫する工程、を含む方法。
- 前記成形する工程が、押出成形、カレンダー成形、圧縮成形、トランスファー成形、射出成形、またはそれらの組合せによって実施されることを特徴とする、請求項12に記載の方法。
- 前記加硫が、酸素の存在下、通常の周囲空気の圧力で、前記加硫可能なゴム組成物を加熱することによって実施されることを特徴とする、請求項12または13に記載の方法。
- 前記加硫が、前記加硫可能なゴム組成物を加熱することによって実施されることを特徴とする、請求項12または13に記載の方法。
- 請求項12〜15のいずれか一項に記載の方法によって作製される、加硫された物品。
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JP2012082422A (ja) * | 2010-10-13 | 2012-04-26 | Lanxess Elastomers Bv | 活性化レゾール硬化ゴム組成物 |
JP2016540097A (ja) * | 2013-12-17 | 2016-12-22 | アランセオ・ネザーランズ・ベー・フェー | 加硫可能なポリマー組成物 |
JP2017505373A (ja) * | 2014-02-05 | 2017-02-16 | ランクセス・ドイチュランド・ゲーエムベーハー | ポリマー組成物 |
JP2018168393A (ja) * | 2014-02-05 | 2018-11-01 | ランクセス・ドイチュランド・ゲーエムベーハー | ポリマー組成物 |
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EP2650327A1 (en) | 2013-10-16 |
US20130274360A1 (en) | 2013-10-17 |
KR20130116025A (ko) | 2013-10-22 |
BR102013008716A2 (pt) | 2017-07-11 |
CN103374149A (zh) | 2013-10-30 |
BR102013008716B1 (pt) | 2021-02-09 |
EP2650327B1 (en) | 2014-09-17 |
JP6250296B2 (ja) | 2017-12-20 |
ES2525036T3 (es) | 2014-12-16 |
CN103374149B (zh) | 2017-03-01 |
KR102058751B1 (ko) | 2019-12-23 |
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