JP2013031422A - Texture or flavor improver for production of soybean processed food, and soybean processed food - Google Patents

Texture or flavor improver for production of soybean processed food, and soybean processed food Download PDF

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JP2013031422A
JP2013031422A JP2011270843A JP2011270843A JP2013031422A JP 2013031422 A JP2013031422 A JP 2013031422A JP 2011270843 A JP2011270843 A JP 2011270843A JP 2011270843 A JP2011270843 A JP 2011270843A JP 2013031422 A JP2013031422 A JP 2013031422A
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soybean
protein
weight
content
emulsified composition
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JP5488576B2 (en
JP2013031422A5 (en
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Chizuru Ueno
千鶴 植野
Koichi Saito
浩一 斉藤
Kimihiro Ito
公祐 伊藤
Hideo Sugano
秀夫 菅野
Masahiko Samoto
将彦 佐本
Jiro Kanamori
二朗 金森
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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Priority to KR1020137034124A priority patent/KR101576797B1/en
Priority to US14/123,837 priority patent/US9101158B2/en
Priority to PCT/JP2012/063110 priority patent/WO2012169347A1/en
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Abstract

PROBLEM TO BE SOLVED: To provide a soybean processed food having novel flavor and texture or a soybean processed food improved in the flavor and texture of a conventional product, which is differentiated from a conventional soybean processed food such as tofu.SOLUTION: The soybean processed food uses, as a raw material, a soybean emulsion composition having a protein content relative to dry material of at least 25 wt.%, a fat content (a content as a chloroform/methanol mixed solvent extract) relative to the protein content of at least 100 wt.%, and an LCI value of at least 55%.

Description

本発明は豆腐等の大豆加工食品、大豆加工食品製造用の食感もしくは風味の改良剤、及び、大豆加工食品の食感もしくは風味の改良方法に関する。特に、新しい食感と風味を有する大豆加工食品、あるいは従来の品質を改良した大豆加工食品に関する。   The present invention relates to a processed soybean food such as tofu, a texture or flavor improver for the production of processed soybean food, and a method for improving the texture or flavor of processed soybean food. In particular, the present invention relates to a processed soybean food having a new texture and flavor, or a processed soybean food having improved conventional quality.

大豆を原料とした豆腐や湯葉、油揚げなどは日本において古くから食されてきた伝統的な大豆加工食品である。一般的には大豆に水を加えて磨砕し、得られた呉(大豆スラリー)を必要により加熱し、遠心分離や濾過等によりオカラを分離して得られた「豆乳」を出発原料として、様々な大豆加工食品が製造されている。豆腐は大豆加工食品の典型例であり、豆乳をニガリなどの凝固剤で固める工程を経て、各種の豆腐が製造されている。凝固剤で固まったカードを切断し、水にさらしたものは「絹ごし豆腐」と呼ばれており、さらにカードを崩しながら濾布で脱水し、成型したものが「木綿豆腐」と呼ばれている。これらの豆腐は比較的しっかりとした保形性のあるゲルで、近年はプラスチック容器に密封された充填豆腐として販売されており、それぞれの硬さは異なるが、いずれも適度な硬さとさっくりとしたゲルの食感を有する点で共通する。これらの伝統的な豆腐は永く好まれて日本人の食生活に欠かせないものとなっているが、一方で産業的には安価で利益率が低いため、伝統的な豆腐と差別化された高付加価値の新しい豆腐が切望されている。そこで最近ではカードを成型せずに直接容器に盛り、カードの組織を一部壊した不定形の形状にした寄せ豆腐が販売されている。
また、豆腐に限らず、その他の油揚げやがんもどき、厚揚げ、湯葉等の大豆加工食品においても、安価な従来品と差別化された高付加価値の新しい品質の製品を開発し、提供することが求められている。
Tofu, yuba, and deep-fried soybeans made from soybeans are traditional processed soybean foods that have been eaten for a long time in Japan. In general, water is added to soybean and ground, and the resulting kure (soybean slurry) is heated as necessary, and the soymilk obtained by separating the okara by centrifugation or filtration is used as a starting material. Various processed soybean foods are manufactured. Tofu is a typical example of processed soybean food, and various types of tofu are produced through a process of solidifying soy milk with a coagulant such as bittern. A piece of curd curd that has been cut with a coagulant and exposed to water is called “silk tofu”, and then the card is dehydrated with a filter cloth while breaking down the card, and the molded one is called “cotton tofu” . These tofu are relatively solid gels that have been sold as filled tofu sealed in plastic containers in recent years. This is common in that it has a texture of gel. These traditional tofu have long been preferred and have become an indispensable part of the Japanese diet. On the other hand, they are differentiated from traditional tofu because they are industrially cheap and have low profit margins. New value-added tofu is eagerly desired. Therefore, recently, tofu that has been placed in a container directly without molding the card and has an irregular shape that partially destroys the card structure has been sold.
In addition to tofu, other high-value-added new quality products that are differentiated from cheap conventional products are also developed and provided for other deep-fried soy processed foods such as deep-fried fried chicken, fried cancer, deep-fried chicken, and yuba. It is demanded.

かかる状況下、上記の市販の豆腐に対して、様々な性状の豆腐の開発が試みられている。例えば、特許文献1(特開2002−209号公報)には、豆腐に増粘ゲル化剤とオリゴ糖や澱粉を混合し、高速カッターで撹拌し、加熱冷却して得られる豆腐ペーストが記載されている。また、特許文献2(特開2003−38096号公報)には、水相部にペースト状に加工した豆腐を添加し、油中水型に乳化してなる豆腐含有油脂組成物が記載されている。
また、特許文献3(特公昭61−3462号公報)には、加熱処理してNSIを低下させた大豆から豆乳を調製し、これを酸沈して蛋白質を濃縮し、さらに中和して蛋白質を再溶解させた後に凝固剤を加えて加熱凝固させ、クリーム様テクスチャーを有する大豆蛋白質カードを製造することが記載されている。
Under such circumstances, development of tofu with various properties has been attempted with respect to the above-mentioned commercially available tofu. For example, Patent Document 1 (Japanese Patent Laid-Open No. 2002-209) describes a tofu paste obtained by mixing a thickening gelling agent, an oligosaccharide or starch with tofu, stirring with a high-speed cutter, and heating and cooling. ing. Patent Document 2 (Japanese Patent Application Laid-Open No. 2003-38096) describes a tofu-containing oil and fat composition obtained by adding tofu processed into a paste to the aqueous phase and emulsifying into a water-in-oil type. .
In Patent Document 3 (Japanese Patent Publication No. 61-3462), soy milk is prepared from soybeans that have been heat-treated to reduce NSI, and this is acid-precipitated to concentrate the protein. It is described that a soy protein curd having a cream-like texture is produced by adding a coagulant after heat-dissolving and coagulating with heating.

特開2002−209号公報Japanese Patent Laid-Open No. 2002-209 特開2003−38096号公報JP 2003-38096 A 特公昭61−3462号公報Japanese Patent Publication No.61-3462

特許文献1,2はいずれも、まず一般的な製法で得た伝統的な豆腐を原料とし、これをすりつぶしてペースト状に加工したものを利用する技術である。これらは従来の豆腐をそのまま利用した加工品であるため、風味は豆腐そのものの風味でしかなく、食感も豆腐のゲルに由来するざらつきが感じられる場合がある。
また、特許文献3の大豆蛋白質カードは豆腐様の食感をクリーム様にするために複雑な工程を要し、また豆乳を一旦酸沈殿させるために大豆の自然な風味とは異質な風味になってしまう。
これに対して、本発明は、従来の豆腐等の大豆加工食品と差別化された、新たな風味と食感を有する大豆加工食品、あるいは従来品の風味と食感を向上させた大豆加工食品を提供することを課題とする。
Each of Patent Documents 1 and 2 is a technology that uses a traditional tofu obtained by a general manufacturing method as a raw material, which is ground and processed into a paste. Since these are processed products using conventional tofu as they are, the flavor is only the flavor of tofu itself, and the texture may be felt from the gel of tofu.
In addition, the soybean protein card of Patent Document 3 requires a complicated process to make the tofu-like texture cream, and the soy milk is acid-precipitated so that it has a different flavor from the natural flavor of soybean. End up.
In contrast, the present invention is a soy processed food having a new flavor and texture that is differentiated from conventional processed soybean foods such as tofu, or a processed soybean food that has improved the flavor and texture of conventional products. It is an issue to provide.

本発明者らは種々検討した結果、NSIが特定の範囲になるまで予め変性処理を施した加工大豆を用いて水抽出した不溶性画分から、中性脂質及び極性脂質が濃縮された大豆乳化組成物として得られ、本大豆乳化組成物が大豆由来の青臭みがなく濃厚なコク味のある大豆由来素材として有用であることを見出した。そして、これを豆乳の一部又は全部に代替して大豆加工食品の原料として使用したところ、従来の豆乳とは異なる物性を示し、食感や風味に特徴のある大豆加工食品を得るに到り、本発明を完成させた。   As a result of various studies, the present inventors have established a soy emulsified composition in which neutral lipids and polar lipids are concentrated from an insoluble fraction extracted with water using processed soybeans that have been modified in advance until the NSI reaches a specific range. The present soybean emulsified composition was found to be useful as a soybean-derived material having a rich and rich taste without the blue odor derived from soybean. And when this was replaced with a part or all of soy milk and used as a raw material for processed soybean food, it resulted in a processed soybean food having physical properties different from those of conventional soy milk and characterized by texture and flavor. The present invention has been completed.

すなわち、本発明は、
(1)乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう、)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物が、原料として使用されていることを特徴とする大豆加工食品、
(2)該大豆乳化組成物中の脂質含量が乾物あたり35重量%以上である、前記(1)記載の大豆加工食品、
(3)該大豆乳化組成物中の食物繊維含量が乾物あたり10重量%以下である、前記(1)記載の大豆加工食品。
(4)大豆乳化組成物中における全蛋白質あたりのリポキシゲナーゼ蛋白質の含量が4%以上である、前記(1)記載の大豆加工食品、
(5)大豆加工食品が、豆腐類、湯葉、大豆調味料、油揚げ、がんもどき又は厚揚げである、前記(1)記載の大豆加工食品。
(6)乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう、)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物を含有することを特徴とする、大豆加工食品製造用の食感又は風味の改良剤、
(7)乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう、)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物を原料に使用することを特徴とする、大豆加工食品の食感又は風味の改良方法、である。
That is, the present invention
(1) The protein content per dry matter is 25% by weight or more, the lipid content (referred to as the chloroform / methanol mixed solvent extract) is 100% by weight or more with respect to the protein content, and the LCI value is 55% The soybean soy emulsified composition as described above is used as a raw material, processed soybean food,
(2) The processed soybean food according to (1), wherein the soybean emulsion composition has a lipid content of 35% by weight or more per dry matter,
(3) The processed soybean food according to (1), wherein the soybean fiber emulsified composition has a dietary fiber content of 10% by weight or less per dry matter.
(4) The processed soybean food according to (1), wherein the content of lipoxygenase protein per total protein in the soybean emulsified composition is 4% or more,
(5) The processed soybean food according to the above (1), wherein the processed soybean food is tofu, yuba, soybean seasoning, deep-fried oil, cancer throbbing, or deep-fried food.
(6) Protein content per dry matter is 25% by weight or more, lipid content (referred to as content in chloroform / methanol mixed solvent extract) is 100% by weight or more with respect to protein content, and LCI value is 55% A texture or flavor improver for manufacturing processed soybean food, comprising the soybean emulsified composition as described above,
(7) The protein content per dry matter is 25% by weight or more, the lipid content (referred to as a chloroform / methanol mixed solvent extract) is 100% by weight or more with respect to the protein content, and the LCI value is 55% A method for improving the texture or flavor of processed soybean foods, characterized in that the soybean emulsified composition as described above is used as a raw material.

本発明に使用する大豆乳化組成物を各種大豆加工食品の原料として用いることにより、概して大豆特有の青臭みがなく、濃厚なコク味と自然な大豆の旨味を付与し、またクリーミーな食感を付与することができ、風味や食感において従来品と差別化された特徴のある大豆加工食品を提供することができる。
特に豆腐類や厚揚げの場合は、軟らかく、従来の製品よりもクリーミーで、口の中でとろけるような口溶けの良い食感のものが得られる。
また湯葉の場合は、容易にすくいたての生湯葉(汲み上げ湯葉)のようなとろりとした食感のものが得られる。
またがんもどきや油揚げのような膨化食品は、従来の製品よりもフライ調理した際の生地原料の膨化がより促進され、膨化率を向上させる効果を与えることができる。そして膨化率が向上することにより、調理後の調味液の吸収力も向上し、よりジューシーな食感を与えることができる。
By using the soybean emulsified composition used in the present invention as a raw material for various processed soybean foods, generally there is no blue odor peculiar to soybeans, a rich body taste and a natural soybean taste are given, and a creamy texture is also provided. It is possible to provide a processed soybean food that has a characteristic that is different from conventional products in flavor and texture.
Especially in the case of tofu and deep-fried food, it is soft, creamy than conventional products, and has a mouthfeel that melts in the mouth.
In the case of Yuba, it is easy to obtain a thick texture like freshly cooked fresh Yuba (pumped Yuba).
In addition, puffed foods such as cancer pounding and deep-fried food can promote the expansion of dough raw materials when fried and cooked more than conventional products, and can give the effect of improving the puffing rate. And the expansion rate improves, The absorptive power of the seasoning liquid after cooking can also improve, and a more juicy food texture can be given.

本発明の大豆加工食品は、下記に説明する「大豆乳化組成物」を原料として使用することが特徴である。詳しくは、日本国出願(特願2011−108598号、未公開)に記載される内容を援用するが、以下、該大豆乳化組成物について説明する。   The processed soybean food of the present invention is characterized by using a “soy emulsified composition” described below as a raw material. In detail, although the content described in a Japanese application (Japanese Patent Application No. 2011-108598, unpublished) is used, this soybean emulsified composition is demonstrated below.

<大豆乳化組成物>
本発明の大豆加工食品に用いられる大豆乳化組成物は、大豆を由来とし、蛋白質のうち、グリシニンやβ−コングリシニン以外の脂質親和性蛋白質(あるいは別の指標としてリポキシゲナーゼ蛋白質)の割合が特に高く、中性脂質及び極性脂質を多く含む乳化組成物である。すなわち、乾物あたりの蛋白質含量が25重量%以上、乾物あたりの脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう。)が乾物あたりの蛋白質含量に対して100重量%以上であって、LCI値が55%以上であることを主要な特徴とするものである。
<Soy emulsified composition>
The soybean emulsified composition used in the processed soybean food of the present invention is derived from soybean, and the ratio of lipophilic protein other than glycinin and β-conglycinin (or lipoxygenase protein as another indicator) among proteins is particularly high, It is an emulsified composition containing a large amount of neutral lipids and polar lipids. That is, the protein content per dry matter is 25% by weight or more, and the lipid content per dry matter (referred to as a chloroform / methanol mixed solvent extract) is 100% by weight or more based on the protein content per dry matter, The main characteristic is that the LCI value is 55% or more.

(脂質)
一般に脂質含量はエーテル抽出法で測定されるが、本発明に用いられる大豆乳化組成物中には中性脂質の他にエーテルで抽出されにくい極性脂質も多く含まれるため、本発明における脂質含量は、クロロホルム:メタノールが2:1(体積比)の混合溶媒を用い、常圧沸点において30分間抽出された抽出物量を総脂質量として、脂質含量を算出した値とする。溶媒抽出装置としてはFOSS社製の「ソックステック」を用いることができる。なお上記の測定法は「クロロホルム/メタノール混合溶媒抽出法」と称するものとする。
(Lipid)
In general, the lipid content is measured by an ether extraction method, but the soybean emulsion composition used in the present invention contains many polar lipids that are difficult to extract with ether in addition to neutral lipids. Using a mixed solvent of chloroform: methanol 2: 1 (volume ratio) and the amount of extract extracted at the normal pressure boiling point for 30 minutes as the total lipid amount, the lipid content is calculated. As the solvent extraction device, “Soxtec” manufactured by FOSS can be used. The above measurement method is referred to as “chloroform / methanol mixed solvent extraction method”.

本発明に用いられる大豆乳化組成物は、この大豆粉の脂質含量/蛋白質含量の比よりも高い値の脂質を含み、特に極性脂質に富むことが特徴である。該脂質は原料となる大豆に由来する脂質である。   The soybean emulsified composition used in the present invention is characterized by containing a lipid having a value higher than the ratio of lipid content / protein content of this soybean flour, and particularly rich in polar lipids. The lipid is a lipid derived from soybean as a raw material.

本発明に用いられる大豆乳化組成物の脂質含量は、乾物あたりの蛋白質含量に対して100重量%以上、好ましくは120〜250重量%、さらに好ましくは120〜200重量%であり、蛋白質よりも脂質が多いことが特徴である。また構成に必須ではないが、脂質含量を絶対量で表す場合、乾物あたり35重量%以上、好ましくは40重量%以上であるのが適当である。大豆乳化組成物を繊維質等が除去されたものとすれば脂質含量を乾物あたり50重量%以上にもすることができる。また脂質含量の上限は限定されないが、好ましくは75重量%以下、より好ましくは70重量%以下である。   The lipid content of the soybean emulsified composition used in the present invention is 100% by weight or more, preferably 120 to 250% by weight, more preferably 120 to 200% by weight, based on the protein content per dry matter. It is characteristic that there are many. Although not essential for the constitution, when the lipid content is expressed in absolute amount, it is appropriate that it is 35% by weight or more, preferably 40% by weight or more per dry matter. If the soybean emulsified composition is one from which fibers and the like are removed, the lipid content can be increased to 50% by weight or more per dry matter. The upper limit of the lipid content is not limited, but is preferably 75% by weight or less, more preferably 70% by weight or less.

(蛋白質)
本発明に用いられる大豆乳化組成物の蛋白質含量は乾物あたり25重量%以上、好ましくは30重量%以上である。また蛋白質含量の上限は限定されないが、好ましくは50重量%以下、より好ましくは40重量%以下である。
(protein)
The protein content of the soybean emulsified composition used in the present invention is 25% by weight or more, preferably 30% by weight or more per dry matter. The upper limit of the protein content is not limited, but is preferably 50% by weight or less, more preferably 40% by weight or less.

○蛋白質含量の分析
本発明における蛋白質含量はケルダール法により窒素量として測定し、該窒素量に6.25の窒素換算係数を乗じて求めるものとする。
Analysis of protein content The protein content in the present invention is measured as the amount of nitrogen by the Kjeldahl method, and is obtained by multiplying the amount of nitrogen by a nitrogen conversion factor of 6.25.

○蛋白質の各成分の組成分析
本発明に用いられる大豆乳化組成物の蛋白質の各成分組成はSDSポリアクリルアミドゲル電気泳動(SDS-PAGE)により分析することができる。
界面活性剤であるSDSと還元剤であるメルカプトエタノールの作用によって蛋白質分子間の疎水性相互作用、水素結合、分子間のジスルフィド結合が切断され、マイナスに帯電した蛋白質分子は固有の分子量に従った電気泳動距離を示ことにより、蛋白質に特徴的な泳動パターンを呈する。電気泳動後に色素であるクマシーブリリアントブルー(CBB)にてSDSゲルを染色した後に、デンシトメーターを用い、全蛋白質のバンドの濃さに対する各種蛋白質分子に相当するバンドの濃さが占める割合を算出する方法により求めることができる。
-Composition analysis of each component of protein Each component composition of the protein of the soybean emulsified composition used in the present invention can be analyzed by SDS polyacrylamide gel electrophoresis (SDS-PAGE).
Hydrophobic interactions, hydrogen bonds, and intermolecular disulfide bonds between protein molecules are cleaved by the action of the surfactant SDS and the reducing agent mercaptoethanol, and negatively charged protein molecules follow their intrinsic molecular weight. By showing the electrophoretic distance, it exhibits a migration pattern characteristic of proteins. After electrophoresis, after staining the SDS gel with Coomassie Brilliant Blue (CBB), calculate the ratio of the density of bands corresponding to various protein molecules to the density of all protein bands using a densitometer. It can be obtained by the method to do.

(リポキシゲナーゼ蛋白質)
本発明に用いられる大豆乳化組成物は、一般に大豆中のオイルボディにはほとんど含まれないリポキシゲナーゼ蛋白質が特定量以上含まれることが大きな特徴であり、大豆乳化組成物中の全蛋白質あたり少なくとも4%以上含有し、好ましくは5%以上含有するものである。
通常の未変性(NSI 90以上)の大豆を原料とした場合ではリポキシゲナーゼ蛋白質は可溶性の状態で存在するため、水抽出すると水溶性画分側へ抽出される。一方、本発明ではリポキシゲナーゼ蛋白質が原料大豆中において加熱処理によって失活され不溶化しているため、不溶性画分側に残る。
蛋白質中におけるリポキシゲナーゼ蛋白質の割合が高まることによって油脂の乳化状態が安定化されるばかりでなく、グロブリン蛋白質を主体とした通常の大豆蛋白質組成では得られない滑らかな物性の食感を得ることができ、また素材にコクのある風味が付与される。
(Lipoxygenase protein)
The soybean emulsified composition used in the present invention is characterized in that the lipoxygenase protein that is hardly contained in the oil body in soybean is generally contained in a specific amount or more, and at least 4% per total protein in the soybean emulsion composition. It is contained above, preferably 5% or more.
When normal undenatured (NSI 90 or higher) soybeans are used as the raw material, the lipoxygenase protein exists in a soluble state, and therefore when extracted with water, it is extracted to the water-soluble fraction side. On the other hand, in the present invention, the lipoxygenase protein remains in the insoluble fraction side because it is inactivated and insolubilized in the raw soybean by heat treatment.
The increase in the proportion of lipoxygenase protein in the protein not only stabilizes the emulsified state of fats and oils, but also provides a smooth texture that cannot be obtained with a normal soy protein composition mainly composed of globulin proteins. In addition, a rich flavor is added to the material.

リポキシゲナーゼ蛋白質の場合は通常L-1、L-2、L-3の3種類が存在し、上記の電気泳動法により、リポキシゲナーゼ蛋白質に相当するこれらのバンドの濃さから含量を算出できる。   In the case of a lipoxygenase protein, there are usually three types, L-1, L-2 and L-3, and the content can be calculated from the intensity of these bands corresponding to the lipoxygenase protein by the above-described electrophoresis method.

(脂質親和性蛋白質)
本発明に用いられる大豆乳化組成物は、蛋白質の種類の中では脂質親和性蛋白質(Lipophilic Proteins)が一般の大豆素材より多く含まれることが特徴である。脂質親和性蛋白質は、大豆の主要な酸沈殿性大豆蛋白質の内、グリシニン(7Sグロブリン)とβ−コングリシニン(11Sグロブリン)以外のマイナーな酸沈殿性大豆蛋白質群をいい、レシチンや糖脂質などの極性脂質を多く随伴するものである。以下、単に「LP」と略記することがある。
LPは雑多な蛋白質が混在したものであるが故、各々の蛋白質を全て特定し、LPの含量を厳密に測定することは困難であるが、下記LCI(Lipophilic Proteins Content Index)値を求めることにより推定することができる。これによれば、大豆乳化組成物中の蛋白質のLCI値は通常55%以上であり、好ましくは58%以上であり、より好ましくは60%以上であり、さらに好ましくは63%以上、最も好ましくは65%以上である。
通常の未変性(NSI 90以上)の大豆を原料とした場合ではLPは可溶性の状態で存在するため、水抽出すると水溶性画分側へ抽出される。一方、本発明に用いられる大豆乳化組成物の場合、LPが原料大豆中において加熱処理によって失活され不溶化しているため、不溶性画分側に残る。
蛋白質中におけるLPの割合が高まることによって油脂の乳化状態が安定化されるばかりでなく、グロブリン蛋白質を主体とした通常の大豆蛋白質組成では得られない滑らかな物性の食感を得ることができ、また素材にコクのある風味が付与される。
(Lipophilic protein)
The soybean emulsified composition used in the present invention is characterized in that among the types of proteins, more lipophilic proteins are contained than general soybean materials. Lipophilic protein is a group of minor acid-precipitating soybean proteins other than glycinin (7S globulin) and β-conglycinin (11S globulin) among the main acid-precipitating soybean proteins of soybean, such as lecithin and glycolipids. It accompanies many polar lipids. Hereinafter, it may be simply abbreviated as “LP”.
LP is a mixture of miscellaneous proteins, so it is difficult to identify each protein and measure the LP content precisely, but by calculating the following LCI (Lipophilic Proteins Content Index) value Can be estimated. According to this, the LCI value of the protein in the soybean emulsified composition is usually 55% or more, preferably 58% or more, more preferably 60% or more, still more preferably 63% or more, most preferably 65% or more.
When normal undenatured soybeans (NSI 90 or higher) are used as raw materials, LP exists in a soluble state, so when extracted with water, it is extracted to the water-soluble fraction. On the other hand, in the soybean emulsified composition used in the present invention, LP remains in the insoluble fraction side because LP is deactivated and insolubilized in the raw soybean by heat treatment.
The increase in the proportion of LP in the protein not only stabilizes the emulsified state of the fats and oils, but also provides a smooth texture that cannot be obtained with a normal soy protein composition mainly composed of globulin proteins. In addition, a rich flavor is imparted to the material.

〔LP含量の推定・LCI値の測定方法〕
(a) 各蛋白質中の主要な蛋白質として、7Sはαサブユニット及びα'サブユニット(α+α')、11Sは酸性サブユニット(AS)、LPは34kDa蛋白質及びリポキシゲナーゼ蛋白質(P34+Lx)を選択し、SDS−PAGEにより選択された各蛋白質の染色比率を求める。電気泳動は表1の条件で行うことが出来る。
(b) X(%)=(P34+Lx)/{(P34+Lx)+(α+α’)+AS}×100(%)を求める。
(c) 低変性脱脂大豆から調製された分離大豆蛋白のLP含量を加熱殺菌前に上記方法1,2の分画法により測定すると凡そ38%となることから、X=38(%)となるよう(P34+Lx)に補正係数k*=6を掛ける。
(d) すなわち、以下の式によりLP推定含量(Lipophilic Proteins Content Index、以下「LCI」と略する。)を算出する。
[LP content estimation / LCI value measurement method]
(a) As the main protein in each protein, 7S selects α subunit and α ′ subunit (α + α ′), 11S selects acidic subunit (AS), LP selects 34 kDa protein and lipoxygenase protein (P34 + Lx), The staining ratio of each protein selected by SDS-PAGE is determined. Electrophoresis can be performed under the conditions shown in Table 1.
(b) X (%) = (P34 + Lx) / {(P34 + Lx) + (α + α ′) + AS} × 100 (%) is obtained.
(c) Since the LP content of the separated soybean protein prepared from low-denatured defatted soybean is measured by the fractionation method of methods 1 and 2 before heat sterilization, it is about 38%, so X = 38 (%). (P34 + Lx) is multiplied by the correction coefficient k * = 6.
(d) That is, the estimated LP content (Lipophilic Proteins Content Index, hereinafter abbreviated as “LCI”) is calculated by the following equation.

(表1)

Figure 2013031422
Figure 2013031422
(Table 1)
Figure 2013031422
Figure 2013031422

(乾物含量)
本発明に用いられる大豆乳化組成物は通常生クリーム様の性状であり、通常の乾物(dry matter)は20〜30重量%程度であるが、特に限定されるものではない。すなわち加水により低粘度の液状としたものや、濃縮加工されてより高粘度のクリーム状としたものであってもよく、また粉末加工されて粉末状としたものであってもよい。
(Dry matter content)
The soybean emulsified composition used in the present invention usually has a cream-like property, and the usual dry matter is about 20 to 30% by weight, but is not particularly limited. That is, it may be a liquid having a low viscosity by water addition, a cream having a higher viscosity by concentration processing, or a powder having been processed by powder.

(大豆乳化組成物の製造態様)
本発明に用いられる大豆乳化組成物は、例えば水溶性窒素指数(Nitrogen Solubility Index、以下「NSI」と称する。)が20〜77、好ましくは20〜70、乾物あたりの脂質含量が15重量%以上の全脂大豆などの含脂大豆に対して、加水して懸濁液を調製する工程の後、該懸濁液を固液分離し、中性脂質及び極性脂質を不溶性画分に移行させて、蛋白質及び糖質を含む水溶性画分を除去し、不溶性画分を回収することにより得ることができる。以下、該製造態様について示す。
(Production aspect of soybean emulsified composition)
The soybean emulsified composition used in the present invention has a water-soluble nitrogen index (Nitrogen Solubility Index, hereinafter referred to as “NSI”) of 20 to 77, preferably 20 to 70, and a lipid content per dry matter of 15% by weight or more. After the step of preparing a suspension by adding water to a fat-containing soybean such as whole fat soybean, the suspension is solid-liquid separated to transfer neutral lipid and polar lipid to the insoluble fraction. It can be obtained by removing the water-soluble fraction containing protein and carbohydrate and recovering the insoluble fraction. Hereinafter, this production mode will be described.

・原料大豆及びその加工
大豆乳化組成物の原料である大豆としては、全脂大豆あるいは部分脱脂大豆等の含脂大豆を用いる。部分脱脂大豆としては、全脂大豆を圧搾抽出等の物理的な抽出処理により部分的に脱脂したものが挙げられる。一般に全脂大豆中には脂質が乾物あたり約20〜30重量%程度含まれ、特殊な大豆品種については脂質が30重量%以上のものもあり、特に限定されないが、用いる含脂大豆としては、少なくとも脂質を15重量以上、好ましくは20重量%以上含むものが適当である。原料の形態は、半割れ大豆、グリッツ、粉末の形状でありうる。
過度に脱脂され脂質含量が少なすぎると本発明に用いられる脂質に富む大豆乳化組成物を得ることが困難となる。特にヘキサン等の有機溶媒で抽出され、中性脂質の含量が1重量%以下となった脱脂大豆は、大豆の良い風味が損なわれ好ましくない。
-Raw soybean and its processing As soybean which is the raw material of the soybean emulsified composition, fat-containing soybean such as full fat soybean or partially defatted soybean is used. Examples of partially defatted soybeans include those obtained by partially defatting whole fat soybeans by physical extraction treatment such as compression extraction. Generally, about 20 to 30% by weight of lipid per dry matter is contained in whole fat soybeans, and there are some special soybean varieties with lipids of 30% by weight or more, although there is no particular limitation, A material containing at least 15% by weight or more, preferably 20% by weight or more of lipid is suitable. The form of the raw material may be in the form of half cracked soybeans, grits, powder.
If it is excessively defatted and the lipid content is too small, it will be difficult to obtain a soybean-emulsified composition rich in lipids used in the present invention. In particular, defatted soybeans extracted with an organic solvent such as hexane and having a neutral lipid content of 1% by weight or less are not preferable because the good flavor of soybeans is impaired.

上記含脂大豆は天然の状態では蛋白質の多くが未変性で可溶性の状態にあり、NSIとしては通常90を超えるが、本発明においては、NSIが20〜77好ましくは20〜70になるよう加工処理を施した加工大豆を用いるのが適当である。より好ましいNSIの下限値は40以上、より好ましくは41以上、さらに好ましくは43以上、最も好ましくは45以上とすることができる。より好ましいNSIの上限値は75未満、より好ましくは70未満とすることができ、またさらに65未満、あるいは60未満、あるいは58未満の低NSIのものを用いることができる。
そのような加工大豆は、加熱処理やアルコール処理等の加工処理を行って得られる。加工処理の手段は特に限定されないが、例えば乾熱処理、水蒸気処理、過熱水蒸気処理、マイクロ波処理等による加熱処理や、含水エタノール処理、高圧処理、およびこれらの組み合わせ等が利用できる。
In the above-mentioned fat-containing soybean, most of the protein is in an unmodified and soluble state in the natural state, and NSI is usually over 90, but in the present invention, NSI is 20 to 77, preferably 20 to 70. It is appropriate to use processed soybeans that have been treated. A more preferable lower limit of NSI can be 40 or more, more preferably 41 or more, still more preferably 43 or more, and most preferably 45 or more. A more preferable upper limit of NSI can be less than 75, more preferably less than 70, and a lower NSI of less than 65, alternatively less than 60, or less than 58 can be used.
Such processed soybeans are obtained by performing processing such as heat treatment or alcohol treatment. The processing means is not particularly limited, and for example, heat treatment such as dry heat treatment, steam treatment, superheated steam treatment, microwave treatment, hydrous ethanol treatment, high pressure treatment, and combinations thereof can be used.

NSIが低すぎると、大豆乳化組成物中の蛋白質の割合が高くなりやすく、蛋白質に対する脂質含量が低くなる。また過加熱による焙煎臭等の雑味が生じやすくなる。逆にNSIが例えば80以上の高い数値になると大豆乳化組成物中の蛋白質の割合が低下し、大豆からの脂質の回収率も低下しやすくなる。また風味は青臭みが強くなる。
例えば過熱水蒸気による加熱処理を行う場合、その処理条件は製造環境にも影響されるため一概に言えないが、おおよそ120〜250℃の過熱水蒸気を用いて5〜10分の間で加工大豆のNSIが上記範囲となるように処理条件を適宜選択すれば良く、加工処理に特段の困難は要しない。簡便には、NSIが上記範囲に加工された市販の大豆を用いることもできる。
When NSI is too low, the ratio of the protein in the soybean emulsified composition tends to be high, and the lipid content to the protein is low. Moreover, miscellaneous taste such as roasting odor due to overheating tends to occur. Conversely, when the NSI is a high value of 80 or more, for example, the protein ratio in the soybean emulsified composition decreases, and the lipid recovery rate from soybean tends to decrease. In addition, the flavor has a strong blue odor.
For example, when performing heat treatment with superheated steam, the treatment conditions are affected by the production environment, so it can not be said unconditionally, but the NSI of processed soybeans is used in about 5 to 10 minutes using superheated steam at about 120 to 250 ° C. The processing conditions may be selected as appropriate so that the value falls within the above range, and no particular difficulty is required for the processing. For convenience, commercially available soybeans with NSI processed in the above range can also be used.

なお、NSIは所定の方法に基づき、全窒素量に占める水溶性窒素(粗蛋白)の比率(重量%)で表すことができ、本発明においては以下の方法に基づいて測定された値とする。
すなわち、試料2.0gに100mlの水を加え、40℃にて60分攪拌抽出し、1400×gにて10分間遠心分離し、上清1を得る。残った沈殿に再度100mlの水を加え、40℃にて60分攪拌抽出し、1400×gにて10分遠心分離し、上清2を得る。上清1および上清2を合わせ、さらに水を加えて250mlとする。No.5Aろ紙にてろ過したのち、ろ液の窒素含量をケルダール法にて測定する。同時に試料中の窒素含量をケルダール法にて測定し、ろ液として回収された窒素(水溶性窒素)の試料中の全窒素に対する割合を重量%として表したものをNSIとする。
NSI can be expressed as a ratio (% by weight) of water-soluble nitrogen (crude protein) in the total amount of nitrogen based on a predetermined method. In the present invention, NSI is a value measured based on the following method. .
That is, 100 ml of water is added to 2.0 g of a sample, followed by stirring and extraction at 40 ° C. for 60 minutes, followed by centrifugation at 1400 × g for 10 minutes to obtain supernatant 1. 100 ml of water is added again to the remaining precipitate, followed by stirring and extraction at 40 ° C. for 60 minutes, and centrifugation at 1400 × g for 10 minutes to obtain supernatant 2. Supernatant 1 and supernatant 2 are combined, and water is further added to make 250 ml. After filtering with No. 5A filter paper, the nitrogen content of the filtrate is measured by Kjeldahl method. At the same time, the nitrogen content in the sample is measured by the Kjeldahl method, and the ratio of the nitrogen recovered as filtrate (water-soluble nitrogen) to the total nitrogen in the sample is expressed as weight%, which is NSI.

前記の加工大豆は水抽出の前に、予め乾式又は湿式による粉砕、破砕、圧偏等の組織破壊処理を施されることが好ましい。組織破壊処理に際して、あらかじめ水浸漬や蒸煮により膨潤させても良く、これによって組織破壊に必要なエネルギーを低減させたり、ホエー蛋白質やオリゴ糖等の不快味を持つ成分を溶出させ除去できると共に、保水性やゲル化性の能力が高いグロブリン蛋白質(特にグリシニン及びβ−コングリシニン)の全蛋白質に対する抽出比率、すなわち水溶性画分への移行比率をより高めることができる。   The processed soybean is preferably subjected to a tissue destruction treatment such as pulverization, crushing, and pressure bias by dry or wet in advance before water extraction. In tissue destruction treatment, it may be swollen in advance by water immersion or steaming, thereby reducing the energy required for tissue destruction, and eluting and removing components with unpleasant taste such as whey protein and oligosaccharides, as well as water retention The extraction ratio of globulin proteins (especially glycinin and β-conglycinin) having a high ability to gel and gelling ability, that is, the ratio of transfer to a water-soluble fraction can be further increased.

・原料大豆からの水抽出
水抽出は含脂大豆に対して3〜20重量倍、好ましくは4〜15重量倍程度の加水をし、含脂大豆を懸濁させて行われる。加水倍率は高い方が水溶性成分の抽出率が高まり、分離を良くすることができるが、高すぎると濃縮が必要となりコストがかかる。また、抽出処理を2回以上繰り返すと水溶性成分の抽出率をより高めることができる。
-Water extraction from raw soybeans Water extraction is performed by adding 3 to 20 times, preferably 4 to 15 times, the amount of water added to fat-containing soybeans and suspending the fat-containing soybeans. The higher the rate of hydrolysis, the higher the extraction rate of the water-soluble component and the better the separation. However, if it is too high, concentration is required and costs increase. Further, when the extraction process is repeated twice or more, the extraction rate of the water-soluble component can be further increased.

抽出温度には特に制限はないが、高い方が水溶性成分の抽出率が高まる反面、油脂も可溶化されやすくなり、大豆乳化組成物の脂質が低くなるため、70℃以下、好ましくは55℃以下で行うと良い。あるいは5〜80℃、好ましくは50〜75℃の範囲で行うこともできる。   The extraction temperature is not particularly limited. However, the higher the extraction rate of the water-soluble component, the more easily the oil and fat are solubilized, and the lower the lipid of the soybean emulsified composition. The following should be done. Or it can also carry out in the range of 5-80 degreeC, Preferably it is 50-75 degreeC.

抽出pH(加水後の大豆懸濁液のpH)も温度と同様に高いほうが水溶性成分の抽出率が高まる反面、油脂も可溶化されやすくなり、大豆乳化組成物の脂質が低くなる傾向にある。逆にpHが低すぎると蛋白質の抽出率が低くなる傾向にある。具体的には下限をpH6以上、もしくはpH6.3以上、もしくはpH6.5以上に調整して行うことができる。また上限は脂質の分離効率を上げる観点でpH9以下、もしくはpH8以下、もしくはpH7以下に調整して行うことができる。あるいは蛋白質の抽出率を高める観点でpH9〜12のよりアルカリ性側に調整して行うことも可能である。   The higher the extraction pH (the pH of the soybean suspension after the addition of water), the higher the temperature, the higher the extraction rate of water-soluble components. . Conversely, if the pH is too low, the protein extraction rate tends to be low. Specifically, the lower limit can be adjusted to pH 6 or higher, pH 6.3 or higher, or pH 6.5 or higher. The upper limit can be adjusted to pH 9 or lower, pH 8 or lower, or pH 7 or lower from the viewpoint of increasing lipid separation efficiency. Alternatively, from the viewpoint of increasing the protein extraction rate, it is possible to adjust the pH to 9 to 12 more alkaline.

・水抽出後の固液分離
水抽出後、含脂大豆の懸濁液を遠心分離、濾過等により固液分離する。この際、中性脂質のみならず極性脂質も含めた大部分の脂質を水抽出物中に溶出させず、不溶化した蛋白質や食物繊維質の方に移行させ沈殿側(不溶性画分)とすることが重要である。具体的には含脂大豆の脂質の70重量%以上を沈殿側に移行させる。また抽出の際に上清側にも少量の脂質が溶出するが、豆乳中の脂質のように微細にエマルション化されたものではなく、15,000×g以下、あるいは5,000×g程度以下の遠心分離によっても容易に浮上させ分離することができ、この点で遠心分離機を使用するのが好ましい。なお遠心分離機は使用する設備によっては10万×g以上の超遠心分離を使用することも可能であるし、本発明に用いられる大豆乳化組成物の場合は超遠心分離機を用いなくとも実施が可能である。
また水抽出の際あるいは水抽出後に解乳化剤を添加して豆乳からの脂質の分離を促進させることも可能であり、解乳化剤は特に限定されないが例えば特許文献2に開示されている解乳化剤を使用すればよい。ただし本発明に用いられる大豆乳化組成物を調製する場合は解乳化剤を用いなくとも実施が可能である。
-Solid-liquid separation after water extraction After water extraction, the suspension of fat-containing soybeans is subjected to solid-liquid separation by centrifugation, filtration or the like. At this time, not only neutral lipids but also most of the lipids including polar lipids are not eluted in the water extract, but transferred to the insolubilized protein or dietary fiber to make the precipitation side (insoluble fraction). is important. Specifically, 70% by weight or more of the lipid of the fat-containing soybean is transferred to the precipitation side. In addition, a small amount of lipid is also eluted on the supernatant side during extraction, but it is not finely emulsified like the lipid in soy milk, and it is centrifuged at 15,000 xg or less, or about 5,000 xg or less. In this respect, it is preferable to use a centrifuge. Depending on the equipment used, the centrifugal separator can be used for ultracentrifugation of 100,000 xg or more. In the case of the soybean emulsion composition used in the present invention, the centrifugal separator is not used. Is possible.
It is also possible to add a demulsifier during or after water extraction to promote lipid separation from soy milk. The demulsifier is not particularly limited, but for example, the demulsifier disclosed in Patent Document 2 is used. do it. However, the preparation of the soybean emulsified composition used in the present invention can be carried out without using a demulsifier.

水抽出工程後の固液分離により、中性脂質のみならず極性脂質を不溶性画分に移行させ、これを回収することにより大豆乳化組成物の画分を得ることができる。
固液分離として遠心分離を用いる場合、二層分離方式、三層分離方式のいずれも使用することができる。二層分離方式の場合は沈殿層である不溶性画分を回収する。また三層分離方式を用いる場合は、(1)浮上層(脂質を含む比重の最も小さいクリーム画分)、(2)中間層(脂質が少なく蛋白質、糖質を多く含む水溶性画分)、(3)沈殿層(脂質と食物繊維を多く含む不溶性画分)、の三層の画分に分けられる。この場合、脂質含量の少ない水溶性画分の中間層(2)を除去又は回収し、不溶性画分として浮上層(1)又は沈殿層(3)を回収するか、あるいは(1)と(3)を合わせて回収するとよい。
By solid-liquid separation after the water extraction step, not only neutral lipids but also polar lipids are transferred to an insoluble fraction, and a fraction of the soybean emulsified composition can be obtained by collecting this.
When centrifugation is used as the solid-liquid separation, either a two-layer separation method or a three-layer separation method can be used. In the case of the two-layer separation method, an insoluble fraction that is a precipitation layer is collected. When using the three-layer separation method, (1) floating layer (cream fraction with the smallest specific gravity containing lipid), (2) intermediate layer (water-soluble fraction containing a small amount of protein and carbohydrate), (3) It is divided into three-layer fractions: a sediment layer (insoluble fraction rich in lipids and dietary fibers). In this case, the intermediate layer (2) of the water-soluble fraction having a low lipid content is removed or recovered, and the floating layer (1) or the precipitated layer (3) is recovered as an insoluble fraction, or (1) and (3 ).

得られた不溶性画分(1)、(3)はそのまま、あるいは必要により濃縮工程、加熱殺菌工程、粉末化工程等を経て本発明に用いられる大豆乳化組成物とすることができる。   The obtained insoluble fractions (1) and (3) can be used as they are, or, if necessary, through a concentration step, a heat sterilization step, a powdering step and the like to obtain a soybean emulsion composition used in the present invention.

・食物繊維の除去
得られた不溶性画分が食物繊維を含む場合、例えば上記(3)又は(1)及び(3)の画分である場合、必要により加水し、高圧ホモゲナイザーあるいはジェットクッカー加熱機等による均質化した後、該均質化液をさらに固液分離して上清を回収する工程を経ることにより、食物繊維(オカラ)を除去することもでき、コクのある風味がより濃縮された大豆乳化組成物を得ることができる。該均質化の前後いずれかにおいて必要により加熱処理工程、アルカリ処理工程等を付加することにより蛋白質をより抽出しやすくすることもできる。この場合、乾物あたりの食物繊維含量は10重量%以下であり、5重量%以下がより好ましい。なお、本発明において食物繊維含量は、「五訂増補日本食品標準成分表」(文部科学省、2005)に準じ、酵素−重量法(プロスキー変法)により測定することができる。
・ Removal of dietary fiber When the obtained insoluble fraction contains dietary fiber, for example, when it is the fraction of (3) or (1) and (3) above, water is added if necessary, and a high-pressure homogenizer or jet cooker heater After homogenization by means of, etc., through the process of further solid-liquid separation of the homogenized liquid and collecting the supernatant, dietary fiber (ocara) can also be removed, and the rich flavor is further concentrated A soybean emulsified composition can be obtained. Proteins can be more easily extracted by adding a heat treatment step, an alkali treatment step or the like, if necessary, before or after the homogenization. In this case, the dietary fiber content per dry matter is 10% by weight or less, and more preferably 5% by weight or less. In the present invention, the dietary fiber content can be measured by the enzyme-weight method (modified Prosky method) according to the “Fiveth Amendment Japanese Food Standard Component Table” (Ministry of Education, Culture, Sports, Science and Technology, 2005).

(大豆乳化組成物の特徴)
本発明に用いられる上記の大豆乳化組成物は、脂質(中性脂質及び極性脂質)及び蛋白質が特定の範囲で含まれ、蛋白質のうち特にLP含量が高いことが重要な特徴であり、必要により繊維質も含まれる乳化組成物である。そして大豆が本来有する自然な美味しさが濃縮されており、従来の問題とされていた大豆の青臭味や収斂味、渋味等の不快味がないか非常に少なく、非常にコクのある風味を有するものである。
通常の大豆粉や分離大豆蛋白に水、油脂を加えて該大豆乳化組成物と類似の組成の乳化組成物にすることは可能であるが、リポキシゲナーゼ蛋白質含量あるいはLCI値を同等なレベルに調整することは困難である。そして本技術により調製された大豆乳化組成物は、このような組み立て製品に比べて格段に風味が良好であり、食品素材としての利用適性が高いことに特徴を有する。
(Characteristics of soybean emulsified composition)
The above-mentioned soybean emulsified composition used in the present invention contains lipids (neutral lipids and polar lipids) and proteins in a specific range, and it is an important feature that the LP content is particularly high among proteins. It is an emulsified composition including fiber. And the natural taste inherent in soybeans is concentrated, and there is no or very little unpleasant taste such as blue odor, astringency, and astringency of soybeans, which has been considered a problem in the past, and a very rich flavor It is what has.
It is possible to add water and fat to normal soy flour and isolated soy protein to make an emulsified composition similar to the soy emulsified composition, but adjust the lipoxygenase protein content or LCI value to an equivalent level It is difficult. And the soybean emulsified composition prepared by this technique is characterized by remarkably good flavor and high suitability for use as a food material compared to such an assembled product.

<大豆加工食品>
本発明の大豆加工食品は、上記の大豆乳化組成物が、原料として使用されていることを特徴とするものである。好ましくは、豆乳や粉末状大豆蛋白等の大豆原料を使用して加工される大豆加工食品であって、大豆原料の一部又は全部が大豆乳化組成物に置換されてなるものをいう。より具体的には豆腐類、湯葉、大豆調味料、油揚げ、がんもどき、厚揚げ、飲用豆乳などであり、これらに類する範疇のものも含まれる。
大豆加工食品に配合される大豆乳化組成物は、通常の原料である豆乳や粉末状大豆蛋白等の大豆原料の全部あるいは一部を置き換えて配合することができる。これによって、大豆加工食品の食感や風味を改良することができる。置換率は大豆加工品の種類にもよるが、豆乳等の大豆原料の10重量%以上とすることができ、15重量%以上が好ましく、20重量%以上がより好ましく、25重量%以上とすることもできる。さらに求める品質により50重量%以上、70重量%以上、90重量%以上、あるいは100重量%とすることも可能である。以下、具体的な大豆加工食品の態様について説明するが、大豆加工食品の種類は下記態様に限定されるものではない。
<Processed soy food>
The processed soybean food of the present invention is characterized in that the soybean emulsified composition is used as a raw material. Preferably, it is a soy processed food processed using soy raw materials such as soy milk and powdered soy protein, wherein part or all of the soy raw material is replaced with a soy emulsified composition. More specifically, there are tofu, yuba, soybean seasoning, deep-fried tofu, cancer throbbing, deep-fried, and soy milk for drinking, and the like categories are also included.
The soybean emulsified composition to be blended with the processed soybean food can be blended by replacing all or part of soybean raw materials such as soybean milk and powdered soybean protein, which are ordinary raw materials. Thereby, the texture and flavor of the processed soybean food can be improved. Although the substitution rate depends on the type of processed soybean product, it can be 10% by weight or more of the soybean raw material such as soy milk, preferably 15% by weight or more, more preferably 20% by weight or more, and 25% by weight or more. You can also Further, depending on the desired quality, it may be 50% by weight, 70% by weight, 90% by weight or 100% by weight. Hereinafter, although the aspect of a specific processed soybean food is demonstrated, the kind of processed soybean food is not limited to the following aspect.

(豆腐類)
本発明に使用する大豆乳化組成物、あるいは大豆乳化組成物と豆乳との混合物に凝固剤を加え、加熱することにより蛋白質を凝固させ、豆腐を製造することができる。豆腐の製造は公知の製法で行うことができ、特に困難なく製造が可能である。凝固剤としてはニガリ(塩化マグネシウム)、塩化カルシウム、硫酸カルシウム、GDLなどを使用することができる。凝固剤の添加量は特に限定されないが、例えば大豆乳化組成物及び豆乳の乾物に対して0.1〜5重量%、好ましくは0.3〜3重量%とすることができる。豆腐の硬さは凝固剤の量を増減させて適宜調整することができ、よりしっかりした硬さの豆腐を製造したい場合は凝固剤の量を多めに添加し、より軟らかくクリーミーな豆腐を製造したい場合は凝固剤の量を少なめに添加すればよい。概して得られた豆腐は従来の豆腐に比べると非常にクリーミーであり、口の中でとろけるような口溶けの良い食感であると共に、青臭い大豆臭がなくコクのある風味を呈する。
なお、豆腐類には一般の製造において添加されている種々の添加剤を添加することができる。例えば凝固剤以外に塩類、オリゴ糖、多糖類、澱粉類、タンパク質などを単独あるいは併用して添加することができる。
(Tofu)
Tofu can be produced by adding a coagulant to the soybean emulsified composition used in the present invention, or a mixture of the soybean emulsified composition and soy milk, and heating to solidify the protein. Tofu can be produced by a known production method and can be produced without any particular difficulty. As the coagulant, bittern (magnesium chloride), calcium chloride, calcium sulfate, GDL and the like can be used. Although the addition amount of a coagulant is not specifically limited, For example, it is 0.1 to 5 weight% with respect to the soybean emulsified composition and the dry matter of soymilk, Preferably it can be 0.3 to 3 weight%. The tofu hardness can be adjusted as appropriate by increasing or decreasing the amount of coagulant, and if you want to produce a firmer tofu, add a larger amount of coagulant to produce a softer and creamier tofu. In this case, a small amount of coagulant may be added. In general, the tofu obtained is very creamy compared to conventional tofu, has a mouthfeel that melts in the mouth, and has a rich flavor without a blue soy odor.
In addition, the various additives currently added in general manufacture can be added to tofu. For example, in addition to the coagulant, salts, oligosaccharides, polysaccharides, starches, proteins and the like can be added alone or in combination.

(湯葉)
本発明に使用する大豆乳化組成物を単独で、あるいは豆乳との併用で原料として使用し、これを加熱又は凍結することにより、表面に膜状の蛋白質の変性物が生成するため、これを回収して湯葉を製造することができる。湯葉の製造法は公知の手段で行うことができる。
得られる湯葉はすくいたての生湯葉(汲み上げ湯葉)のようなとろりとした食感であり、通常の湯葉よりもコクのある風味を有する。また、食感の改質を行う場合、塩類、多糖類、デンプン類、タンパク質などを単独あるいは併用して大豆乳化組成物に添加し、湯葉を調製することができる。
(Yuba)
The soybean emulsified composition used in the present invention is used alone or in combination with soy milk as a raw material, and this is heated or frozen to produce a membrane-like protein denatured product, which is recovered. Yuba can be manufactured. The manufacturing method of yuba can be performed by a known means.
The yuba obtained has a rich texture like freshly cooked yuba (pumped yuba), and has a richer flavor than normal yuba. In addition, when modifying the texture, salts, polysaccharides, starches, proteins and the like can be added to the soybean emulsified composition alone or in combination to prepare yuba.

(大豆調味料)
本発明に使用する大豆乳化組成物を調味料の原料に配合し、大豆調味料を製造することができる。調味料としては、ポン酢、しょう油、マヨネーズ、ドレッシング、ソース、ケチャップ、タレ、だし等の他、即席麺等に添付される液体もしくは粉末の調味料等が挙げられる。
該大豆乳化組成物は調味料中に例えば20〜80重量%配合することができる。
(Soy seasoning)
The soybean emulsified composition used in the present invention can be blended with the seasoning raw material to produce a soybean seasoning. Examples of the seasoning include ponzu, soy sauce, mayonnaise, dressing, sauce, ketchup, sauce, dashi, etc., and liquid or powder seasonings attached to instant noodles.
The soybean emulsified composition can be blended in the seasoning, for example, 20 to 80% by weight.

(油揚げ・がんもどき・厚揚げ)
上記の大豆乳化組成物を原料の一部に使用し、公知の製造法により油揚げ、がんもどき又は厚揚げ等の大豆加工食品を調製することができる。これらの大豆加工食品は、伝統的な製法で豆腐類を原料生地としてもよいし、あるいは粉末状大豆蛋白、水及び油脂をカッター等で混練し、乳化させて得られる大豆蛋白ペーストを原料生地としてもよい。
厚揚げの場合、大豆乳化組成物を使用すると豆腐類にこれを使用した場合と同様の食感と風味を付与することができる。
また油揚げやがんもどきに大豆乳化組成物を使用した場合、同様に大豆のコクのある風味を付与するだけでなく、フライ調理した際の生地原料の膨化をより促進し、膨化率を向上させる効果を与えることができる。そして膨化率が向上することにより、調理後の調味液の吸液性も向上し、よりジューシーな食感を与えることができる。
(Deep-fried / Candied / Deep-fried)
The soybean emulsified composition described above can be used as a part of the raw material, and processed soybean foods such as deep-fried, crushed and thick-fried can be prepared by a known production method. These processed soybean foods may use tofu as a raw material dough by a traditional manufacturing method, or use a soybean protein paste obtained by kneading and emulsifying powdered soy protein, water and fat with a cutter etc. as a raw material dough Also good.
In the case of deep-fried food, when a soybean emulsion composition is used, the same texture and flavor can be imparted to tofu as when it is used.
In addition, when using a soybean emulsified composition for deep-fried fried chicken or cancer, it not only gives a rich flavor of soybeans, but also promotes the expansion of the dough ingredients when fried and improves the expansion rate. Can give an effect. And the expansion rate improves, The liquid absorptivity of the seasoning liquid after cooking can also improve, and a more juicy food texture can be given.

(飲用豆乳)
飲用豆乳は、豆腐製品の製造用豆乳ではなく、近年広く一般消費者に飲用されるようになった豆乳を利用した飲料であり、本発明においてはその製品規格は問わず豆乳が使用される飲料全般を含む。飲用豆乳に大豆乳化組成物を使用すると、大豆のコクやクリーミー感を付与することができる。
(Drinking soy milk)
Drinking soymilk is not a soymilk for the production of tofu products, but a beverage that uses soymilk that has been widely consumed by general consumers in recent years. In the present invention, soymilk is used regardless of the product standard. Includes general. If a soybean emulsified composition is used for drinking soymilk, the richness and creamy feeling of soybeans can be imparted.

(冷凍大豆加工食品)
本発明の大豆加工食品はオリゴ糖、多糖類、澱粉類、ゼラチンなどの公知の冷凍変性防止剤を添加することにより、凍結解凍後も凍結前と同様の食感を維持する、冷凍耐性を付与させた大豆加工食品とすることもできる。これらは例えば冷凍豆腐、冷凍湯葉、冷凍厚揚げ、冷凍がんもどき、冷凍油揚げなどの冷凍食品として製品化することができる。冷凍変性防止剤の添加量は豆腐類中0.1〜10重量%が好ましい。
例えば従来の冷凍豆腐は風味があっさりとして大豆風味が少なく、食感は硬く口残りしやすいものであったが、本発明によれば大豆乳化組成物の使用により冷凍豆腐の場合でも豆腐類への使用効果と同様の効果が得られる。
(Frozen soy processed food)
The processed soy food of the present invention is provided with freeze resistance by maintaining the same texture after freezing and thawing by adding known antifreezing agents such as oligosaccharides, polysaccharides, starches and gelatin. It can also be made the processed soybean food. These can be commercialized as frozen foods such as frozen tofu, frozen yuba, deep-fried deep-fried, frozen cancer, and deep-fried frozen oil. The addition amount of the freezing denaturation inhibitor is preferably 0.1 to 10% by weight in the tofu.
For example, the conventional frozen tofu has a light and light soybean flavor, and the texture is hard and easy to taste, but according to the present invention, the use of the soybean emulsified composition makes it possible to convert tofu tofu even in the case of frozen tofu. The same effect as the use effect can be obtained.

(乾燥大豆加工食品)
本発明の大豆加工食品は最終的にフリーズドライ、スプレードライ、マイクロ波乾燥、オーブン乾燥、自然乾燥、減圧乾燥等の種々の手段により、乾燥豆腐、乾燥湯葉、乾燥大豆調味料、乾燥油揚げ、粉末豆乳等の乾燥大豆加工品とすることができる。
本発明の大豆加工食品が油揚げである場合、フライ後の油揚げを各種調味料を含む調味液に浸漬するなどして調味してから乾燥を行い、即席用具材としても用いることができる。本発明の油揚げは大豆乳化組成物の使用により膨らみが良いため、調味し、乾燥した後もそのボリュームを維持し、湯を注いで復元させる場合においても、そのボリュームと優れた復元性(湯戻り性)を有する。
(Dried soybean processed food)
The processed soybean food of the present invention is finally dried tofu, dried yuba, dried soybean seasoning, dried fried oil, powder by various means such as freeze drying, spray drying, microwave drying, oven drying, natural drying, reduced pressure drying, etc. It can be set as processed soybean products such as soy milk.
When the processed soybean food of the present invention is fried, the fried fried food is seasoned by immersing it in a seasoning liquid containing various seasonings and dried, and can also be used as an instant ingredient. The fried chicken of the present invention has a good swelling due to the use of the soybean emulsified composition. Therefore, even after seasoning and drying, the volume is maintained and even when hot water is poured and restored, the volume and excellent resilience (return to hot water) ).

以下に本発明の実施例を記載する。なお、以下「%」、「部」は特に断りのない限り「重量%」、「重量部」を意味する。脂質の分析は特に断りがない限りクロロホルム/メタノール混合溶媒抽出法に準じて行ったものである。   Examples of the present invention will be described below. Hereinafter, “%” and “parts” mean “% by weight” and “parts by weight” unless otherwise specified. Analysis of lipids was performed according to the chloroform / methanol mixed solvent extraction method unless otherwise specified.

(製造例1) 大豆乳化組成物の調製1
湿熱加熱処理によりNSI 59.4とした大豆粉3.5kgに対して4.5倍量、50℃の水を加えて懸濁液とし、保温しながら30分間攪拌し、水抽出した。このときのpHは6.7であった。3層分離方式の遠心分離を6,000×gにて連続的に行い、(1)浮上層・(2)中間層・(3)沈殿層に分離させた。そして浮上層と沈殿層を合わせた画分6.3kgを回収し、大豆乳化組成物Aを調製した。
(Production Example 1) Preparation of soybean emulsified composition 1
The suspension was made by adding 4.5 times the amount of water at 50 ° C. to 3.5 kg of soybean powder made to NSI 59.4 by wet heat treatment, and stirred for 30 minutes while keeping warm and extracted with water. The pH at this time was 6.7. Centrifugation of a three-layer separation method was continuously performed at 6,000 × g, and separated into (1) a floating layer, (2) an intermediate layer, and (3) a precipitation layer. And the fraction 6.3kg which combined the floating layer and the precipitation layer was collect | recovered, and the soybean emulsification composition A was prepared.

(製造例2) 大豆乳化組成物の調製2
製造例1にて調製した大豆乳化組成物Aに対して0.5重量倍の加水を行い、さらに13MPaにて高圧ホモゲナイザーで均質化した後、該均質化液を蒸気直接吹き込み方式で142℃7秒間加熱処理し、連続式遠心分離機にて6,000×gにて不溶性の繊維質を分離除去し、上清画分を得、これを大豆乳化組成物Bとした。
(Production Example 2) Preparation of soybean emulsified composition 2
The soybean emulsified composition A prepared in Production Example 1 was added 0.5 times by weight and further homogenized with a high-pressure homogenizer at 13 MPa, and then the homogenized liquid was heated at 142 ° C. for 7 seconds by a steam direct blowing method. The insoluble fiber was separated and removed at 6,000 × g with a continuous centrifuge, and a supernatant fraction was obtained.

製造例1,2で得られた大豆乳化組成物A,Bを分析用に一部凍結乾燥し、一般成分として乾物、並びに、乾物あたりの蛋白質(ケルダール法による)、脂質(クロロホルム/メタノール混合溶媒抽出法による)及び灰分を測定し、さらにSDS-PAGEによりリポキシゲナーゼ蛋白質含量、LPの含量の推定値としてLCI値の分析を行った。また比較として、原料に用いた大豆粉、及び、米国特許第6,548,102号公報の方法で製造されていると推定される市販の大豆乳化組成物「Soy Supreme Kreme」(サンオプタ社(SunOpta Grains and Foods Group)製、粉末タイプ)についても同様に分析を行った。各分析値を表2に示す。   The soybean emulsified compositions A and B obtained in Production Examples 1 and 2 were partially lyophilized for analysis, dried as general components, protein per dry matter (by Kjeldahl method), lipid (chloroform / methanol mixed solvent) (By an extraction method) and ash content were measured, and further, LCI value was analyzed as an estimated value of lipoxygenase protein content and LP content by SDS-PAGE. For comparison, the soy flour used as a raw material and the commercially available soybean emulsified composition “Soy Supreme Kreme” (SunOpta Grains and Foods Group) presumed to be produced by the method of US Pat. No. 6,548,102 ) And powder type) were similarly analyzed. Each analysis value is shown in Table 2.

(表2)

Figure 2013031422
(Table 2)
Figure 2013031422

大豆乳化組成物A,Bは大豆粉と比べると蛋白質に対する脂質含量に富み、さらに蛋白質組成が大豆粉や市販の大豆乳化組成物とは大きく異なるものであった。すなわちLCI値が55以上、好ましくは58以上、さらに60以上という高値であることから、LPが濃縮されたものであり、リポキシゲナーゼ蛋白質も高い含量であった。このような組成を有する大豆乳化組成物は、従来の豆乳やオカラなどにはない成分組成である。これらの組成物A,Bの風味も既存の豆乳、大豆が本来有する自然な美味しさが濃縮されており、従来の問題とされていた大豆の青臭味や収斂味、渋味等の不快味がなく、非常にコクのある風味を有するものであった。   Soy emulsified compositions A and B were rich in lipid content relative to protein compared to soybean flour, and the protein composition was significantly different from soybean flour and commercially available soybean emulsified compositions. That is, the LCI value was 55 or more, preferably 58 or more, and further 60 or more, so that LP was concentrated and the amount of lipoxygenase protein was also high. The soybean emulsified composition having such a composition is a component composition not found in conventional soymilk or okara. The flavors of these compositions A and B are also concentrated in the natural taste inherent in existing soymilk and soybeans, and unpleasant tastes such as the blue odor, astringent taste, and astringency of soybeans, which were previously considered problems. No, it had a very rich flavor.

(比較例1) 豆腐(対照)
市販の豆乳(乾物含量11%)80部に、にがり0.5部を添加し、良く混合して容器に充填し、95℃で25分間蒸し器で蒸煮し、自然冷却し、従来から製造されている伝統的な豆腐を得た。
得られた豆腐は、硬く、もろいゲルであり、口の中ではすぐに溶けず、咀嚼することにより細かく砕けるような食感であった。
(Comparative Example 1) Tofu (control)
Traditionally produced traditionally manufactured by adding 0.5 parts of bittern to 80 parts of commercial soymilk (dry matter content 11%), mixing well, filling into a container, steaming in a steamer at 95 ° C for 25 minutes, naturally cooling Got a typical tofu.
The tofu obtained was a hard and fragile gel that did not melt immediately in the mouth, and had a texture that could be finely broken by chewing.

(実施例1) 豆腐2
製造例2で得られた大豆乳化組成物B(乾物含量18.2%)80部に、にがりを0.1部添加し、良く混合して、容器に充填し、95℃で25分間蒸し器で蒸煮し、自然冷却して豆腐を得た。
得られた豆腐は、比較例1の豆腐のように硬くてもろいゲル物性ではなく、軟らかくてさっくりとしたスプーン通りである物性であった。また食感はクリーミーでとろけるように口溶けが良いもので、豆腐というよりも、滑らかな食感のクリーム入りのプリン、あるいは、あんきも(アンコウの肝)のようなコクのある口溶けの良い食感であった。また風味は比較例1の豆腐の風味とは明らかに異なるものであり、より濃厚かつ良好な大豆の風味を有していた。
得られた本発明の豆腐にポン酢しょう油をかけると非常に美味であった。
(Example 1) Tofu 2
Add 80 parts of bittern to 80 parts of soybean emulsified composition B (dry matter content 18.2%) obtained in Production Example 2, mix well, fill into a container, cook in a steamer at 95 ° C for 25 minutes, Cooled to obtain tofu.
The obtained tofu was not as hard and brittle as the tofu of Comparative Example 1, but had a soft and crisp physical property. In addition, the mouthfeel is creamy and melts well in the mouth, rather than tofu, with a creamy pudding with a smooth mouthfeel, or a rich mouthfeel like Ankimo (ancho liver) there were. The flavor was clearly different from that of Comparative Example 1 and had a richer and better soybean flavor.
When ponzu soy sauce was applied to the obtained tofu of the present invention, it was very delicious.

(実施例2) 豆腐3
比較例1の配合において、豆乳8部、32部、48部をそれぞれ製造例2の大豆乳化組成物Bと置換し、同様の方法で豆乳の置換率が10%、40%、60%の各豆腐を得た。
得られた豆腐は置換率が高いほどコクのある風味で、クリーミー感が付与された食感となった。
(Example 2) Tofu 3
In the composition of Comparative Example 1, 8 parts, 32 parts, and 48 parts of soy milk were replaced with the soybean emulsified composition B of Production Example 2, and the substitution rate of soy milk was 10%, 40%, and 60% in the same manner. Got tofu.
The obtained tofu had a richer flavor as the substitution rate was higher, and became a texture with a creamy feeling.

(実施例3) 大豆調味料
製造例2で得られた大豆乳化組成物B 75部に対してポン酢しょう油25部を加えてよく混合し、大豆調味料を得た。この調味料を刺身にかけて食したところ、クリーミーでまろやかな酸味とコクがあり、ゴマだれ様の外観色と粘度であり、刺身との風味の相性も非常に良いものであった。
(Example 3) Soy seasoning Soy emulsified composition B obtained in Production Example 2 was mixed with 75 parts of ponzu soy sauce and mixed well to obtain a soy seasoning. When this seasoning was eaten over sashimi, it had a creamy, mellow acidity and richness, an appearance color and viscosity similar to sesame seeds, and a very good flavor compatibility with sashimi.

(実施例4) 湯葉
製造例2で得られた大豆乳化組成物Bを平板状のトレーに高さ2cmまで満たし、−20℃の凍結庫で10日間凍結した。これを解凍したところ、細かい湯葉片となり、これを食すると、とろみのある食感で、くみ上げ湯葉様の食感と風味になった。これに調味液を加えるとさらに美味しく食すことができた。
(Example 4) Yuba The soybean emulsion composition B obtained in Production Example 2 was filled in a flat tray to a height of 2 cm and frozen in a freezer at -20 ° C for 10 days. When this was thawed, it became a fine yuba piece, and when it was eaten, it had a thick texture and a texture and flavor of kumage yuba. When seasoning liquid was added to this, it was able to eat more deliciously.

(参考例1) 冷凍豆腐(対照)
丸大豆5kgに対して水(10℃)15kgを加え、14時間浸漬した。これを、10メッシュのフルイで浸漬ホエーと浸漬大豆とに分離した。次に、この浸漬大豆を挽き水(20℃)25kgと共にグラインダー((株)長沢機械製作所製。以下、同様)を用いて呉にした。これを、分離機((株)トーファー製。以下、同様)を用いて豆乳(固形分濃度9%)とオカラに分けた。この豆乳を間接加熱装置((株)星高製。以下、同様)を用いて98℃で5分間加熱処理を行った。得られた豆乳を濃縮機((株)日阪製作所製。以下、同様)で真空圧100torrで固形分濃度12%に調整し、濃縮豆乳を得た。
次に、この濃縮豆乳を75℃に調温し、濃縮豆乳100部に対して、ワキシーコーンスターチ「デリカSE」(日澱化学(株)製)を3部、デキストリン「サンデック250」(三和澱粉工業(株)製)を2部、塩化マグネシウム製剤「マグネスファインTG」(花王(株)製)0.9部を加え、型箱に入れ凝固させた。凝固温度は70℃であった。凝固後、90℃で40分間蒸し加熱を行った。これを、20℃以下に冷却後、所定のサイズに切断し、約−35℃の雰囲気下で急速冷凍し、冷凍豆腐(対照)を得た。
(Reference Example 1) Frozen tofu (control)
15 kg of water (10 ° C.) was added to 5 kg of whole soybeans and immersed for 14 hours. This was separated into soaked whey and soaked soybeans with a 10 mesh sieve. Next, the soaked soybeans were made into kure using a grinder (manufactured by Nagasawa Machinery Co., Ltd., hereinafter the same) together with 25 kg of ground water (20 ° C.). This was separated into soy milk (solid content concentration 9%) and okara using a separator (manufactured by Topher Co., Ltd., hereinafter the same). This soymilk was heat-treated at 98 ° C. for 5 minutes using an indirect heating apparatus (manufactured by Hoshitaka Co., Ltd., hereinafter the same). The obtained soymilk was adjusted to a solid content concentration of 12% at a vacuum pressure of 100 torr with a concentrator (manufactured by Nisaka Manufacturing Co., Ltd., hereinafter the same) to obtain concentrated soymilk.
Next, this concentrated soymilk is adjusted to 75 ° C., and 100 parts of the concentrated soymilk, 3 parts of waxy corn starch “Delica SE” (manufactured by Nissho Chemical Co., Ltd.) and dextrin “Sandeck 250” (Sanwa Starch) 2 parts of Kogyo Co., Ltd.) and 0.9 part of Magnesium Fine TG “Magnes Fine TG” (manufactured by Kao Corporation) were added and solidified in a mold box. The solidification temperature was 70 ° C. After solidification, steaming and heating were performed at 90 ° C. for 40 minutes. This was cooled to 20 ° C. or lower, cut into a predetermined size, and rapidly frozen in an atmosphere of about −35 ° C. to obtain frozen tofu (control).

(実施例5,6) 冷凍豆腐
参考例1で得た濃縮豆乳に対して、製造例2で得られた大豆乳化組成物B(固形分濃度18.2%)を、濃縮豆乳:大豆乳化組成物B=70:30(実施例5)、40:60(実施例6)の割合で混合し、参考例1と同様の方法で調製し、冷凍豆腐を得た。
(Examples 5 and 6) Frozen tofu For the concentrated soy milk obtained in Reference Example 1, the soy emulsified composition B (solid content concentration 18.2%) obtained in Production Example 2 was added to the concentrated soy milk: soy emulsified composition. Product B = 70: 30 (Example 5), 40:60 (Example 6) were mixed at a ratio and prepared in the same manner as in Reference Example 1 to obtain frozen tofu.

(参考例2) 冷凍厚揚げ(対照)
豆乳の固形分濃度16%とした以外は、参考例1と同様に処理し、冷凍前の豆腐を調製した。この豆腐を180℃、2分間の条件で、ナタネ油でフライし、その後、約−35℃の雰囲気下で急速凍結し、冷凍厚揚げ(対照)を得た。
(Reference Example 2) Frozen deep fried (control)
The tofu before freezing was prepared in the same manner as in Reference Example 1 except that the soymilk solid content concentration was 16%. This tofu was fried in rapeseed oil at 180 ° C. for 2 minutes, and then snap-frozen in an atmosphere of about −35 ° C. to obtain a frozen deep-fried (control).

(実施例7〜9) 冷凍厚揚げ
参考例2で得た濃縮豆乳に対して、製造例2で得られた大豆乳化組成物B(固形分濃度18.2%)を、濃縮豆乳:大豆乳化組成物B=85:15(実施例7)、70:30(実施例8)、40:60(実施例9)の割合で混合し、参考例1と同様の方法で調製し、冷凍前の豆腐を調製した。この豆腐を180℃、2分間の条件で、ナタネ油でフライし、その後、約−35℃の雰囲気下で急速凍結し、冷凍厚揚げを得た。
(Examples 7 to 9) Frozen deep-frying Concentrated soy milk obtained in Production Example 2 (solid content concentration 18.2%) with concentrated soy milk obtained in Reference Example 2, concentrated soy milk: soy emulsified Composition B = 85: 15 (Example 7), 70:30 (Example 8), mixed at a ratio of 40:60 (Example 9), prepared in the same manner as in Reference Example 1, and before freezing Tofu was prepared. This tofu was fried with rapeseed oil at 180 ° C. for 2 minutes, and then quickly frozen in an atmosphere of about −35 ° C. to obtain a deep-fried deep-fried chicken.

(品質評価方法)
食感は、冷凍豆腐および厚揚げを室温解凍してから官能評価した。滑らかで豆腐らしい食感のものを5点、硬く口溶けの悪いものや澱粉添加によるネタツキのあるものを1点とした。風味は、好ましい豆の風味を感じるものを5点、豆の味を感じないものを1点とした。評価は、5人のパネラーにて5点満点の評点法で評価した。
(Quality evaluation method)
The texture was sensory evaluated after thawing frozen tofu and deep-fried to room temperature. A smooth and tofu-like texture was scored 5 points, a hard and poorly melted mouthfeel, and a grainy texture due to the addition of starch was scored 1 point. As for the flavor, 5 points were given to feel the preferred bean flavor, and 1 point was given to those that did not feel the bean taste. Evaluation was performed by a five-point scoring method with five panelists.

(表3) 冷凍豆腐に対する大豆乳化組成物Bの添加効果

Figure 2013031422
(Table 3) Additive effect of soybean emulsified composition B on frozen tofu
Figure 2013031422

(冷凍豆腐評価)
参考例1は、大豆の濃厚な風味が少なくあっさりとした風味であった。また食感は硬めであり、従来の豆腐と同様の食感であった。
実施例5の濃縮豆乳:大豆乳化組成物B=70:30の場合は、参考例1に比べて、大豆の濃厚な(コクのある)風味が感じられ、それでいて青臭くなく、また、食感は軟らかくかつ滑らかで口溶けが良くなり、咀嚼時に豆腐の粒が溶けるような食感であった。
実施例6の濃縮豆乳:大豆乳化組成物B=40:60の場合は、実施例5に比べて、さらに濃厚な大豆風味が感じられ、さらに、食感においては、プリンのように非常に軟らかくかつ滑らかで口溶けが非常によく、クリーミーな食感であった。
(Frozen tofu evaluation)
Reference Example 1 had a light flavor with little rich soybean flavor. Moreover, the texture was hard and was the same texture as the conventional tofu.
In the case of the concentrated soymilk: soy emulsified composition B = 70: 30 in Example 5, compared to Reference Example 1, a rich (rich) flavor of soybeans is felt, yet it does not smell blue, and the texture is The texture was soft and smooth with good mouth melting, and the tofu grains melted when chewed.
In the case of concentrated soymilk: soy emulsified composition B = 40: 60 in Example 6, a thicker soybean flavor is felt compared to Example 5, and the texture is very soft like pudding. It was smooth and melted well in the mouth, with a creamy texture.

(表4) 冷凍絹厚揚げに対する大豆乳化組成物Bの添加効果

Figure 2013031422
(Table 4) Effect of adding soybean emulsified composition B to deep-fried frozen silk
Figure 2013031422

(絹厚揚げ評価)
参考例2は、大豆の濃厚な風味が少なくあっさりとしていた。また食感は硬く、口の中で直ぐには溶けずに口溶けは悪い食感であった。
実施例7の濃縮豆乳:大豆乳化組成物B=85:15の場合は、参考例2に比べて、やや大豆の風味が感じられ、軟らかく滑らかな食感への変化が感じられた。
実施例8の濃縮豆乳:大豆乳化組成物B=70:30の場合は、実施例7に比べて、より濃厚な大豆の風味が感じられ、さらに、食感においては、軟らかく滑らかな食感であった。
実施例9の濃縮豆乳:大豆乳化組成物B=40:60の場合は、実施例8と比べて、濃厚な大豆の風味がさらに強く感じられ好ましく、食感においても非常に軟らかくかつ滑らかで口溶けも良好であり、非常にクリーミーな食感であった。
(Evaluation of deep-fried silk)
In Reference Example 2, the rich flavor of soybean was small and light. In addition, the texture was hard, and it did not melt immediately in the mouth, but the mouth melted was bad.
In the case of the concentrated soymilk: soy emulsified composition B = 85: 15 in Example 7, a slightly soy flavor was felt compared to Reference Example 2, and a change to a soft and smooth texture was felt.
In the case of the concentrated soymilk: soy emulsified composition B = 70: 30 in Example 8, a thicker soybean flavor is felt than in Example 7, and the texture is soft and smooth. there were.
In the case of the concentrated soymilk: soy emulsified composition B = 40: 60 in Example 9, it is preferable that the flavor of rich soybean is felt stronger than in Example 8, and the texture is very soft and smooth and melts in the mouth. Was also very good and had a very creamy texture.

以上実施例5〜9および参考例1,2の結果から、十分な添加効果が得られる、豆乳に対する大豆乳化組成物Bの置換率は15%以上が好ましく、より好ましくは20%以上であると濃厚な大豆の風味が付与され軟らかく滑らかな食感とすることができた。   From the results of Examples 5 to 9 and Reference Examples 1 and 2 described above, a sufficient addition effect is obtained, and the replacement ratio of the soybean emulsified composition B with respect to soy milk is preferably 15% or more, more preferably 20% or more. A rich soybean flavor was imparted, and a soft and smooth texture was achieved.

(参考例3) がんもどき1(対照)
大豆蛋白原料として粉末状分離大豆蛋白「フジプロE」(不二製油(株)製、以下の例において同じ。)を450部、なたね油360部、水1420部をサイレントカッターに投入して、約20℃で混練し、3分間均一に乳化させ、乳化物を調製した。この乳化物に調味料15部、おから18部、小麦粉30部を加え、さらにダイス状のにんじん150部、ごま9部を加え混合し生地を得た。
生地を成型機で直径58mm、厚み10mm、1個27gに成形した。これを低温部(92〜135℃)8分、高温部(155〜180℃)1分30秒のフライ加熱を行い、空冷後、−35℃で急速凍結を行い、冷凍のがんもどきを得た。
(Reference Example 3) Cancer pound 1 (control)
As a soy protein raw material, powdered separated soy protein “Fuji Pro E” (Fuji Oil Co., Ltd., the same in the following examples) 450 parts, rapeseed oil 360 parts and water 1420 parts are put into a silent cutter, and about 20 parts. The mixture was kneaded at 0 ° C. and uniformly emulsified for 3 minutes to prepare an emulsion. To this emulsion, 15 parts of seasoning, 18 parts of okara and 30 parts of flour were added, and 150 parts of diced carrot and 9 parts of sesame were added and mixed to obtain a dough.
The dough was formed into a diameter of 58 mm, a thickness of 10 mm, and one piece of 27 g with a molding machine. This is heated in the low temperature part (92-135 ° C) for 8 minutes and in the high temperature part (155-180 ° C) for 1 minute 30 seconds. After air cooling, it is rapidly frozen at -35 ° C to obtain frozen cancer. It was.

(実施例10) がんもどき2(大豆乳化組成物Bを配合)
参考例3のがんもどきの製造において、水を製造例2で得られた大豆乳化組成物Bで全量置換し、その他は同様にしてがんもどきを得た。
得られたがんもどきは、内部はスポンジ状組織を有し、これまでのがんもどきよりも大きく、煮込んだ後もボリュームを維持しながら、調味液をよく含み、従来にないジューシーな口あたりの食感を有していた。さらに風味は大豆本来のコク味も有していた。
(Example 10) Cancer pounding 2 (with soybean emulsified composition B)
In the preparation of the cancer mushroom of Reference Example 3, the whole amount of water was replaced with the soybean emulsified composition B obtained in Production Example 2, and the others were similarly obtained.
The resulting cancer mushroom has a sponge-like structure inside, is larger than conventional cancer mushrooms, maintains a volume even after boiling, contains a seasoning liquid, and has an unprecedented juicy mouthfeel. Had a texture. In addition, the flavor had the original richness of soybeans.

(比較例2)
参考例3のがんもどきの製造法において、水を丸大豆豆乳(固形分9.1%、たん白質4.7%、油分3.6%)で全量置換し、その他は同様にしてがんもどきを得た。
(Comparative Example 2)
In the method for producing cancer refractory of Reference Example 3, the whole amount of water was replaced with whole soybean soymilk (solid content: 9.1%, protein: 4.7%, oil content: 3.6%). I got back.

(比較例3)
参考例3のがんもどきの製造法において、水の代わりに練り込み用クリーム「ミルレア」(固形分28.4%、油分15.0%、不二製油(株)製)で全量置換し、その他は同様にしてがんもどきを得た。
(Comparative Example 3)
In the cancer-drinking production method of Reference Example 3, the entire amount was replaced with a kneading cream “Milrea” (solid content 28.4%, oil content 15.0%, manufactured by Fuji Oil Co., Ltd.) instead of water. I got cancer.

(実施例11〜14) がんもどき3(大豆乳化組成物Bの配合量変化)
参考例3のがんもどきの製造法において、製造例2で得られた大豆乳化組成物Bを生地仕込みあたり、142部、355部、710部、1420部を配合し、生地中に含まれる蛋白質量が等しくなるよう、加水調整を行い、その他は同様にして最終的に水との置換率が10%、25%、50%、100%の各がんもどきを得た(実施例11、12、13、14)。得られたがんもどきは、大豆乳化組成物Bの配合量が多いほど、フライ後のボリュームがあり、調味液の含みも良いがんもどきが得られた。
(Examples 11-14) Cancer mocking 3 (change in blending amount of soybean emulsified composition B)
In the method for producing cancer remorse of Reference Example 3, the soybean emulsified composition B obtained in Production Example 2 is blended with 142 parts, 355 parts, 710 parts, 1420 parts per dough, and the protein contained in the dough The amount of water was adjusted so that the amounts were equal, and in the other cases, each cancer reversion with a water substitution rate of 10%, 25%, 50%, and 100% was finally obtained in the same manner (Examples 11 and 12). , 13, 14). As for the obtained cancer mushroom, as the blended amount of the soybean emulsified composition B was increased, the volume after fried food was increased, and a cancer mushroom that contained a seasoning liquid was obtained.

(評価方法)
得られたがんもどきは、生地の膨化度合いを目視で観察した上で、長辺(X)、短辺(Y)、厚み(H)のサイズをノギスで測定し、5個の平均値(mm)から体積を算出し、フライ後の膨化状態を確認した。なお、体積(V)は、長辺と短辺の平均値の1/2を半径(Rcm)とし、V≒R×3.14×H として算出した。数値は参考例3の体積を100としたときの比率(%)で表した。
そして、和風の調味液(しょうゆ大さじ2、砂糖大さじ4、みりん小さじ4、酒小さじ4、だし汁800cc)にて、約15分程度煮込んだ後、取り出して重量を測定した。そしてがんもどきの調味液の吸収倍率を煮込み前がんもどき重量に対する煮込み後がんもどき重量の比率(%)で測定した。
さらにがんもどきの風味、形状(膨らみ)及び吸液性について、(+++)非常に良好、(++)良好、(+)やや良好、(±)普通、(−)悪いの5段階で評価した。
(Evaluation method)
The obtained cancer squirrel was measured by visually observing the degree of swelling of the dough and measuring the long side (X), short side (Y), and thickness (H) with a caliper. The volume was calculated from mm), and the expanded state after the frying was confirmed. The volume (V) was calculated as V≈R 2 × 3.14 × H, where ½ of the average value of the long side and short side was the radius (Rcm). The numerical value was expressed as a ratio (%) when the volume of Reference Example 3 was 100.
Then, it was boiled for about 15 minutes in a Japanese-style seasoning liquid (2 tablespoons soy sauce, 4 tablespoons sugar, 4 teaspoons of mirin, 4 teaspoons of sake, and 800 cc of soup stock), and then taken out and weighed. Then, the absorption ratio of the seasoning liquid of the cancer pounding was measured by the ratio (%) of the cancer pounding weight after boiling to the weight of the cancer pounding before cooking.
Furthermore, the taste, shape (swelling) and liquid absorbency of cancer resurrection were evaluated in five levels: (++++) very good, (++) good, (+) slightly good, (±) normal, (−) bad. .

(表5)

Figure 2013031422
(Table 5)
Figure 2013031422

(評価結果)
実施例10〜14、比較例2、3から、十分な添加効果が得られる水に対する大豆乳化組成物Bの置換率の目安としては、水に対する大豆乳化組成物Bの置換率が 10%以上が好ましく、より好ましくは25%以上であり、更に好ましくは50%以上であると、フライ後の形状に厚みがあり、ボリュームのあるがんもどきを得ることができた。内部はキメの細かなスポンジ状組織を有し、煮込んだ後は調味液を良く含み、ジューシーな味わいのあるがんもどきを得ることができた。
(Evaluation results)
From Examples 10 to 14 and Comparative Examples 2 and 3, as a measure of the substitution rate of the soy emulsified composition B with respect to water that provides a sufficient addition effect, the substitution rate of the soy emulsified composition B with respect to water is 10% or more. If it is preferably 25% or more, more preferably 50% or more, the shape after frying has a thickness and a cancerous rejuvenation can be obtained. The inside had a fine sponge-like structure, and after boiling it well contained the seasoning liquid, and it was possible to obtain a succulent and thrilling cancer.

(参考例4) 油揚げ1(対照)
粉末状分離大豆たん白500部、油脂(パーム油)60部、水1550部、コーンスターチ25部、食塩5部をサイレントカッターに投入し、約20℃で混練し、3分間均一に混合乳化し、乳化物を調製した。その後、塩化マグネシウム12部を水15部に溶かしたものを加え、更に1分間混合させ、適度な固さの生地が調製できた。この生地を成型機を用いて、66.5×46mm、15.5gに成型した。これを100×77mmの型枠を使用した3段フライヤー(70℃で4分、110℃で2分、170℃で4分)でフライし、油揚げを得た。
(Reference Example 4) Fried chicken 1 (control)
500 parts of powdered soy protein, 60 parts of fat (palm oil), 1550 parts of water, 25 parts of corn starch and 5 parts of salt are put into a silent cutter, kneaded at about 20 ° C., and uniformly mixed and emulsified for 3 minutes. An emulsion was prepared. Thereafter, 12 parts of magnesium chloride dissolved in 15 parts of water was added, and the mixture was further mixed for 1 minute to prepare a dough having an appropriate hardness. This dough was molded into 65.5 × 46 mm, 15.5 g using a molding machine. This was fried in a three-stage fryer (4 minutes at 70 ° C., 2 minutes at 110 ° C., 4 minutes at 170 ° C.) using a 100 × 77 mm mold to obtain fried chicken.

(実施例15) 油揚げ2(大豆乳化組成物Bを配合)
参考例4の油揚げの製造において、水1550部のうち760部を製造例2で得られた大豆乳化組成物Bで置換した以外は、参考例4と同様にして、油揚げを得た。
得られた油揚げは、ふっくらとした外観を有し、内部はキメの細かい組織であった。従来の油揚げに比べ、大豆由来のコク味が付与された風味となっており、調味液で着味した場合、調味液の吸収が良く、ジューシーな味付け油揚げが得られた。
この油揚げをさらに油揚げと調味液の重量が1:1となる程度に脱液した後、加熱乾燥を行うと 調味前に近いボリューム(厚み)のある油揚げが得られた。この味付け乾燥油揚げの湯戻り状態も良く、調味液をよく含んだ油揚げが得られた。
(Example 15) Fried chicken 2 (mixed with soybean emulsified composition B)
In the production of deep-fried food of Reference Example 4, deep-fried food was obtained in the same manner as Reference Example 4 except that 760 parts of 1550 parts of water were replaced with soybean emulsified composition B obtained in Production Example 2.
The obtained fried chicken had a plump appearance and the inside was a fine texture. Compared to conventional fried chicken, it has a flavor with a rich soybean-derived taste, and when seasoned with a seasoning liquid, the seasoning liquid is well absorbed and a juicy seasoned fried food is obtained.
This fried chicken was further fried and drained so that the weight of the seasoning liquid was 1: 1, and then heat-dried to obtain a deep-fried fried chicken with a volume (thickness) close to that before seasoning. The seasoned dry fried chicken was well returned to the hot water, and a deep-fried fried chicken well containing the seasoning liquid was obtained.

(比較例4)
参考例4の油揚げの製造において、水1550部のうち760部を丸大豆豆乳(固形分9.1%、たん白質4.7%、油分3.6%)で置換した以外は、参考例4と同様にして、油揚げを得た。
(Comparative Example 4)
Reference Example 4 except that 760 parts of 1550 parts of water were replaced with whole soybean soy milk (solid content: 9.1%, protein: 4.7%, oil content: 3.6%) In the same manner as above, fried chicken was obtained.

(比較例5)
製造例4の油揚げの製造において、水1550部のうち760部を練り込み用クリーム「ミルレア」(固形分28.4%、油分15.0%、不二製油(株)製)で置換した以外は、参考例4と同様にして、油揚げを得た。
(Comparative Example 5)
Reference Example, except that 760 parts of 1550 parts of water were replaced with kneading cream “Mirrea” (solid content 28.4%, oil content 15.0%, manufactured by Fuji Oil Co., Ltd.) In the same manner as in No. 4, fried chicken was obtained.

(実施例16〜19) 油揚げ3(大豆乳化組成物Bの配合量変化)
参考例4の油揚げの製造において、粉末状分離大豆蛋白を500部、なたね油60部とし、製造例2で得られた大豆乳化組成物Bを生地仕込みあたり、150部、380部、760部、1525部を配合し、生地中に含まれる蛋白質量が等しくなるよう加水調整を行い、その他は同様にして最終的に水との置換率が10%、25%、50%、85%の各油揚げを得た(実施例16、17、18、19)。
(Examples 16 to 19) Deep-fried oil 3 (change in blending amount of soybean emulsified composition B)
In the production of deep-fried fried food of Reference Example 4, 500 parts of powdered soy protein and 60 parts of rapeseed oil were prepared, and the soybean emulsified composition B obtained in Production Example 2 was 150 parts, 380 parts, 760 parts, 1525 per dough preparation. The water content is adjusted so that the amount of protein contained in the dough is equal, and the rest of the frying is 10%, 25%, 50%, and 85%. Obtained (Examples 16, 17, 18, 19).

(評価方法)
得られた油揚げは、生地の膨化度合いを目視で観察した上で、長辺、短辺、厚みのサイズをノギスで測定し、5個の平均値(mm)から、体積を算出し、フライ後の膨化状態を確認した。数値は参考例4の体積を100としたときの比率(%)で表した。
そして、得られた油揚げを和風の調味液で、約3分程度煮込んだ後、取り出して重量を測定した。そして油揚げの調味液の吸収倍率を煮込み前重量に対する煮込み後重量の比率(%)で測定した。
さらに油揚げの風味、形状(膨らみ)及び吸液性について、(+++)非常に良好、(++)良好、(+)やや良好、(±)普通、(−)悪いの5段階で評価した。
(Evaluation method)
The resulting deep-fried fried food was measured by visually observing the degree of expansion of the dough, then measuring the size of the long side, short side, and thickness with calipers, calculating the volume from the average value of 5 pieces (mm), The swelling state of was confirmed. The numerical value was expressed as a ratio (%) when the volume of Reference Example 4 was 100.
And the obtained fried chicken was boiled for about 3 minutes with a Japanese-style seasoning liquid, then taken out and weighed. And the absorptivity of the fried seasoning liquid was measured by the ratio (%) of the weight after cooking to the weight before cooking.
Furthermore, the flavor, shape (bulge) and liquid absorbency of fried chicken were evaluated in five levels: (++) very good, (++) good, (+) slightly good, (±) normal, (−) bad.

(表6)

Figure 2013031422
(Table 6)
Figure 2013031422

(評価結果)
実施例15〜19、比較例4、5から、十分な添加効果が得られる水に対する大豆乳化組成物Bの置換率の目安としては、水に対する大豆乳化組成物Bの置換率が 10%以上が好ましく、より好ましくは25%以上であり、更に好ましくは50%以上であると、フライ後の形状に厚みがあり、ボリュームのある油揚げを得ることができた。内部はキメの細かなスポンジ状組織を有し、煮込んだ後は調味液を良く含み、ジューシーな味わいのある油揚げを得ることができた。
(Evaluation results)
From Examples 15 to 19 and Comparative Examples 4 and 5, as a measure of the substitution rate of the soy emulsified composition B with respect to water that provides a sufficient addition effect, the substitution rate of the soy emulsified composition B with respect to water is 10% or more. If it is preferably 25% or more, more preferably 50% or more, the shape after frying has a thickness, and a deep fried chicken can be obtained. The inside had a fine sponge-like structure, and after boiling it well contained the seasoning liquid, and a fried chicken with a juicy taste could be obtained.

すなわち、本発明は、
(1)乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物が、原料として使用されていることを特徴とする大豆加工食品、
(2)該大豆乳化組成物中の脂質含量が乾物あたり35重量%以上である、前記(1)記載の大豆加工食品、
(3)該大豆乳化組成物中の食物繊維含量が乾物あたり10重量%以下である、前記(1)記載の大豆加工食品。
(4)大豆乳化組成物中における全蛋白質あたりのリポキシゲナーゼ蛋白質の含量が4%以上である、前記(1)記載の大豆加工食品、
(5)大豆加工食品が、豆腐類、湯葉、大豆調味料、油揚げ、がんもどき又は厚揚げである、前記(1)記載の大豆加工食品。
(6)乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物を含有することを特徴とする、大豆加工食品製造用の食感又は風味の改良剤、
(7)乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物を原料に使用することを特徴とする、大豆加工食品の食感又は風味の改良方法、である。
That is, the present invention
(1) Protein content per dry matter 25% by weight or more, (meaning a content of a chloroform / methanol mixed solvent extract.) Lipid content is not more 100% or more by weight for the protein content, LCI value of 55% The soybean soy emulsified composition as described above is used as a raw material, processed soybean food,
(2) The processed soybean food according to (1), wherein the soybean emulsion composition has a lipid content of 35% by weight or more per dry matter,
(3) The processed soybean food according to (1), wherein the soybean fiber emulsified composition has a dietary fiber content of 10% by weight or less per dry matter.
(4) The processed soybean food according to (1), wherein the content of lipoxygenase protein per total protein in the soybean emulsified composition is 4% or more,
(5) The processed soybean food according to the above (1), wherein the processed soybean food is tofu, yuba, soybean seasoning, deep-fried oil, cancer throbbing, or deep-fried food.
(6) Protein content per dry matter 25% by weight or more, (meaning a content of a chloroform / methanol mixed solvent extract.) Lipid content is not more 100% or more by weight for the protein content, LCI value of 55% A texture or flavor improver for manufacturing processed soybean food, comprising the soybean emulsified composition as described above,
(7) a protein content per dry matter 25% by weight or more, (meaning a content of a chloroform / methanol mixed solvent extract.) Lipid content is not more 100% or more by weight for the protein content, LCI value of 55% A method for improving the texture or flavor of processed soybean foods, characterized in that the soybean emulsified composition as described above is used as a raw material.

・水抽出後の固液分離
水抽出後、含脂大豆の懸濁液を遠心分離、濾過等により固液分離する。この際、中性脂質のみならず極性脂質も含めた大部分の脂質を水抽出物中に溶出させず、不溶化した蛋白質や食物繊維質の方に移行させ沈殿側(不溶性画分)とすることが重要である。具体的には含脂大豆の脂質の70重量%以上を沈殿側に移行させる。また抽出の際に上清側にも少量の脂質が溶出するが、豆乳中の脂質のように微細にエマルション化されたものではなく、15,000×g以下、あるいは5,000×g程度以下の遠心分離によっても容易に浮上させ分離することができ、この点で遠心分離機を使用するのが好ましい。なお遠心分離機は使用する設備によっては10万×g以上の超遠心分離を使用することも可能であるし、本発明に用いられる減脂大豆蛋白素材の場合は超遠心分離機を用いなくとも実施が可能である。
また水抽出の際あるいは水抽出後に解乳化剤を添加して豆乳からの脂質の分離を促進させることも可能であり、解乳化剤は特に限定されない。ただし本発明に用いられる減脂大豆蛋白素材を調製する場合は解乳化剤を用いなくとも実施が可能である。
-Solid-liquid separation after water extraction After water extraction, the suspension of fat-containing soybeans is subjected to solid-liquid separation by centrifugation, filtration or the like. At this time, not only neutral lipids but also most of the lipids including polar lipids are not eluted in the water extract, but transferred to the insolubilized protein or dietary fiber to make the precipitation side (insoluble fraction). is important. Specifically, 70% by weight or more of the lipid of the fat-containing soybean is transferred to the precipitation side. In addition, a small amount of lipid is also eluted on the supernatant side during extraction, but it is not finely emulsified like the lipid in soy milk, and it is centrifuged at 15,000 xg or less, or about 5,000 xg or less. In this respect, it is preferable to use a centrifuge. Depending on the equipment used, the centrifugal separator can be ultracentrifugated at 100,000 × g or more. In the case of the reduced-fat soy protein material used in the present invention, the ultracentrifugal separator is not used. Implementation is possible.
Further it is also possible to promote lipid separation from soymilk by adding demulsifier after the time of water extraction or water extraction, demulsifier has a particularly limited. However, the preparation of the reduced-fat soybean protein material used in the present invention can be carried out without using a demulsifier.

Claims (7)

乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう。)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物が、原料として使用されていることを特徴とする大豆加工食品。 The protein content per dry matter is 25% by weight or more, the lipid content (referred to as a chloroform / methanol mixed solvent extract) is 100% by weight or more with respect to the protein content, and the LCI value is 55% or more. A soybean processed food, wherein the soybean emulsion composition is used as a raw material. 該大豆乳化組成物中の脂質含量が乾物あたり35重量%以上である、請求項1記載の大豆加工食品。 The processed soybean food according to claim 1, wherein the soybean emulsion composition has a lipid content of 35% by weight or more per dry matter. 該大豆乳化組成物中の食物繊維含量が乾物あたり10重量%以下である、請求項1記載の大豆加工食品。 The processed soybean food according to claim 1, wherein the content of dietary fiber in the soybean emulsified composition is 10% by weight or less per dry matter. 大豆乳化組成物中における全蛋白質あたりのリポキシゲナーゼ蛋白質の含量が4%以上である、請求項1記載の大豆加工食品。 The processed soybean food according to claim 1, wherein the content of lipoxygenase protein per total protein in the soybean emulsified composition is 4% or more. 大豆加工食品が、豆腐類、湯葉、大豆調味料、油揚げ、がんもどき又は厚揚げである、請求項1記載の大豆加工食品。 The processed soybean food according to claim 1, wherein the processed soybean food is tofu, yuba, soybean seasoning, deep-fried oil, cancer throbbing, or deep-fried food. 乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう。)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物を含有することを特徴とする、大豆加工食品製造用の食感又は風味の改良剤。 The protein content per dry matter is 25% by weight or more, the lipid content (referred to as a chloroform / methanol mixed solvent extract) is 100% by weight or more with respect to the protein content, and the LCI value is 55% or more. A texture or flavor improver for producing a processed soybean food, comprising a soybean emulsified composition. 乾物あたりの蛋白質含量が25重量%以上、脂質含量(クロロホルム/メタノール混合溶媒抽出物としての含量をいう。)が蛋白質含量に対して100重量%以上であって、LCI値が55%以上である大豆乳化組成物を原料に使用することを特徴とする、大豆加工食品の食感又は風味の改良方法。 The protein content per dry matter is 25% by weight or more, the lipid content (referred to as a chloroform / methanol mixed solvent extract) is 100% by weight or more with respect to the protein content, and the LCI value is 55% or more. A method for improving the texture or flavor of processed soybean food, characterized by using a soybean emulsified composition as a raw material.
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JP2019535289A (en) * 2016-11-24 2019-12-12 シージェイ チェイルジェダン コーポレーションCj Cheiljedang Corporation Tofu with improved quality and method for producing the same
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