JP2013013868A - 過酸化水素分解触媒及びその製造方法、並びに、消毒方法 - Google Patents
過酸化水素分解触媒及びその製造方法、並びに、消毒方法 Download PDFInfo
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- JP2013013868A JP2013013868A JP2011149358A JP2011149358A JP2013013868A JP 2013013868 A JP2013013868 A JP 2013013868A JP 2011149358 A JP2011149358 A JP 2011149358A JP 2011149358 A JP2011149358 A JP 2011149358A JP 2013013868 A JP2013013868 A JP 2013013868A
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- hydrogen peroxide
- catalyst
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- active metal
- solution
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 277
- 239000003054 catalyst Substances 0.000 title claims abstract description 136
- 238000000354 decomposition reaction Methods 0.000 title claims abstract description 36
- 238000004659 sterilization and disinfection Methods 0.000 title claims description 29
- 238000000034 method Methods 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 62
- 239000002184 metal Substances 0.000 claims abstract description 62
- 239000000463 material Substances 0.000 claims abstract description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052809 inorganic oxide Inorganic materials 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000000249 desinfective effect Effects 0.000 claims abstract description 11
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 11
- 239000007791 liquid phase Substances 0.000 claims abstract description 9
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 8
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 7
- 229910052762 osmium Inorganic materials 0.000 claims abstract description 7
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 7
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 23
- 239000011734 sodium Substances 0.000 claims description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 13
- 239000011148 porous material Substances 0.000 claims description 13
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000010304 firing Methods 0.000 claims description 4
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- 235000010344 sodium nitrate Nutrition 0.000 claims description 3
- 239000004317 sodium nitrate Substances 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 42
- 239000000243 solution Substances 0.000 description 31
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 20
- 230000000694 effects Effects 0.000 description 15
- 239000000645 desinfectant Substances 0.000 description 14
- 239000007864 aqueous solution Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000000704 physical effect Effects 0.000 description 9
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 8
- 238000007654 immersion Methods 0.000 description 7
- 125000004429 atom Chemical group 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 5
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004061 bleaching Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 235000020188 drinking water Nutrition 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000004453 electron probe microanalysis Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000011946 reduction process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 241000694440 Colpidium aqueous Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001784 detoxification Methods 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 238000013507 mapping Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000003918 potentiometric titration Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003696 structure analysis method Methods 0.000 description 1
- 238000004154 testing of material Methods 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Apparatus For Disinfection Or Sterilisation (AREA)
- Removal Of Specific Substances (AREA)
- Catalysts (AREA)
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JP2011149358A JP2013013868A (ja) | 2011-07-05 | 2011-07-05 | 過酸化水素分解触媒及びその製造方法、並びに、消毒方法 |
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JP2011149358A JP2013013868A (ja) | 2011-07-05 | 2011-07-05 | 過酸化水素分解触媒及びその製造方法、並びに、消毒方法 |
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JP2013013868A true JP2013013868A (ja) | 2013-01-24 |
JP2013013868A5 JP2013013868A5 (enrdf_load_stackoverflow) | 2014-08-07 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20170083582A (ko) | 2014-12-11 | 2017-07-18 | 다나카 기킨조쿠 고교 가부시키가이샤 | 과산화수소 분해용 촉매 및 그 제조 방법 그리고 그 촉매를 사용한 과산화수소를 분해하는 방법 |
JP2017159228A (ja) * | 2016-03-09 | 2017-09-14 | 国立大学法人大阪大学 | コンタクトレンズ消毒用過酸化水素の分解触媒およびその製造方法 |
KR20180025716A (ko) * | 2016-09-01 | 2018-03-09 | 국방과학연구소 | 고농도 과산화수소 분해를 위한 촉매 조성물 및 그 제조 방법 |
CN111704229A (zh) * | 2020-06-22 | 2020-09-25 | 东南大学 | 降解腈纶废水用纳米低维催化剂的制备方法及降解方法 |
CN114949376A (zh) * | 2022-06-11 | 2022-08-30 | 华中科技大学同济医学院附属协和医院 | 一种抗腹腔粘连金属纳米酶Ru-PEG NDs及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07232072A (ja) * | 1993-12-28 | 1995-09-05 | Kawaken Fine Chem Co Ltd | 過酸化水素分解触媒およびその製造方法 |
JP2007185587A (ja) * | 2006-01-12 | 2007-07-26 | Kurita Water Ind Ltd | 過酸化水素の除去方法及び除去装置 |
JP2010105864A (ja) * | 2008-10-30 | 2010-05-13 | National Institute Of Advanced Industrial Science & Technology | 過酸化水素の連続分解方法 |
-
2011
- 2011-07-05 JP JP2011149358A patent/JP2013013868A/ja active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07232072A (ja) * | 1993-12-28 | 1995-09-05 | Kawaken Fine Chem Co Ltd | 過酸化水素分解触媒およびその製造方法 |
JP2007185587A (ja) * | 2006-01-12 | 2007-07-26 | Kurita Water Ind Ltd | 過酸化水素の除去方法及び除去装置 |
JP2010105864A (ja) * | 2008-10-30 | 2010-05-13 | National Institute Of Advanced Industrial Science & Technology | 過酸化水素の連続分解方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20170083582A (ko) | 2014-12-11 | 2017-07-18 | 다나카 기킨조쿠 고교 가부시키가이샤 | 과산화수소 분해용 촉매 및 그 제조 방법 그리고 그 촉매를 사용한 과산화수소를 분해하는 방법 |
US10441943B2 (en) | 2014-12-11 | 2019-10-15 | Tanaka Kikinzoku Kogyo K.K. | Catalyst for hydrogen peroxide decomposition, process for producing the same, and method for decomposing hydrogen peroxide using the catalyst |
JP2017159228A (ja) * | 2016-03-09 | 2017-09-14 | 国立大学法人大阪大学 | コンタクトレンズ消毒用過酸化水素の分解触媒およびその製造方法 |
KR20180025716A (ko) * | 2016-09-01 | 2018-03-09 | 국방과학연구소 | 고농도 과산화수소 분해를 위한 촉매 조성물 및 그 제조 방법 |
CN111704229A (zh) * | 2020-06-22 | 2020-09-25 | 东南大学 | 降解腈纶废水用纳米低维催化剂的制备方法及降解方法 |
CN111704229B (zh) * | 2020-06-22 | 2022-03-04 | 东南大学 | 降解腈纶废水用纳米低维催化剂的制备方法及降解方法 |
CN114949376A (zh) * | 2022-06-11 | 2022-08-30 | 华中科技大学同济医学院附属协和医院 | 一种抗腹腔粘连金属纳米酶Ru-PEG NDs及其制备方法和应用 |
CN114949376B (zh) * | 2022-06-11 | 2023-11-24 | 华中科技大学同济医学院附属协和医院 | 一种抗腹腔粘连金属纳米酶Ru-PEG NDs及其制备方法和应用 |
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