JP2012527527A - 摩耗保護層構造、並びに摩耗保護層構造を備えた構成要素 - Google Patents
摩耗保護層構造、並びに摩耗保護層構造を備えた構成要素 Download PDFInfo
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- JP2012527527A JP2012527527A JP2012511208A JP2012511208A JP2012527527A JP 2012527527 A JP2012527527 A JP 2012527527A JP 2012511208 A JP2012511208 A JP 2012511208A JP 2012511208 A JP2012511208 A JP 2012511208A JP 2012527527 A JP2012527527 A JP 2012527527A
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- 239000002347 wear-protection layer Substances 0.000 title claims abstract description 24
- 239000010410 layer Substances 0.000 claims abstract description 37
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 25
- 239000011241 protective layer Substances 0.000 claims abstract description 23
- 239000000446 fuel Substances 0.000 claims abstract description 13
- 229910003481 amorphous carbon Inorganic materials 0.000 claims abstract description 12
- 230000003647 oxidation Effects 0.000 claims abstract description 11
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 9
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000002347 injection Methods 0.000 claims abstract description 9
- 239000007924 injection Substances 0.000 claims abstract description 9
- 239000010936 titanium Substances 0.000 claims abstract description 9
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 239000010955 niobium Substances 0.000 claims description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 2
- 238000005240 physical vapour deposition Methods 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/0605—Carbon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
- C23C14/025—Metallic sublayers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Fuel-Injection Apparatus (AREA)
- Physical Vapour Deposition (AREA)
Abstract
Description
本発明によれば、摩耗保護層構造は、比較的高い温度において不活性ガス雰囲気下又は酸化ガス雰囲気下でより高い接着強さを有するように、構成されている。本発明の基本的な考え方は、チタンより成る接着促進剤層に追加的に、耐酸化性の元素のうちの1つの元素を添加するという点にある。このような成分によって、チタンの高い化学反応性が減少されるか、若しくは接着促進剤層の耐酸化性が高められ、それによって、全体的に保護層の接着強さが高められる。
Claims (9)
- 高い圧力及び高い温度にさらされる、特に燃料噴射システムの構成要素(B)のための摩耗保護層構造(20)であって、正方晶系に結合されたアモルファス炭素より形成されているか、又は一部が正方晶系に結合されたアモルファス炭素を有する保護層(21)を有しており、該保護層(21)と前記構成要素(B)との間に、チタンを含有する接着促進剤層(22)を有している形式のものにおいて、
前記接着促進剤層(22)が、チタンの他に追加的に少なくとも1つの耐酸化性の元素を含有していることを特徴とする、摩耗保護層構造(20)。 - 少なくとも1つの耐酸化性の元素が、ニオブ、クロム、バナジウム、ケイ素、ニッケル、プラセオジム、モリブデン又はタンタルの元素グループの元素である、請求項1記載の摩耗保護層構造。
- 少なくとも1つの耐酸化性の元素の割合が、1%〜40%、特に10%〜20%である、請求項1又は2記載の摩耗保護層構造。
- 前記接着促進剤層(22)が、PVD法によって構成要素(B)上に施されている、請求項1から3までのいずれか1項記載の摩耗保護層構造。
- 前記保護層(21)が、真空PVD法によって接着促進剤層(22)上に施されている、請求項1から4までのいずれか1項記載の摩耗保護層構造。
- 前記接着促進剤層(22)が、50nm乃至300nmの層厚を有している、請求項4又は5記載の摩耗保護層構造。
- 前記摩耗保護層構造(20)の全厚さが、約1μm乃至10μmの範囲より選択されている、請求項1から6までのいずれか1項記載の摩耗保護層構造。
- 特に燃料噴射システムの、有利には鋼より成る構成要素において、請求項1から7までのいずれか1項記載の摩耗保護層構造(20)を備えていることを特徴とする、構成要素。
- 前記構成要素(B)が、燃料インジェクタの構成部分、特にノズルニードル、又は燃料高圧ポンプの構成部分である、請求項8記載の構成要素。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200910003192 DE102009003192A1 (de) | 2009-05-18 | 2009-05-18 | Verschleißschutzschichtanordnung sowie Bauelement mit Verschleißschutzschichtanordnung |
DE102009003192.8 | 2009-05-18 | ||
PCT/EP2010/053701 WO2010133388A1 (de) | 2009-05-18 | 2010-03-22 | VERSCHLEIßSCHUTZSCHICHTANORDNUNG SOWIE BAUELEMENT MIT VERSCHLEIßSCHUTZSCHICHTANORDNUNG |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2012527527A true JP2012527527A (ja) | 2012-11-08 |
Family
ID=42173752
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012511208A Pending JP2012527527A (ja) | 2009-05-18 | 2010-03-22 | 摩耗保護層構造、並びに摩耗保護層構造を備えた構成要素 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20120175434A1 (ja) |
EP (1) | EP2432914B1 (ja) |
JP (1) | JP2012527527A (ja) |
CN (1) | CN102428207B (ja) |
DE (1) | DE102009003192A1 (ja) |
WO (1) | WO2010133388A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019058754A1 (ja) * | 2017-09-25 | 2019-03-28 | 日立オートモティブシステムズ株式会社 | 高圧燃料供給装置 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102536569A (zh) * | 2012-01-19 | 2012-07-04 | 浙江汇锦梯尔镀层科技有限公司 | 一种新型喷油器油针及其表面处理方法 |
DE102016225449A1 (de) | 2016-12-19 | 2018-06-21 | Robert Bosch Gmbh | Verfahren zum Beschichten eines metallischen Bauteils mit einer Verschleißschutzschicht, metallisches Bauteil sowie Kraftstoffeinspritzsystem |
DE102020205537A1 (de) | 2020-04-30 | 2021-11-04 | Robert Bosch Gesellschaft mit beschränkter Haftung | Verschleißschutzbeschichtetes Bauteil sowie Verfahren zum Beschichten desselben |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002372127A (ja) * | 2001-06-12 | 2002-12-26 | Tdk Corp | Dlcを施したシム |
JP2007308758A (ja) * | 2006-05-18 | 2007-11-29 | Denso Corp | 成膜装置及び成膜方法 |
JP2007327135A (ja) * | 2006-05-12 | 2007-12-20 | Denso Corp | 皮膜構造及びその形成方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4117968A (en) * | 1975-09-04 | 1978-10-03 | Jury Vladimirovich Naidich | Method for soldering metals with superhard man-made materials |
DE10038954A1 (de) * | 2000-08-09 | 2002-02-28 | Siemens Ag | Ventil, insbesondere Einspritzventil |
DE102004002678B4 (de) * | 2004-01-19 | 2005-12-01 | Siemens Ag | Ventilnadel und Ventil |
DE102004041235A1 (de) * | 2004-08-26 | 2006-03-02 | Ina-Schaeffler Kg | Verschleißfeste Beschichtung und Verfahren zur Herstellung derselben |
DE102004054193A1 (de) * | 2004-11-10 | 2006-06-01 | Thomas Kronenberger | Gegen Abrasion und hohe Flächenpressungen beständige Hartstoffbeschichtung auf nachgiebigen Substraten |
JP5755830B2 (ja) * | 2005-08-18 | 2015-07-29 | スルザー メタプラス ゲーエムベーハー | 四面体炭素膜を備える層状構造体により被覆した基板 |
US20070224242A1 (en) * | 2006-03-21 | 2007-09-27 | Jet Engineering, Inc. | Tetrahedral Amorphous Carbon Coated Medical Devices |
-
2009
- 2009-05-18 DE DE200910003192 patent/DE102009003192A1/de not_active Withdrawn
-
2010
- 2010-03-22 US US13/321,068 patent/US20120175434A1/en not_active Abandoned
- 2010-03-22 EP EP20100710577 patent/EP2432914B1/de not_active Not-in-force
- 2010-03-22 CN CN2010800216307A patent/CN102428207B/zh not_active Expired - Fee Related
- 2010-03-22 WO PCT/EP2010/053701 patent/WO2010133388A1/de active Application Filing
- 2010-03-22 JP JP2012511208A patent/JP2012527527A/ja active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002372127A (ja) * | 2001-06-12 | 2002-12-26 | Tdk Corp | Dlcを施したシム |
JP2007327135A (ja) * | 2006-05-12 | 2007-12-20 | Denso Corp | 皮膜構造及びその形成方法 |
JP2007308758A (ja) * | 2006-05-18 | 2007-11-29 | Denso Corp | 成膜装置及び成膜方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019058754A1 (ja) * | 2017-09-25 | 2019-03-28 | 日立オートモティブシステムズ株式会社 | 高圧燃料供給装置 |
Also Published As
Publication number | Publication date |
---|---|
DE102009003192A1 (de) | 2010-11-25 |
EP2432914B1 (de) | 2013-02-13 |
CN102428207B (zh) | 2013-10-30 |
WO2010133388A1 (de) | 2010-11-25 |
CN102428207A (zh) | 2012-04-25 |
EP2432914A1 (de) | 2012-03-28 |
US20120175434A1 (en) | 2012-07-12 |
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