JP2012522873A - 臭化リチウム/水中のイオン性化合物、吸収サイクルシステム - Google Patents
臭化リチウム/水中のイオン性化合物、吸収サイクルシステム Download PDFInfo
- Publication number
- JP2012522873A JP2012522873A JP2012503643A JP2012503643A JP2012522873A JP 2012522873 A JP2012522873 A JP 2012522873A JP 2012503643 A JP2012503643 A JP 2012503643A JP 2012503643 A JP2012503643 A JP 2012503643A JP 2012522873 A JP2012522873 A JP 2012522873A
- Authority
- JP
- Japan
- Prior art keywords
- group
- acid
- methylimidazolium
- butyl
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 title claims abstract description 163
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 115
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 81
- 150000008040 ionic compounds Chemical class 0.000 title claims abstract description 58
- 239000000203 mixture Substances 0.000 claims abstract description 133
- 239000012530 fluid Substances 0.000 claims abstract description 32
- 238000002425 crystallisation Methods 0.000 claims abstract description 25
- 230000008025 crystallization Effects 0.000 claims abstract description 25
- 239000003507 refrigerant Substances 0.000 claims description 164
- 229910052757 nitrogen Inorganic materials 0.000 claims description 94
- 150000001336 alkenes Chemical class 0.000 claims description 62
- 125000001072 heteroaryl group Chemical group 0.000 claims description 51
- 125000005842 heteroatom Chemical group 0.000 claims description 51
- 229910052760 oxygen Inorganic materials 0.000 claims description 51
- 229910052710 silicon Inorganic materials 0.000 claims description 51
- 229910052717 sulfur Inorganic materials 0.000 claims description 51
- 150000001450 anions Chemical class 0.000 claims description 39
- 239000006096 absorbing agent Substances 0.000 claims description 38
- 150000001924 cycloalkanes Chemical class 0.000 claims description 38
- 125000003107 substituted aryl group Chemical group 0.000 claims description 34
- 229940058352 levulinate Drugs 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 30
- JOOXCMJARBKPKM-UHFFFAOYSA-M 4-oxopentanoate Chemical compound CC(=O)CCC([O-])=O JOOXCMJARBKPKM-UHFFFAOYSA-M 0.000 claims description 29
- 150000001768 cations Chemical class 0.000 claims description 29
- 229910052794 bromium Inorganic materials 0.000 claims description 28
- 229910052731 fluorine Inorganic materials 0.000 claims description 27
- 229910052740 iodine Inorganic materials 0.000 claims description 27
- 229910052801 chlorine Inorganic materials 0.000 claims description 26
- 125000001424 substituent group Chemical group 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 23
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 claims description 19
- 125000004122 cyclic group Chemical group 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 17
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 12
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 10
- 229960001231 choline Drugs 0.000 claims description 9
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 9
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 claims description 8
- ZKHQWZAMYRWXGA-KQYNXXCUSA-J ATP(4-) Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O)[C@@H](O)[C@H]1O ZKHQWZAMYRWXGA-KQYNXXCUSA-J 0.000 claims description 8
- ZKHQWZAMYRWXGA-UHFFFAOYSA-N Adenosine triphosphate Natural products C1=NC=2C(N)=NC=NC=2N1C1OC(COP(O)(=O)OP(O)(=O)OP(O)(O)=O)C(O)C1O ZKHQWZAMYRWXGA-UHFFFAOYSA-N 0.000 claims description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 8
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 8
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 claims description 8
- 150000003973 alkyl amines Chemical group 0.000 claims description 8
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 8
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 8
- MBKDYNNUVRNNRF-UHFFFAOYSA-N medronic acid Chemical compound OP(O)(=O)CP(O)(O)=O MBKDYNNUVRNNRF-UHFFFAOYSA-N 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 229940005657 pyrophosphoric acid Drugs 0.000 claims description 8
- HVVRUQBMAZRKPJ-UHFFFAOYSA-N 1,3-dimethylimidazolium Chemical compound CN1C=C[N+](C)=C1 HVVRUQBMAZRKPJ-UHFFFAOYSA-N 0.000 claims description 7
- XTWYTFMLZFPYCI-KQYNXXCUSA-N 5'-adenylphosphoric acid Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OP(O)(O)=O)[C@@H](O)[C@H]1O XTWYTFMLZFPYCI-KQYNXXCUSA-N 0.000 claims description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 claims description 7
- KZWJWYFPLXRYIL-UHFFFAOYSA-M 1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F KZWJWYFPLXRYIL-UHFFFAOYSA-M 0.000 claims description 6
- ARSMIBSHEYKMJT-UHFFFAOYSA-M 1,3-dimethylimidazolium iodide Chemical compound [I-].CN1C=C[N+](C)=C1 ARSMIBSHEYKMJT-UHFFFAOYSA-M 0.000 claims description 6
- QPDGLRRWSBZCHP-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;2,2,2-trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F.CCCC[N+]=1C=CN(C)C=1 QPDGLRRWSBZCHP-UHFFFAOYSA-M 0.000 claims description 6
- MXBRPRXKTHPJRI-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;2-methylpropanoate Chemical compound CC(C)C([O-])=O.CCCCN1C=C[N+](C)=C1 MXBRPRXKTHPJRI-UHFFFAOYSA-M 0.000 claims description 6
- BJMHXLGHJQKGNI-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;propanoate Chemical compound CCC([O-])=O.CCCC[N+]=1C=CN(C)C=1 BJMHXLGHJQKGNI-UHFFFAOYSA-M 0.000 claims description 6
- JOKVYNJKBRLDAT-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;2,2,2-trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F.CC[N+]=1C=CN(C)C=1 JOKVYNJKBRLDAT-UHFFFAOYSA-M 0.000 claims description 6
- XIYUIMLQTKODPS-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;acetate Chemical compound CC([O-])=O.CC[N+]=1C=CN(C)C=1 XIYUIMLQTKODPS-UHFFFAOYSA-M 0.000 claims description 6
- DTQVDTLACAAQTR-UHFFFAOYSA-M Trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-M 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- OEDJAKMCWJUAHH-UHFFFAOYSA-M methyl(trioctyl)azanium;2,2,2-trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F.CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC OEDJAKMCWJUAHH-UHFFFAOYSA-M 0.000 claims description 6
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910016467 AlCl 4 Inorganic materials 0.000 claims description 5
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 5
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 235000010323 ascorbic acid Nutrition 0.000 claims description 5
- 239000011668 ascorbic acid Substances 0.000 claims description 5
- 150000003841 chloride salts Chemical class 0.000 claims description 5
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 4
- ZIPFNZZMKGEBFU-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2-trifluoro-2-(1,1,2,2,2-pentafluoroethoxy)ethanesulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)OC(F)(F)C(F)(F)F ZIPFNZZMKGEBFU-UHFFFAOYSA-M 0.000 claims description 4
- MIQNTLMZSDFZQY-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2-trifluoro-2-(trifluoromethoxy)ethanesulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)OC(F)(F)F MIQNTLMZSDFZQY-UHFFFAOYSA-M 0.000 claims description 4
- QDHGQJQZPJPKJK-UHFFFAOYSA-N 2-[carboxymethyl-(2,4,6-trioxo-1,3-diazinan-5-yl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C1C(=O)NC(=O)NC1=O QDHGQJQZPJPKJK-UHFFFAOYSA-N 0.000 claims description 4
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 4
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 claims description 4
- 239000004153 Potassium bromate Substances 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N Propionic acid Chemical compound CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 229910018286 SbF 6 Inorganic materials 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 4
- 229940072107 ascorbate Drugs 0.000 claims description 4
- 150000003983 crown ethers Chemical class 0.000 claims description 4
- 239000001630 malic acid Substances 0.000 claims description 4
- 235000011090 malic acid Nutrition 0.000 claims description 4
- 229940094037 potassium bromate Drugs 0.000 claims description 4
- 235000019396 potassium bromate Nutrition 0.000 claims description 4
- 239000000276 potassium ferrocyanide Substances 0.000 claims description 4
- JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical compound [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 claims description 4
- 239000001230 potassium iodate Substances 0.000 claims description 4
- 235000006666 potassium iodate Nutrition 0.000 claims description 4
- 229940093930 potassium iodate Drugs 0.000 claims description 4
- 229940023144 sodium glycolate Drugs 0.000 claims description 4
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 claims description 4
- ROJODBUHUVCAJX-UHFFFAOYSA-M 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate;trihexyl(tetradecyl)phosphanium Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC ROJODBUHUVCAJX-UHFFFAOYSA-M 0.000 claims description 3
- IEOTWKMBQULPKX-UHFFFAOYSA-M 1,1,2,2-tetrafluoroethanesulfonate;tetrakis(2-hydroxyethyl)azanium Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.OCC[N+](CCO)(CCO)CCO IEOTWKMBQULPKX-UHFFFAOYSA-M 0.000 claims description 3
- BCAMEJSXAFAOHI-UHFFFAOYSA-M 1,1,2,2-tetrafluoroethanesulfonate;tributyl(tetradecyl)phosphanium Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC BCAMEJSXAFAOHI-UHFFFAOYSA-M 0.000 claims description 3
- BGGUZIZLOYTWFU-UHFFFAOYSA-M 1,1,2,3,3,3-hexafluoropropane-1-sulfonate;tributyl(tetradecyl)phosphanium Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F.CCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC BGGUZIZLOYTWFU-UHFFFAOYSA-M 0.000 claims description 3
- XHCDOFZBVYGCFK-UHFFFAOYSA-M 1-butyl-1-methylpyrrolidin-1-ium;2,2,2-trifluoroacetate Chemical compound [O-]C(=O)C(F)(F)F.CCCC[N+]1(C)CCCC1 XHCDOFZBVYGCFK-UHFFFAOYSA-M 0.000 claims description 3
- VFKJFIDWVGPBDV-UHFFFAOYSA-M 1-butyl-2,3-dimethylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCC[N+]=1C=CN(C)C=1C VFKJFIDWVGPBDV-UHFFFAOYSA-M 0.000 claims description 3
- KUWPEQAOGNPMOP-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)F KUWPEQAOGNPMOP-UHFFFAOYSA-M 0.000 claims description 3
- MXDXOYOYMBHGQD-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;1,1,2,3,3,3-hexafluoropropane-1-sulfonate Chemical compound CCCC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F MXDXOYOYMBHGQD-UHFFFAOYSA-M 0.000 claims description 3
- BSKSXTBYXTZWFI-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;acetate Chemical compound CC([O-])=O.CCCC[N+]=1C=CN(C)C=1 BSKSXTBYXTZWFI-UHFFFAOYSA-M 0.000 claims description 3
- DBEDBKKZBBRGDK-UHFFFAOYSA-N 1-butyl-3-methylimidazol-3-ium;dihydrogen phosphite Chemical compound OP(O)[O-].CCCCN1C=C[N+](C)=C1 DBEDBKKZBBRGDK-UHFFFAOYSA-N 0.000 claims description 3
- MEMNKNZDROKJHP-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCN1C=C[N+](C)=C1 MEMNKNZDROKJHP-UHFFFAOYSA-M 0.000 claims description 3
- CTEAXVWYCINNCA-UHFFFAOYSA-M 1-ethyl-3-methylimidazol-3-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound CC[N+]=1C=CN(C)C=1.[O-]S(=O)(=O)C(F)(F)C(F)F CTEAXVWYCINNCA-UHFFFAOYSA-M 0.000 claims description 3
- KPTIHKIMIVDQEG-UHFFFAOYSA-M 1-methyl-3-octylimidazol-1-ium;1,1,2,2-tetrafluoroethanesulfonate Chemical compound [O-]S(=O)(=O)C(F)(F)C(F)F.CCCCCCCCN1C=C[N+](C)=C1 KPTIHKIMIVDQEG-UHFFFAOYSA-M 0.000 claims description 3
- FURUVJOXOXSHDX-UHFFFAOYSA-M 2,2-dichloroacetate;tetramethylazanium Chemical compound C[N+](C)(C)C.[O-]C(=O)C(Cl)Cl FURUVJOXOXSHDX-UHFFFAOYSA-M 0.000 claims description 3
- JSGREAVPDCFWAB-UHFFFAOYSA-M 2-oxopropanoate;tetramethylazanium Chemical compound C[N+](C)(C)C.CC(=O)C([O-])=O JSGREAVPDCFWAB-UHFFFAOYSA-M 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- VHRRKJWPRRTKLZ-UHFFFAOYSA-N acetic acid;2-methoxy-n-(2-methoxyethyl)ethanamine Chemical compound CC([O-])=O.COCC[NH2+]CCOC VHRRKJWPRRTKLZ-UHFFFAOYSA-N 0.000 claims description 3
- HXQJXUWXAOFEQT-UHFFFAOYSA-M benzyl(trimethyl)azanium;2-phosphonoacetate Chemical compound OP(O)(=O)CC([O-])=O.C[N+](C)(C)CC1=CC=CC=C1 HXQJXUWXAOFEQT-UHFFFAOYSA-M 0.000 claims description 3
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 claims description 3
- BKMGMIWOLYYOCK-UHFFFAOYSA-L butanedioate;tetrabutylphosphanium Chemical compound [O-]C(=O)CCC([O-])=O.CCCC[P+](CCCC)(CCCC)CCCC.CCCC[P+](CCCC)(CCCC)CCCC BKMGMIWOLYYOCK-UHFFFAOYSA-L 0.000 claims description 3
- 229910052792 caesium Inorganic materials 0.000 claims description 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 3
- OUTUSTULKLPJNX-UHFFFAOYSA-N dihydrogen phosphite;1-ethyl-3-methylimidazol-3-ium Chemical compound OP(O)[O-].CCN1C=C[N+](C)=C1 OUTUSTULKLPJNX-UHFFFAOYSA-N 0.000 claims description 3
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 claims description 3
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 claims description 3
- CBKJDTFDVVXSJR-UHFFFAOYSA-M methyl sulfate;1,2,4-trimethylpyrazol-2-ium Chemical compound COS([O-])(=O)=O.CC1=CN(C)[N+](C)=C1 CBKJDTFDVVXSJR-UHFFFAOYSA-M 0.000 claims description 3
- WLTHPEHYBIKNHR-UHFFFAOYSA-M methyl sulfate;tris(2-hydroxyethyl)-methylazanium Chemical compound COS([O-])(=O)=O.OCC[N+](C)(CCO)CCO WLTHPEHYBIKNHR-UHFFFAOYSA-M 0.000 claims description 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims description 3
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- BJQWBACJIAKDTJ-UHFFFAOYSA-N tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC BJQWBACJIAKDTJ-UHFFFAOYSA-N 0.000 claims description 3
- WWIYWFVQZQOECA-UHFFFAOYSA-M tetramethylazanium;formate Chemical compound [O-]C=O.C[N+](C)(C)C WWIYWFVQZQOECA-UHFFFAOYSA-M 0.000 claims description 3
- DBMLHBBWANTBLN-UHFFFAOYSA-N trimethyl-[2-(4-oxopentanoyloxy)ethyl]azanium Chemical compound CC(=O)CCC(=O)OCC[N+](C)(C)C DBMLHBBWANTBLN-UHFFFAOYSA-N 0.000 claims description 3
- JEJAMASKDTUEBZ-UHFFFAOYSA-N tris(1,1,3-tribromo-2,2-dimethylpropyl) phosphate Chemical compound BrCC(C)(C)C(Br)(Br)OP(=O)(OC(Br)(Br)C(C)(C)CBr)OC(Br)(Br)C(C)(C)CBr JEJAMASKDTUEBZ-UHFFFAOYSA-N 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- XTWYTFMLZFPYCI-UHFFFAOYSA-N Adenosine diphosphate Natural products C1=NC=2C(N)=NC=NC=2N1C1OC(COP(O)(=O)OP(O)(O)=O)C(O)C1O XTWYTFMLZFPYCI-UHFFFAOYSA-N 0.000 claims 6
- 229910019142 PO4 Inorganic materials 0.000 claims 6
- 235000021317 phosphate Nutrition 0.000 claims 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 4
- 239000010452 phosphate Substances 0.000 claims 4
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 claims 3
- 150000007513 acids Chemical class 0.000 claims 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 claims 2
- 150000001805 chlorine compounds Chemical class 0.000 claims 2
- 229910000085 borane Inorganic materials 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 230000002829 reductive effect Effects 0.000 abstract description 33
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- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000806 fluorine-19 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- QFWPJPIVLCBXFJ-UHFFFAOYSA-N glymidine Chemical compound N1=CC(OCCOC)=CN=C1NS(=O)(=O)C1=CC=CC=C1 QFWPJPIVLCBXFJ-UHFFFAOYSA-N 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- LSACYLWPPQLVSM-UHFFFAOYSA-N isobutyric acid anhydride Chemical compound CC(C)C(=O)OC(=O)C(C)C LSACYLWPPQLVSM-UHFFFAOYSA-N 0.000 description 1
- RSNHXDVSISOZOB-UHFFFAOYSA-N lithium nickel Chemical compound [Li].[Ni] RSNHXDVSISOZOB-UHFFFAOYSA-N 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- IPLONMMJNGTUAI-UHFFFAOYSA-M lithium;bromide;hydrate Chemical compound [Li+].O.[Br-] IPLONMMJNGTUAI-UHFFFAOYSA-M 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 description 1
- LVTHXRLARFLXNR-UHFFFAOYSA-M potassium;1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F LVTHXRLARFLXNR-UHFFFAOYSA-M 0.000 description 1
- OKFMRBZZUDSEFE-UHFFFAOYSA-M potassium;1,1,2,3,3,3-hexafluoropropane-1-sulfonate Chemical compound [K+].[O-]S(=O)(=O)C(F)(F)C(F)C(F)(F)F OKFMRBZZUDSEFE-UHFFFAOYSA-M 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
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- 238000001556 precipitation Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- 229940107700 pyruvic acid Drugs 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000006268 reductive amination reaction Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- JDVPQXZIJDEHAN-UHFFFAOYSA-M succinamate Chemical compound NC(=O)CCC([O-])=O JDVPQXZIJDEHAN-UHFFFAOYSA-M 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- RKHXQBLJXBGEKF-UHFFFAOYSA-M tetrabutylphosphanium;bromide Chemical compound [Br-].CCCC[P+](CCCC)(CCCC)CCCC RKHXQBLJXBGEKF-UHFFFAOYSA-M 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- ABOMDVBQHBNUGW-UHFFFAOYSA-L tetramethylazanium formate hydroxide Chemical compound C(=O)[O-].[OH-].C[N+](C)(C)C.C[N+](C)(C)C ABOMDVBQHBNUGW-UHFFFAOYSA-L 0.000 description 1
- MYXKPFMQWULLOH-UHFFFAOYSA-M tetramethylazanium;hydroxide;pentahydrate Chemical compound O.O.O.O.O.[OH-].C[N+](C)(C)C MYXKPFMQWULLOH-UHFFFAOYSA-M 0.000 description 1
- JCQGIZYNVAZYOH-UHFFFAOYSA-M trihexyl(tetradecyl)phosphanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[P+](CCCCCC)(CCCCCC)CCCCCC JCQGIZYNVAZYOH-UHFFFAOYSA-M 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/047—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for absorption-type refrigeration systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B15/00—Sorption machines, plants or systems, operating continuously, e.g. absorption type
- F25B15/02—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas
- F25B15/06—Sorption machines, plants or systems, operating continuously, e.g. absorption type without inert gas the refrigerant being water vapour evaporated from a salt solution, e.g. lithium bromide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2315/00—Sorption refrigeration cycles or details thereof
- F25B2315/001—Crystallization prevention
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
- Y02B30/62—Absorption based systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Sorption Type Refrigeration Machines (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
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| US16516609P | 2009-03-31 | 2009-03-31 | |
| US16517309P | 2009-03-31 | 2009-03-31 | |
| US16516009P | 2009-03-31 | 2009-03-31 | |
| US61/165,160 | 2009-03-31 | ||
| US61/165,173 | 2009-03-31 | ||
| US61/165,166 | 2009-03-31 | ||
| PCT/US2010/029322 WO2010117836A1 (en) | 2009-03-31 | 2010-03-31 | Ionic compounds in lithium bromide/water absorption cycle systems |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012522873A true JP2012522873A (ja) | 2012-09-27 |
| JP2012522873A5 JP2012522873A5 (enExample) | 2013-05-09 |
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| JP2012503643A Abandoned JP2012522873A (ja) | 2009-03-31 | 2010-03-31 | 臭化リチウム/水中のイオン性化合物、吸収サイクルシステム |
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| Country | Link |
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| US (1) | US20120011886A1 (enExample) |
| EP (1) | EP2414476A1 (enExample) |
| JP (1) | JP2012522873A (enExample) |
| KR (1) | KR20120003471A (enExample) |
| CN (1) | CN102449101A (enExample) |
| AU (1) | AU2010234813A1 (enExample) |
| BR (1) | BRPI1006734A2 (enExample) |
| CA (1) | CA2754599A1 (enExample) |
| WO (1) | WO2010117836A1 (enExample) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013513002A (ja) * | 2009-12-07 | 2013-04-18 | エボニック デグサ ゲーエムベーハー | 吸収式冷凍機用作動媒体 |
| JP2013543965A (ja) * | 2010-11-08 | 2013-12-09 | エボニック デグサ ゲーエムベーハー | 吸収式ヒートポンプのための作動媒体 |
| JP2019517654A (ja) * | 2016-05-26 | 2019-06-24 | 矢崎総業株式会社 | 吸収式冷凍機におけるグアニジニウム系イオン液体 |
| JP2019203101A (ja) * | 2018-05-25 | 2019-11-28 | 株式会社日立パワーソリューションズ | 吸収冷温水機、吸収冷温水機用追加液、吸収冷温水機用吸収液及びメンテナンス方法 |
| JP2020015688A (ja) * | 2018-07-25 | 2020-01-30 | 国立大学法人千葉大学 | 硫黄を含むホスホニウム型カチオン及び硫黄を含むホスホニウム型イオン液体 |
| JP2022517053A (ja) * | 2019-01-15 | 2022-03-04 | 矢崎総業株式会社 | 吸収式冷凍機における吸収剤として使用するためのイオン液体添加剤 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP2087930A1 (de) * | 2008-02-05 | 2009-08-12 | Evonik Degussa GmbH | Verfahren zur Absorption eines flüchtigen Stoffes in einem flüssigen Absorptionsmittel |
| EP2088389B1 (de) * | 2008-02-05 | 2017-05-10 | Evonik Degussa GmbH | Absorptionskältemaschine |
| WO2010054230A2 (en) * | 2008-11-07 | 2010-05-14 | E. I. Du Pont De Nemours And Company | Absorption cycle utilizing ionic compounds and/or non-ionic absorbents as working fluids |
| DE102011077377A1 (de) | 2010-11-12 | 2012-05-16 | Evonik Degussa Gmbh | Verfahren zur Absorption von sauren Gasen aus Gasmischungen |
| JP5937303B2 (ja) * | 2011-05-13 | 2016-06-22 | ミヨシ油脂株式会社 | 耐腐食性イオン液体を熱媒体に用いた冷却液、不凍液、凍結防止剤、融雪剤 |
| WO2013072147A1 (de) | 2011-11-14 | 2013-05-23 | Evonik Degussa Gmbh | Verfahren und vorrichtung zur abtrennung von sauren gasen aus einer gasmischung |
| DE102012200907A1 (de) | 2012-01-23 | 2013-07-25 | Evonik Industries Ag | Verfahren und Absorptionsmedium zur Absorption von CO2 aus einer Gasmischung |
| DE102012207509A1 (de) | 2012-05-07 | 2013-11-07 | Evonik Degussa Gmbh | Verfahren zur Absorption von CO2 aus einer Gasmischung |
| WO2014172042A1 (en) * | 2013-03-15 | 2014-10-23 | Sandia Corporation | Synthesis of novel ionic liquids from lignin-derived compounds |
| US8720216B1 (en) | 2013-10-01 | 2014-05-13 | King Fahd University Of Petroleum And Minerals | Hybrid aqua-ammonia and lithium bromide-water absorption chiller |
| US20160231032A1 (en) * | 2015-02-07 | 2016-08-11 | Morteza Ghassemi | Piezo Electric and High Voltage Absorption Cooling System |
| JP6224648B2 (ja) * | 2015-04-28 | 2017-11-01 | ファナック株式会社 | スポット溶接の品質診断システム |
| DE102015212749A1 (de) | 2015-07-08 | 2017-01-12 | Evonik Degussa Gmbh | Verfahren zur Entfeuchtung von feuchten Gasgemischen |
| GB201513304D0 (en) * | 2015-07-28 | 2015-09-09 | Innospec Ltd | Compositions and Methods |
| WO2017058747A1 (en) | 2015-09-28 | 2017-04-06 | University Of Florida Research Foundation, Inc. | Ionic liquid-based absorption cooling system with high coefficient of performance |
| DE102016106234B4 (de) * | 2016-04-06 | 2022-03-03 | Fahrenheit Gmbh | Adsorptionswärmepumpe und Verfahren zum Betreiben einer Adsorptionswärmepumpe |
| WO2017205807A1 (en) * | 2016-05-26 | 2017-11-30 | Yazaki Corporation | Eutectic mixtures of ionic liquids in absorption chillers |
| WO2017214334A1 (en) | 2016-06-07 | 2017-12-14 | National Technology & Engineering Solutions Of Sandia, Llc | Conversion of lignin to ionic liquids |
| DE102016210478A1 (de) | 2016-06-14 | 2017-12-14 | Evonik Degussa Gmbh | Verfahren zur Entfeuchtung von feuchten Gasgemischen |
| DE102016210483A1 (de) | 2016-06-14 | 2017-12-14 | Evonik Degussa Gmbh | Verfahren und Absorptionsmittel zur Entfeuchtung von feuchten Gasgemischen |
| DE102016210484A1 (de) | 2016-06-14 | 2017-12-14 | Evonik Degussa Gmbh | Verfahren zur Entfeuchtung von feuchten Gasgemischen |
| EP3257568B1 (de) | 2016-06-14 | 2019-09-18 | Evonik Degussa GmbH | Verfahren zur entfeuchtung von feuchten gasgemischen mit ionischen flüssigkeiten |
| EP3257843A1 (en) | 2016-06-14 | 2017-12-20 | Evonik Degussa GmbH | Method of preparing a high purity imidazolium salt |
| DE102016210481B3 (de) | 2016-06-14 | 2017-06-08 | Evonik Degussa Gmbh | Verfahren zum Reinigen einer ionischen Flüssigkeit |
| US10584904B2 (en) * | 2017-03-27 | 2020-03-10 | Rebound Technologies, Inc. | Cycle enhancement methods, systems, and devices |
| WO2018186859A1 (en) | 2017-04-05 | 2018-10-11 | General Electric Company | Absorption cycle apparatus and related method |
| US11028249B2 (en) * | 2017-08-31 | 2021-06-08 | National Technology & Engineering Solutions Of Sandia, Llc | Methods of synthesizing ionic liquids from primary alcohol-containing lignin compounds |
| CN108190916B (zh) * | 2017-12-29 | 2020-09-18 | 新奥泛能网络科技股份有限公司 | 合成氨分离的方法和系统 |
| ES3020410T3 (en) | 2018-02-23 | 2025-05-22 | Rebound Tech Inc | Freeze point suppression cycle control systems, methods, and devices |
| US11034669B2 (en) | 2018-11-30 | 2021-06-15 | Nuvation Bio Inc. | Pyrrole and pyrazole compounds and methods of use thereof |
| WO2020132467A1 (en) | 2018-12-20 | 2020-06-25 | Rebound Technologies, Inc. | Thermo-chemical recuperation systems, devices, and methods |
| GB2600445A (en) * | 2020-10-29 | 2022-05-04 | Burton Geoff | Phase change material |
| CN112944719A (zh) * | 2021-03-24 | 2021-06-11 | 苏州佳永新能源科技有限公司 | 一种化学吸收制冷循环用复配工质对和应用方法 |
| CN113025282B (zh) * | 2021-03-26 | 2022-04-08 | 苏州佳永新能源科技有限公司 | 一种化学吸收循环用复配吸附介质 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5176210A (en) * | 1990-07-06 | 1993-01-05 | Arctic Systems Limited | Thermochemical ice melting |
| GB9123794D0 (en) * | 1991-11-08 | 1992-01-02 | Atkinson Stephen | Vapour absorbent compositions |
| JP2750834B2 (ja) * | 1995-06-30 | 1998-05-13 | 川崎重工業株式会社 | 吸収冷凍機用吸収液 |
| US5653117A (en) * | 1996-04-15 | 1997-08-05 | Gas Research Institute | Absorption refrigeration compositions containing thiocyanate, and absorption refrigeration apparatus |
| US6177025B1 (en) * | 1998-11-17 | 2001-01-23 | University Of Utah | Absorption heat pumps having improved efficiency using a crystallization-inhibiting additive |
| US6155057A (en) * | 1999-03-01 | 2000-12-05 | Arizona Board Of Regents | Refrigerant fluid crystallization control and prevention |
| WO2000061698A1 (en) * | 1999-04-12 | 2000-10-19 | Arizona Board Of Regents | Two-phase refrigeration fluid for an absorption refrigeration apparatus and a method of preventing corrosion |
| JP2000319646A (ja) * | 1999-05-06 | 2000-11-21 | Yazaki Corp | 吸収冷凍機用吸収液および吸収冷凍機 |
| DE102004024967A1 (de) | 2004-05-21 | 2005-12-08 | Basf Ag | Neue Absorptionsmedien für Absorptionswärmepumpen, Absorptionskältemaschinen und Wärmetransformatoren |
| US7157588B2 (en) | 2005-04-15 | 2007-01-02 | E. I. Du Pont De Nemours And Company | Ionic liquids |
| DE102005028451B4 (de) * | 2005-06-17 | 2017-02-16 | Evonik Degussa Gmbh | Verfahren zum Transport von Wärme |
| FR2890395B1 (fr) * | 2005-09-05 | 2009-05-01 | Inst Francais Du Petrole | Methode et inhibiteurs thermodynamiques d'hydrates de gaz dans les fluides a base d'eau |
| US8506839B2 (en) * | 2005-12-14 | 2013-08-13 | E I Du Pont De Nemours And Company | Absorption cycle utilizing ionic liquids and water as working fluids |
-
2010
- 2010-03-31 CN CN2010800241084A patent/CN102449101A/zh active Pending
- 2010-03-31 JP JP2012503643A patent/JP2012522873A/ja not_active Abandoned
- 2010-03-31 AU AU2010234813A patent/AU2010234813A1/en not_active Abandoned
- 2010-03-31 KR KR1020117025482A patent/KR20120003471A/ko not_active Withdrawn
- 2010-03-31 WO PCT/US2010/029322 patent/WO2010117836A1/en not_active Ceased
- 2010-03-31 BR BRPI1006734A patent/BRPI1006734A2/pt not_active IP Right Cessation
- 2010-03-31 EP EP10712637A patent/EP2414476A1/en not_active Withdrawn
- 2010-03-31 US US13/259,229 patent/US20120011886A1/en not_active Abandoned
- 2010-03-31 CA CA2754599A patent/CA2754599A1/en not_active Abandoned
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013513002A (ja) * | 2009-12-07 | 2013-04-18 | エボニック デグサ ゲーエムベーハー | 吸収式冷凍機用作動媒体 |
| JP2013543965A (ja) * | 2010-11-08 | 2013-12-09 | エボニック デグサ ゲーエムベーハー | 吸収式ヒートポンプのための作動媒体 |
| JP2019517654A (ja) * | 2016-05-26 | 2019-06-24 | 矢崎総業株式会社 | 吸収式冷凍機におけるグアニジニウム系イオン液体 |
| JP2019203101A (ja) * | 2018-05-25 | 2019-11-28 | 株式会社日立パワーソリューションズ | 吸収冷温水機、吸収冷温水機用追加液、吸収冷温水機用吸収液及びメンテナンス方法 |
| US10976081B2 (en) | 2018-05-25 | 2021-04-13 | Clearize Co., Ltd. | Absorption chiller-heater, replenishing liquid for absorption chiller-heater, absorption liquid for absorption chiller-heater, and maintenance method |
| JP2020015688A (ja) * | 2018-07-25 | 2020-01-30 | 国立大学法人千葉大学 | 硫黄を含むホスホニウム型カチオン及び硫黄を含むホスホニウム型イオン液体 |
| JP2022517053A (ja) * | 2019-01-15 | 2022-03-04 | 矢崎総業株式会社 | 吸収式冷凍機における吸収剤として使用するためのイオン液体添加剤 |
| JP7189322B2 (ja) | 2019-01-15 | 2022-12-13 | 矢崎総業株式会社 | 吸収式冷凍機における吸収剤として使用するためのイオン液体添加剤 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2754599A1 (en) | 2010-10-14 |
| EP2414476A1 (en) | 2012-02-08 |
| KR20120003471A (ko) | 2012-01-10 |
| BRPI1006734A2 (pt) | 2019-04-02 |
| AU2010234813A1 (en) | 2011-09-22 |
| AU2010234813A2 (en) | 2011-09-22 |
| CN102449101A (zh) | 2012-05-09 |
| WO2010117836A1 (en) | 2010-10-14 |
| US20120011886A1 (en) | 2012-01-19 |
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