JP2012512023A - 高いアクセシビリティー・インデックスを有する層状球状体触媒 - Google Patents
高いアクセシビリティー・インデックスを有する層状球状体触媒 Download PDFInfo
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- JP2012512023A JP2012512023A JP2011542160A JP2011542160A JP2012512023A JP 2012512023 A JP2012512023 A JP 2012512023A JP 2011542160 A JP2011542160 A JP 2011542160A JP 2011542160 A JP2011542160 A JP 2011542160A JP 2012512023 A JP2012512023 A JP 2012512023A
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- catalyst
- metal
- alumina
- outer layer
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- 239000003054 catalyst Substances 0.000 title claims abstract description 100
- 229910052751 metal Inorganic materials 0.000 claims abstract description 53
- 239000002184 metal Substances 0.000 claims abstract description 53
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000005977 Ethylene Substances 0.000 claims abstract description 39
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 32
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims abstract description 22
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims abstract description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical group [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 22
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 21
- 230000000694 effects Effects 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- 229910052697 platinum Inorganic materials 0.000 claims description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims description 7
- 150000004706 metal oxides Chemical group 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910021536 Zeolite Inorganic materials 0.000 claims description 4
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- 229910052732 germanium Inorganic materials 0.000 claims description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000004645 aluminates Chemical class 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 229910052878 cordierite Inorganic materials 0.000 claims description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical group [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 claims description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims description 2
- 229910052839 forsterite Inorganic materials 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 239000010931 gold Substances 0.000 claims description 2
- 229910052622 kaolinite Inorganic materials 0.000 claims description 2
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- 239000002808 molecular sieve Substances 0.000 claims description 2
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 2
- 229910052863 mullite Inorganic materials 0.000 claims description 2
- 150000004767 nitrides Chemical class 0.000 claims description 2
- 229910052609 olivine Inorganic materials 0.000 claims description 2
- 239000010450 olivine Substances 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910000275 saponite Inorganic materials 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052596 spinel Inorganic materials 0.000 claims description 2
- 239000011029 spinel Substances 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 239000011135 tin Substances 0.000 claims description 2
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 claims 1
- 229910052850 kyanite Inorganic materials 0.000 claims 1
- 239000010443 kyanite Substances 0.000 claims 1
- 239000011343 solid material Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 26
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- 239000011149 active material Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 47
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- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 13
- 230000003197 catalytic effect Effects 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 229930195733 hydrocarbon Natural products 0.000 description 10
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 9
- 150000002430 hydrocarbons Chemical class 0.000 description 9
- 229910002091 carbon monoxide Inorganic materials 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- -1 olefin hydrocarbons Chemical class 0.000 description 6
- 239000011800 void material Substances 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 150000001340 alkali metals Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 229910052744 lithium Inorganic materials 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
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- 230000009467 reduction Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
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- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
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- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
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- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/04—Ethylene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
- C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/66—Silver or gold
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
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Abstract
【選択図】図1
Description
[0035]所望量の担体に適当な金属塩の溶液を加えることによって触媒を調製した。適当な金属塩は通常は硝酸塩である。特に、担体重量に対して1%のHNO3溶液を脱イオン水で希釈して、担体体積にほぼ等量の溶液の体積、或いは1:1の溶液:担体の体積比を与えた。溶液を、室温において、一定の撹拌を行いながら、或いは良好な担体と溶液の接触を確実にするために転動させながら、担体と1時間接触させた。次に、溶液を100℃に加熱し、液体を3時間超の一定時間にわたって蒸発させ、それによって含侵担体を生成させた。最終的な担体は、容器内で「自由に転動する」か、又は自由に動くものでなければならない。最終的な湿分含量は特定の担体で変化するが、通常は20〜30重量%の範囲である。
Claims (10)
- 不活性材料を含む内部コア;
内部コアに結合している、金属酸化物を含む外側層;
外側層上に堆積している、IUPACの8〜10族の金属である第1の金属;及び
外側層上に堆積している、IUPACの11族又は14族の金属である第2の金属;
を有する層状触媒を含み;
該触媒が、3〜500の間のアクセシビリティー・インデックス(AI)を有する;
アセチレンのエチレンへの選択的水素化において用いるための触媒。 - アクセシビリティー・インデックスが3〜20の間である。請求項1に記載の触媒。
- 第1の金属が触媒の100〜50,000重量ppmの間の濃度を有する、請求項1に記載の触媒。
- 第1の金属が触媒の200〜20,000重量ppmの間の濃度を有する、請求項3に記載の触媒。
- 第1の金属が白金、パラジウム、及びこれらの混合物からなる群から選択される、請求項1に記載の触媒。
- 第2の金属が、銅、銀、金、スズ、ゲルマニウム、鉛、及びこれらの混合物からなる群から選択される、請求項1に記載の触媒。
- 内部コアが0.05mm〜10mmの有効直径を有する、請求項1に記載の触媒。
- 外側層が20〜100μmの間の有効厚さを有する、請求項1に記載の触媒。
- 外側層が、γ−アルミナ、δ−アルミナ、η−アルミナ、θ−アルミナ、シリカ−アルミナ、ゼオライト、非ゼオライトモレキュラーシーブ、チタニア、ジルコニア、及びこれらの混合物からなる群から選択される、請求項1に記載の触媒。
- 内部コアが、コージエライト、ムライト、オリバイン、ジルコニア、スピネル、カイヤナイト、アルミナ、シリカ、アルミン酸塩、ケイ酸塩、チタニア、窒化物、炭化物、ホウケイ酸塩、ボリア、ケイ酸アルミニウム、マグネシア、フォルステライト、カオリン、カオリナイト、モンモリロナイト、サポナイト、ベントナイト、酸性活性がわずかしかないか又は低い、クレー、γ−アルミナ、δ−アルミナ、η−アルミナ、θ−アルミナ、及びこれらの混合物からなる群から選択される固体材料を含む、請求項1に記載の触媒。
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US12/335,643 | 2008-12-16 | ||
US12/335,643 US20100152026A1 (en) | 2008-12-16 | 2008-12-16 | Layered Sphere Catalysts with High Accessibility Indexes |
PCT/US2009/061576 WO2010074798A1 (en) | 2008-12-16 | 2009-10-22 | Layered sphere catalysts with high accessibility indexes |
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JP2012512023A true JP2012512023A (ja) | 2012-05-31 |
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JP2011542160A Pending JP2012512023A (ja) | 2008-12-16 | 2009-10-22 | 高いアクセシビリティー・インデックスを有する層状球状体触媒 |
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US (1) | US20100152026A1 (ja) |
EP (1) | EP2365876A4 (ja) |
JP (1) | JP2012512023A (ja) |
KR (1) | KR20110106339A (ja) |
CN (1) | CN102281947A (ja) |
BR (1) | BRPI0922595A2 (ja) |
CA (1) | CA2746353A1 (ja) |
EG (1) | EG26170A (ja) |
RU (1) | RU2501604C2 (ja) |
SG (1) | SG172089A1 (ja) |
WO (1) | WO2010074798A1 (ja) |
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US20100152507A1 (en) * | 2008-12-16 | 2010-06-17 | Gajda Gregory J | Process for Using Layered Sphere Catalysts with High Accessibility Indexes |
US20100331171A1 (en) * | 2009-06-29 | 2010-12-30 | Gajda Gregory J | Layered Sphere Catalysts with High Accessibility Indexes |
CN109772291B (zh) * | 2019-03-13 | 2020-07-10 | 西南化工研究设计院有限公司 | 一种选择性加氢脱炔催化剂及其制备方法与应用 |
US11000832B1 (en) * | 2020-03-13 | 2021-05-11 | Uop Llc | Dehydrogenation catalyst with minimized aromatic production |
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- 2009-10-22 CA CA2746353A patent/CA2746353A1/en not_active Abandoned
- 2009-10-22 KR KR1020117015557A patent/KR20110106339A/ko not_active Application Discontinuation
- 2009-10-22 CN CN2009801544912A patent/CN102281947A/zh active Pending
- 2009-10-22 WO PCT/US2009/061576 patent/WO2010074798A1/en active Application Filing
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JP2003527962A (ja) * | 2000-03-28 | 2003-09-24 | ビーエーエスエフ アクチェンゲゼルシャフト | 気相水素添加用のコーティング触媒 |
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EP2365876A1 (en) | 2011-09-21 |
RU2011129690A (ru) | 2013-01-27 |
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WO2010074798A1 (en) | 2010-07-01 |
CA2746353A1 (en) | 2010-07-01 |
US20100152026A1 (en) | 2010-06-17 |
KR20110106339A (ko) | 2011-09-28 |
BRPI0922595A2 (pt) | 2015-12-22 |
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RU2501604C2 (ru) | 2013-12-20 |
EG26170A (en) | 2013-04-03 |
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