JP2012511601A - ポリマーのマトリクス中に分散された、表面を官能基化したナノゼオライトに基づく、h2oに敏感な装置の保護のための複合材料 - Google Patents
ポリマーのマトリクス中に分散された、表面を官能基化したナノゼオライトに基づく、h2oに敏感な装置の保護のための複合材料 Download PDFInfo
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- JP2012511601A JP2012511601A JP2011540032A JP2011540032A JP2012511601A JP 2012511601 A JP2012511601 A JP 2012511601A JP 2011540032 A JP2011540032 A JP 2011540032A JP 2011540032 A JP2011540032 A JP 2011540032A JP 2012511601 A JP2012511601 A JP 2012511601A
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Abstract
Description
a. 有機的に官能基化されていない;
b. 重合可能な化合物に含まれるものと異なる化学分類に属する有機基によって官能基化される;
c. 重合可能な化合物に含まれるものと同じ化学分類に属するが、同一ではない有機基によって官能基化される; または
d. 重合可能な化合物に含まれるもののうちの少なくとも1つと同じ化学分類に属し、同一である有機基によって官能基化される;
による様々な場合で主に区別され得ることを見出した。
7.74グラムの、真空下で240℃における熱処理を通して前もって活性化されたLTA 4A-PODを、31.36グラムのEpo-tek OG 142-17樹脂(エピクロロヒドリンとビスフェノールAに基づく、単一成分の商業的なエポキシ樹脂、粘度 300〜500cPa s、Tg 54℃)に加えた。その後、組成物(DGBEAエポキシ-POD)を、単純な機械的な攪拌によって前もって分散し、続けていわゆる3本ロールミルミキサーを使用して均一にした。前に記載した全ての操作を、乾燥窒素雰囲気下で、チャンバーの内部で行った(一般的に「グローブボックス」として表される)。
230.8グラムのPMMA(Aldrich、MW 120000)を、800mlの無水トルエン99%(Aldrich)中に前もって溶解した。透明な粘性のPMMA/トルエン懸濁液を、80℃における30分間の還流加熱および機械的な攪拌下で得た。
a) PMMA-POD組成物: 31.32グラムのPMMA/トルエン溶液中の、1.91グラムのLTA-4A POD(240℃における熱処理を通して前もって活性化された);
b) PMMA-OD組成物: 31.50グラムのPMMA/トルエン溶液中の、1.90グラムのLTA-4A OD(170℃における熱処理を通して前もって活性化された); または
c) PMMA-MCR組成物: 29.9グラムのPMMA/トルエン溶液中の、1.79グラムのLTA-4A MCR(180℃における熱処理を通して前もって活性化された)。
1.50グラムの、真空下で240℃における熱処理を通して前もって活性化されたLTA 4A-PODを、28.00グラムのEpo-tek OG-603樹脂(単一成分のアクリル樹脂、粘度 300〜500cPa s、Tg 54℃)に加えた。その後、組成物(アクリル-POD)を、単純な機械的な攪拌によって前もって分散し、続けていわゆる3本ロールミルミキサーを使用して均一にした。前に記載した全ての操作を、グローブボックス中で行った。
0.42グラムの、真空下で450℃における熱処理を通して活性化されたLTA 4Aを、1.60グラムのEpofix塩基、0.07グラムのEpofix硬化剤(商業的に利用可能な二成分のDGEBAエポキシ樹脂)、および0.1グラムの(3-グリシドキシプロピル)トリメトキシシラン(ABCR)の混合物に加えた。その後、組成物(低温硬化エポキシ-なし)を、単純な機械的な攪拌によって前もって分散し、続けていわゆる3本ロールミルミキサーを使用して均一にした。全ての操作を、グローブボックス中で行った。
Claims (25)
- 重合可能な化合物中の、表面を官能基化されたナノゼオライトの均一な分散体を含む、H2Oの浸入に対するバリア複合材料であって、前記ナノゼオライトがポリマーの化合物の少なくとも1つの官能基と同じ化学分類に属する表面改質有機基を含むことを特徴とする、バリア複合材料。
- 前記ナノゼオライトの表面改質有機基が、前記重合可能な化合物の少なくとも1つの官能基と同じである、請求項1に記載のバリア複合材料。
- 前記表面を改質されたナノゼオライトの官能基化が芳香族基を含んで行われる、請求項1または2に記載のバリア複合材料。
- 前記芳香族基がフェニル基である、請求項3に記載のバリア複合材料。
- 前記表面改質有機基のうちの少なくとも1つが脂肪族基である、請求項1または2に記載のバリア複合材料。
- 前記ナノゼオライトの表面改質基が重合可能な基である、請求項2に記載のバリア複合材料。
- 前記表面改質基が、グリシドキシ基、アクリル基またはメタクリル基である、請求項6に記載のバリア複合材料。
- 前記重合可能な化合物が有機樹脂であり、エポキシ樹脂またはアクリル樹脂である、請求項1に記載のバリア複合材料。
- 前記ポリマーの化合物がノボラック樹脂である、請求項1に記載のバリア複合材料。
- 前記表面改質されたナノゼオライトが、LTA、FAU、LTLまたはGISゼオライトであるという事実によって特徴付けられる、請求項1に記載のバリア複合材料。
- 前記エポキシ樹脂が、単一成分の樹脂であるという事実によって特徴付けられる、請求項8に記載のバリア複合材料。
- 前記単一成分の樹脂が、ビスフェノールおよびエピクロロヒドリン(DGEBA)ベースの樹脂である、請求項11に記載のバリア複合材料。
- バリア前駆体の付着プロセス、続けて硬化プロセスによって請求項1に記載のバリアを製造するための方法。
- 前記付着がセリグラフィーによってなされる、請求項13に記載の方法。
- 前記付着が微粒分散によって得られる、請求項13に記載の方法。
- 前記微粒分散がシリンジで得られる、請求項15に記載の方法。
- 前記硬化プロセスが、UV照射、熱およびこれらの組合せから選択される、請求項13に記載の方法。
- 請求項1に記載のバリア複合材料を含む、敏感な装置。
- 前記バリア複合材料が、敏感な装置の端部に存在する、請求項18に記載の敏感な装置。
- 前記バリア複合材料が、敏感な装置の内側の部分を覆う、請求項18に記載の敏感な装置。
- 前記装置が太陽電池である、請求項18に記載の敏感な装置。
- 前記装置がOLEDの画面である、請求項18に記載の敏感な装置。
- 前記装置が微小電気機械装置である、請求項18に記載の敏感な装置。
- 前記装置がエネルギー貯蔵装置である、請求項18に記載の敏感な装置。
- 前記装置がリチウムバッテリーである、請求項24に記載の敏感な装置。
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IT002206A ITMI20082206A1 (it) | 2008-12-12 | 2008-12-12 | Materiale composito per la protezione di dispositivi sensibili ad h2o costituito da nanozeoliti disperse in una matrice polimerica |
PCT/EP2009/066445 WO2010066647A1 (en) | 2008-12-12 | 2009-12-04 | Composite material for the protection of h2o sensitive devices based on surface functionalized nanozeolites dispersed in a polymeric matrix |
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JP2021080483A (ja) * | 2021-03-04 | 2021-05-27 | 旭化成株式会社 | 複合体 |
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EP2373729A1 (en) | 2011-10-12 |
KR20160119267A (ko) | 2016-10-12 |
CN102264820A (zh) | 2011-11-30 |
EP2373729B1 (en) | 2015-04-01 |
CN104327305B (zh) | 2016-04-06 |
US20170152416A1 (en) | 2017-06-01 |
TWI469827B (zh) | 2015-01-21 |
CN104327305A (zh) | 2015-02-04 |
JP5581332B2 (ja) | 2014-08-27 |
US10053604B2 (en) | 2018-08-21 |
KR20110104023A (ko) | 2011-09-21 |
TW201034747A (en) | 2010-10-01 |
WO2010066647A1 (en) | 2010-06-17 |
ITMI20082206A1 (it) | 2010-06-13 |
KR101768726B1 (ko) | 2017-08-16 |
US20110293895A1 (en) | 2011-12-01 |
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