JP2012501940A - 改質された表面を有するケイ酸塩ガラス物品 - Google Patents
改質された表面を有するケイ酸塩ガラス物品 Download PDFInfo
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- JP2012501940A JP2012501940A JP2011525407A JP2011525407A JP2012501940A JP 2012501940 A JP2012501940 A JP 2012501940A JP 2011525407 A JP2011525407 A JP 2011525407A JP 2011525407 A JP2011525407 A JP 2011525407A JP 2012501940 A JP2012501940 A JP 2012501940A
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- Prior art keywords
- glass
- silicate glass
- diffusion
- glass article
- ions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000005368 silicate glass Substances 0.000 title claims abstract description 88
- 239000011521 glass Substances 0.000 claims abstract description 429
- 238000009792 diffusion process Methods 0.000 claims abstract description 208
- 238000010438 heat treatment Methods 0.000 claims abstract description 92
- 150000001768 cations Chemical class 0.000 claims abstract description 89
- 238000000034 method Methods 0.000 claims abstract description 72
- 239000000126 substance Substances 0.000 claims abstract description 67
- 239000000203 mixture Substances 0.000 claims abstract description 51
- 239000012298 atmosphere Substances 0.000 claims abstract description 38
- 230000035939 shock Effects 0.000 claims abstract description 8
- 150000002500 ions Chemical class 0.000 claims description 162
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 121
- 239000000377 silicon dioxide Substances 0.000 claims description 57
- 230000009467 reduction Effects 0.000 claims description 52
- 239000007789 gas Substances 0.000 claims description 48
- 229910052760 oxygen Inorganic materials 0.000 claims description 46
- 239000001301 oxygen Substances 0.000 claims description 44
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 39
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 35
- 239000007788 liquid Substances 0.000 claims description 31
- 230000009477 glass transition Effects 0.000 claims description 29
- -1 transition metal cation Chemical class 0.000 claims description 20
- 230000036961 partial effect Effects 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 229910052723 transition metal Inorganic materials 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 5
- 230000003287 optical effect Effects 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 4
- 238000003860 storage Methods 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- 235000013405 beer Nutrition 0.000 claims description 3
- 230000005684 electric field Effects 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000001569 carbon dioxide Substances 0.000 claims description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 2
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 289
- 239000011575 calcium Substances 0.000 description 86
- 239000000523 sample Substances 0.000 description 71
- 239000011734 sodium Substances 0.000 description 69
- 238000006722 reduction reaction Methods 0.000 description 56
- 229910052742 iron Inorganic materials 0.000 description 54
- 239000003513 alkali Substances 0.000 description 48
- 239000002344 surface layer Substances 0.000 description 48
- 239000010410 layer Substances 0.000 description 44
- 230000006870 function Effects 0.000 description 33
- 238000007254 oxidation reaction Methods 0.000 description 32
- 230000007423 decrease Effects 0.000 description 29
- 230000003647 oxidation Effects 0.000 description 29
- 230000008859 change Effects 0.000 description 28
- 230000015572 biosynthetic process Effects 0.000 description 27
- 238000005259 measurement Methods 0.000 description 26
- 229910052708 sodium Inorganic materials 0.000 description 25
- 238000001228 spectrum Methods 0.000 description 23
- 230000000694 effects Effects 0.000 description 22
- 230000007246 mechanism Effects 0.000 description 22
- 230000004913 activation Effects 0.000 description 21
- 230000008569 process Effects 0.000 description 20
- 230000002829 reductive effect Effects 0.000 description 20
- 238000010521 absorption reaction Methods 0.000 description 19
- 229910052791 calcium Inorganic materials 0.000 description 18
- 238000002474 experimental method Methods 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 16
- 229910052700 potassium Inorganic materials 0.000 description 16
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 15
- 239000010949 copper Substances 0.000 description 15
- 229910052701 rubidium Inorganic materials 0.000 description 14
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 12
- 238000010586 diagram Methods 0.000 description 12
- 238000000584 ultraviolet--visible--near infrared spectrum Methods 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 11
- 229910052792 caesium Inorganic materials 0.000 description 11
- 238000002425 crystallisation Methods 0.000 description 11
- 230000008025 crystallization Effects 0.000 description 11
- 239000003607 modifier Substances 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 241000894007 species Species 0.000 description 10
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 230000008033 biological extinction Effects 0.000 description 9
- 239000010948 rhodium Substances 0.000 description 9
- 238000005452 bending Methods 0.000 description 8
- 239000002052 molecular layer Substances 0.000 description 8
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 8
- 238000004813 Moessbauer spectroscopy Methods 0.000 description 7
- 238000002835 absorbance Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 239000000395 magnesium oxide Substances 0.000 description 7
- 235000012245 magnesium oxide Nutrition 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000004048 modification Effects 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 229910052720 vanadium Inorganic materials 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 6
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 239000012670 alkaline solution Substances 0.000 description 6
- 239000010432 diamond Substances 0.000 description 6
- 229910003460 diamond Inorganic materials 0.000 description 6
- 238000002386 leaching Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- 239000012085 test solution Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 5
- 229910002808 Si–O–Si Inorganic materials 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 5
- 229910052788 barium Inorganic materials 0.000 description 5
- 238000012512 characterization method Methods 0.000 description 5
- 239000003153 chemical reaction reagent Substances 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 238000010348 incorporation Methods 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 229910044991 metal oxide Inorganic materials 0.000 description 5
- 150000004706 metal oxides Chemical class 0.000 description 5
- 239000000075 oxide glass Substances 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- 238000005498 polishing Methods 0.000 description 5
- 238000011946 reduction process Methods 0.000 description 5
- 238000004247 secondary neutral particle mass spectroscopy Methods 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229910052712 strontium Inorganic materials 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 229910018557 Si O Inorganic materials 0.000 description 4
- 229910004283 SiO 4 Inorganic materials 0.000 description 4
- 239000003637 basic solution Substances 0.000 description 4
- 239000002419 bulk glass Substances 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 238000007496 glass forming Methods 0.000 description 4
- 239000000156 glass melt Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 125000004430 oxygen atom Chemical group O* 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 229910001415 sodium ion Inorganic materials 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000001392 ultraviolet--visible--near infrared spectroscopy Methods 0.000 description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 4
- 229910001369 Brass Inorganic materials 0.000 description 3
- 229910014460 Ca-Fe Inorganic materials 0.000 description 3
- 229910008051 Si-OH Inorganic materials 0.000 description 3
- 229910006358 Si—OH Inorganic materials 0.000 description 3
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 239000010951 brass Substances 0.000 description 3
- 238000004364 calculation method Methods 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 229910001447 ferric ion Inorganic materials 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000007373 indentation Methods 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 238000012933 kinetic analysis Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002715 modification method Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000006176 redox buffer Substances 0.000 description 3
- 229910052703 rhodium Inorganic materials 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 230000003595 spectral effect Effects 0.000 description 3
- 238000002411 thermogravimetry Methods 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 238000004584 57Fe Moessbauer spectroscopy Methods 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000012897 Levenberg–Marquardt algorithm Methods 0.000 description 2
- 238000001669 Mossbauer spectrum Methods 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229910007991 Si-N Inorganic materials 0.000 description 2
- 229910006294 Si—N Inorganic materials 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000006107 alkali alkaline earth silicate glass Substances 0.000 description 2
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000004630 atomic force microscopy Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002329 infrared spectrum Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 238000005325 percolation Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 238000005381 potential energy Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000008707 rearrangement Effects 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 239000013074 reference sample Substances 0.000 description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
- 229910052594 sapphire Inorganic materials 0.000 description 2
- 239000010980 sapphire Substances 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 201000000724 Chronic recurrent multifocal osteomyelitis Diseases 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910002552 Fe K Inorganic materials 0.000 description 1
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 1
- 241000789014 Hexaplex Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910021260 NaFe Inorganic materials 0.000 description 1
- 241000204914 Salmonella enterica subsp. enterica serovar Give Species 0.000 description 1
- 229910020175 SiOH Inorganic materials 0.000 description 1
- 241001408653 Siona Species 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 238000004847 absorption spectroscopy Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000005397 alkali-lead silicate glass Substances 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000002238 attenuated effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000005251 gamma ray Effects 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 238000007542 hardness measurement Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000012886 linear function Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000013178 mathematical model Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000005298 paramagnetic effect Effects 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000001028 reflection method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000003238 silicate melt Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000005361 soda-lime glass Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/007—Other surface treatment of glass not in the form of fibres or filaments by thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/35—Exuding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/131—Glass, ceramic, or sintered, fused, fired, or calcined metal oxide or metal carbide containing [e.g., porcelain, brick, cement, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Surface Treatment Of Glass (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200801249 | 2008-09-05 | ||
| DKPA200801249 | 2008-09-05 | ||
| PCT/DK2009/050224 WO2010025735A1 (en) | 2008-09-05 | 2009-09-03 | A silicate glass article with a modified surface |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2012501940A true JP2012501940A (ja) | 2012-01-26 |
| JP2012501940A5 JP2012501940A5 (enExample) | 2013-06-06 |
Family
ID=40510556
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011525407A Pending JP2012501940A (ja) | 2008-09-05 | 2009-09-03 | 改質された表面を有するケイ酸塩ガラス物品 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20110159219A1 (enExample) |
| EP (1) | EP2346793A1 (enExample) |
| JP (1) | JP2012501940A (enExample) |
| CN (1) | CN102143923A (enExample) |
| WO (1) | WO2010025735A1 (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015156206A1 (ja) * | 2014-04-09 | 2015-10-15 | 日本電気硝子株式会社 | ガラスの製造方法及びガラス |
| KR20170102315A (ko) * | 2014-12-31 | 2017-09-08 | 코닝 인코포레이티드 | 유리 제품을 처리하는 방법 |
| WO2019049770A1 (ja) * | 2017-09-06 | 2019-03-14 | 富士フイルム株式会社 | 薬液収容体 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012036074A (ja) * | 2010-07-12 | 2012-02-23 | Nippon Electric Glass Co Ltd | ガラス板 |
| JP5983100B2 (ja) * | 2011-07-19 | 2016-08-31 | 日本電気硝子株式会社 | ガラス基材 |
| JP6410108B2 (ja) * | 2011-07-19 | 2018-10-24 | 日本電気硝子株式会社 | ガラス基材 |
| JP5790303B2 (ja) * | 2011-08-21 | 2015-10-07 | 日本電気硝子株式会社 | 強化ガラス板の製造方法 |
| US9533907B1 (en) | 2011-10-31 | 2017-01-03 | Corning Incorporated | Methods and apparatus for predicting glass dynamics |
| CN103086590B (zh) * | 2011-11-02 | 2015-10-21 | 富泰华工业（深圳）有限公司 | 雾面玻璃制造方法 |
| DE102014214083C5 (de) * | 2014-07-18 | 2021-04-08 | Schott Ag | Vorrichtung und Verfahren zum thermischen Behandeln eines ringförmigen Bereichs einer inneren Oberfläche eines aus einem Borosilikat-Rohrglas hergestellten Glasbehälters |
| WO2016109697A1 (en) | 2014-12-31 | 2016-07-07 | Corning Incorporated | Methods for thermally treating glass articles |
| US10626047B2 (en) | 2016-10-18 | 2020-04-21 | Owens-Brockway Glass Container Inc. | Glass container coating process |
| JP6972802B2 (ja) * | 2017-09-08 | 2021-11-24 | 三菱瓦斯化学株式会社 | 過酸化水素の製造方法 |
| CN111517640B (zh) * | 2020-06-30 | 2021-03-02 | 成都光明光电股份有限公司 | 环保玻璃材料 |
| JP7627557B2 (ja) * | 2020-08-31 | 2025-02-06 | Hoya株式会社 | 着色層を有するガラスおよびその製造方法 |
| CN113754248B (zh) * | 2021-09-18 | 2023-04-14 | 淄博市宝泉轻工制品有限公司 | 一种表面具有金属光泽的玻璃的制造方法 |
| CN116246717B (zh) * | 2021-12-08 | 2024-06-28 | 中国科学院大连化学物理研究所 | 一种提高水中亚铁氰酸根溶解度的添加剂筛选方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3460927A (en) * | 1966-05-25 | 1969-08-12 | Owens Illinois Inc | Process for glass strengthening |
| US3764444A (en) * | 1971-05-17 | 1973-10-09 | Owens Illinois Inc | Glass ceramic and process therefor |
| US3779856A (en) * | 1971-07-23 | 1973-12-18 | Owens Illinois Inc | Glass-ceramic and method for making same |
| FR2863607B1 (fr) * | 2003-12-11 | 2006-09-29 | Snc Eurokera | Vitroceramiques a surface modifiee et leur preparation |
-
2009
- 2009-09-03 JP JP2011525407A patent/JP2012501940A/ja active Pending
- 2009-09-03 CN CN2009801344545A patent/CN102143923A/zh active Pending
- 2009-09-03 EP EP09811067A patent/EP2346793A1/en not_active Withdrawn
- 2009-09-03 US US13/061,398 patent/US20110159219A1/en not_active Abandoned
- 2009-09-03 WO PCT/DK2009/050224 patent/WO2010025735A1/en not_active Ceased
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| CN105829260B (zh) * | 2014-04-09 | 2019-09-24 | 日本电气硝子株式会社 | 玻璃的制造方法和玻璃 |
| CN105829260A (zh) * | 2014-04-09 | 2016-08-03 | 日本电气硝子株式会社 | 玻璃的制造方法和玻璃 |
| KR20160144344A (ko) * | 2014-04-09 | 2016-12-16 | 니폰 덴키 가라스 가부시키가이샤 | 유리의 제조방법 및 유리 |
| WO2015156206A1 (ja) * | 2014-04-09 | 2015-10-15 | 日本電気硝子株式会社 | ガラスの製造方法及びガラス |
| KR102297729B1 (ko) | 2014-04-09 | 2021-09-03 | 니폰 덴키 가라스 가부시키가이샤 | 유리의 제조방법 및 유리 |
| KR20170102315A (ko) * | 2014-12-31 | 2017-09-08 | 코닝 인코포레이티드 | 유리 제품을 처리하는 방법 |
| KR102152978B1 (ko) * | 2014-12-31 | 2020-09-08 | 코닝 인코포레이티드 | 유리 제품을 처리하는 방법 |
| JP2018505836A (ja) * | 2014-12-31 | 2018-03-01 | コーニング インコーポレイテッド | ガラス物品の処理方法 |
| WO2019049770A1 (ja) * | 2017-09-06 | 2019-03-14 | 富士フイルム株式会社 | 薬液収容体 |
| KR20200028422A (ko) * | 2017-09-06 | 2020-03-16 | 후지필름 가부시키가이샤 | 약액 수용체 |
| JPWO2019049770A1 (ja) * | 2017-09-06 | 2020-11-12 | 富士フイルム株式会社 | 薬液収容体 |
| KR102299069B1 (ko) * | 2017-09-06 | 2021-09-07 | 후지필름 가부시키가이샤 | 약액 수용체 |
| JP7029459B2 (ja) | 2017-09-06 | 2022-03-03 | 富士フイルム株式会社 | 薬液収容体 |
| US11976001B2 (en) | 2017-09-06 | 2024-05-07 | Fujifilm Corporation | Chemical liquid storage body |
| US12434997B2 (en) | 2017-09-06 | 2025-10-07 | Fujifilm Corporation | Chemical liquid storage body |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2346793A1 (en) | 2011-07-27 |
| US20110159219A1 (en) | 2011-06-30 |
| CN102143923A (zh) | 2011-08-03 |
| WO2010025735A1 (en) | 2010-03-11 |
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