JP2012065580A - Oil-and-fat composition for whipped cream - Google Patents

Oil-and-fat composition for whipped cream Download PDF

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JP2012065580A
JP2012065580A JP2010212305A JP2010212305A JP2012065580A JP 2012065580 A JP2012065580 A JP 2012065580A JP 2010212305 A JP2010212305 A JP 2010212305A JP 2010212305 A JP2010212305 A JP 2010212305A JP 2012065580 A JP2012065580 A JP 2012065580A
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JP5745804B2 (en
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Kiichi Yasutake
貴一 安武
Takashi Yoshida
吉田  孝
Toshihiro Nakamura
年宏 中村
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Taiyo Yushi Corp
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Abstract

PROBLEM TO BE SOLVED: To provide an oil-and-fat composition for whipped cream enabling production of whipped cream which is excellent in emulsion stability even under a low-temperature distribution and has good meltabilities in the mouth.SOLUTION: The oil-and-fat composition for whipped cream contains at least two kinds of oil and fat. The oil-and-fat composition is such as to satisfy the following: (1) first oil and fat includes oil and fat selected from (A) transesterified oil and fat obtained by mixing coconut oil and extremely hardened high erucic oilseed rape at a rate of 4:6-9:1 and transesterifying the mixture, and (B) mixture oil and fat comprising the oil and fat (A) and oil and fat obtained by transesterifying 100% coconut oil; (2) second oil and fat includes oil and fat which is extremely hardened oil and fat from palm core oil, or partially-hydrogenated oil and fat, and has a melting point of ≥30°C; and (3) the content of a C22 fatty acid is 0.5-4.5 mass% based on 100 mass% of the whole constituent fatty acid of the oil-and-fat composition, the total mass of the oil-and-fat composition contains ≥22 mass% of the second oil and fat, and the melting point of the oil-and-fat composition is ≤36°C.

Description

本発明は、乳化安定性に優れたホイップクリーム用水中油型乳化油脂組成物を製造でき、かつ口融けが良いホイップクリームを製造できる、トランス酸が低減された、ホイップクリーム用油脂組成物に関する。   The present invention relates to an oil / fat composition for whipped cream with reduced trans acid, which can produce an oil-in-water emulsified oil / fat composition for whipped cream excellent in emulsification stability and can produce a whipped cream with good melting.

従来から、製菓や料理に用いられるホイップクリームとして、植物性油脂を原料として製造される植物性クリーム(水中油型乳化物)を用いることが知られている。植物性クリームは生乳から得られる生クリームに比べて安定性に優れ、かつ比較的安価に製造されるという利点を有するためにその消費量は多い。
この植物性クリームの製造では、流通時の温度変化する条件でも乳化安定性に優れ、口融け、造花性、気泡性に優れたホイップクリームが求められており、従来より数多くの提案がなされている。
Conventionally, it is known to use vegetable creams (oil-in-water emulsions) produced using vegetable oils and fats as whipped creams used in confectionery and cooking. Since vegetable cream has the advantage of being excellent in stability and being manufactured at a relatively low cost compared to fresh cream obtained from raw milk, its consumption is large.
In the production of this vegetable cream, there has been a demand for a whipped cream that has excellent emulsification stability even under conditions of temperature change during distribution, and has excellent thawing, flower-forming properties, and foam properties, and many proposals have been made. .

起泡前のクリームの状態で流通させるクリームでは、起泡性(ホイップ時の操作性)、ホイップ後の保形性、更に口の中での融けやすさ(口融け)などの性能に加えて、輸送中の温度変化によりクリームの粘度が上昇しない(ヒートショック耐性)という特性が求められる。   In addition to performance such as foaming (operability during whipping), shape retention after whipping, and ease of melting in the mouth (mouth melting) The property that the viscosity of the cream does not increase due to temperature change during transportation (heat shock resistance) is required.

これらの性能を満たすクリームを得るために、様々な油脂の組み合わせが提案されている。特に、従来、菜種油やパーム油などの部分水素添加油が用いられてきた。
しかし、近年、従来用いられてきた硬化油中に含まれるトランス脂肪酸の過剰摂取が心疾患のリスクを高めるとの報告もあり、米国、カナダなどではトランス脂肪酸含有量の表示義務が課されている。従って、ホイップクリーム用の油脂組成物の開発にあたっては、トランス脂肪酸含量をできる限り低く抑えたいという要望もある。
これに対し、上記の部分水素添加油に代わり完全水素添加油(極度硬化油)を用いることによりトランス酸を低下させることができる。しかし、完全水素添加油(極度硬化油)は融点が高く、口融けを低下させてしまう。
In order to obtain a cream that satisfies these performances, various combinations of fats and oils have been proposed. In particular, conventionally hydrogenated oils such as rapeseed oil and palm oil have been used.
However, in recent years, there are reports that excessive intake of trans fatty acids contained in conventionally used hardened oils increases the risk of heart disease, and the United States, Canada, etc. are obligated to indicate the content of trans fatty acids. . Therefore, in the development of an oil and fat composition for whipped cream, there is also a demand for keeping the trans fatty acid content as low as possible.
On the other hand, trans acid can be reduced by using completely hydrogenated oil (extremely hardened oil) instead of the above partially hydrogenated oil. However, completely hydrogenated oil (extremely hardened oil) has a high melting point and reduces melting.

例えば、実質的にトランス酸を含有せず、耐振性や耐熱性に優れ、シャープな口どけ性を維持できるホイップクリームを与える油脂組成物として、所定の構成脂肪酸を有するように混合したランダムエステル交換油脂の混合物を用いた起泡性クリーム用油脂組成物を用いることが提案されている(特許文献1)。   For example, as a fat composition that provides a whipped cream that does not substantially contain trans acid, has excellent vibration resistance and heat resistance, and can maintain a sharp mouth-feel, random transesterification mixed to have a predetermined constituent fatty acid It has been proposed to use an oil and fat composition for foaming cream using a mixture of oils and fats (Patent Document 1).

また、融点が33〜42℃であり、炭素数22の飽和脂肪酸を5〜15質量部含み、ヨウ素価2以下のエステル交換硬化油脂と、融点10〜15℃である油脂を組み合わせることにより、実質的にトランス酸を含有しない油脂組成物にも関わらず、水中油型乳化液の振動耐性や温度安定性等の乳化安定性、短時間でホイップが可能なホイップ性能、ホイップクリームの造花性及び口あたりや口融け等の食感に優れたホイップクリーム用油脂組成物が提供されることも報告されている(特許文献2)。   Further, the melting point is 33 to 42 ° C., 5 to 15 parts by mass of a saturated fatty acid having 22 carbon atoms, and the transesterified oil and fat having an iodine value of 2 or less and the oil and fat having a melting point of 10 to 15 ° C. are combined. Despite the oil composition that does not contain trans acid, the emulsion stability such as vibration resistance and temperature stability of oil-in-water emulsions, whipping performance that can be whipped in a short time, the whipping cream's flowering ability and mouth It has also been reported that an oil and fat composition for whipped cream having an excellent texture such as hit or melted mouth is provided (Patent Document 2).

特開2009−219391号JP 2009-219391 A 特開2010−004810号JP 2010-004810 A

本発明は、流通時の温度が変化する条件においても、乳化安定性に優れており、かつ口融けがよいホイップクリームを製造することができる、ホイップクリーム用油脂組成物を提供することを目的とする。
本発明はまた、流通時の温度が変化する条件でも乳化安定性に優れており、更にホイップ操作がしやすく、かつ口融けがよいホイップクリームを製造するための油脂組成物を提供することを目的とする。
本発明はまた、流通時の温度が変化する条件でも乳化安定性と口融けにおいて優れており、更にトランス脂肪酸を低減させたホイップクリームを製造するための油脂組成物を提供することを目的とする。
An object of the present invention is to provide an oil / fat composition for whipped cream, which is capable of producing a whipped cream that is excellent in emulsion stability and melts well even under conditions where the temperature during distribution changes. To do.
Another object of the present invention is to provide an oil and fat composition for producing a whipped cream that is excellent in emulsion stability even under conditions in which the temperature at the time of distribution is changed, is easy to perform a whipping operation, and has good meltability. And
Another object of the present invention is to provide an oil / fat composition for producing a whipped cream which is excellent in emulsion stability and meltability even under conditions in which the temperature during distribution changes, and further reduced in trans fatty acids. .

本発明者らは、上記の点に鑑み研究した結果、ホイップクリーム用油脂組成物において、ヤシ油と極度硬化ハイエルシン菜種油を所定範囲で混合してエステル交換した油脂あるいは前記エステル交換油脂に更にヤシ油エステル交換油脂を混合した油脂を第1の油脂として使用し、さらにパーム核油の極度硬化油脂あるいは部分水素添加油脂を第2の油脂を所定の質量比で含む油脂組成物を用いることにより、上記目的を達成することができるという知見を得て、本発明を完成するに至った。   As a result of studies conducted in view of the above points, the present inventors have found that in a whipped cream fat composition, coconut oil and extremely hardened Hyelsin rapeseed oil are mixed within a predetermined range and transesterified, or the transesterified fat and oil are further mixed with coconut oil. By using an oil / fat mixed with transesterified oil / fat as the first oil / fat, and using an oil / fat composition containing the second oil / fat in a predetermined mass ratio of the extremely hardened oil / fat of the palm kernel oil or the partially hydrogenated oil / fat. Obtaining knowledge that the object can be achieved, the present invention has been completed.

すなわち、本発明は以下を提供する。
<1>少なくとも2種類の油脂を含むホイップクリーム用油脂組成物であって、
(1)第1の油脂が、(A)第1の油脂が、ヤシ油と極度硬化ハイエルシン菜種油を4:6〜9:1の範囲で混合し、エステル交換したエステル交換油脂、及び(B)前記油脂(A)とヤシ油100%をエステル交換した油脂との混合油脂から選択される油脂であり、
(2)第2の油脂が、パーム核油の極度硬化油脂あるいは部分水素添加油脂であって、融点が30℃以上の油脂からなり、及び
(3)油脂組成物の全構成脂肪酸100質量%に対してC22の脂肪酸含有量が0.5〜4.5質量%であり、油脂組成物全質量に対して、第2の油脂が25質量%以上の量で含まれており、かつ融点が36℃以下である、上記油脂組成物。
<2>
第1の油脂と第2の油脂が10:90〜75:25の比である、上記<1>に記載の油脂組成物。
<3>
第1の油脂と第2の油脂の合計含有量が65質量%以上の量で含まれる、上記<1>または2>に記載の油脂組成物。
<4>
更に、極度硬化ヤシ油、パームオレイン硬化油、またはハイオレイック菜種油を含む、上記<1>〜<3>のいずれか一項に記載の油脂組成物。
<5>
水相部と油相部からなり、前記油相部が上記<1>〜<4>のいずれか一項に記載の油脂組成物を含むことを特徴とする、水中油型乳化油脂組成物。
<6>
水中油型乳化油脂組成物質量に対する油相部の質量が20%〜50%であることを特徴とする、請求項<5>記載の水中油型乳化油脂組成物。
<7>
油相部が更に乳脂肪を含むことを特徴とする、上記<5>または<6>に記載の水中油型乳化油脂組成物。
<8>
乳脂肪と上記<1>〜<4>のいずれか一に記載の油脂組成物の質量比が0:100〜80:20の範囲であることを特徴とする、上記<5>〜<7>のいずれか一に記載の水中油型乳化油脂組成物。
<9>
上記<5>〜<8>のいずれか一に記載の水中油型乳化油脂組成物の、ホイップクリーム製造における使用。
<10>
上記<5>〜<8>のいずれか一に記載の水中油型乳化油脂組成物を用いて製造されたホイップクリーム。
That is, the present invention provides the following.
<1> An oil and fat composition for whipped cream containing at least two types of oil and fat,
(1) The first fat is (A) the first fat is transesterified fat mixed with coconut oil and extremely hardened Hyelsin rapeseed oil in the range of 4: 6 to 9: 1, and (B) It is a fat selected from the mixed fats and oils of the fats and oils (A) and fats obtained by transesterification of 100% coconut oil,
(2) The second fat / oil is an extremely hardened fat / partially hydrogenated fat / oil of palm kernel oil, and has a melting point of 30 ° C. or higher, and
(3) The fatty acid content of C22 is 0.5 to 4.5% by mass with respect to 100% by mass of the total constituent fatty acids of the oil / fat composition, and the second oil / fat is 25% by mass with respect to the total mass of the oil / fat composition. % Of the oil and fat composition, which is contained in an amount of not less than% and has a melting point of 36 ° C. or less.
<2>
The oil and fat composition according to <1>, wherein the first oil and fat are in a ratio of 10:90 to 75:25.
<3>
The oil / fat composition according to the above <1> or 2>, wherein the total content of the first oil / fat and the second oil / fat is contained in an amount of 65% by mass or more.
<4>
Furthermore, the oil-fat composition as described in any one of said <1>-<3> containing extremely hardened coconut oil, palm olein hardened oil, or high oleic rapeseed oil.
<5>
An oil-in-water emulsified oil / fat composition comprising an aqueous phase part and an oil phase part, wherein the oil phase part comprises the oil / fat composition according to any one of the above items <1> to <4>.
<6>
The oil-in-water emulsified oil / fat composition according to claim <5>, wherein the mass of the oil phase part relative to the amount of the oil-in-water emulsified oil / fat composition is 20% to 50%.
<7>
The oil-in-water emulsified oil / fat composition according to <5> or <6> above, wherein the oil phase part further contains milk fat.
<8>
<5> to <7> above, wherein the mass ratio of the milk fat and the oil composition according to any one of <1> to <4> is in the range of 0: 100 to 80:20. The oil-in-water emulsified oil / fat composition according to any one of the above.
<9>
Use of the oil-in-water emulsified oil / fat composition according to any one of the above <5> to <8> in the production of whipped cream.
<10>
Whipped cream produced using the oil-in-water emulsified oil / fat composition according to any one of <5> to <8> above.

本発明により、流通時の温度が変化する条件に対して乳化安定性に優れ、かつ口融け、起泡性、ヒートショック耐性等に優れたホイップクリームを製造することができるホイップクリーム用水中油型乳化油脂組成物が提供される。
特に、本発明のホイップクリーム用水中油型乳化油脂組成物は高いヒートショック耐性を有し、ホイップ後の乳化安定性を示す一方で、優れた口融けを実現するため、従来品と比べて極めて優れた商品価値を与えるものである。
According to the present invention, an oil-in-water emulsification for whipped cream that can produce a whipped cream that is excellent in emulsification stability with respect to conditions under which the temperature during distribution changes and that is excellent in melting, foaming, heat shock resistance, etc An oil and fat composition is provided.
In particular, the oil-in-water emulsified oil / fat composition for whipped cream of the present invention has high heat shock resistance and exhibits emulsification stability after whipping, while achieving excellent mouth melting, and is extremely superior to conventional products. The product value is given.

<ホイップクリーム用油脂組成物>
本発明のホイップクリーム用油脂組成物は、少なくとも2種類の油脂を含むホイップクリーム用油脂組成物であって、
(1)(A)第1の油脂が、ヤシ油と極度硬化ハイエルシン菜種油を4:6〜9:1の範囲で混合し、エステル交換したエステル交換油脂、及び(B)前記油脂(A)とヤシ油100%をエステル交換した油脂との混合油脂から選択される油脂であり、
(2)第2の油脂が、パーム核油の極度硬化油脂あるいは部分水素添加油脂であって、融点が30℃以上の油脂からなり、及び
(3)油脂組成物の全構成脂肪酸100質量%に対してC22の脂肪酸含有量が0.5〜4.5質量%であり、油脂組成物全質量に対して、第2の油脂が25質量%以上の量で含まれており、かつ融点が36℃以下であることを特徴とする。
<Oil composition for whipped cream>
The oil and fat composition for whipped cream of the present invention is an oil and fat composition for whipped cream containing at least two types of oil and fat,
(1) (A) The first fat / oil is a mixture of coconut oil and extremely hardened Hyelsin rapeseed oil in the range of 4: 6 to 9: 1 and transesterified, and (B) the fat (A) It is a fat selected from a mixed fat with a fat obtained by transesterification of 100% coconut oil,
(2) The second fat / oil is an extremely hardened fat / partially hydrogenated fat / oil of palm kernel oil, and has a melting point of 30 ° C. or higher, and
(3) The fatty acid content of C22 is 0.5 to 4.5% by mass with respect to 100% by mass of the total constituent fatty acids of the oil / fat composition, and the second oil / fat is 25% by mass with respect to the total mass of the oil / fat composition. %, And the melting point is 36 ° C. or less.

なお、本明細書において、「ホイップクリーム」は起泡した水中油型乳化油脂組成物(起泡済クリーム状組成物)を意味する。「ホイップクリーム用水中油型乳化油脂組成物」は起泡前のクリーム状の水中油型乳化油脂組成物を意味する。「ホイップクリーム用油脂組成物」は、ホイップクリーム用水中油型乳化油脂組成物を製造するために用いられる油脂組成物」を意味する。   In the present specification, “whipped cream” means a foamed oil-in-water emulsified oil / fat composition (foamed cream-like composition). The “oil-in-water emulsified oil / fat composition for whipped cream” means a creamy oil-in-water emulsified oil / fat composition before foaming. “Oil composition for whipped cream” means “oil composition used for producing an oil-in-water emulsified oil composition for whipped cream”.

本発明のホイップクリーム用油脂組成物から水中油型乳化油脂組成物を作成する際には、後述するように油相部に乳脂肪を添加することができるが、本明細書において「ホイップクリーム用油脂組成物」あるいは「油脂組成物」という場合には、特に断らない限り、植物性油脂(すなわち、乳脂肪を除く油脂)からなる油脂組成物を意味する。   When preparing an oil-in-water emulsified oil / fat composition from the whipped cream oil / fat composition of the present invention, milk fat can be added to the oil phase part as described later. The term “oil / fat composition” or “oil / fat composition” means an oil / fat composition comprising vegetable oil / fat (that is, oil / fat excluding milk fat) unless otherwise specified.

(1)第1の油脂
本発明の油脂組成物において、第1の油脂は、(A)ヤシ油と極度硬化ハイエルシン菜種油を質量比で4:6〜9:1の範囲で混合し、エステル交換した油脂、及び(B)前記油脂(A)とヤシ油100%をエステル交換した油脂とを混合した混合油脂から選択される。
前記ヤシ油は、ヤシから得られる油脂であり、水素添加されていないいわゆる生のヤシ油(非水素添加油脂または非硬化油)を意味する。
極度硬化ハイエルシン菜種油とは、ハイエルシン菜種油を完全に水素添加した(極度硬化した)油脂である。「極度硬化」とは、水素添加によって不飽和脂肪酸を完全に飽和することである。水素添加の方法は当業者に公知の方法により適宜行うことができる。例えば「食用油製造の実際」(宮川高明著、幸書房、昭和63年7月5日 初版第1刷発行)に記載の方法に従い行うことができる。
(1) 1st fats and oils In the fats and oils composition of this invention, 1st fats and oils mix (A) coconut oil and extremely hardened hyercine rapeseed oil in the range of 4: 6-9: 1 by mass ratio, and transesterify. And (B) the mixed fats and oils obtained by mixing the fats and oils (A) and the fats and oils obtained by transesterifying 100% of the coconut oil.
The coconut oil is an oil and fat obtained from coconut and means a so-called raw coconut oil (non-hydrogenated oil or non-hardened oil) that is not hydrogenated.
Extremely hardened Hyelsin rapeseed oil is a fat or oil obtained by completely hydrogenating (extremely hardened) Hyelsin rapeseed oil. “Extreme curing” is the complete saturation of unsaturated fatty acids by hydrogenation. The method of hydrogenation can be suitably performed by a method known to those skilled in the art. For example, it can be carried out in accordance with the method described in “Actual cooking oil production” (Takaaki Miyagawa, Sachishobo, first edition issued on July 5, 1988).

第1の油脂の油脂(A)において、ヤシ油と極度硬化ハイエルシン菜種油の質量比は、4:6〜9:1の範囲であればよいが、油脂組成物の全構成脂肪酸100質量%に対してC22の脂肪酸含有量が0.5〜4.5質量%となるように油脂(A)におけるヤシ油と極度硬化ハイエルシン菜種油の質量比並びに油脂(A)と油脂(B)との質量比を決めることが重要である。
ただし、C22の脂肪酸含有量が上記範囲内であっても、油脂(A)の種類、あるいは油脂(A)と油脂(B)の種類の組み合わせによってヒートショック耐性は高くなるが、戻り硬度が低下したり、口融けが低下してしまう場合がある。
例えば、ヤシ油と極度硬化ハイエルシン菜種油の質量比が5:5のエステル交換油脂は、融点が非常に高いので、使用する量によって、口融けが低下しやすくなる。従って、特にヤシ油と極度硬化ハイエルシン菜種油の5:5のエステル交換油脂を用いる場合には、かかる油脂の油脂組成物の全組成物に対する含有量を20質量%以下として、C22の脂肪酸含有量が4.5質量%以下となるように調整することが好ましい。
In the fats and oils (A) of the first fat and oil, the mass ratio of coconut oil and extremely hardened Hyelsin rapeseed oil may be in the range of 4: 6 to 9: 1, but with respect to 100% by mass of the total constituent fatty acids of the fat and oil composition. The mass ratio of coconut oil to extremely hardened Hyelsin rapeseed oil and the mass ratio of fat (A) to fat (B) so that the fatty acid content of C22 is 0.5 to 4.5 mass%. It is important to decide.
However, even if the fatty acid content of C22 is within the above range, heat shock resistance is increased by the type of fat (A), or the combination of fat (A) and fat (B), but the return hardness is lowered. Or melting of the mouth may be reduced.
For example, transesterified fats and oils having a mass ratio of coconut oil to extremely hardened Hyelsin rapeseed oil of 5: 5 have a very high melting point, so that melting of the mouth tends to decrease depending on the amount used. Therefore, particularly when using a 5: 5 transesterified oil / fat of coconut oil and extremely hardened Hyelsin rapeseed oil, the content of such oil / fat with respect to the total composition of the oil / fat composition is 20% by mass or less, and the fatty acid content of C22 is It is preferable to adjust so that it may become 4.5 mass% or less.

油脂のエステル交換の方法は当該技術分野で公知の方法で行うことができる。エステル交換には、例えば、ランダム(非選択的)エステル交換反応方法、選択型(指向型)エステル交換反応方法がある(参考文献:安田耕作、福永良一郎、松井宣也、渡辺正男、新版油脂製品の知識、幸書房)、本発明では、ランダムエステル交換反応方法が好ましい。
ランダムエステル交換は、例えば、ナトリウムメチラート、水酸化ナトリウム等を触媒としてエステル交換を行う化学的な方法、非選択的リパーゼ等を触媒としてエステル交換を行う酵素的な方法に従って行うことができる。特に、化学的な方法でランダムエステル交換反応を行うことにより、簡便であるため、より好ましい。
The method of transesterification of fats and oils can be performed by a method known in the art. Examples of transesterification include a random (non-selective) transesterification method and a selective (directed) transesterification method (reference documents: Kosaku Yasuda, Ryoichiro Fukunaga, Nobuya Matsui, Masao Watanabe, new oil products) In the present invention, a random transesterification reaction method is preferred.
Random transesterification can be performed, for example, according to a chemical method in which transesterification is performed using sodium methylate, sodium hydroxide or the like as a catalyst, or an enzymatic method in which transesterification is performed using non-selective lipase or the like as a catalyst. In particular, it is more preferable to perform a random transesterification reaction by a chemical method because it is simple.

(2)第2の油脂
第2の油脂は、パーム核油の極度硬化油脂あるいは部分水素添加油脂であって、融点が30℃以上の油脂からなる。
かかる油脂と、上述した第1の油脂を混合することにより、第1の油脂により奏されるホイップ性とヒートショック耐性と口融けを良好に保ちつつ、冷蔵保存時の経時変化が小さい(戻り硬度)が良好なホイップクリーム用油脂組成物を得ることができる。
パーム核油の極度硬化油脂は、パーム核油を極度硬化処理した油脂であり、通常、融点は40℃前後、より好ましくは40℃である。パーム核油はエステル交換を行ったものであってもよい。
パーム核油の部分水素添加油脂は、パーム核を部分水素添加した油脂である。通常、ヨウ素価3〜12程度となるように水素添加した油脂であって、融点が30℃以上、より好ましくは33℃以上、更に35℃以上であればよい。
パーム核油の極度硬化油脂あるいは部分水素添加油脂は、更にエステル交換処理をされていてもよい。
(2) 2nd fats and oils The 2nd fats and oils are extremely hardened fats or partially hydrogenated fats and oils of palm kernel oil, and consist of fats and oils whose melting | fusing point is 30 degreeC or more.
By mixing such fats and oils with the above-mentioned first fats and oils, the change over time during refrigerated storage is small while maintaining the whipping properties, heat shock resistance, and mouth melting exhibited by the first fats and oils (return hardness) ) Can be obtained.
The extremely hardened fat of palm kernel oil is a fat obtained by extremely hardening palm kernel oil, and usually has a melting point of around 40 ° C, more preferably 40 ° C. Palm kernel oil may be transesterified.
The partially hydrogenated fat of palm kernel oil is a fat obtained by partially hydrogenating palm kernel. Usually, the oil is hydrogenated to have an iodine value of about 3 to 12, and the melting point is 30 ° C. or higher, more preferably 33 ° C. or higher, and further 35 ° C. or higher.
The extremely hardened oil or partially hydrogenated oil of palm kernel oil may be further transesterified.

(3)第2の油脂の含有量
油脂組成物の全構成脂肪酸100質量%に対してC22の脂肪酸含有量が0.5〜4.5質量%であることを条件として、第2の油脂は、油脂組成物全質量に対して、22質量%以上の量で含まれている。C22の脂肪酸含有量と第2の油脂の量がかかる範囲にある場合には、ヒートショック耐性と乳化安定性(戻り硬度)のいずれも満足する性能を与えるからである。第2の油脂は、油脂組成物全質量に対して、25質量%以上であることが更に好ましい。
(3) Content of 2nd fats and oils On condition that the fatty-acid content of C22 is 0.5-4.5 mass% with respect to 100 mass% of all the constituent fatty acids of fats and oils composition, 2nd fats and oils are And 22% by mass or more based on the total mass of the oil and fat composition. This is because, when the fatty acid content of C22 and the amount of the second oil and fat are within such ranges, performance satisfying both heat shock resistance and emulsion stability (return hardness) is provided. The second fat / oil is more preferably 25% by weight or more based on the total weight of the fat / oil composition.

(4)油脂組成物の融点
本明細書において、「融点」は「上昇融点」を意味する。本発明の油脂組成物の融点は36.0℃以下である。かかる範囲の融点を有する場合には口融けが優れているからである。好ましくは35.0℃以下であり、34.0℃以下であることが更に好ましく、更に33℃以下であることが好ましい。
(4) Melting point of oil and fat composition In the present specification, "melting point" means "rising melting point". The melting point of the oil and fat composition of the present invention is 36.0 ° C. or less. This is because melting is excellent when the melting point is in this range. Preferably it is 35.0 degrees C or less, More preferably, it is 34.0 degrees C or less, Furthermore, it is preferable that it is 33 degrees C or less.

(5)油脂組成物中の構成脂肪酸組成
本発明の油脂組成物は、油脂組成物の全構成脂肪酸100質量%に対してC22の脂肪酸を0.5〜4.5質量%含む。C22の量は、第1の油脂のハイエルシンナタネ油に由来するものがほとんどである。C22のより好ましい量は1.0〜4.0質量%であり、最も好ましくは2.0〜3.6質量%である。かかる範囲においてホイップ性とヒートショック耐性と口融けを良好に保つからである。
(5) Constituent Fatty Acid Composition in Oil and Fat Composition The oil and fat composition of the present invention contains 0.5 to 4.5 mass% of C22 fatty acid with respect to 100 mass% of all constituent fatty acids of the oil and fat composition. Most of the amount of C22 is derived from the first oil or fat, high rapeseed oil. A more preferable amount of C22 is 1.0 to 4.0% by mass, and most preferably 2.0 to 3.6% by mass. This is because whipability, heat shock resistance and melting of the mouth are kept good in such a range.

本明細書において、油脂組成物の脂肪酸組成は、基準油脂分析法(暫17-2007 トランス脂肪酸含量 キャピラリーガスクロマトグラフ法)に準じて測定した値を意味する。上記基準油脂分析において、ガスクロマトグラフィー装置は、例えば、島津製作所(株)製、GC-2010型、カラムは、SUPELCO社製、SP-2560、を用いることができる。   In the present specification, the fatty acid composition of the oil / fat composition means a value measured according to a standard oil / fat analysis method (provisional 17-2007 trans fatty acid content capillary gas chromatograph method). In the reference oil analysis, for example, a gas chromatography apparatus manufactured by Shimadzu Corporation, GC-2010, and a column manufactured by SUPELCO, SP-2560 can be used.

(6)第1の油脂と第2の油脂の質量比
上記(1)〜(5)の要件を満たす範囲において、第1の油脂と第2の油脂の質量比は10:90〜78:22の比であることが好ましい。また、20:80〜75:25であることが更に好ましく、30:70〜70:30であることがより好ましい。かかる範囲において、高いヒートショック耐性を有し、ホイップ後の高い保形性を示す一方で、優れた口融けのホイップクリームを得ることができるからである。
(6) Mass ratio of 1st fats and oils In the range which satisfy | fills the requirements of said (1)-(5), the mass ratio of 1st fats and oils and 2nd fats is 10: 90-78: 22. The ratio is preferably. Moreover, it is still more preferable that it is 20: 80-75: 25, and it is more preferable that it is 30: 70-70: 30. This is because, within such a range, while having high heat shock resistance and high shape retention after whipping, an excellent whipped cream can be obtained.

(7)第1の油脂と第2の油脂の合計含量
第1の油脂と第2の油脂は合計で65質量%以上、より好ましくは70質量%以上である。これより少ないと本発明の効果を十分に奏することができない。
(7) Total content of 1st fat and oil and 2nd fat and oil The 1st fat and oil and 2nd fat and oil are 65 mass% or more in total, More preferably, it is 70 mass% or more. If it is less than this, the effects of the present invention cannot be sufficiently achieved.

(8)第3の油脂
更に、本発明の油脂組成物には、更に、風味付け、口融け、乳化安定性などを改良する観点から、極度硬化ヤシ油、パームオレイン硬化油、及びハイオレイック菜種油からなる群より選択される第3の油脂を含んでいてもよい。
硬化ヤシ油は口融けを良好にするため好ましい。パームオレイン硬化油は乳化安定性を良くなるため好ましい。ハイオレイック菜種は乳化安定性と口融けを良くするために使用する事ができるため、好ましい。
第3の油脂は、油脂組成物質量に対して、35質量%以下の範囲で含むことが好ましく、30質量%以下であることが更に好ましい。
(8) Third oil and fat Further, the oil and fat composition of the present invention further includes extremely hardened coconut oil, palm olein hardened oil, and high oleic rapeseed oil from the viewpoint of improving flavoring, melting in the mouth, and emulsion stability. The 3rd fats and oils selected from the group which consists of may be included.
Hardened coconut oil is preferable because it improves the melting of the mouth. Palm olein hydrogenated oil is preferable because it improves emulsion stability. High oleic rapeseed is preferred because it can be used to improve emulsification stability and meltability.
It is preferable that 3rd fats and oils are included in 35 mass% or less with respect to the amount of oil-fat composition substances, and it is still more preferable that it is 30 mass% or less.

(9)トランス脂肪酸含有量
本発明の目的の1つは、トランス脂肪酸含有量を低減させた油脂組成物を提供することである。本発明において、油脂組成物全質量に対するトランス脂肪酸含有量は、好ましくは10質量%以下、更に好ましくは8質量%以下、より好ましくは5質量%以下、最も好ましくは3質量%以下である。
(9) Trans Fatty Acid Content One of the objects of the present invention is to provide an oil / fat composition having a reduced trans fatty acid content. In the present invention, the trans fatty acid content with respect to the total mass of the oil and fat composition is preferably 10% by mass or less, more preferably 8% by mass or less, more preferably 5% by mass or less, and most preferably 3% by mass or less.

<水中油型乳化油脂組成物>
本発明の水中油型乳化油脂組成物は、水相部と油相部からなり、上述した本発明のホイップクリーム用油脂組成物を油相部に含む。水相部と油相部の質量比はホイップクリームを製造するために適宜設定することができるが、通常、80:20〜50:50程度である。
前記油相部は、油脂として本発明のホイップクリーム用油脂組成物のみを含んでいてもよく、また乳脂肪を更に含んでいてもよい。乳脂肪としてバターオイル、バター、生クリーム、牛乳等を由来とする乳脂肪が挙げられる。以下、上述した本発明のホイップクリーム用油脂組成物を特に乳脂肪と区別して述べる場合には、「植物性油脂組成物」とも呼ぶ。
乳脂肪と植物性油脂組成物の混合比は、質量比で乳脂肪:植物性油脂組成物が0:100〜80:20の範囲内で変えることができる。前記範囲内であれば、植物性油脂組成物の乳化安定性、口融け、造花性、起泡性等の効果を損なうことなく、ホイップクリームを製造することができる。
<Oil-in-water emulsified oil / fat composition>
The oil-in-water emulsified oil / fat composition of the present invention comprises an aqueous phase part and an oil phase part, and includes the above-described oil / fat composition for whipped cream in the oil phase part. The mass ratio of the water phase part and the oil phase part can be appropriately set in order to produce a whipped cream, but is usually about 80:20 to 50:50.
The oil phase part may contain only the oil and fat composition for whipped cream of the present invention as an oil or fat, and may further contain milk fat. Examples of milk fat include milk fat derived from butter oil, butter, fresh cream, milk and the like. Hereinafter, when the oil and fat composition for whipped cream of the present invention described above is particularly distinguished from milk fat, it is also referred to as “vegetable oil and fat composition”.
The mixing ratio of the milk fat and the vegetable oil composition can be changed within a range of 0: 100 to 80:20 of the milk fat: vegetable oil composition by mass ratio. If it is in the said range, a whipped cream can be manufactured, without impairing effects, such as emulsification stability of a vegetable oil-fat composition, a mouth melting, an artificial flower property, and foaming property.

本発明の水中油型乳化油脂組成物は、一般的な製造方法により製造できるが、代表的な方法を述べると、先ず使用する乳化剤が親油性のものは原料油脂(本発明のホイップクリーム用油脂組成物)の一部または全部に添加し溶解ないし分散させて油相部を調製する。このような乳化剤としては、例えばレシチン、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、有機酸モノグリセリド等従来公知の乳化剤のうちHLBの低い乳化剤が例示でき、本発明においてはこれらのいずれを適宜組み合わせて使用してもよい。
また、バターオイル、バター、生クリーム、牛乳等を由来とする乳脂肪を用いる場合には、これらを必要に応じて加熱融解して油相物を調製して用いる。乳脂肪を含む油相部と、上述した植物性油脂からなる本発明のホイップクリーム用油脂組成物を含む油相部は、水相部に混合した後添加してもよく、また各々添加してもよい。
The oil-in-water emulsified oil / fat composition of the present invention can be produced by a general production method. When a typical method is described, the emulsifier to be used is a lipophilic raw material (oil / fat for whipped cream of the present invention). The oil phase part is prepared by adding to part or all of the composition and dissolving or dispersing. Examples of such an emulsifier include an emulsifier having a low HLB among conventionally known emulsifiers such as lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, and organic acid monoglyceride. Any of these may be used in appropriate combination.
Moreover, when using milk fat derived from butter oil, butter, fresh cream, milk or the like, these are heated and melted as necessary to prepare and use an oil phase product. The oil phase part containing milk fat and the oil phase part containing the oil composition for whipped cream of the present invention consisting of the above-described vegetable oil may be added after being mixed in the aqueous phase part, and each may be added. Also good.

次に、水相部にカゼインナトリウム、脱脂粉乳、糖類や必要に応じて、蔗糖脂肪酸エステル、クエン酸ナトリウム、トリポリりん酸ナトリウム、第二りん酸ナトリウム、重炭酸ナトリウム、ヘキサメタりん酸ナトリウム、増粘多糖類、香料などを添加し調製する。
無脂乳固形分の量は、組成物の全質量に対して、1〜10質量%であることが好ましく、更に2〜7質量%であることが好ましく、3〜6質量%であることが最も好ましい。このような範囲で添加することにより、乳化安定性が改善され、また風味が改善される場合があるからである。無脂乳固形分の含有量が約1質量%未満であると、乳化組成物を泡立てて得られるホイップクリームの風味が悪くなる。また、無脂乳固形分の含有量が約10質量%を越えると乳化組成物の粘度が高くなり、エージング中に粘度上昇が起こる恐れがある。
Next, in the aqueous phase, sodium caseinate, skim milk powder, saccharides and sucrose fatty acid ester, sodium citrate, sodium tripolyphosphate, sodium diphosphate, sodium bicarbonate, sodium hexametaphosphate, thickening as necessary Prepare by adding polysaccharides, fragrances, etc.
The amount of the non-fat milk solid content is preferably 1 to 10% by mass, more preferably 2 to 7% by mass, and 3 to 6% by mass with respect to the total mass of the composition. Most preferred. It is because the emulsion stability is improved and the flavor may be improved by adding in such a range. When the content of the non-fat milk solids is less than about 1% by mass, the flavor of the whipped cream obtained by foaming the emulsion composition becomes poor. Moreover, when content of non-fat milk solid content exceeds about 10 mass%, the viscosity of an emulsion composition will become high and there exists a possibility that a viscosity raise may occur during aging.

これら、油相部と水相部を60℃から80℃に加温し、混合して予備乳化を行う。予備乳化後、ホモゲナイザーにて均質化し、バッチ式殺菌法、または間接加熱方式あるいは直接加熱方式によるUHT滅菌処理法にて滅菌し、再びホモゲナイザーにて均質化し冷却しエージングする。
本発明の水中油型乳化油脂組成物には、甘味や粘度の調節を目的として糖類を配合してもよい。糖類としては、例えば、水飴、粉飴、ショ糖、麦芽糖、ソルビトール、マルチトール、エリスリトール、トレハロース等が挙げられ、これは必要に応じ適宜組み合わせて配合される。
These oil phase part and water phase part are heated from 60 ° C. to 80 ° C. and mixed to perform preliminary emulsification. After preliminary emulsification, the mixture is homogenized by a homogenizer, sterilized by a batch sterilization method, a UHT sterilization method using an indirect heating method or a direct heating method, homogenized again by a homogenizer, cooled and aged.
In the oil-in-water emulsified oil / fat composition of the present invention, a saccharide may be blended for the purpose of adjusting sweetness and viscosity. Examples of the saccharide include starch syrup, powdered potato, sucrose, maltose, sorbitol, maltitol, erythritol, trehalose, and the like, and these are blended in combination as appropriate.

<ホイップクリーム>
本発明において、ホイップクリームは、本発明の水中油型乳化油脂組成物を、当該技術分野において通常の方法により起泡されたものである。
以下、本発明の水中油型乳化油脂組成物を使用したホイップクリームの製造例を示すが、本発明はかかる例に限定されるものではない。
<Whipped cream>
In the present invention, the whipped cream is obtained by foaming the oil-in-water emulsified oil / fat composition of the present invention by a usual method in the art.
Hereinafter, although the manufacture example of the whipped cream which uses the oil-in-water type emulsified oil-fat composition of this invention is shown, this invention is not limited to this example.

まず、本発明の油脂組成物を融解混合等により調製する。油脂組成物に、レシチン、蔗糖脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル等の乳化剤等の任意の添加剤を加え、混合して油相を調製する。
一方、水相部として、水に、メタリン酸Na、増粘多糖類、乳蛋白等の任意の添加剤を加えた後、これらを分散させて水相を調製する。
50〜85℃にて油相と水相を混合させ、予備乳化を行う。次いで75〜85℃にて加熱殺菌をする。次いで20〜150kg/cm2の圧力下で均質化を行い、その後5〜10℃にまで冷却し、6〜24時間程度エージングを行なう。
このクリーム状油脂組成物をホバートミキサーにてホイップしてホイップクリームを得る。
First, the oil and fat composition of the present invention is prepared by melt mixing or the like. Arbitrary additives such as emulsifiers such as lecithin, sucrose fatty acid ester, sorbitan fatty acid ester and glycerin fatty acid ester are added to the oil and fat composition and mixed to prepare an oil phase.
On the other hand, as an aqueous phase part, after adding arbitrary additives, such as sodium metaphosphate, thickening polysaccharide, milk protein, to water, these are disperse | distributed and an aqueous phase is prepared.
The oil phase and the aqueous phase are mixed at 50 to 85 ° C. and pre-emulsified. Next, heat sterilization is performed at 75 to 85 ° C. Next, homogenization is performed under a pressure of 20 to 150 kg / cm 2 , and then the mixture is cooled to 5 to 10 ° C. and aged for 6 to 24 hours.
This creamy fat composition is whipped with a Hobart mixer to obtain a whipped cream.

油脂調製方法
以下の実施例で使用した油脂の内容を示す。
[第1の油脂の製造例]
極度硬化したハイエルシンナタネ50質量部、ヤシ油50質量部の混合油を油脂に対して0.143%のナトリウムメチラートを触媒とし、115℃で30分間、非選択的エステル交換反応を行い、脱色、脱臭を行い、エステル交換油脂A−1を得た。エステル交換油脂A−1の融点は46.5℃、トランス酸含有量は0.1%であった。
極度硬化したハイエルシンナタネとヤシ油の割合をそれぞれ3:7及び1:9にかえて同様にエステル交換反応、脱色、脱臭を行い、エステル交換油脂A−2,A−3をそれぞれ得た。エステル交換油脂A−2及びA−3の融点はそれぞれ40.3℃、30.2℃である、トランス酸含有量はそれぞれ0.1%、0.1%であった。
また、ヤシ油のみを同様にエステル交換反応し、脱色、脱臭を行い、エステル交換油脂A−4を作成した。エステル交換油脂A−4の融点は27.6℃であり、トランス酸含量は0.1%であった。
Oil and fat preparation method The contents of the oil and fat used in the following examples are shown.
[Example of production of first oil]
A non-selective transesterification reaction is carried out at 115 ° C. for 30 minutes using a mixed oil of 50 parts by mass of highly hardened hay rapeseed oil and 50 parts by mass of coconut oil with 0.143% sodium methylate as a catalyst for the oil and fat. Decolorization and deodorization were performed to obtain a transesterified fat / oil A-1. The melting point of the transesterified oil A-1 was 46.5 ° C., and the trans acid content was 0.1%.
Transesterification, decolorization, and deodorization were carried out in the same manner by changing the ratios of extremely hardened hyel rapeseed and coconut oil to 3: 7 and 1: 9, respectively, to obtain transesterified oils A-2 and A-3, respectively. The melting points of the transesterified fats and oils A-2 and A-3 were 40.3 ° C. and 30.2 ° C., respectively, and the trans acid contents were 0.1% and 0.1%, respectively.
Moreover, only coconut oil was transesterified similarly, and decoloring and deodorizing were performed, and transesterification fat and oil A-4 was created. The melting point of the transesterified fat / oil A-4 was 27.6 ° C., and the trans acid content was 0.1%.

[第2の油脂の製造例]
パーム核油100部に対して、0.115%のNi触媒(堺化学製 SO850)を触媒とし、水素添加反応を140℃で行い、脱色、脱臭を行って、パーム核硬化油36℃(油脂B−3)を得た。パーム核硬化油36℃の融点は35.6℃、トランス酸量は4.0%であった。
[Example of production of second oil]
For 100 parts of palm kernel oil, 0.115% Ni catalyst (SO850 made by Sakai Chemical) is used as a catalyst, hydrogenation reaction is performed at 140 ° C., decolorization and deodorization are performed, and palm kernel hardened oil 36 ° C. (oil and fat B-3) was obtained. The melting point of palm kernel hydrogenated oil 36 ° C. was 35.6 ° C., and the amount of trans acid was 4.0%.

油脂B−2(パーム核極度硬化油)は次のように製造した。パーム核油100部に対して、0.115%のNi触媒(堺化学製 SO850)を触媒とし、極度硬化処理を行い、脱色、脱臭を行って、パーム核極度硬化油(油脂B−2)を得た。油脂B−2の融点は41.0℃、トランス酸量は0.3%であった。
油脂B−1(パーム核極度硬化油エステル交換油脂)は次のように製造した。上記油脂B−2を0.114%のナトリウムメチラートを触媒とし、90℃で30分間、非選択的エステル交換反応を行い、脱色、脱臭を行って、油脂B−1を得た。油脂B−1の融点は35.2℃、トランス酸量は0.2%であった。
Oil B-2 (palm core extremely hardened oil) was produced as follows. 100 parts of palm kernel oil is 0.115% Ni catalyst (SO850 made by Sakai Chemical), and is subjected to extreme curing treatment, decolorization and deodorization, and palm kernel extreme hardening oil (oil B-2) Got. Oil B-2 had a melting point of 41.0 ° C. and a trans acid amount of 0.3%.
Oil B-1 (palm core extremely hardened oil transesterified oil) was produced as follows. The fat / oil B-2 was subjected to non-selective transesterification at 90 ° C. for 30 minutes using 0.114% sodium methylate as a catalyst, and decolorized and deodorized to obtain fat / oil B-1. Oil B-1 had a melting point of 35.2 ° C. and a trans acid amount of 0.2%.

[第3の油脂の物性及び製造例]
極度硬化ヤシ油は次のようにして製造した。
ヤシ油100部に対して、0.135%のNi触媒(堺化学製 SO850)を触媒とし、極度硬化処理を行い、脱色、脱臭を行って、極度硬化ヤシ油を得た。極度硬化ヤシ油の融点は32.0℃、トランス酸量は0.1%であった。
パームオレイン硬化油は次のようにして製造した。パームオレイン100部に対して、0.115%のNi触媒(堺化学製 SO100-A)を触媒とし、硬化処理を行い、脱色、脱臭を行って、パームオレイン硬化油を得た。パームオレイン硬化油の融点は33.1℃、トランス酸量は11.1%であった。
ハイオレイック菜種油は市販品を使用した(トランス酸量:0.7、ヨウ素価:101)。
菜種硬化油は次のようにして製造した。菜種油100部に対して、0.183%のNi触媒(堺化学製 SO100-A)を触媒とし、硬化処理を行い、脱色、脱臭を行って菜種硬化油を得た。菜種硬化油の融点は34.2℃、トランス酸は54.0%であった。
[Physical properties and production example of the third oil and fat]
Extremely hardened coconut oil was produced as follows.
With respect to 100 parts of coconut oil, 0.135% Ni catalyst (SO850 made by Sakai Chemical) was used as a catalyst, an extreme curing treatment was performed, and decolorization and deodorization were performed to obtain an extremely cured coconut oil. The extremely hardened coconut oil had a melting point of 32.0 ° C. and a trans acid amount of 0.1%.
Palm olein hydrogenated oil was produced as follows. With respect to 100 parts of palm olein, 0.115% of Ni catalyst (SO100-A manufactured by Sakai Chemical) was used as a catalyst, followed by curing treatment, decolorization and deodorization to obtain a cured palm olein oil. The melting point of the hardened palm olein oil was 33.1 ° C., and the amount of trans acid was 11.1%.
High oleic rapeseed oil was a commercial product (trans acid amount: 0.7, iodine value: 101).
The rapeseed oil was produced as follows. 100 parts of rapeseed oil was subjected to a curing treatment using 0.183% Ni catalyst (SO100-A manufactured by Sakai Chemical) as a catalyst, and decolorized and deodorized to obtain a rapeseed cured oil. The rapeseed hydrogenated oil had a melting point of 34.2 ° C. and trans acid was 54.0%.

実施例1〜13及び比較例1〜6
油脂A−3を4.444質量部、油脂B−3を39.996質量部を加え、融解混合した。これにレシチン0.22質量部、シュガーエステル0.15質量部、不飽和モノグリ0.11質量部、飽和モノグリ0.08質量部を加え油相を調製した。
一方、水50.93質量部と脱脂粉乳4.0質量部、メタリン酸Na0.07質量部を加えた後、分散させて水相を調製した。
油相と水相を混合し、65℃で予備乳化を行い、85℃にて加熱殺菌を行った。次いで、80kg/cm2、20kg/cm2の圧力下で均質化した。冷却後、5℃、1晩のエージングをした(実施例1)。
このクリーム状油脂組成物のエージング粘度は100cpであった。このクリームを500gに砂糖50gを添加し、ホバートミキサーにてホイップしたところ6分40秒でオーバーラン189%、硬度146の気泡物を得た。得られた気泡物は冷蔵保存性、ヒートショック耐性が良好であった。
Examples 1-13 and Comparative Examples 1-6
4.444 mass parts of fats and oils A-3 and 39.996 mass parts of fats and oils B-3 were added and melt-mixed. An oil phase was prepared by adding 0.22 parts by mass of lecithin, 0.15 parts by mass of sugar ester, 0.11 parts by mass of unsaturated monoguri, and 0.08 parts by mass of saturated monogly.
On the other hand, after adding 50.93 parts by mass of water, 4.0 parts by mass of skim milk powder, and 0.07 parts by mass of sodium metaphosphate, the mixture was dispersed to prepare an aqueous phase.
The oil phase and the aqueous phase were mixed, pre-emulsified at 65 ° C., and heat sterilized at 85 ° C. Then homogenized under a pressure of 80kg / cm 2, 20kg / cm 2. After cooling, it was aged at 5 ° C. overnight (Example 1).
The aging viscosity of this creamy fat composition was 100 cp. When 500 g of this cream was added with 50 g of sugar and whipped with a Hobart mixer, a foam with an overrun of 189% and a hardness of 146 was obtained in 6 minutes and 40 seconds. The obtained foam was good in refrigerated storage and heat shock resistance.

下記表に記載された油脂を、実施例1と同様に作製した(実施例2〜13及び比較例1〜6)。
作製した油脂について、それぞれ、エージング粘度、ホイップ時間、戻り硬度、ヒートショック耐性、口融けについて、以下の方法により評価した。
The fats and oils described in the following table were prepared in the same manner as in Example 1 (Examples 2 to 13 and Comparative Examples 1 to 6).
About the produced fats and oils, the aging viscosity, whipping time, return hardness, heat shock resistance, and mouth melting were evaluated by the following methods, respectively.

エージング粘度
水中油型乳化油脂組成物を、5.1℃で一晩静置してエージングを行い、500mlのビーカーに水中油型乳化油脂組成物を500g入れ、B型粘度計(BROOK FIELD社製粘度計のLVT)(スピンドル2番)で30秒経過時の値を測定した。
エージング粘度が120cp以下である場合に満足する性能を有すると評価した。
Aging viscosity Oil-in-water emulsified oil / fat composition is allowed to stand at 5.1 ° C. overnight, and 500 g of oil-in-water emulsified oil / fat composition is placed in a 500 ml beaker. Viscometer LVT) (spindle # 2) was measured for 30 seconds.
When the aging viscosity was 120 cp or less, it was evaluated as having satisfactory performance.

ホイップ時間
水中油型乳化油脂組成物(クリーム)500gに砂糖を50g加え、5.0℃に温調し、10分立て(硬度140〜160)となるまでホバートミキサーにて速度2にてホイップした。ホイップにかかる時間(10分立てまでの時間)を記載した。
ホイップ時間が5.0分以上である場合に満足する性能を有すると評価した。
Whip time 50 g of sugar was added to 500 g of an oil-in-water emulsified oil / fat composition (cream), temperature-controlled at 5.0 ° C., and whipped at speed 2 with a Hobart mixer until 10 minutes standing (hardness 140-160). . The time required for whipping (time until 10 minutes) was described.
It was evaluated as having satisfactory performance when the whipping time was 5.0 minutes or longer.

翌日戻り試験
ホイップクリーム(10分立て)を三角袋に詰めて500mlビーカーに絞り、5.0℃にて1晩置き、翌日の硬度を測定した。
戻り硬度が90以上である場合に満足する性能を有すると評価した。
Next day return test Whipped cream (10 minutes standing) was packed in a triangular bag, squeezed into a 500 ml beaker, placed at 5.0 ° C. overnight, and the hardness of the next day was measured.
It was evaluated that it had satisfactory performance when the return hardness was 90 or more.

ヒートショック試験
牛乳瓶にホイップ前の水中油型乳化油脂組成物を約150g入れ、25℃の恒温槽に1時間入れ、その後、5℃の恒温槽に6時間保存した。保存後、粘度を評価した。これらの評価は、乳化安定性の指標となる。
B型粘度計…No.3ローター(スピンドル3番)でスピード30にて5分後の粘度を測定した。また。固化または粘度測定不能時には、その時間を測定した。
ヒートショック試験後の粘度が400以下である場合に満足する性能を有すると評価した。
Heat shock test About 150 g of the oil-in-water emulsified oil / fat composition before whipping was put in a milk bottle, placed in a thermostatic bath at 25 ° C. for 1 hour, and then stored in a thermostatic bath at 5 ° C. for 6 hours. After storage, the viscosity was evaluated. These evaluations are indicators of emulsion stability.
B-type viscometer: The viscosity after 5 minutes was measured at a speed of 30 with a No. 3 rotor (spindle No. 3). Also. When solidification or viscosity measurement was not possible, the time was measured.
When the viscosity after the heat shock test was 400 or less, it was evaluated that the performance was satisfactory.

口融け評価
専門パネラー5名により、ホイップクリーム(10分立て)を実際に食して口融けを下記の基準により評価した。
◎…非常に良好
○…普通
×…悪い
Mouth melting evaluation panelists evaluated the melting of the mouth according to the following criteria by actually eating whipped cream (10 minutes).
◎… very good ○… normal ×… bad

油脂組成物の分析方法は以下の方法により行った。
・脂肪酸組成、トランス脂肪酸含量
基準油脂分析法(暫17-2007 トランス脂肪酸含量 キャピラリーガスクロマトグラフ法)に準じて測定した。
ガスクロマトグラフィー装置は、島津製作所(株)製、GC-2010型。カラムは、SUPELCO社製、SP-2560。
・上昇融点
基準油脂分析法(2.2.4.2-1996 融点 上昇融点)に準じて測定した。
The analysis method of the oil and fat composition was performed by the following method.
-Fatty acid composition, trans fatty acid content Measured according to the standard fat analysis method (provisional 17-2007 trans fatty acid content capillary gas chromatographic method).
The gas chromatography system is GC-2010, manufactured by Shimadzu Corporation. The column is SP-2560 manufactured by SUPELCO.
-Rising melting point Measured according to the standard fat and oil analysis method (2.2.4.2-1996 melting point rising melting point).

上記評価結果を表1〜3に示した。各表において「%」は質量%を意味する。
表1〜3の結果から、本発明のホイップクリーム用油脂組成物から製造される水中油型乳化油脂組成物が、乳化安定性(エージング粘度、戻り硬度、ヒートショック耐性)、ホイップクリーム製造時の口融けにおいてバランスのとれた優れた組成物であることがわかる(実施例1〜13)。
一方、第1の油脂である油脂を用いず、C22の脂肪酸を全く含まない油脂組成物を用いたホイップクリーム用油脂組成物は、ヒートショック耐性を示さず、粘度が非常に上昇してしまった(比較例1、比較例4)。
また、油脂組成物全質量に対して、第2の油脂を22質量%以下である場合には、戻り硬度が低減してしまい、ホイップクリームとして充分な性能を示さなかった(比較例2及び3)。
第1の油脂としてヤシ油と極度硬化ハイエルシン菜種油の質量比が、5:5のエステル交換油脂を20質量%用いた場合、油脂組成物全体の融点が36℃となり、口融けが低下した(比較例5)。
また、本発明の第1の油脂も第2の油脂も用いない場合であっても、乳化安定性と口融けのバランスの良い油脂組成物を作成することは可能であるが(例えば比較例6)、トランス酸量を5%以下程度に低く抑えることは難しい。
The said evaluation result was shown to Tables 1-3. In each table, “%” means mass%.
From the results of Tables 1 to 3, the oil-in-water emulsified oil / fat composition produced from the whipped cream oil / fat composition of the present invention has an emulsion stability (aging viscosity, return hardness, heat shock resistance), and whipped cream production. It turns out that it is the composition excellent in the balance in melting (Examples 1-13).
On the other hand, the oil and fat composition for whipped cream using the oil and fat composition which does not use the first oil and fat and does not contain any fatty acid of C22 does not exhibit heat shock resistance, and the viscosity has increased significantly. (Comparative Example 1 and Comparative Example 4).
Moreover, when the 2nd fats and oils were 22 mass% or less with respect to fats and oils composition total mass, return hardness reduced and it did not show sufficient performance as a whipped cream (Comparative Examples 2 and 3). ).
When the mass ratio of coconut oil and extremely hardened Hyelsin rapeseed oil of 5: 5 was used as the first fat / oil, 20% by mass of the transesterified fat / oil, the melting point of the whole fat / oil composition became 36 ° C., and the melting of the mouth decreased (Comparison Example 5).
Even when neither the first fat nor the second fat according to the present invention is used, it is possible to prepare an oil composition having a good balance between emulsification stability and melting (for example, Comparative Example 6). ), It is difficult to keep the amount of trans acid as low as 5% or less.

Figure 2012065580
Figure 2012065580

Figure 2012065580
Figure 2012065580

Figure 2012065580
Figure 2012065580

Claims (10)

少なくとも2種類の油脂を含むホイップクリーム用油脂組成物であって、
(1)(A)第1の油脂が、ヤシ油と極度硬化ハイエルシン菜種油を4:6〜9:1の範囲で混合し、エステル交換したエステル交換油脂、及び(B)前記油脂(A)とヤシ油100%をエステル交換した油脂との混合油脂から選択される油脂であり、
(2)第2の油脂が、パーム核油の極度硬化油脂あるいは部分水素添加油脂であって、融点が30℃以上の油脂からなり、及び
(3)油脂組成物の全構成脂肪酸100質量%に対してC22の脂肪酸含有量が0.5〜4.5質量%であり、油脂組成物全質量に対して、第2の油脂が22質量%以上の量で含まれており、かつ融点が36℃以下である、上記油脂組成物。
A fat composition for whipped cream comprising at least two types of fats and oils,
(1) (A) The first fat / oil is a mixture of coconut oil and extremely hardened Hyelsin rapeseed oil in the range of 4: 6 to 9: 1 and transesterified, and (B) the fat (A) It is a fat selected from a mixed fat with a fat obtained by transesterification of 100% coconut oil,
(2) The second fat / oil is an extremely hardened fat / partially hydrogenated fat / oil of palm kernel oil, and has a melting point of 30 ° C. or higher, and
(3) The fatty acid content of C22 is 0.5 to 4.5% by mass with respect to 100% by mass of the total constituent fatty acids of the oil / fat composition, and the second oil / fat is 22% by mass with respect to the total mass of the oil / fat composition. % Of the oil and fat composition, which is contained in an amount of not less than% and has a melting point of 36 ° C. or less.
第1の油脂と第2の油脂の質量比が10:90〜78:22の比である、請求項1に記載の油脂組成物。   The oil and fat composition according to claim 1, wherein the mass ratio of the first oil and fat to the second oil and fat is a ratio of 10:90 to 78:22. 第1の油脂と第2の油脂の合計含有量が65質量%以上の量で含まれる、請求項1または2に記載の油脂組成物。   The fat composition according to claim 1 or 2, wherein the total content of the first fat and the second fat is contained in an amount of 65% by mass or more. 更に、極度硬化ヤシ油、パームオレイン硬化油、またはハイオレイック菜種油を含む、請求項1〜3のいずれか一項に記載の油脂組成物。   Furthermore, the fats-and-oils composition as described in any one of Claims 1-3 containing extremely hardened coconut oil, palm olein hardened oil, or high oleic rapeseed oil. 水相部と油相部からなり、前記油相部が請求項1〜4のいずれか一項に記載の油脂組成物を含むことを特徴とする、水中油型乳化油脂組成物。   An oil-in-water emulsified oil / fat composition comprising an aqueous phase part and an oil phase part, wherein the oil phase part comprises the oil / fat composition according to any one of claims 1 to 4. 水中油型乳化油脂組成物質量に対する油相部の質量が20%〜50%であることを特徴とする、請求項5記載の水中油型乳化油脂組成物。   The oil-in-water emulsified oil / fat composition according to claim 5, wherein the mass of the oil phase part relative to the amount of the oil-in-water emulsified oil / fat composition is 20% to 50%. 油相部が更に乳脂肪を含むことを特徴とする、請求項5または6に記載の水中油型乳化油脂組成物。   The oil-in-water emulsified oil / fat composition according to claim 5 or 6, wherein the oil phase part further contains milk fat. 乳脂肪と請求項1〜4のいずれか一項に記載の油脂組成物の質量比が0:100〜80:20の範囲であることを特徴とする、請求項5〜7のいずれか一項に記載の水中油型乳化油脂組成物。   The mass ratio of the fat and fat composition according to any one of claims 1 to 4 is in the range of 0: 100 to 80:20, and any one of claims 5 to 7 is characterized. The oil-in-water emulsified oil / fat composition described in 1. 請求項5〜8のいずれか一項に記載の水中油型乳化油脂組成物の、ホイップクリーム製造における使用。   Use of the oil-in-water emulsified oil / fat composition according to any one of claims 5 to 8 in the manufacture of whipped cream. 請求項5〜8のいずれか一項に記載の水中油型乳化油脂組成物を用いて製造されたホイップクリーム。   Whipping cream manufactured using the oil-in-water type emulsified oil-fat composition as described in any one of Claims 5-8.
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JP2014233241A (en) * 2013-05-31 2014-12-15 太陽油脂株式会社 Fat composition for whipped cream
JP2016208970A (en) * 2015-05-01 2016-12-15 太陽油脂株式会社 Oil and fat composition for frozen whip cream
JP2020068699A (en) * 2018-10-30 2020-05-07 太陽油脂株式会社 Oil/fat composition for frozen whipped cream

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009057451A1 (en) * 2007-10-30 2009-05-07 Fuji Oil Company, Limited Fat composition for chocolate coatings
JP2009284869A (en) * 2008-05-30 2009-12-10 Taiyo Yushi Kk Oil-in-water emulsified oil-and-fat composition for whipped-cream

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009057451A1 (en) * 2007-10-30 2009-05-07 Fuji Oil Company, Limited Fat composition for chocolate coatings
JP2009284869A (en) * 2008-05-30 2009-12-10 Taiyo Yushi Kk Oil-in-water emulsified oil-and-fat composition for whipped-cream

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014233241A (en) * 2013-05-31 2014-12-15 太陽油脂株式会社 Fat composition for whipped cream
JP2016208970A (en) * 2015-05-01 2016-12-15 太陽油脂株式会社 Oil and fat composition for frozen whip cream
JP2020068699A (en) * 2018-10-30 2020-05-07 太陽油脂株式会社 Oil/fat composition for frozen whipped cream
WO2020090208A1 (en) * 2018-10-30 2020-05-07 太陽油脂株式会社 Oil or fat composition for frozen whipped cream
JP7382709B2 (en) 2018-10-30 2023-11-17 太陽油脂株式会社 Oil and fat composition for frozen whipped cream

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