JP5444972B2 - Oil composition for whipped cream - Google Patents

Oil composition for whipped cream Download PDF

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JP5444972B2
JP5444972B2 JP2009207830A JP2009207830A JP5444972B2 JP 5444972 B2 JP5444972 B2 JP 5444972B2 JP 2009207830 A JP2009207830 A JP 2009207830A JP 2009207830 A JP2009207830 A JP 2009207830A JP 5444972 B2 JP5444972 B2 JP 5444972B2
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JP2011055752A (en
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和一郎 小柳
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Taiyo Yushi Corp
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本発明は、流通時の温度が変化する条件、特に低温流通を行っても、乳化安定性に優れており、かつ口溶けがよいホイップクリームを製造することができる、低油分ホイップクリーム用油脂組成物に関する。   The present invention is a low-oil whipped cream oil and fat composition that can produce a whipped cream that is excellent in emulsion stability and melts well even under low temperature conditions, particularly under conditions where the temperature during distribution changes. About.

従来から、製菓や料理に用いられるホイップクリームとして、植物性油脂を原料として製造される植物性クリーム(水中油型乳化物)を用いることが知られている。植物性クリームは生乳から得られる生クリームに比べて安定性に優れ、かつ比較的安価に製造されるという利点を有するためにその消費量は多い。
この植物性クリームから製造されるホイップクリームについては、起泡した状態のホイップクリームを冷凍で流通させるもの、起泡した状態のホイップクリームを常温で流通させるもの、あるいは、起泡前のクリームの状態で流通させ、起泡してから短時間のうちに消費させるものなどがあり、クリームの味、口溶け、起泡時の性能についての要求は、同じホイップクリームでありながら、その流通態様によりかなり異なっている。また、クリームの組成は、ホイップクリームの状態で流通させるか否か、更には流通させる温度によっても全く異なってくるが、これは、ホイップクリームが泡状であって長時間の保形が困難であり、更に常温で細菌が繁殖しやすいなどの問題があるからである。
例えば、常温流通型ホイップクリームでは、炭素数が高い(例えば、炭素数合計50〜62)トリグリセライドのような比較的高融点の油脂を用いることにより、あるいは常温での保形性を維持し、更に大量の水飴を用いて、保形性及び細菌の繁殖を抑制している(例えば特許文献1参照)。
起泡後、凍結して流通させる凍結用ホイップクリームを製造するための油脂組成物として、パーム核油分別高融点部を用いることにより、解凍後、良好な保形性をもつ凍結用ホイップクリームを製造できることが報告されている(特許文献2参照)。
Conventionally, it is known to use vegetable creams (oil-in-water emulsions) produced using vegetable oils and fats as whipped creams used in confectionery and cooking. Since vegetable cream has the advantage of being excellent in stability and being manufactured at a relatively low cost compared to fresh cream obtained from raw milk, its consumption is large.
About the whipped cream produced from this vegetable cream, the whipped cream in a foamed state is circulated by freezing, the whipped cream in a foamed state is circulated at room temperature, or the state of the cream before foaming There are things that can be distributed in a short time after foaming, etc., and the requirements for the taste of the cream, melting in the mouth, foaming performance are quite different depending on the distribution mode even though it is the same whipped cream ing. The composition of the cream is completely different depending on whether or not it is circulated in the state of whipped cream, and further, depending on the temperature at which it is circulated. This is because the whipped cream is foamy and it is difficult to keep the shape for a long time. In addition, there is a problem that bacteria are likely to propagate at room temperature.
For example, in a normal temperature circulation type whipped cream, by using a relatively high melting point oil and fat such as triglyceride having a high carbon number (for example, a total carbon number of 50 to 62), or maintaining the shape retention at normal temperature, A large amount of water tanks are used to suppress shape retention and bacterial growth (see, for example, Patent Document 1).
As a fat and oil composition for producing frozen whipped cream to be frozen and distributed after foaming, a whipped cream for freezing having good shape retention after thawing is obtained by using a palm kernel oil fractionation high melting point part. It has been reported that it can be manufactured (see Patent Document 2).

特開2007−282535号JP 2007-282535 A 特開2006−304713号JP 2006-304713 A

本発明は、水中油型乳化油脂組成物の状態で低温(5〜10℃)流通させるホイップクリーム用水中油型乳化油脂組成物であって、起泡性、口溶けに優れており、かつ流通時の温度変化に対しても安定性を有する組成物及びかかる水中油型乳化油脂組成物を製造するための油脂組成物を提供することを目的とする。
本発明はまた、低油分(30〜42%油分)であっても、流通時の温度変化に対しても安定性に優れたホイップクリーム用水中油型乳化油脂組成物及びかかる組成物製造のための油脂組成物を提供することを目的とする。
The present invention is an oil-in-water emulsified oil / fat composition for whipped cream that is circulated at a low temperature (5 to 10 ° C.) in the state of an oil-in-water emulsified oil / fat composition, and has excellent foaming properties and meltability in the mouth. It aims at providing the oil-and-fat composition for manufacturing the composition which has stability also with respect to a temperature change, and this oil-in-water type emulsified oil-and-fat composition.
The present invention also provides an oil-in-water emulsified oil / fat composition for whipped cream, which has a low oil content (30-42% oil content) and is excellent in stability against temperature changes during distribution, and the production of such a composition. It aims at providing an oil-and-fat composition.

本発明者らは、上記の点に鑑み研究した結果、少なくとも2種類の油脂成分を含むホイップクリーム用油脂組成物であって、(A)第1の油脂が、パーム核分別油高融点部からなり、(B)第2の油脂が、ヤシ油をランダムエステル交換処理した油脂、ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂、パーム核油と他の油脂の混合油をランダムエステル交換処理した油脂、及び液体油からなる群より選択される油脂であって、及び(C)油脂組成物の全トリグリセライド100質量%に対してC50のトリグリセライド含有量が2質量%以下であり、かつ油脂組成物の上昇融点が31℃以下の油脂である、上記油脂組成物を用いることにより、上記目的を達成することができるという知見を得て、本発明を完成するに至った。 As a result of studies conducted in view of the above points, the inventors of the present invention are oil and fat compositions for whipped cream containing at least two types of oil and fat components, wherein (A) the first oil and fat is from a palm core fractionated oil high melting point portion. (B) The second fat / oil is a fat / oil obtained by random transesterification of coconut oil, a fat / oil obtained by random transesterification of a mixed oil of coconut oil and other fat / oil, and a mixed oil of palm kernel oil and other fat / oil. A fat and oil selected from the group consisting of a transesterified oil and a liquid oil, and (C) the triglyceride content of C50 is 2% by mass or less with respect to 100% by mass of the total triglyceride of the oil and fat composition; And the rising melting | fusing point of an oil-fat composition obtained the knowledge that the said objective can be achieved by using the said oil-fat composition which is fats and oils of 31 degrees C or less, and came to complete this invention.

本明細書において、「ホイップクリーム」は起泡した水中油型乳化油脂組成物(起泡済クリーム状組成物)を意味する。「ホイップクリーム用水中油型乳化油脂組成物」は起泡前のクリーム状の水中油型乳化油脂組成物を意味する。「ホイップクリーム用油脂組成物」は、ホイップクリーム用水中油型乳化油脂組成物を製造するために用いられる油脂組成物」を意味する。   In the present specification, “whipped cream” means a foamed oil-in-water emulsified oil / fat composition (foamed cream-like composition). The “oil-in-water emulsified oil / fat composition for whipped cream” means a creamy oil-in-water emulsified oil / fat composition before foaming. “Oil composition for whipped cream” means “oil composition used for producing an oil-in-water emulsified oil composition for whipped cream”.

すなわち、本発明は、少なくとも2種類の油脂成分を含むホイップクリーム用油脂組成物であって、(A)第1の油脂が、パーム核分別油高融点部からなり、(B)第2の油脂が、ヤシ油をランダムエステル交換処理した油脂、ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂、パーム核油と他の油脂の混合油をランダムエステル交換処理した油脂、液体油、及びパーム核油からなる群より選択され、及び(C)油脂組成物の全トリグリセライド100質量%に対してC50のトリグリセライド含有量が5質量%以下である、上記油脂組成物を提供する。かかる油脂組成物により、5℃程度の低温で保存しても、粘度の上昇や離水などがおきず乳化安定性に優れたホイップクリーム用水中油型乳化油脂組成物を製造することができ、更に口溶け、造花性、起泡性、に優れたホイップクリームを製造することができる。
また、前記油脂組成物中の油脂の全構成脂肪酸質量に対するトランス脂肪酸含量は7質量%以下、より好ましくは3質量%以下、更に好ましくは1質量%以下である。
That is, the present invention is an oil / fat composition for whipped cream comprising at least two types of oil / fat components, wherein (A) the first oil / fat comprises a palm core fractionated oil high melting point part, and (B) the second oil / fat. However, oil obtained by random transesterification of coconut oil, oil obtained by random transesterification of mixed oil of coconut oil and other oils, oil obtained by random transesterification of mixed oil of palm kernel oil and other oils, liquid oil, The oil composition is selected from the group consisting of palm kernel oil, and (C) the triglyceride content of C50 is 5% by mass or less with respect to 100% by mass of the total triglyceride of the oil composition. Such an oil / fat composition can produce an oil-in-water emulsified oil / fat composition for whipped cream that has excellent emulsification stability without increasing viscosity or water separation even when stored at a low temperature of about 5 ° C. It is possible to produce a whipped cream having excellent flower-forming properties and foaming properties.
Moreover, the trans fatty acid content is 7% by mass or less, more preferably 3% by mass or less, and still more preferably 1% by mass or less with respect to the total constituent fatty acid mass of the oil / fat in the oil / fat composition.

本発明により、低温流通時に起こりやすい温度変化に対して乳化安定性に優れ、かつ口溶け、造花性、起泡性等に優れたホイップクリームを製造することができるホイップクリーム用水中油型乳化油脂組成物が提供される。
特に、本発明のホイップクリーム用水中油型乳化油脂組成物は高いヒートショック耐性を有し、流通時の温度変化に耐えて乳化安定性を示す一方で、ホイップクリームを製造した時、優れた口溶けを実現するため、従来製品に比べて、非常に優れた商品価値を与えるものである。
According to the present invention, an oil-in-water emulsified oil / fat composition for whipped cream capable of producing a whipped cream that has excellent emulsification stability with respect to temperature changes that are likely to occur during low-temperature circulation, and that is excellent in mouth melting, flower-forming properties, foaming properties, etc. Is provided.
In particular, the oil-in-water emulsified oil / fat composition for whipped cream of the present invention has high heat shock resistance, and resists temperature change during distribution and exhibits emulsification stability. In order to achieve this, it provides a very superior commercial value compared to conventional products.

<ホイップクリーム用油脂組成物>
本発明のホイップクリーム用油脂組成物は、少なくとも2種類の油脂成分を含むホイップクリーム用油脂組成物であって、(A)第1の油脂が、パーム核分別油高融点部からなり、(B)第2の油脂が、ヤシ油をランダムエステル交換処理した油脂、ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂、パーム核油と他の油脂の混合油をランダムエステル交換処理した油脂、液体油、及びパーム核油からなる群より選択される油脂であって、及び(C)油脂組成物の全トリグリセライド100質量%に対してC50のトリグリセライド含有量が5質量%以下であり、かつ油脂組成物の上昇融点が31℃以下の油脂であることを特徴とする。
<Oil composition for whipped cream>
The whipped cream oil / fat composition of the present invention is a whipped cream oil / fat composition containing at least two types of oil / fat ingredients, wherein (A) the first oil / fat comprises a palm core fractionated oil high melting point part, (B ) The second oil / fat was obtained by random transesterification of palm oil, oil / fat obtained by random transesterification of a mixed oil of palm oil and other oils, and random transesterification of a mixed oil of palm kernel oil and other oils / fats. An oil or fat selected from the group consisting of oil and fat, liquid oil, and palm kernel oil, and (C) the triglyceride content of C50 is 5% by mass or less with respect to 100% by mass of the total triglyceride of the oil and fat composition, And the rising melting | fusing point of an oil-fat composition is 31 degrees C or less, It is characterized by the above-mentioned.

なお、本発明のホイップクリーム用油脂組成物から水中油型乳化油脂組成物を作成する際には、後述するように油相部に乳脂肪を添加することができるが、本明細書において「ホイップクリーム用油脂組成物」あるいは「油脂組成物」という場合には、特に断らない限り、植物性油脂(すなわち、乳脂肪を除く油脂)からなる油脂組成物を意味する。
油脂全質量(植物性油脂と乳脂肪の合計質量)に対して本発明のホイップクリーム用油脂組成物(植物性油脂)の質量は30〜100質量%であり、好ましくは50〜100質量%である。乳脂肪が多すぎると造花性が悪くなり、荒れやすくなる。
In preparing an oil-in-water emulsified oil / fat composition from the whipped cream oil / fat composition of the present invention, milk fat can be added to the oil phase part as described later. The term “oil composition for cream” or “oil composition” means an oil composition composed of vegetable oils (ie, fats and oils excluding milk fat) unless otherwise specified.
The mass of the oil / fat composition for whipped cream (vegetable oil / fat) of the present invention is 30-100% by mass, preferably 50-100% by mass, based on the total mass of the oil / fat (total mass of vegetable oil / fat and milk fat). is there. If there is too much milk fat, artificial flower property will worsen and it will become rough easily.

(1)第1の油脂
本発明の油脂組成物において、第1の油脂はパーム核分別油高融点部からなる。「パーム核分別高融点部」とは、パーム核油を自然分別、溶剤分別、界面活性剤分別等の分別方法により高融点部と低融点部に2分割して得られた高融点部を意味する(分別収率は30〜50%)。前記高融点部の融点範囲は、28〜35℃であることが好ましく、29〜34℃であることがより好ましく、30〜33℃であることがさらに好ましい。
第1の油脂は、油脂組成物の質量に対して、20〜80質量%の範囲で含まれることが好ましく、30〜80質量%の範囲で含まれることがより好ましく、40〜70質量%の範囲であることが更に好ましい。
第1の油脂量が少なくなると、ホイップ時の腰が弱くなり、また乳化安定性も低下する傾向にあるため好ましくない。
(1) 1st fats and oils In the fats and oils composition of this invention, 1st fats and oils consist of a palm core fractionation oil high melting | fusing point part. "Palm kernel fractionation high melting point part" means a high melting point part obtained by dividing palm kernel oil into a high melting point part and a low melting point part by a fractionation method such as natural fractionation, solvent fractionation, and surfactant fractionation. (Fractionation yield is 30-50%). The melting point range of the high melting point portion is preferably 28 to 35 ° C, more preferably 29 to 34 ° C, and further preferably 30 to 33 ° C.
It is preferable that 1st fats and oils are contained in the range of 20-80 mass% with respect to the mass of an oil-fat composition, It is more preferable that it is contained in the range of 30-80 mass%, 40-70 mass% More preferably, it is in the range.
If the amount of the first oil / fat is decreased, the waist during whipping is weakened and the emulsion stability tends to be lowered, which is not preferable.

(2)第2の油脂
第2の油脂は、
(i)ヤシ油をランダムエステル交換処理した油脂、
(ii)ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂、
(iii)パーム核油と他の油脂の混合油をランダムエステル交換処理した油脂、
(iv)液体油、及び
(v)パーム核油
からなる群より選択される。第2の油脂は上記油脂群より2種類以上を選択して混合してもよい。
(2) Second oil and fat The second oil and fat is
(i) fats and oils obtained by random transesterification of coconut oil,
(ii) oils and fats obtained by random transesterification of a mixed oil of coconut oil and other oils and fats,
(iii) Oils and fats obtained by random transesterification of a mixed oil of palm kernel oil and other oils and fats,
(iv) liquid oil, and
(v) selected from the group consisting of palm kernel oil. You may select and mix 2 or more types of 2nd fats and oils from the said fat group.

更に、第2の油脂は、上昇融点が31℃以下である油脂を用いることが好ましい。これより高い上昇融点の油脂を第2の油脂として用いると、油脂組成物全体の上昇融点が高くなり、ホイップクリームの口溶けが悪くなるからである。
また、より好ましくは、第2の油脂のステアリン酸含量は9質量%以下である。そのような油脂を第1の油脂に混合することにより、ホイップクリームの口溶けが良くなるためである。
Furthermore, it is preferable to use fats and oils whose rising melting point is 31 ° C. or less as the second fats and oils. This is because when an oil having a higher melting point than this is used as the second oil, the rising melting point of the entire oil and fat composition is increased, and the melting of the whipped cream is worsened.
More preferably, the stearic acid content of the second fat is 9% by mass or less. This is because mixing such oil and fat with the first oil and fat improves the melting of the whipped cream.

(A)パーム核分別油高融点部からなる油脂を第1の油脂として用いて、かつ(B)これらの群より選択される油脂を第2の油脂として用い、(C)油脂組成物の全トリグリセライド100質量%に対してC50のトリグリセライド含有量が2質量%以下であり、かつ油脂組成物の上昇融点が31℃以下の油脂組成物を用いることにより、起泡性、口溶けに優れており、かつ流通時の温度変化に対しても安定性を有する水中油型乳化油脂組成物を得ることができる。
第2の油脂は、油脂組成物の質量に対して20〜70質量%含まれることが好ましい。
(A) Using fat and oil consisting of the high melting point part of palm kernel fractionated oil as the first fat, and (B) Using fat and oil selected from these groups as the second fat and oil, (C) All of the fat and oil composition By using an oil or fat composition in which the triglyceride content of C50 is 2% by mass or less with respect to 100% by mass of triglyceride and the rising melting point of the oil or fat composition is 31 ° C. or less, the foaming property and melting in the mouth are excellent. And the oil-in-water type emulsified oil-fat composition which has stability also with respect to the temperature change at the time of distribution | circulation can be obtained.
It is preferable that 20-70 mass% of 2nd fats and oils are contained with respect to the mass of an oil-fat composition.

口溶けとヒートショックの観点から、第2の油脂としてより好ましくは、ラウリン油脂のエステル交換油、中鎖脂肪酸トリグリセライドであり、最も好ましくは(i)ヤシ油をランダムエステル交換処理した油脂である。
ただし、(i)ヤシ油をランダムエステル交換処理した油脂量が多くなると、ホイップ時の腰が弱くなり、また乳化安定性も悪くなる傾向にある。
From the viewpoint of melting in the mouth and heat shock, the second fat is more preferably transesterified oil of lauric fat or oil and medium-chain fatty acid triglyceride, and most preferably (i) fat obtained by random transesterification of coconut oil.
However, (i) when the amount of fats and oils obtained by random transesterification of coconut oil increases, the waist during whipping becomes weak and the emulsification stability tends to deteriorate.

上記(ii)ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂における他の油脂は、ハイエルシン菜種油の極度硬化油、パーム分別油高融点部、中鎖脂肪酸トリグリセライドからなる群より選択されることが好ましい。
上記(ii)ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂における、ヤシ油と他の油脂の比率(質量比)は、50:50〜100:0であることが好ましく、50:50〜90:10であることがより好ましく、80:20〜90:10であることが更に好ましい。
また、上記(ii)ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂における、他の油脂が、ハイエルシン菜種油の極度硬化油、またはパーム分別油高融点部である場合には、ヤシ油と他の油脂の比率(質量比)は、80:20〜100:0であることが好ましく、85:15〜95:5であることがより好ましい。ハイエルシン菜種油の極度硬化油、またはパーム分別油高融点部の量が多くなると口溶けが悪くなるため好ましくない。
The other fats and oils in the (ii) oil and fat obtained by random transesterification treatment of a mixed oil of coconut oil and other fats and oils are selected from the group consisting of a highly hardened oil of hay rapeseed rapeseed oil, a palm fractionated oil high melting point part, and a medium chain fatty acid triglyceride. It is preferable.
The ratio (mass ratio) of coconut oil and other fats and oils in the fat and oil obtained by randomly transesterifying the mixed oil of coconut oil and other fats is preferably 50:50 to 100: 0, : 50 to 90:10 is more preferable, and 80:20 to 90:10 is more preferable.
In addition, in the above (ii) oil and fat obtained by random transesterification of a mixed oil of coconut oil and other oils and fats, when the other oil or fat is an extremely hardened oil of Hyelin rapeseed oil or a palm fractionated oil high melting point part, The ratio (mass ratio) of the oil and other fats is preferably 80:20 to 100: 0, and more preferably 85:15 to 95: 5. If the amount of the highly hardened oil of the hay rapeseed oil or the high melting point part of the palm fractionated oil is increased, the meltability in the mouth deteriorates, which is not preferable.

また、上記(ii)ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂における、他の油脂が、中鎖脂肪酸トリグリセライドである場合には、ヤシ油と他の油脂の比率(質量比)は、50:50〜95:5であることが好ましく、70:30〜95:5であることがより好ましい。ただし、中鎖脂肪酸トリグリセライドは比較的高コストであるため、大量に使用することは好ましくない。   In addition, when the other fat / oil is a medium-chain fatty acid triglyceride in the fat / oil obtained by random transesterification of the mixed oil of the coconut oil and the other fat / oil (ii), the ratio (mass ratio) of the coconut oil and the other fat / oil. ) Is preferably 50:50 to 95: 5, and more preferably 70:30 to 95: 5. However, since medium chain fatty acid triglycerides are relatively expensive, it is not preferable to use them in large quantities.

上記(iii)パーム核油と他の油脂の混合油をランダムエステル交換処理した油脂における他の油脂は、ハイエルシン菜種油の極度硬化油、パーム分別油高融点部、中鎖脂肪酸トリグリセライドからなる群より選択されることが好ましい。
上記(iii)パーム核油と他の油脂の混合油をランダムエステル交換処理した油脂における、パーム核油と他の油脂の比率(質量比)は、50:50〜95:5であることが好ましく、80:20〜90:10であることがより好ましい。
(Iii) Other fats and oils in the oil obtained by random transesterification of a mixed oil of palm kernel oil and other fats and oils are selected from the group consisting of a highly hardened oil of Hyelsin rapeseed oil, a high melting point part of palm fractionated oil, and a medium chain fatty acid triglyceride It is preferred that
The ratio (mass ratio) of palm kernel oil and other fats and oils in the fat and oil obtained by random transesterification of the mixed oil of palm kernel oil and other fats is preferably 50:50 to 95: 5. 80:20 to 90:10 is more preferable.

油脂のエステル交換の方法は当該技術分野で公知の方法で行うことができる。エステル交換には、例えば、ランダム(非選択的)エステル交換反応方法、選択型(指向型)エステル交換反応方法がある(参考文献:安田耕作、福永良一郎、松井宣也、渡辺正男、新版 油脂製品の知識、幸書房)、本発明では、ランダムエステル交換反応方法が好ましい。ランダムエステル交換は、例えば、ナトリウムメチラート、水酸化ナトリウム等を触媒としてエステル交換を行う化学的な方法、非選択的リパーゼ等を触媒としてエステル交換を行う酵素的な方法に従って行うことができる。特に、化学的な方法でランダムエステル交換反応を行うことにより、簡便であるため、より好ましい。   The method of transesterification of fats and oils can be performed by a method known in the art. Examples of transesterification include random (non-selective) transesterification methods and selective (directed) transesterification methods (reference documents: Kosaku Yasuda, Ryoichiro Fukunaga, Nobuya Matsui, Masao Watanabe, new edition oil and fat products) In the present invention, a random transesterification reaction method is preferred. Random transesterification can be performed, for example, according to a chemical method in which transesterification is performed using sodium methylate, sodium hydroxide or the like as a catalyst, or an enzymatic method in which transesterification is performed using non-selective lipase or the like as a catalyst. In particular, it is more preferable to perform a random transesterification reaction by a chemical method because it is simple.

本明細書において(iv)液体油とは、5℃におけるSFC(固体脂含量:基準油脂分析法(2.2.9-2003 固体脂含量 NMR法)に準じて測定)が0である油脂を意味する。具体的には、コメ油、オリーブ油、サフラワー油、大豆油、コーン油、ナタネ油、ヒマワリ油、綿実油、ハイオレイックヒマワリ油、ハイオレイックナタネ油、ハイオレイックサフラワー油、及び中鎖脂肪酸トリグリセライドが挙げられる。好ましくは、コメ油、ナタネ油、及び中鎖脂肪酸トリグリセライドが挙げられ、更に好ましくはコメ油及び中鎖脂肪酸トリグリセライドが挙げられる。
本明細書において、中鎖脂肪酸トリグリセライドとは、脂肪酸とグリセリンから合成される合成油脂であり、脂肪酸組成がC−8とC−10からなる油脂をいう。C−8とC−10の割合は100:0〜50:50程度であることが好ましい。
In this specification, (iv) liquid oil means an oil whose SFC (solid fat content: measured according to the standard fat analysis method (2.2.9-2003 solid fat content NMR method)) is 0 at 5 ° C. . Specifically, rice oil, olive oil, safflower oil, soybean oil, corn oil, rapeseed oil, sunflower oil, cottonseed oil, high oleic sunflower oil, high oleic rapeseed oil, high oleic safflower oil, and medium chain Examples include fatty acid triglycerides. Preferably, rice oil, rapeseed oil, and medium chain fatty acid triglyceride are mentioned, More preferably, rice oil and medium chain fatty acid triglyceride are mentioned.
In the present specification, the medium-chain fatty acid triglyceride is a synthetic fat / oil synthesized from a fatty acid and glycerin, and means a fat / oil having a fatty acid composition of C-8 and C-10. The ratio of C-8 to C-10 is preferably about 100: 0 to 50:50.

本明細書において、「硬化」とは、水素添加によって不飽和脂肪酸を飽和することである。また、「極度硬化」とは、水素添加によって不飽和脂肪酸を完全に飽和することである。水素添加の方法は当業者に公知の方法により適宜行うことができる。例えば「食用油製造の実際」(宮川高明著、幸書房、昭和63年7月5日 初版第1刷発行)に記載の方法に従い、行うことができる。   In the present specification, “curing” is to saturate unsaturated fatty acids by hydrogenation. In addition, “extreme curing” is to completely saturate unsaturated fatty acids by hydrogenation. The method of hydrogenation can be suitably performed by a method known to those skilled in the art. For example, it can be carried out according to the method described in “Actual edible oil production” (authored by Takaaki Miyagawa, Yuki Shobo, first edition issued on July 5, 1988).

(3)油脂組成物のトリグリセライド組成及び脂肪酸組成
本発明の油脂組成物の全トリグリセライド100質量%に対してC50のトリグリセライド含有量は2質量%以下である。C50のトリグリセライドが多く含まれると、ヒートショック安定性が悪くなる場合があるからである。好ましくはC50のトリグリセライドは、1質量%以下である。
また、本発明の油脂組成物の全脂肪酸100質量%に対するステアリン酸含有量は1質量%以上4質量%以下であることが好ましい。ステアリン酸量が5質量%より多くなると、ホイップクリームの口溶けが低下する。トリステアリルグリセリドなど口溶けを低下させる高融点のグリセリドが多くなることが原因の一つと考えられる。
また、本発明の油脂組成物の全トリグリセライド100質量%に対するC32+C34のトリグリセライド含有量は7〜16質量%程度であることが好ましい。理由は不明であるが、C32〜C34のトリグリセライド含有量が16質量%よりも多くなると、ヒートショック耐性が低下したり、ホイップ時の腰が弱くなる場合があるからである。
(3) Triglyceride composition and fatty acid composition of oil / fat composition The triglyceride content of C50 is 2% by mass or less with respect to 100% by mass of the total triglyceride of the oil / fat composition of the present invention. This is because if a large amount of C50 triglyceride is contained, the heat shock stability may deteriorate. Preferably, the C50 triglyceride is 1% by mass or less.
Moreover, it is preferable that the stearic acid content with respect to 100 mass% of all fatty acids of the oil-fat composition of this invention is 1 mass% or more and 4 mass% or less. When the amount of stearic acid is more than 5% by mass, the melting of the whipped cream is reduced. One of the causes is considered to be an increase in high melting point glycerides such as tristearyl glyceride which lowers the melting in the mouth.
Moreover, it is preferable that C32 + C34 triglyceride content with respect to 100 mass% of all the triglycerides of the oil-fat composition of this invention is about 7-16 mass%. The reason is unclear, but if the triglyceride content of C32 to C34 is more than 16% by mass, heat shock resistance may be reduced or the waist during whipping may be weakened.

本明細書において、油脂組成物の脂肪酸組成は、基準油脂分析法(暫17-2007 トランス脂肪酸含量 キャピラリーガスクロマトグラフ法)に準じて測定した値を意味する。上記基準油脂分析において、ガスクロマトグラフィー装置は、例えば、島津製作所(株)製、GC-2010型、カラムは、SUPELCO社製、SP-2560、を用いることができる。
本明細書において、トリグリセライド組成は、基準油脂分析法(2.2.6.1-1996 トリアシルグリセリン組成(ガスクロマトグラフ法))に準じて測定する。
In the present specification, the fatty acid composition of the oil / fat composition means a value measured according to a standard oil / fat analysis method (provisional 17-2007 trans fatty acid content capillary gas chromatograph method). In the reference oil analysis, for example, a gas chromatography apparatus manufactured by Shimadzu Corporation, GC-2010, and a column manufactured by SUPELCO, SP-2560 can be used.
In the present specification, the triglyceride composition is measured according to the standard fat and oil analysis method (2.2.6.1-1996 triacylglycerol composition (gas chromatographic method)).

(4)油脂組成物の上昇融点
本発明の油脂組成物の上昇融点は31℃以下である。これより高いと口溶けが悪くなるからである。
(4) Rising melting point of oil and fat composition The rising melting point of the oil and fat composition of the present invention is 31 ° C or lower. If the temperature is higher than this, the melting of the mouth becomes worse.

(5)第3の油脂
本発明の油脂組成物には、(C)油脂組成物の全トリグリセライド100質量%に対してC50のトリグリセライド含有量が2質量%以下であり、かつ油脂組成物の上昇融点が31℃以下の油脂であるという条件を満たす限り、第2の油脂とは異なる第3の油脂を更に添加してもよい。
また更に、第3の油脂を加える場合には、第1の油脂が油脂組成物質量に対して少なくとも50質量%含まれることが好ましい。
第3の油脂は、油脂組成物質量に対して、20質量%以下の範囲で含むことが好ましく、10質量%以下であることがより好ましく、7質量%以下であることが更に好ましい。
第3の油脂として、より具体的には、ハイエルシン菜種油の極度硬化油(上昇融点60℃)、パーム核分別油高融点部極度硬化油(上昇融点36℃)、菜種硬化油(上昇融点23℃)から選択される油脂が挙げられる。
(5) 3rd fats and oils In the fats and oils composition of this invention, the triglyceride content of C50 is 2 mass% or less with respect to 100 mass% of all the triglycerides of (C) fats and oils composition, and an increase in fats and oils composition As long as the condition that the melting point is 31 ° C. or lower is satisfied, a third fat different from the second fat may be further added.
Furthermore, when adding 3rd fats and oils, it is preferable that 1st fats and oils are contained at least 50 mass% with respect to the amount of fats and oils composition substances.
It is preferable that 3rd fats and oils are included in the range of 20 mass% or less with respect to the amount of fats and oils composition substance, It is more preferable that it is 10 mass% or less, It is still more preferable that it is 7 mass% or less.
More specifically, as the third fats and oils, Hyershin rapeseed oil extremely hardened oil (rising melting point 60 ° C), palm kernel fractionated oil high melting point extremely hardened oil (rising melting point 36 ° C), rapeseed hardened oil (rising melting point 23 ° C) ) And fats selected from.

<水中油型乳化油脂組成物>
本発明の水中油型乳化油脂組成物は、水相部と油相部からなり、上述した本発明のホイップクリーム用油脂組成物を油相部に含む。水相部と油相部の質量比はホイップクリームを製造するために適宜設定することができるが、通常、80:20〜50:50程度である。
前記油相部は、油脂として本発明のホイップクリーム用油脂組成物のみを含んでいてもよく、また乳脂肪を更に含んでいてもよい。乳脂肪としてバターオイル、バター、生クリーム、牛乳等を由来とする乳脂肪が挙げられる。以下、上述した本発明のホイップクリーム用油脂組成物を特に乳脂肪と区別して述べる場合には、「植物性油脂組成物」とも呼ぶ。
乳脂肪と植物性油脂組成物の混合比は、質量比で乳脂肪:植物性油脂組成物が0:100〜70:30の範囲内で変えることができる。前記範囲内であれば、植物性油脂組成物の乳化安定性、口溶け、造花性、起泡性等の効果を損なうことなく、ホイップクリームを製造することができる。
<Oil-in-water emulsified oil / fat composition>
The oil-in-water emulsified oil / fat composition of the present invention comprises an aqueous phase part and an oil phase part, and includes the above-described oil / fat composition for whipped cream in the oil phase part. The mass ratio of the water phase part and the oil phase part can be appropriately set in order to produce a whipped cream, but is usually about 80:20 to 50:50.
The oil phase part may contain only the oil and fat composition for whipped cream of the present invention as an oil or fat, and may further contain milk fat. Examples of milk fat include milk fat derived from butter oil, butter, fresh cream, milk and the like. Hereinafter, when the oil and fat composition for whipped cream of the present invention described above is particularly distinguished from milk fat, it is also referred to as “vegetable oil and fat composition”.
The mixing ratio of the milk fat and the vegetable oil composition can be changed within a range of 0: 100 to 70:30 in terms of the mass ratio of the milk fat: the vegetable oil composition. If it is in the said range, a whipped cream can be manufactured, without impairing effects, such as emulsification stability of a vegetable oil-fat composition, mouth melting, artificial flower property, and foaming property.

本発明の水中油型乳化油脂組成物は、一般的な製造方法により製造できるが、代表的な方法を述べると、先ず使用する乳化剤が親油性のものは原料油脂(本発明のホイップクリーム用油脂組成物)の一部または全部に添加し溶解ないし分散させて油相部を調製する。このような乳化剤としては、例えばレシチン、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、有機酸モノグリセリド等従来公知の乳化剤のうちHLBの低い乳化剤が例示でき、本発明においてはこれらのいずれを適宜組み合わせて使用してもよい。
また、バターオイル、バター、生クリーム、牛乳等を由来とする乳脂肪を用いる場合には、これらを必要に応じて加熱融解して油相物を調製して用いる。乳脂肪を含む油相部と、上述した植物性油脂からなる本発明のホイップクリーム用油脂組成物を含む油相部は、水相部に混合した後添加してもよく、また各々添加してもよい。
The oil-in-water emulsified oil / fat composition of the present invention can be produced by a general production method. When a typical method is described, the emulsifier to be used is a lipophilic raw material (oil / fat for whipped cream of the present invention). The oil phase part is prepared by adding to part or all of the composition and dissolving or dispersing. Examples of such emulsifiers include low emulsifiers having a low HLB among conventionally known emulsifiers such as lecithin, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, and organic acid monoglyceride. Any of these may be used in appropriate combination.
Moreover, when using milk fat derived from butter oil, butter, fresh cream, milk or the like, these are heated and melted as necessary to prepare and use an oil phase product. The oil phase part containing milk fat and the oil phase part containing the oil composition for whipped cream of the present invention consisting of the above-described vegetable oil may be added after being mixed in the aqueous phase part, and each may be added. Also good.

次に、水相部にカゼインナトリウム、脱脂粉乳、糖類や必要に応じて、蔗糖脂肪酸エステル、クエン酸ナトリウム、トリポリりん酸ナトリウム、第二りん酸ナトリウム、重炭酸ナトリウム、ヘキサメタりん酸ナトリウム、増粘多糖類、香料などを添加し調製する。
無脂乳固形分の量は、組成物の全質量に対して、1〜10質量%であることが好ましく、更に2〜7質量%であることが好ましく、3〜6質量%であることが最も好ましい。このような範囲で添加することにより、乳化安定性が改善され、また風味が改善される場合があるからである。無脂乳固形分の含有量が約1質量%未満であると、乳化組成物を泡立てて得られるホイップクリームの風味が悪くなる。また、無脂乳固形分の含有量が約10質量%を越えると乳化組成物の粘度が高くなり、エージング中に粘度上昇が起こる恐れがある。
Next, in the aqueous phase, sodium caseinate, skim milk powder, saccharides and sucrose fatty acid ester, sodium citrate, sodium tripolyphosphate, sodium diphosphate, sodium bicarbonate, sodium hexametaphosphate, thickening as necessary Prepare by adding polysaccharides, fragrances, etc.
The amount of the non-fat milk solid content is preferably 1 to 10% by mass, more preferably 2 to 7% by mass, and 3 to 6% by mass with respect to the total mass of the composition. Most preferred. It is because the emulsion stability is improved and the flavor may be improved by adding in such a range. When the content of the non-fat milk solids is less than about 1% by mass, the flavor of the whipped cream obtained by foaming the emulsion composition becomes poor. Moreover, when content of non-fat milk solid content exceeds about 10 mass%, the viscosity of an emulsion composition will become high and there exists a possibility that a viscosity raise may occur during aging.

これら、油相部と水相部を60℃から80℃に加温し、混合して予備乳化を行う。予備乳化後、ホモゲナイザーにて均質化し、バッチ式殺菌法、または間熱加熱方式あるいは直接加熱方式によるUHT滅菌処理法にて滅菌し、再びホモゲナイザーにて均質化し冷却しエージングする。
本発明の油脂組成物には、甘味や粘度の調節を目的として糖類を配合してもよい。糖類としては、例えば、水飴、粉飴、ショ糖、麦芽糖、ソルビトール、マルチトール、エリスリトール、トレハロース等が挙げられ、これは必要に応じ適宜組み合わせて配合される。
These oil phase part and water phase part are heated from 60 ° C. to 80 ° C. and mixed to perform preliminary emulsification. After preliminary emulsification, the mixture is homogenized by a homogenizer, sterilized by a batch sterilization method, a UHT sterilization method using an intermediate heating method or a direct heating method, homogenized again by a homogenizer, cooled and aged.
In the oil and fat composition of the present invention, saccharides may be blended for the purpose of adjusting sweetness and viscosity. Examples of the saccharide include starch syrup, powdered potato, sucrose, maltose, sorbitol, maltitol, erythritol, trehalose, and the like, and these are blended in combination as appropriate.

<ホイップクリーム>
本発明において、ホイップクリームは、本発明の水中油型乳化油脂組成物を、当該技術分野において通常の方法により起泡されたものである。
以下、本発明の水中油型乳化油脂組成物を使用したホイップクリームの製造例を示すが、本発明はかかる例に限定されるものではない。
<Whipped cream>
In the present invention, the whipped cream is obtained by foaming the oil-in-water emulsified oil / fat composition of the present invention by a usual method in the art.
Hereinafter, although the manufacture example of the whipped cream which uses the oil-in-water type emulsified oil-fat composition of this invention is shown, this invention is not limited to this example.

まず、本発明の油脂組成物を融解混合等により調製する。油脂組成物に、レシチン、蔗糖脂肪酸エステル、ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル等の乳化剤等の任意の添加剤を加え、混合して油相を調製する。
一方、水相部として、水に、メタリン酸Na、増粘多糖類、乳蛋白等の任意の添加剤を加えた後、これらを分散させて水相を調製する。
50〜85℃にて油相と水相を混合させ、予備乳化を行う。次いで20〜150kg/cm2の圧力下で均質化を行い、次いで75〜85℃にて加熱殺菌する。その後5〜10℃にまで冷却し、6〜24時間程度エージングを行なう。
このクリーム状油脂組成物をホバートミキサーにてホイップして起泡済みホイップクリームを得る。
First, the oil and fat composition of the present invention is prepared by melt mixing or the like. Arbitrary additives such as emulsifiers such as lecithin, sucrose fatty acid ester, sorbitan fatty acid ester and glycerin fatty acid ester are added to the oil and fat composition and mixed to prepare an oil phase.
On the other hand, as an aqueous phase part, after adding arbitrary additives, such as sodium metaphosphate, thickening polysaccharide, milk protein, to water, these are disperse | distributed and an aqueous phase is prepared.
The oil phase and the aqueous phase are mixed at 50 to 85 ° C. and pre-emulsified. Next, homogenization is carried out under a pressure of 20 to 150 kg / cm 2 , followed by heat sterilization at 75 to 85 ° C. Thereafter, it is cooled to 5 to 10 ° C. and aged for 6 to 24 hours.
This creamy fat composition is whipped with a Hobart mixer to obtain a foamed whipped cream.

油脂調製方法
以下の実施例で使用した油脂の内容を示す。

Figure 0005444972
Oil and fat preparation method The contents of the oil and fat used in the following examples are shown.
Figure 0005444972

上記表に記載された油脂を以下のようにして得た。
・油脂A...パーム核油を自然分別方法により高融点部と低融点部に2分割して得られた高融点部(上昇融点32℃)を脱色、脱臭を行い油脂Aを得た。
・エステル交換油脂1...ヤシ油を0.12%のナトリウムメチラートを触媒とし、90℃で30分間、非選択的エステル交換反応を行い、脱色、脱臭を行いエステル交換油脂1を得た。
・エステル交換油脂2...ヤシ油85%、油脂F15%の混合油を0.12%のナトリウムメチラートを触媒とし、90℃で30分間、非選択的エステル交換反応を行い、脱色、脱臭を行いエステル交換油脂2を得た。
・エステル交換油脂3...パーム核油90%、油脂F10%の混合油を0.12%のナトリウムメチラートを触媒とし、90℃で30分間、非選択的エステル交換反応を行い、脱色、脱臭を行いエステル交換油脂3を得た。
The fats and oils described in the above table were obtained as follows.
Fat and oil A: The fat and oil A was obtained by decoloring and deodorizing the high melting point portion (increased melting point 32 ° C.) obtained by dividing the palm kernel oil into the high melting point portion and the low melting point portion by a natural separation method.
-Transesterified oil and fat 1 ... A non-selective transesterification reaction was carried out at 90 ° C for 30 minutes using 0.12% sodium methylate as a catalyst for palm oil, and decolorized and deodorized to obtain a transesterified oil and fat 1. .
・ Transesterified fats and oils 2 ... Decolorized and deodorized by a non-selective transesterification reaction at 90 ° C for 30 minutes using 0.12% sodium methylate as a catalyst of 85% coconut oil and 15% fat F To obtain a transesterified oil 2.
-Transesterified oil and fat 3 ... A mixed oil of 90% palm kernel oil and 10% fat F is used as a catalyst with 0.12% sodium methylate, and a non-selective transesterification reaction is performed at 90 ° C for 30 minutes to remove the color. Deodorization was performed to obtain a transesterified oil 3.

・エステル交換油脂4...ヤシ油85%、パーム分別油高融点部15%の混合油を0.12%のナトリウムメチラートを触媒とし、90℃で30分間、非選択的エステル交換反応を行い、脱色、脱臭を行いエステル交換油脂4を得た。
・エステル交換油脂5...ヤシ油55%、中鎖脂肪酸トリグリセライド45%(脂肪酸組成C8=99%、C10=1%)の混合油を0.12%のナトリウムメチラートを触媒とし、90℃で30分間、非選択的エステル交換反応を行い、脱色、脱臭を行いエステル交換油脂5を得た。
・エステル交換油脂6...パーム核油75%、パーム極度硬化油25%の混合油を0.12%のナトリウムメチラートを触媒とし、90℃で30分間、非選択的エステル交換反応を行い、脱色、脱臭を行いエステル交換油脂6を得た。
・ Transesterified oils and fats 4 ... Non-selective transesterification reaction at 90 ° C for 30 minutes using a mixed oil of 85% coconut oil and 15% palm fraction oil high melting point 0.12% sodium methylate Decolorization and deodorization were carried out to obtain a transesterified oil 4.
・ Transesterified fats and oils 5 ... Mixed oil of 55% coconut oil and 45% medium-chain fatty acid triglyceride (fatty acid composition C8 = 99%, C10 = 1%) with 0.12% sodium methylate as catalyst, 90 ° C For 30 minutes, a non-selective transesterification reaction was carried out, and decolorization and deodorization were carried out to obtain a transesterified oil and fat 5.
・ Transesterified oils and fats 6 ... A non-selective transesterification reaction is carried out at 90 ° C for 30 minutes using 0.12% sodium methylate as a catalyst in a mixed oil of 75% palm kernel oil and 25% palm extremely hardened oil. , Decolorization and deodorization were carried out to obtain a transesterified oil 6.

・油脂B...パーム核油を脱色、脱臭を行い油脂Bを得た。
・油脂C...中鎖脂肪酸トリグリセライド(脂肪酸組成C8=75%、C10=25%)脱色、脱臭を行い油脂Cを得た。
・油脂D...コメ油を脱色、脱臭を行い油脂Dを得た。
・油脂E...ヤシ油を脱色、脱臭を行い油脂Eを得た。
・油脂F...ハイエルシン菜種油の極度硬化処理を行い、脱色、脱臭を行い油脂Fを得た。
・油脂G...油脂Aの極度硬化処理を行い、脱色、脱臭を行い油脂Gを得た。
・油脂H...ナタネ油をヨウ素価83となるように硬化を行い、脱色、脱臭を行い油脂Hを得た(融点23℃)。
・油脂I...パーム分別低融点部(IV57)を脱色、脱臭を行い油脂Iを得た。
Fats and oils B: Palm kernel oil was decolorized and deodorized to obtain fats and oils B.
Fats and oils C: Medium chain fatty acid triglycerides (fatty acid composition C8 = 75%, C10 = 25%) were decolorized and deodorized to obtain fats and oils C.
-Oil D: Rice oil was decolorized and deodorized to obtain oil D.
・ Oil E ... Decolorized and deodorized coconut oil to obtain oil E.
・ Oil F ... Hyelin rapeseed oil was subjected to extreme curing treatment, decolorized and deodorized to obtain oil F.
Fats and oils G: Fats and oils A were subjected to extreme curing treatment, and decolorized and deodorized to obtain fats and oils G.
Fats and oils H: Rapeseed oil was cured to an iodine value of 83, decolorized and deodorized to obtain fats and oils H (melting point 23 ° C.).
・ Oil I: Oil and fat I was obtained by decolorizing and deodorizing the low melting point part (IV57) of the palm fraction.

実施例1〜15及び比較例1〜7
水中油型乳化油脂組成物の調製
表1に記載の各油脂を用いて、表2〜表4に記載の配合で油脂組成物を作成した。
Examples 1-15 and Comparative Examples 1-7
Preparation of oil-in-water emulsified oil / fat composition Using each oil / fat described in Table 1, an oil / fat composition was prepared with the formulation described in Tables 2 to 4.

Figure 0005444972
Figure 0005444972

Figure 0005444972
Figure 0005444972

Figure 0005444972
Figure 0005444972

表2〜4に記載の各油脂36.38質量%(乳化油脂組成物全質量に対する質量%、以下同様)を加熱溶解し、そこに大豆レシチン0.23質量%、飽和酸モノグリセリド(パルミチン酸モノグリセリド)0.19質量%、ショ糖脂肪酸エステル(HLB=1)0.15質量%、ソルビタン脂肪酸エステル0.05質量%を加え融解し油相を調製した。
一方、水56.80質量%と脱脂粉乳6.00質量%、メタリン酸Na0.10質量%、ショ糖脂肪酸エステル(HLB=11)0.10質量%を加えた後、分散させて水相を調製した。
油相と水相を混合させ、65℃で予備乳化を行い、80kg/cm2の圧力下で均質化した。次いで、75℃にて加熱殺菌を行い、20kg/cm2の圧力下で均質化を行い、冷却してクリーム状水中油型乳化油脂組成物を得た。その後、組成物を冷却し、5℃で1晩のエージングをした。
36.38% by mass of each fat and oil listed in Tables 2 to 4 (% by mass with respect to the total mass of the emulsified oil and fat composition, hereinafter the same) is dissolved by heating, 0.23% by mass of soybean lecithin, saturated acid monoglyceride (palmitic acid monoglyceride) ) 0.19% by mass, 0.15% by mass of sucrose fatty acid ester (HLB = 1) and 0.05% by mass of sorbitan fatty acid ester were added and melted to prepare an oil phase.
On the other hand, 56.80% by mass of water, 6.00% by mass of skim milk powder, 0.10% by mass of sodium metaphosphate, and 0.10% by mass of sucrose fatty acid ester (HLB = 11) were added and dispersed to disperse the aqueous phase. Prepared.
The oil phase and the aqueous phase were mixed, pre-emulsified at 65 ° C., and homogenized under a pressure of 80 kg / cm 2 . Next, the mixture was sterilized by heating at 75 ° C., homogenized under a pressure of 20 kg / cm 2 , and cooled to obtain a creamy oil-in-water emulsified oil / fat composition. The composition was then cooled and aged overnight at 5 ° C.

実施例16
油脂量を31.38質量%とし、水の量を61.80質量%に変えた以外は、実施例1と同様に水中油型乳化油脂組成物を調製し、同様に評価を行った。
Example 16
An oil-in-water emulsified oil / fat composition was prepared in the same manner as in Example 1 except that the amount of oil was 31.38% by mass and the amount of water was changed to 61.80% by mass.

実施例17
油脂量を41.38質量%とし、水の量を51.80質量%に変えた以外は、実施例1と同様に水中油型乳化油脂組成物を調製し、同様に評価を行った。
Example 17
An oil-in-water emulsified oil / fat composition was prepared and evaluated in the same manner as in Example 1 except that the amount of oil and fat was 41.38% by mass and the amount of water was changed to 51.80% by mass.

実施例18
以下のようにして、実施例18〜20の水中油型乳化油脂組成物を調製し、実施例1と同様に評価を行った。
実施例2に記載の油脂(油脂Aとエステル交換油脂1の混合油脂)25.47質量%を加熱溶解し、そこに大豆レシチン0.23質量%、飽和酸モノグリセリド(パルミチン酸モノグリセリド)0.19質量%、ソルビタン脂肪酸エステル0.05質量%を加え融解し油相−1を調製した。
無塩バター(乳脂肪分83%)13.64質量%(油脂全質量に対して乳脂肪分30%)を加熱溶解して油相−2を調製した。
一方、水54.07質量%と脱脂粉乳6.00質量%、メタリン酸Na0.10質量%、ショ糖脂肪酸エステル(HLB=11)0.10質量%を加えた後、分散させて水相を調製した。
水相を攪拌しながら、油相−1及び油相−2を順次投入して混合し、65℃で予備乳化を行い、60kg/cm2、40kg/cm2の圧力下で均質化した。次いで、75℃にて加熱殺菌を行い、冷却してクリーム状水中油型乳化油脂組成物を得た。その後、組成物を冷却し、5℃で1晩のエージングをした。
Example 18
The oil-in-water type emulsified oil / fat compositions of Examples 18 to 20 were prepared as follows and evaluated in the same manner as in Example 1.
25.47% by mass of the oil and fat described in Example 2 (mixed fat / oil of fat A and transesterified oil 1) was dissolved by heating, 0.23% by mass of soybean lecithin, 0.19 of saturated acid monoglyceride (palmitic acid monoglyceride). Oil phase-1 was prepared by adding mass% and sorbitan fatty acid ester 0.05 mass% and melting.
Unsalted butter (milk fat content 83%) 13.64% by mass (milk fat content 30% with respect to the total fat mass) was heated and dissolved to prepare oil phase-2.
On the other hand, 54.07% by mass of water, 6.00% by mass of skim milk powder, 0.10% by mass of sodium metaphosphate, and 0.10% by mass of sucrose fatty acid ester (HLB = 11) were added and dispersed to disperse the aqueous phase. Prepared.
While stirring the aqueous phase, oil phase-1 and oil phase-2 were sequentially added and mixed, pre-emulsified at 65 ° C., and homogenized under pressures of 60 kg / cm 2 and 40 kg / cm 2 . Subsequently, it heat-sterilized at 75 degreeC, it cooled and the cream-like oil-in-water type emulsified oil-fat composition was obtained. The composition was then cooled and aged overnight at 5 ° C.

実施例19及び20
実施例2に記載の油脂(油脂Aとエステル交換油脂1の混合油脂)それぞれ18.19質量%、25.47質量%を用いて実施例18と同様に油相−1を2種類調製した。
無塩バター(乳脂肪分83%)をそれぞれ22.74質量%(油脂全質量に対して乳脂肪分50%)、31.83質量%(油脂全質量に対して乳脂肪分70%)を加熱溶解して油相−2を2種類調製した。
水相を実施例18と同様に調製した。
実施例18と同様に油相−1、油相−2及び水相を混合し、実施例19及び20のクリーム状水中油型乳化油脂組成物を得た。
Examples 19 and 20
Two types of oil phase-1 were prepared in the same manner as in Example 18 using 18.19 mass% and 25.47 mass% of the fats and oils described in Example 2 (mixed fats and oils of fat A and transesterified fat 1), respectively.
Unsalted butter (milk fat content 83%) was 22.74% by mass (milk fat content 50% with respect to the total fat mass) and 31.83 mass% (milk fat content 70% with respect to the total fat mass). Two types of oil phase-2 were prepared by heating and dissolving.
The aqueous phase was prepared as in Example 18.
In the same manner as in Example 18, the oil phase-1, the oil phase-2, and the aqueous phase were mixed to obtain the creamy oil-in-water emulsified oil / fat compositions of Examples 19 and 20.

粘度
水中油型乳化油脂組成物を、5℃で一晩静置してエージングを行い、500mlのビーカーに水中油型乳化油脂組成物を500g入れ、B型粘度計(BROOK FIELD社製粘度計のLVT)、スピンドル2番、スピード30にて測定した。
Viscosity oil-in-water emulsified oil / fat composition is allowed to stand at 5 ° C. overnight and aged, and 500 g of oil-in-water emulsified oil / fat composition is put into a 500 ml beaker, and a B-type viscometer (BROOK FIELD Viscometer LVT), spindle 2 and speed 30.

ホイップ時間
水中油型乳化油脂組成物(クリーム)500gに砂糖を50g加え、5.0℃に温調し、8分立てとなるまでホバートミキサーにて速度2にてホイップした。8分立てホイップクリームを更に10分立て(硬度140〜170)まで手立てした。ホイップにかかる時間(10分立てまでの時間)を記載した。
Whip time 50 g of sugar was added to 500 g of an oil-in-water emulsified oil / fat composition (cream), temperature-controlled at 5.0 ° C., and whipped at a speed of 2 with a Hobart mixer until 8 minutes standing. 8 minutes standing whipped cream was further handed to 10 minutes (hardness 140-170). The time required for whipping (time until 10 minutes) was described.

オーバーラン
ホイップ後(10分立て)の体積増加率(%)。ただし、体積増加率は、式:((a)(一定体積の水の重量−水と同体積のホイップ後のクリームの重量)/(b)(水と同体積のホイップ後のクリームの重量))×100、に従って計算した。
Volume increase rate (%) after overrun whip (10 minutes). However, the volume increase rate is expressed by the formula: ((a) (weight of a certain volume of water−weight of cream after whipping of the same volume as water) / (b) (weight of cream after whipping of the same volume as water) ) × 100.

硬度
ホイップした水中油型乳化油脂組成物(クリーム)を45.5ml容器に入れ、ミクロペネメーター:RIGOSHA製のPENETRO METER使用、円スイ(1g)を使用し、平らにしたクリームへの円スイの針入度を測定(単位は1/10mm)した。
Put oil-in-water emulsified oil composition which was hardness whipping (cream) to 45.5ml container, micro penetrometer meter: RIGOSHA made of PENETRO METER use, use the circle Sui (1g), the circle Sui to the flat in the cream The penetration was measured (unit: 1/10 mm).

造花性評価
ホイップクリーム(10分立て)を三角袋に詰めて絞った時の、腰、伸び、艶、荒れを下記の5段階の基準により評価した。
5…非常に良好
4…良好
3…普通
2…やや悪い
1…悪い
Artificial flower evaluation Whipping, stretching, luster and roughness when whipped cream (10 minutes standing) was packed in a triangular bag and squeezed were evaluated according to the following five criteria.
5 ... very good 4 ... good 3 ... normal 2 ... somewhat bad 1 ... bad

翌日戻り試験
ホイップクリーム(10分立て)を三角袋に詰めて500mlビーカーに絞り、5.0℃にて1晩置き、翌日のオーバーラン、硬度を測定し、離水を評価した。
Next day return test Whipped cream (10 minutes standing) was packed in a triangular bag, squeezed into a 500 ml beaker and placed at 5.0 ° C. overnight, overrun and hardness of the next day were measured, and water separation was evaluated.

離水評価
ホイップクリーム(10分立て)を三角袋に詰めて500mlビーカーに絞り、5.0℃にて1晩置き、目視にて離水量を下記の5段階の基準により評価した。
5…ない
4…わずかにある
3…普通
2…やや多い
1…非常に多い
Water separation evaluation Whipped cream (10 minutes standing) was packed in a triangular bag, squeezed into a 500 ml beaker, placed at 5.0 ° C. overnight, and the amount of water separation was evaluated visually according to the following five criteria.
5 ... No 4 ... Slightly 3 ... Normal 2 ... Slightly 1 ... Very many

ヒートショック試験
牛乳瓶にホイップ前の水中油型乳化油脂組成物を約150g入れ、25℃の恒温槽に1時間入れ、その後、5℃の恒温槽に6時間保存した。保存後、分離、ボテ、粘度を評価した。これらの評価は、乳化安定性の指標となる。
B型粘度計…No.3ローター スピード30にて5分後の粘度を測定した。または、5分以内で4000mPa・s以上になった場合にはその時間を示した(表1では括弧を付して時間を示した)。
リオン…No.3ローターにて5分後の粘度を測定した。または、5分以内で10dPa・s以上になった場合にはその時間を示した。
Heat shock test About 150 g of the oil-in-water emulsified oil / fat composition before whipping was put in a milk bottle, placed in a thermostatic bath at 25 ° C. for 1 hour, and then stored in a thermostatic bath at 5 ° C. for 6 hours. After storage, separation, bottling and viscosity were evaluated. These evaluations are indicators of emulsion stability.
B-type viscometer: No. 3 rotor The viscosity after 5 minutes was measured at a speed of 30. Or when it became 4000 mPa * s or more within 5 minutes, the time was shown (In Table 1, the time was shown in parenthesis).
Rion: The viscosity after 5 minutes was measured with a No. 3 rotor. Or when it became more than 10 dPa * s within 5 minutes, the time was shown.

口溶け評価
専門パネラー5名により、ホイップクリーム(10分立て)を実際に食して口溶けを下記の基準により評価した。
5…非常に良好
4…良好
3…普通
2…やや悪い
1…悪い
Mouth melting evaluation panelists evaluated the mouth melting according to the following criteria by actually eating whipped cream (10 minutes standing).
5 ... very good 4 ... good 3 ... normal 2 ... somewhat bad 1 ... bad

油脂組成物の分析方法は以下の方法により行った。
・脂肪酸組成、トランス脂肪酸含量
基準油脂分析法(暫17-2007 トランス脂肪酸含量 キャピラリーガスクロマトグラフ法)に準じて測定した。
ガスクロマトグラフィー装置は、島津製作所(株)製、GC-2010型。カラムは、SUPELCO社製、SP-2560。
・SFC(固体脂含量)
基準油脂分析法(2.2.9-2003 固体脂含量 NMR法)に準じて測定した。
・上昇融点
基準油脂分析法(2.2.4.2-1996 融点 上昇融点)に準じて測定した。
・トリグリセライド組成
基準油脂分析法(2.2.6.1-1996 トリアシルグリセリン組成(ガスクロマトグラフ法)
The analysis method of the oil and fat composition was performed by the following method.
-Fatty acid composition, trans fatty acid content Measured according to the standard fat analysis method (provisional 17-2007 trans fatty acid content capillary gas chromatographic method).
The gas chromatography system is GC-2010, manufactured by Shimadzu Corporation. The column is SP-2560 manufactured by SUPELCO.
・ SFC (solid fat content)
Measured according to the standard fat analysis method (2.2.9-2003 solid fat content NMR method).
-Rising melting point Measured according to the standard fat and oil analysis method (2.2.4.2-1996 melting point rising melting point).
・ Triglyceride composition Reference oil analysis method (2.2.6.1-1996 Triacylglycerol composition (gas chromatographic method)

上記評価結果を表5〜8に示した。各表において「%」は質量%を意味する。   The said evaluation result was shown to Tables 5-8. In each table, “%” means mass%.

Figure 0005444972
Figure 0005444972

Figure 0005444972
Figure 0005444972

Figure 0005444972
Figure 0005444972

Figure 0005444972
Figure 0005444972

各表の結果から明らかなように、本発明の油脂組成物から製造される水中油型乳化油脂組成物は特にヒートショック試験において良好であり、また本発明の油脂組成物から製造されたホイップクリームの造花性、口溶けも非常に良好であった(実施例1〜15)。
また、乳化油脂組成物中の全体の油脂量を変えた場合でも同様の効果を奏した。
As is apparent from the results in each table, the oil-in-water emulsified oil / fat composition produced from the oil / fat composition of the present invention is particularly good in a heat shock test, and the whipped cream produced from the oil / fat composition of the present invention. The artificial flowering property and meltability in the mouth were also very good (Examples 1 to 15).
Moreover, the same effect was produced even when the total amount of fats and oils in the emulsified fat and oil composition was changed.

これに対して、第1の油脂であるパーム核分別油高融点部を単独で用いた場合には、造花性が悪く、またヒートショック試験ではB型粘度計測定時1440cpとなり、安定ではなかった(比較例1)。
第2の油脂であるヤシ油をランダムエステル交換処理した油脂を単独で使用すると、造花性が悪く、また離水も見られ、乳化安定性が劣る結果であった(比較例2)。
On the other hand, when the palm core fractionation oil high melting point part which is the first fat or oil was used alone, the flower-forming property was poor, and in the heat shock test, it was 1440 cp at the time of measuring the B-type viscometer and was not stable ( Comparative Example 1).
When the fat and oil obtained by subjecting the coconut oil, which is the second fat and oil, to the random transesterification, was used alone, the flowering property was poor, water separation was observed, and the emulsion stability was poor (Comparative Example 2).

油脂Aの極度硬化油を単独で使用した場合には、油脂組成物の上昇融点が36℃となった。この場合には、口溶けが悪く、商品価値が低い(比較例3)。
第2の油脂として、パーム核油とパーム極度硬化油の75:25混合油のランダムエステル交換処理した油脂を用いた油脂組成物であって、上昇融点が32℃の油脂組成物を用いた場合には、造花性、乳化安定性、口溶けのいずれも悪いものであった(比較例4)。
When the extremely hardened oil of fat A was used alone, the rising melting point of the fat composition was 36 ° C. In this case, melting in the mouth is poor and the commercial value is low (Comparative Example 3).
In the case of using an oil and fat composition using a fat and oil obtained by random transesterification of 75:25 mixed oil of palm kernel oil and palm extremely hardened oil as the second oil and fat, and having an ascending melting point of 32 ° C. In addition, all of the artificial flower property, the emulsion stability, and the mouth melting were bad (Comparative Example 4).

第2の油脂として、パーム分別低融点部(IV57)を用いた場合には、油脂組成物のトリグリセライド組成のうちC50が9質量%となり、B型粘度計測定時4000cp到達まで23sであり、ヒートショック耐性が極めて低かった(比較例5)。
第2の油脂として、エステル交換未処理のヤシ油をそのまま使用した場合には、ヒートショック試験ではB型粘度計測定時900cpとなり、安定ではなかった(比較例6)。実施例3のエステル交換処理を行ったヤシ油を用いた場合には、ヒートショック試験において非常に安定な結果を示しており、第2の油脂としてヤシ油に代わり、ヤシ油のエステル交換処理を行うた油脂を用いることでこのように優れた安定性が得られることは従来報告されておらず、本発明の効果の顕著性を裏付けるものである。
When the palm fractionation low melting point part (IV57) is used as the second oil or fat, C50 is 9% by mass in the triglyceride composition of the oil or fat composition, and it is 23 s until reaching 4000 cp when measuring the B-type viscometer. Resistance was extremely low (Comparative Example 5).
When the transesterified untreated coconut oil was used as it was as the second fat, the heat shock test showed 900 cp when measured with a B-type viscometer and was not stable (Comparative Example 6). When the coconut oil subjected to the transesterification treatment of Example 3 was used, a very stable result was shown in the heat shock test, and the coconut oil transesterification treatment was performed instead of the coconut oil as the second fat. It has not been reported in the past that such excellent stability can be obtained by using the fats and oils used, and supports the remarkable effect of the present invention.

第2の油脂として、ヤシ油のランダムエステル交換処理した油脂を用い、第3の油脂としてパーム分別低融点部(IV57)を用いた場合には、油脂組成物のトリグリセライド組成のうちC50が9質量%となり、B型粘度計測定時4000cp到達まで4m52sであり、ヒートショック耐性が無いことを示した(比較例7)。   When oil and fat subjected to random transesterification treatment of palm oil is used as the second oil and fat, and the palm fraction low melting point part (IV57) is used as the third oil and fat, C50 is 9 mass in the triglyceride composition of the oil and fat composition. It was 4 m52 s until reaching 4000 cp at the time of measuring the B-type viscometer, indicating that there was no heat shock resistance (Comparative Example 7).

以上の結果から、本発明のホイップクリーム用油脂組成物から製造される水中油型乳化油脂組成物が、乳化安定性(特にヒートショック耐性)とホイップクリーム製造時の口溶け、造花性において、バランスのとれた優れた組成物であることがわかる。   From the above results, the oil-in-water emulsified oil / fat composition produced from the oil / fat composition for whipped cream according to the present invention has a good balance in emulsification stability (particularly heat shock resistance), mouth melting at the time of whipped cream production, and flowering ability. It can be seen that the composition is excellent.

Claims (11)

少なくとも2種類の油脂成分を含むホイップクリーム用油脂組成物であって、(A)第1の油脂が、パーム核分別油高融点部からなり、(B)第2の油脂が、ヤシ油をランダムエステル交換処理した油脂、ヤシ油と他の油脂の混合油をランダムエステル交換処理した油脂、パーム核油と他の油脂の混合油をランダムエステル交換処理した油脂、及び中鎖脂肪酸トリグリセリドからなる群より選択される油脂であって、及び(C)油脂組成物の全トリグリセライド100質量%に対してC50のトリグリセライド含有量が2質量%以下であり、かつ油脂組成物の上昇融点が31℃以下の油脂である、上記油脂組成物。 An oil / fat composition for whipped cream comprising at least two types of oil / fat ingredients, wherein (A) the first oil / fat consists of a high melting point part of palm kernel fractionated oil, and (B) the second oil / fat randomly adds palm oil. fat was transesterified processing, palm oil and other fats and oils were randomized transesterification process oil mixture of oil, palm kernel oil and other fats and oils were randomized transesterification process oil mixture of oil, and medium-chain triglycerides or Ranaru group (C) The triglyceride content of C50 is 2% by mass or less with respect to 100% by mass of the total triglyceride of the oil / fat composition, and the rising melting point of the oil / fat composition is 31 ° C. or less. The said fats and oils composition which is fats and oils. (B)第2の油脂が、(B) The second fat is
(i)ヤシ油をランダムエステル交換処理した油脂、(i) fats and oils obtained by random transesterification of coconut oil,
(ii)ヤシ油またはパーム核油と他の油脂の混合油をランダムエステル交換処理した油脂(ただし、他の油脂はハイエルシンナタネ油の極度硬化油または中鎖脂肪酸トリグリセリドからなる群より選択される)、及び(ii) Fats and oils obtained by random transesterification of a mixed oil of coconut oil or palm kernel oil and other fats and oils (however, the other fats and oils are selected from the group consisting of highly hardened oils of Haieru rapeseed oil or medium-chain fatty acid triglycerides) ),as well as
(iii)中鎖脂肪酸トリグリセリド(iii) Medium chain triglyceride
からなる群より選択される油脂である、請求項1に記載の油脂組成物。The fat composition according to claim 1, wherein the fat composition is selected from the group consisting of:
第1の油脂を、油脂組成物質量に対して、20〜80質量%の範囲で含む、請求項1または2に記載の組成物。 The composition of Claim 1 or 2 which contains 1st fats and oils in the range of 20-80 mass% with respect to the amount of fats and oils composition substance. (C)油脂組成物の全脂肪酸100質量%に対するステアリン酸含有量は1質量%以上4質量%以下である、請求項1〜3のいずれか一項に記載の組成物。 (C) The composition as described in any one of Claims 1-3 whose stearic acid content with respect to 100 mass% of all the fatty acids of an oil-fat composition is 1 mass% or more and 4 mass% or less. 更に、第3の油脂を、油脂組成物質量に対して、20質量%以下の範囲で含む、請求項1〜のいずれか一項に記載の組成物。 Furthermore, the composition as described in any one of Claims 1-4 which contains 3rd fats and oils in the range of 20 mass% or less with respect to the amount of fats and oils composition substances. 水相部と油相部からなり、前記油相部が請求項1〜のいずれか一項に記載の油脂組成物を含むことを特徴とする、水中油型乳化油脂組成物。 An oil-in-water emulsified oil / fat composition comprising an aqueous phase part and an oil phase part, wherein the oil phase part comprises the oil / fat composition according to any one of claims 1 to 5 . 水中油型乳化油脂組成物質量に対する油相部の質量が30%〜42%であることを特徴とする、請求項記載の水中油型乳化油脂組成物。 The oil-in-water emulsified oil / fat composition according to claim 6 , wherein the mass of the oil phase part relative to the amount of the oil-in-water emulsified oil / fat composition is 30% to 42%. 油相部が更に乳脂肪を含むことを特徴とする、請求項またはに記載の水中油型乳化油脂組成物。 The oil-in-water emulsified oil / fat composition according to claim 6 or 7 , wherein the oil phase part further contains milk fat. 乳脂肪と請求項1〜のいずれか一項に記載の油脂組成物の質量比が0:100〜70:30の範囲であることを特徴とする、請求項のいずれか一項に記載の水中油型乳化油脂組成物。 The mass ratio of the fat and oil composition according to any one of claims 1 to 5 is in the range of 0: 100 to 70:30, and any one of claims 6 to 8 is characterized. The oil-in-water emulsified oil / fat composition described in 1. 請求項のいずれか一項に記載の水中油型乳化油脂組成物の、ホイップクリーム製造における使用。 Use of the oil-in-water emulsified oil / fat composition according to any one of claims 6 to 9 in the production of whipped cream. 請求項のいずれか一項に記載の水中油型乳化油脂組成物を用いて製造されたホイップクリーム。 It claims 6-9 or whipped cream prepared with an oil-in-water emulsified oil composition according to one of.
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